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Tytuł:
Thermal decomposition of acrylic pressure-sensitive adhesives
Autorzy:
Czech, Z.
Pełech, R.
Zych, K.
Powiązania:
https://bibliotekanauki.pl/articles/778846.pdf
Data publikacji:
2009
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
kopolimery akrylowe
kopolimery metakrylowe
kleje samoprzylepne
piroliza
degradacja termiczna
acrylic and methacrylic copolymers
pressure-sensitive adhesives
pyrolysis
thermal degradation products
analysis and identification
Opis:
The general aim of this article is to review the state of knowledge on pressure-sensitive adhesives (PSAs) and pyrolysis. Recent research data in the field of pyrolysis gas- chromatography (Py-GC) analysis of acrylic PSAs are presented. First, PSA characteristics and applications, pyrolysis (including Py-GC) as an analytical method, and system solutions, are described. The latest scientific achievements in the analysis of thermal degradation products of acrylic PSAs are then presented.
Źródło:
Polish Journal of Chemical Technology; 2009, 11, 4; 7-12
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Acrylic Pressure-Sensitive Adhesives Containing SiO2 Nanoparticles
Autorzy:
Czech, Z.
Kowalczyk, A.
Ortyl, J.
Świderska, J.
Powiązania:
https://bibliotekanauki.pl/articles/779344.pdf
Data publikacji:
2013
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
pressure-sensitive adhesives
SiO2 nanoparticles
tack
peel adhesion
shrinkage
Opis:
The use of acrylic pressure-sensitive adhesives (PSAs) is increasing in a variety of industrial fi elds. They have been applied in the manufacture of mounting tapes, self-adhesive labels, protective fi lms, mas king tapes, splicing tapes, carrier-free tapes, sign and marking fi lms, and in diverse medical products, such as pads or self-adhesive bioelectrodes. In this study, the application of SiO2 nanoparticles in acrylic PSA was investigated. The properties of the newly synthesized and modifi ed PSA were evaluated via the tack, peel adhesion, shear-strength and shrinkage. It has been found that the nanotechnologically-reinforced systems consisting of monodisperse non-agglomerated SiO2 nanoparticles and self-crosslinked acrylic PSAs showed a great enhancement in tack, peel adhesion, shear resistance and shrinkage, without showing the disadvantages known to result from the use of other inorganic additives. In this paper we evaluate the performance of SiO2 nanoparticles with a size of about 30 nm as inorganic fi ller into the synthesized solvent-borne acrylic PSA.
Źródło:
Polish Journal of Chemical Technology; 2013, 15, 1; 12-14
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Pressure Sensitive Mats as Safety Devices in Danger Zones
Autorzy:
Dąbrowski, S.
Brański, Z.
Powiązania:
https://bibliotekanauki.pl/articles/90785.pdf
Data publikacji:
1998
Wydawca:
Centralny Instytut Ochrony Pracy
Tematy:
pressure sensitive mat
safety sensors
danger zone
safety device
czujnik bezpieczeństwa
strefa niebezpieczna
zabezpieczenie
Opis:
Developing prototypes of pressure sensitive mats and testing their practical application were the aims of this study. Two contact plate mats were designed and constructed: rubber-rubber (R) and metal-metal (M). A recipe for rubber mixes and the production technology were prepared. Two laboratory test stands for measuring the actuating force, response time, static pressure resistance, and the durability of the mats were constructed. Computer software was written to control the operation of those test stands. Methods of testing pressure sensitive mats were based on PrDIN 31 006 (Deutsches Institut fur Normung [DIN], 1990) and EN 1760-1 (Comite Europeen de Normalisation [CEN], 1997). Both prototypes of contact plate mats were tested under laboratory and industrial conditions. The test results proved that the design was correct, the setup requirements were fulfilled, and the mats were efficient and reliable in the industrial environment.
Źródło:
International Journal of Occupational Safety and Ergonomics; 1998, 4, 4; 499-519
1080-3548
Pojawia się w:
International Journal of Occupational Safety and Ergonomics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fotoreaktwne poliakrylanowe kleje samoprzylepne
Photoreactive acrylics pressure-sensitive adhesives
Autorzy:
Kowalska, J.
Czech, Z.
Powiązania:
https://bibliotekanauki.pl/articles/171714.pdf
Data publikacji:
2016
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
kleje samoprzylepne
kleje fotoreaktywne
sieciowanie
pressure-sensitive adhesives
photoreactive adhesives
crosslinking
Opis:
Pressure-sensitive adhesives (PSAs) are non-metallic materials used to bond other materials, mainly on their surfaces through adhesion and cohesion. Adhesion and cohesion are phenomena, which may be described thermodynamically and chemically, but actually they cannot be measured precisely. It was shown that the most important bonding processes are bonding by adhesion and bonding with pressure- -sensitive adhesives. The difference between pressure-sensitive adhesives and other adhesives, such as contact adhesives, is in the permanent surface stickiness of the pressure-sensitive adhesives before, or after, the application. The fastest developing polymers departments are: initiating UV photopolymerization and photocrosslinking. Ultraviolet radiation (UV) part of the electromagnetic radiation having a wavelength of 100 to 400 nm, the practical use has an area of 200 to 400 nm. UV radiation does not cause visual impressions results in a strongly fluorescence, photoelectric, photochemical reactions and has a high biological activity. It is particularly important industrial use of UV crosslinking which is used in the manufacture of a wide range of self-adhesives, such as assembly lines, labels, decorative films, protective films, patches and biomedical electrode. Especially important critical point during UV-curing is the balance between adhesion and cohesion of the crosslinked pressure-sensitive adhesive layer. An important element is finding the appropriate beneficial relationship between tack, adhesion and cohesion of the crosslinked pressure-sensitive adhesives that offer assurance to their respective industrial applications. Ultraviolet radiation crosslinking is carried out at room temperature and does not require high temperatures, an important disadvantage pressure-sensitive adhesives crosslinked by heat. Compared to systems crosslinked thermally, the use of UV crosslinking process provides greater speed and effective a crosslinking process, and also does not damage the materials with low thermal resistance.
Źródło:
Wiadomości Chemiczne; 2016, 70, 7-8; 541-551
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electrically conductive acrylic pressure-sensitive adhesives containing carbon black
Autorzy:
Czech, Z.
Pełech, R.
Kowalczyk, A.
Kowalski, A.
Wróbel, R. J.
Powiązania:
https://bibliotekanauki.pl/articles/779803.pdf
Data publikacji:
2011
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
akrylowe kleje samoprzylepne
sadza
materiały przewodzące elektryczność
acrylic pressure-sensitive adhesives
carbon black
electrical conductive materials
Opis:
Acrylic pressure-sensitive adhesives (PSA) are non electrical conductive materials. The electrical conductivity is incorporated into acrylic self-adhesive polymer after adding electrically conductive additives like carbon black, especially nano carbon black. After an addition of electrical conductive carbon black, the main and typical properties of pressure-sensitive adhesives such as tack, peel adhesion and shear strength, are deteriorated. The investigations reveals that the acrylic pressure-sensitive adhesives basis must be synthesised with ameliorated initial performances, like high tack, excellent adhesion and very good cohesion. Currently, the electrical conductive solvent-borne acrylic PSA containing carbon black are not commercially available on the market. They are promising materials which can be applied for the manufacturing of diverse technical high performance self-adhesive products, such as broadest line of special electrically conductive sensitive tapes.
Źródło:
Polish Journal of Chemical Technology; 2011, 13, 4; 77-81
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Sieciowanie samoprzylepnych klejów silikonowych
Crosslinking of silicone pressure-sensitive adhesives
Autorzy:
Antosik, A. K.
Czech, Z.
Powiązania:
https://bibliotekanauki.pl/articles/172358.pdf
Data publikacji:
2016
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
kleje samoprzylepne
polimery
silikonowe kleje samoprzylepne
pressure-sensitive adhesives
polimer
silicone pressure sensitive adhesives
Opis:
Pressure-sensitive adhesives (PSAs) represent a system that actually dates back to the invention of the self-adhesive articles in 1935 when R. Stanton Avery produced the first coating unit using a wooden cigar box with two holes cut in the bottom. PSAs can be defined as a special category of adhesive which in dry form are permanently tacky at room temperature [1–4]. Since 1960s, silicone pressure-sensitive adhesives have found many uses. They are used in industrial plants, as tapes for joining materials with low surface energy, as well as in the sectors of electrical and electronic, medical care, health care and automotive industry. For about 10 years there has been great interest in new uses for the silicone PSA, particularly for medical and industrial belts. The above examples describe a growing range of potential commercial applications of silicone pressure- -sensitive adhesives. Silicone pressure-sensitive adhesives typically consist of large segments of the silane-functional silicone polymers and silicone resins (MQ). It is well known that silicone pressure-sensitive adhesives because of their unique properties are special-purpose products. The combination of the properties of silicones such as high flexibility of connections Si-O-Si, low intermolecular interaction, low surface tension, excellent thermal stability and transparency for UV radiation, excellent electrical properties, high chemical resistance and weather resistance makes silicone adhesives have improved properties compared to other typical polymeric organic adhesives. Due to the low surface tension of silicone adhesives, adhesive is easily spread on the surface of various materials [4–9]. The properties of silicone pressure sensitive adhesives (Si-PSA) crosslinking thermally by organic peroxides (according to a radical mechanism) depend on the type and concentration of crosslinker used. Benzoyl peroxide (BPO) and 2,4-dichlorobenzoyl peroxide (DClBPO) are the most commonly used peroxides the industry. Increasing the content of BPO or DClBPO in a predominantly affects significantly increase the cohesion, while reducing the adhesion of tested adhesives [1, 5, 6]. With the market testing of pressure sensitive adhesives and literature studies clearly show that there were no studies to date on the process of UV-curing silicone pressure sensitive adhesives; and there is no sales sided adhesive tapes, silicone crosslinked by UV radiation.
Źródło:
Wiadomości Chemiczne; 2016, 70, 1-2; 25-32
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adhesion measurement of pressure-sensitive adhesives
Pomiar adhezji klejów samoprzylepnych
Autorzy:
Czech, Z.
Sowa, D.
Kowalczyk, A.
Świderska, J.
Powiązania:
https://bibliotekanauki.pl/articles/271070.pdf
Data publikacji:
2012
Wydawca:
Centralny Ośrodek Badawczo-Rozwojowy Aparatury Badawczej i Dydaktycznej, COBRABiD
Tematy:
adhezja
adhezja przy oddzieraniu
metody pomiaru
kleje samoprzylepne
adhesion
peel adhesion
measurement methods
pressure-sensitive adhesives
Opis:
The term pressure-sensitive adhesive (PSA) has a very precise technical definition and was dealt with extensively in the chemical literature. Pressure-sensitive adhesives (PSA) are nonmetallic materials used to bond other materials, mainly on their surfaces through adhesion and cohesion [1]. Adhesion and cohesion are phenomena, which may be described thermodynamically and chemically, but actually they cannot be measured precisely. It was shown [2] that the most important bonding processes are bonding by adhesion and bonding with pressure-sensitive adhesives. A theoretical treatment of adhesion in terms of intermolecular interaction is not just confined to bond energies; other important factors are the number of contact points of the interacting atoms or molecules, intermolecular distances, the mobility of atomic groups and the structure of neighboring matter. Adhesion on the area of PSA is described by mechanical interlocking, adsorption or thermodynamic theory, electrostatic theory, chemical bonding theory, diffusion theory, adhesive effect of thin liquid films and theory of weak boundary layers. Adhesion of PSA plays the significant role by the application of self-adhesive materials in different industry branches [3].
Pojęcie klej samoprzylepny jest bardzo precyzyjnie zdefiniowane i obszernie opisane w fachowej literaturze chemicznej. Kleje samoprzylepne to niemetaliczne materiały, służące do łączenia powierzchni różnorodnych materiałów poprzez adhezję oraz kohezję [1]. Adhezja oraz kohezja są zjawiskami, które można stosunkowo dokładnie opisać za pomocą termodynamiki oraz znanych reakcji chemicznych, lecz ich pomiar nie pozwala na daleko idącą precyzję. Udowodniono, że najważniejszymi procesami, prowadzącymi do bardzo trwałych połączeń, są połączenia związane z adhezją klejów samoprzylepnych [2]. Teoretyczne podstawy wielu teorii adhezji w połączeniu z oddziaływaniami energetycznymi są bardzo ważne, ale najważniejszymi parametrami zjawiska adhezji są: wielkość sklejanej powierzchni, odległość intermolekularna sklejanych powierzchni, ruchliwość, polarność oraz reaktywność grup funkcyjnych kleju samoprzylepnego. Adhezja klejów samoprzylepnych jest wyjaśniana i opisywana poprzez adhezję mechaniczną, adsorpcję, zależności termodynamiczne, teorię elektrostatyczną, teorię wiązań chemicznych, dyfuzję, teorię cienkich warstw granicznych oraz zwilżalność sklejanych powierzchni przez warstwę polimeru o właściwościach samoprzylepnych [3].
Źródło:
Aparatura Badawcza i Dydaktyczna; 2012, 17, 2; 7-11
2392-1765
Pojawia się w:
Aparatura Badawcza i Dydaktyczna
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
UV-crosslinkable warm-melt pressure-sensitive adhesives based on acrylics
Autorzy:
Czech, Z.
Butwin, A.
Powiązania:
https://bibliotekanauki.pl/articles/778081.pdf
Data publikacji:
2010
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
akryl
klej topliwy
sieciowanie UV
rozcieńczalniki reaktywne
kleje samoprzylepne
ciepło topnienia
acrylics
hot-melts
UV-crosslinking
reactive diluents
pressure-sensitive adhesives
warm-melts
Opis:
The target of this article is to show the preparation of new generation of UV-crosslinkable warm-melt acrylic pressure-sensitive adhesives (PSAs) and the experimental test of their adhesive properties in comparison with typical conventional hot-melts adhesives. New generation of UV-crosslinkable acrylic warm-melts PSAs containing unsaturated photoinitiator, incorporated during polymerization process into polymer chain, and photoreactive diluents added to PSA systems after polymerization allows producing of wide range of selfadhesive materials, such as labels, mounting tapes, masking and splicing tapes, and sign and marking films.
Źródło:
Polish Journal of Chemical Technology; 2010, 12, 4; 58-61
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Water-borne pressure-sensitive adhesives acrylics modified using amorphous silica nanoparticles
Autorzy:
Czech, Z.
Maciejewski, Z.
Kondratowicz-Maciejewska, K.
Powiązania:
https://bibliotekanauki.pl/articles/779506.pdf
Data publikacji:
2016
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
water-borne pressure-sensitive adhesives
acrylics
amorphous silica
tack
peel adhesion
shear strength
Opis:
The application of water-borne pressure-sensitive adhesives (PSA) based on acrylics is increasing in a variety of industrial areas. The have been used for manufacturing of double sided and carrier free mounting tapes, splicing tapes, marking and sign films, self-adhesive labels, packaging tapes, protective films and diverse high quality medical materials. Nano-sized inorganic fillers can modify diverse adhesive and self-adhesive coating properties such as tack, peel adhesion, shear strength at 20°C and 70°C, and removability Amorphous synthetic silica nanoparticles in form of water dispersions: Ludox PX-30 (30 wt.% silica stabilizing with counter ion sodium), Ludox PT-40 (40 wt.% silica stabilizing with counter ion sodium), Ludox PT-40AS (40 wt.% silica stabilizing with counter ion ammonium), and Ludox PW-50 (50 wt.% silica stabilizing with counter ion sodium) (from Grace) in concentrations between 1 and 5wt.% were used for modifying of water-born pressure-sensitive adhesive acrylics: Acronal 052, Acronal CR 516 (both BASF) and Plextol D273 (Synthomer) properties. It has been found in this study that the nano-technologically reinforced system containing of Acronal 052 and amorphous silica Ludox PX-30 showed a great enhancement in tack, peel adhesion and shear strength. In this paper we evaluate the performance of Acronal 052 modified with amorphous silica Ludox PX-30.
Źródło:
Polish Journal of Chemical Technology; 2016, 18, 4; 124-128
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermal degradation of poly(alkyl methacrylates) and polyurethane pressure-sensitive adhesives
Autorzy:
Zych, K.
Pełech, R.
Czech, Z.
Powiązania:
https://bibliotekanauki.pl/articles/778075.pdf
Data publikacji:
2010
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
chromatografia
poli(akrylany alkilowe
poliuretany
rozpuszczalnik polimeryzacji
degradacja termiczna
piroliza
chromatography
poly(alkyl acrylates)
polyurethanes
solvent polymerization
thermal degradation
pyrolysis
Opis:
Gas chromatography, coupled with the temperature controlled pyrolysis technique, can be used as a quick method of identification of polymers such as acrylates, methacrylates and polyurethanes. Polymers based on alkyl methacrylates are widely used as construction materials and coatings. Polyurethanes are widely used as self-adhesives, sealants and electrical products (due to polyurethane's low glass transition temperature Tg). The aim of this work is to investigate which products can be obtained from polymethacrylates and polyurethanes.
Źródło:
Polish Journal of Chemical Technology; 2010, 12, 4; 40-43
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-10 z 45

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