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Wyświetlanie 1-10 z 33
Tytuł:
Experimental and computational study of levofloxacin as corrosion inhibitor for carbon steel in acidic media
Autorzy:
Ikpi, M. E.
Abeng, F. E.
Okonkwo, B. O.
Powiązania:
https://bibliotekanauki.pl/articles/1118353.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Corrosion Inhibition
Polarization
levofloxacin and Adsorption
Opis:
The corrosion inhibition behaviour of levofloxacin was investigated on carbon steel by means of a 2 M HCl solution, using potentiodynamic polarization measurement and Quantum chemical studies. The inhibitive effect of the studied compound was found to increase with increasing concentration and to increase with increasing temperature. The study reveals that levofloxacin is a mixed-type corrosion inhibitor. The adsorption of levofloxacin on carbon steel surface obeys the Langmuir adsorption isotherm and involves physical adsorption mechanisms. Quantum chemical studies corroborate experimental results.
Źródło:
World News of Natural Sciences; 2017, 9; 79-90
2543-5426
Pojawia się w:
World News of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Badania toksyczności inhibitora korozji (Silenalu P)
Investigations on toxicity of a corrosion inhibitor (Silenal P)
Autorzy:
Nowak, K.
Sadowski, S.
Powiązania:
https://bibliotekanauki.pl/articles/872889.pdf
Data publikacji:
1976
Wydawca:
Narodowy Instytut Zdrowia Publicznego. Państwowy Zakład Higieny
Tematy:
zwierzeta doswiadczalne
szczury
szczury Wistar
dodatki do wody
Silenal P
inhibitory korozji
toksycznosc
zmiany biochemiczne
badania doswiadczalne
doswiadczenia na zwierzetach
Źródło:
Roczniki Państwowego Zakładu Higieny; 1976, 27, 5
0035-7715
Pojawia się w:
Roczniki Państwowego Zakładu Higieny
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Green corrosion inhibitor for mild steel in 2 M HCl solution: Flavonoid extract of Erigeron floribundus
Autorzy:
Abeng, Fidelis Ebunta
Idim, Veronica David
Powiązania:
https://bibliotekanauki.pl/articles/1177856.pdf
Data publikacji:
2018
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Erigeron floribundus
Flavonoid
Green inhibitor
corrosion
mild steel
Opis:
The potential of flavonoid extract of Erigeron floribundus as green inhibitor for the corrosion of mild steel in 2 M HCl solution was studied using gasometric method. The results obtained, indicated that the extract is an adsorption inhibitor for the corrosion of mild steel. The inhibition efficiency of the inhibitor was found to increased with increase in concentration of the inhibitor. From the observed trend for the variation of inhibition efficiency with temperature and the range of value obtained from activation energy (16.16-3.02 KJmol-1), enthalpy (13.5-38.84 KJmol-1), entropy (-22.67 to 88.44 KJmol-1) and free energy (-4.23 to -2.61 KJmol-1), a chemical and physical adsorption mechanism is propose for the adsorption of the inhibitor on the mild steel surface. In addition, the adsorption is endothermic, spontaneous and is best described by Langmuir adsorption isotherm.
Źródło:
World Scientific News; 2018, 98; 89-99
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characterization and optimization study of Ficus exasperata extract as corrosion inhibitor for mild steel in seawater
Autorzy:
Oyewole, O.
Aondoakaa, E.
Abayomi, T. S.
Ogundipe, S. J.
Oshin, T. A.
Powiązania:
https://bibliotekanauki.pl/articles/1031411.pdf
Data publikacji:
2021
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Corrosion
Ficus exasperata
inhibition efficiency
optimization
weight loss
Opis:
This study investigated the characterization of Ficus exasperata extract and the optimization of the process variables on inhibition of mild steel in seawater environment. Box Behnken Design was employed to examine the influence of three process variables: Temperature: 25-29 °C; Time: 3 – 6 days; Inhibitor concentration: 1-5 v/v. Phytochemical screening of the extract was done. The physicochemical constituents of the seawater were also determined. The experimental data was statistically determined and Scanning Electron Microscope (SEM) was used to characterize the mild steel. The result of the phytochemical screening of the Ficus exasperata plant extract (FEPE) showed the presence of contain inhibitive constituents: alkaloids, tannins, saponins, flavonoids and glycosides. The highest inhibition efficiency of 86.31% at a temperature of 29 ℃ for 6days at an inhibition concentration of 3v/v was observed from the experimental run. The optimal process levels of time: 5.74 days, temperature: 27.95 ℃ and inhibitor concentration: 2.90v/v, gave 87.52% as its inhibition efficiency. The result of the SEM from the optimal process level validated showed that more passive film was formed which can be attributed to the adsorption of the Ficus exasperata extract. It can be concluded that the Ficus exasperata was a good eco-friendly inhibitor.
Źródło:
World Scientific News; 2021, 151; 78-94
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Optimization of Chrysophyllum albidum leaf extract as corrosion inhibitor for aluminium in 0.5 M H2SO4
Autorzy:
Ezeugo, J. O.
Onukwuli, O. D.
Ikebudu, K. O.
Ezechukwu, V. C.
Nwaeto, L. O.
Powiązania:
https://bibliotekanauki.pl/articles/1075618.pdf
Data publikacji:
2019
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Aluminium
Chrysophyllum albidum
corrosion
electrochemical
optimal
Opis:
Inhibition of Chrysophyllum albidum leave (CAL) extract toward 0.5 M H2SO4 corrosion of aluminium was optimized applying response surface methodology. Corrosion analysis was carried out using weight loss and electrochemical techniques. The results of the various analyses of the leave extracts acted as a good corrosion inhibitor for aluminium in 0.5 M H2SO4. Inhibition efficiency increases as the extract concentration increased. Results of molecular dynamic simulations of the active constituents of the extracts confirmed the adsorption potentials of the ethanol extracts of CAL. Optimal inhibition efficiency of 78.43(%) was obtained at optimum inhibitor concentration of 1.00 g/l, 11.71hs and temperature of 303.60k
Źródło:
World Scientific News; 2019, 125; 32-50
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption behavior of pharmaceutically active dexketoprofen as sustainable corrosion Inhibitor for API X80 carbon steel in acidic medium
Autorzy:
Nkem, B. Iroha
Abosede, O. James
Powiązania:
https://bibliotekanauki.pl/articles/1076601.pdf
Data publikacji:
2019
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Adsorption
Carbon steel
Dexketoprofen
Inhibition
SEM
Opis:
The inhibition of X80 carbon steel corrosion in 1 M HCl solution by dexketoprofen (DKP) was studied using weight loss (WL), electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PDP) and scanning electron microscopy (SEM) techniques. The results indicated that DKP acts by way of adsorption as an effective protective inhibitor in the aggressive acid medium. The inhibition efficiency of DKP increased with concentration but was lower at higher temperature. The results of potentiodynamic polarization showed that DKP molecule behaved as a mixed type inhibitor by reducing both the anodic and the cathodic electrochemical reactions. Dexketoprofen was adsorbed on the X80 steel surface in accordance with Langmuir adsorption isotherm. SEM analyses supported formation of protective film on the X80 steel in the presence of DKP.
Źródło:
World News of Natural Sciences; 2019, 27; 22-37
2543-5426
Pojawia się w:
World News of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Optimization of corrosion inhibition of Picralima nitida leaves extract as green corrosion inhibitor for zinc in 1.0 M HCl
Autorzy:
Ezeugo, J. N. O.
Onukwuli, O. D.
Omotioma, M.
Powiązania:
https://bibliotekanauki.pl/articles/1113582.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Picralima nitida
Zinc
corrosion
inhibitor
optimization
Opis:
Herein, the optimization of inhibitive action of the ethanol extract of oil from Picralima nitida leaves, towards acid corrosion of zinc, was tested using weight loss and thermometry methods. We found that the extract acts as a good corrosion inhibitor for zinc corrosion in 0.1 M HCl solutions. The inhibition action of the extract was discussed in view of Langmuir adsorption isotherm. This revealed that spontaneous processes govern the adsorption of the extract on zinc surface. Herein, the inhibition efficiency (IE) increases in line with corresponding increase in extract concentration. The temperature effect of the corrosion inhibition on the IE was also studied. This indicated that the presence of the extract increases the needed activation energy of the corrosion reaction. Furthermore, in our work, an optimal inhibition efficiency IE (%) of 86.78 was obtained at optimum inhibitor concentration of 1.2 gl-1, optimum temperature and time of 313 k and 8 hrs, respectively. From the calculated thermodynamic parameters, it can be said, then, that Picralima nitida extract provides good protection to zinc against pitting corrosion in chloride ion containing solutions.
Źródło:
World News of Natural Sciences; 2017, 15; 139-161
2543-5426
Pojawia się w:
World News of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Deployment of Antepsin (Sucralfate) as Corrosion Inhibitor of Mild Steel in H2SO4 Medium: Chemical and Electrochemical Studies
Autorzy:
Udeh, B. C.
Onukwuli, O. D.
Omotioma, M.
Powiązania:
https://bibliotekanauki.pl/articles/1839460.pdf
Data publikacji:
2021
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Antepsin
Corrosion
H2SO4
Inhibitor
Mild Steel
Opis:
This study presents the deployment of antepsin (sucralfate) as corrosion inhibitor of mild steel in H2SO4 medium. Chemical (gravimetric) and electrochemical (potentiodynamic polarization and electrochemical impedance spectroscopy) techniques were used in the corrosion control investigation. The antepsin drug was characterized by gas chromatography mass spectrophotometer (GCMS) and Fourier transform infrared (FTIR) spectroscopy. Effects of inhibitor concentration, temperature and time on weight loss, corrosion rate, inhibition efficiency and degree of surface coverage were examined. Thermodynamic and adsorption properties of the corrosion inhibition process were determined. Inhibition efficiency was optimized using central composite design tool of Design Expert software version 12. Potentiodynamic polarization and electrochemical impedance spectroscopy were employed to determine the type and effectiveness of the inhibitor. As a confirmatory test, scanning electron microscopy (SEM) was employed to examine the surface morphology of the mild steel samples. Analysis of the results showed that major constituents of antepsin include tetradecanoate, metronidazole, hexadecanoic acid, methyl ester and 11-octadecenoic acid. The predominant functional groups include; C=O stretch, C-H bend and symmetric and asymmetric =C-O-C. Adsorption of the molecules of antepsin on the surface of the mild steel was spontaneous and occurred in agreement with physical adsorption. A quadratic model adequately described the relationship between inhibition efficiency and corrosion control variables of concentration of the inhibitor, temperature and time. Optimum inhibition efficiency of antepsin was obtained as 86.75%. Chemical and electrochemical results agreed that antepsin is suitable for corrosion control of mild steel in H2SO4 solution. Antepsin acted as mixed-type inhibitor (controlled both cathodic and anodic reactions).
Źródło:
World News of Natural Sciences; 2021, 37; 117-134
2543-5426
Pojawia się w:
World News of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of multifunctional fluids to improve hydrocarbon production
Autorzy:
Knapik, E.
Stopa, J.
Powiązania:
https://bibliotekanauki.pl/articles/299010.pdf
Data publikacji:
2013
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
foam
gas wells dewatering
corrosion inhibitor
synergism
Opis:
In the course of the mature gas fields exploitation there are many technical problems including the corrosion damage, formation of hydrates and water cut. In many cases, an effective solution of these problems is the dosage of appropriately selected chemicals. Commercially available corrosion inhibitors, hydrate inhibitors, demulsifiers and foaming agents are injected in a form of single, multifunctional mixture through one liner which reduces injection costs. The paper presents the results of laboratory tests, which aim was to investigate synergism and antagonism in multifunctional mixture containing different commercially available surfactants, corrosion and hydrate inhibitors. Correlations between final product composition and performances such as liquid unloading efficiency, corrosion protection and pour point were studied. The described approach allows to adapt the tertiary mixture composition (foaming agent + corrosion inhibitor + hydrates inhibitor) to the current production conditions. The polarization behavior of electrodes in brines with and without mixture of additives has been studied by a cyclic voltammetric method. The addition of increasing concentrations of each chemicals causes the reduction in the corrosion current density. The measurements using a modified method of the US Bureau of Mines show synergistic effect of surfactants and corrosion inhibitor on foamabilities. Multifunctional mixtures are stable under storage conditions and not cause any compatibility problems with reservoir fluids.
Źródło:
AGH Drilling, Oil, Gas; 2013, 30, 1; 117-125
2299-4157
2300-7052
Pojawia się w:
AGH Drilling, Oil, Gas
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electrochemical and Quantum Chemical Investigation on Adsorption of Nifedipine as Corrosion Inhibitor at API 5L X-52 Steel / HCl Acid Interface
Autorzy:
Ikpi, M. E.
Abeng, F. E.
Powiązania:
https://bibliotekanauki.pl/articles/356191.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
nifedipine
corrosion inhibition
electrochemical impedance
carbon steel
quantum chemical study
Opis:
Nifedipine, a pyridine derivative was investigated as corrosion inhibitor for API 5L X-52 steel in 2 M HCl solution by potentiodynamic polarization, electrochemical impedance spectroscopy and quantum chemical calculations. Statistical tools were used to compare results of the experimental methods. The results showed that nifedipine is capable of inhibiting the corrosion of API 5L X-52 steel in 2 M HCl solution. Potentiodynamic polarization results reveal that nifedipine functions as a mixed-type inhibitor and presents an inhibition efficiency of about 78% at 500 ppm. Impedance data reveal an increasing charge transfer resistance with increasing inhibitor concentration and also shows comparable inhibition efficiency of about 89-94% at 500 ppm. Thermodynamic parameters imply that nifedipine is adsorbed on the steel surface by a physiochemical process and obeys Langmuir adsorption isotherm. The calculated molecular properties namely the highest occupied molecular orbital energy, lowest unoccupied molecular orbital energy, chemical hardness, energy gap, dipole moment, electronegativity and global nucleophilicity index all show a positive relationship to the observed corrosion inhibition efficiency.
Źródło:
Archives of Metallurgy and Materials; 2020, 65, 1; 125-131
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-10 z 33

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