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Tytuł:
The influence of holmium on catalytic properties of Fe or Cu-modified vermiculites
Autorzy:
Samojeden, Bogdan
Grzybek, Teresa
Kowal, Joanna
Szymaszek, Agnieszka
Jabłońska, Magdalena
Gläser, Roger
Motak, Monika
Powiązania:
https://bibliotekanauki.pl/articles/109844.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
selective catalytic reduction
deNOx
holmium
vermiculite
Opis:
Natural layered clay, vermiculite, was modified and tested as catalyst for the selective catalytic reduction of NOx with ammonia (NH3-SCR). Its modification included the application of the blowing agent (azodicarbonamide), acid treatment and pillaring with Al2O3. Active phase (transition metals: Cu or Fe) was introduced via impregnation. The obtained materials were characterized by N2 sorption (texture), XRD (structure), DR-UV-Vis (oxidation state and aggregation of the active phase), H2-TPR (reducibility of the active phase), in situ DRIFTS (types of adsorbed species due to contact of the sample NH3) and NH3-TPD (type/strength of the acidic sites). The initial modification procedures (treatment with azodicarboamide) resulted in the increase of specific surface area of vermiculite. The introduction of transition metal ions provided a significant amount of acidic sites. The promoting impact of holmium was confirmed by the increased strength of the sites. The highest catalytic activity was exhibited by the sample Fe-containing vermiculite and doped with Ho.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 6; 1484-1495
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structure and Catalytic Properties of Co-Fe Systems in the Reaction of CO₂ Methanation
Autorzy:
Zhludenko, M.
Dyachenko, A.
Bieda, O.
Gaidai, S.
Filonenko, M.
Ischenko, O.
Powiązania:
https://bibliotekanauki.pl/articles/1030910.pdf
Data publikacji:
2018-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
82.30.Hk
82.30.-b
82.20.-w
Opis:
The properties of Fe-Co catalysts in the reaction of CO₂ hydrogenation were investigated. Samples with high cobalt concentrations have shown higher activity. Morphology of the obtained catalysts was observed by using scanning electron microscopy and the elemental composition of surface of the catalysts was determined by scanning electron microscopy-energy dispersive X-ray method. Energy dispersive X-ray analysis showed that metal distribution is not homogeneous with various metal ratio in selected points of the surface for the Fe-rich less active samples, whereas for the Co-rich samples with higher activity metals are homogeneously distributed, which is possibly connected to the formation of single phase.
Źródło:
Acta Physica Polonica A; 2018, 133, 4; 1084-1087
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Catalytic Properties of Iron Oxides in the Reaction of Low-Temperature Ozone Decomposition
Autorzy:
Rakitskaya, T.
Truba, A.
Ennan, A.
Baumer, V.
Volkova, V.
Powiązania:
https://bibliotekanauki.pl/articles/1030914.pdf
Data publikacji:
2018-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
iron oxides
synthesis
thermal treatment
ozone decomposition
catalytic activity
Opis:
Two sets of iron oxide samples were synthesized applying different iron(III) precursors (FeCl₃ and Fe₂(SO₄)₃) and calcination temperature (200, 300, and 500°C). The samples were characterized by powder X-ray analysis and the Fourier transform infrared spectroscopy. Depending on the synthesis conditions, samples of iron oxides with different phase composition were obtained: polyphase (α -Fe₂O₃, γ -Fe₂O₃, Fe₃O₄, and α -FeO(OH)) and monophase (γ -Fe₂O₃ or α -Fe₂O₃) ones. For the samples of homogeneous composition, it has been found that the activity of γ -Fe₂O₃ in the reaction of ozone decomposition at ozone concentration in gaseous phase of 1 mg/m³ is much higher than the activity of α -Fe₂O₃.
Źródło:
Acta Physica Polonica A; 2018, 133, 4; 1079-1083
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Catalytic Properties of Ni-Fe Systems in the Reaction of CO₂ Methanation at Atmospheric Pressure
Autorzy:
Meshkini-Far, R.
Dyachenko, A.
Gaidai, S.
Bieda, O.
Filonenko, M.
Ischenko, O.
Powiązania:
https://bibliotekanauki.pl/articles/1030898.pdf
Data publikacji:
2018-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
82.30.Hk
82.30.-b
82.20.-w
Opis:
Catalytic activity, phase composition, and morphology of binary Ni-Fe metallic systems in CO₂ hydrogenation were investigated. High methane yield was detected in the region of high Ni content, except the sample with 75% of Ni which has shown a sharp drop in activity. By means of scanning electron microscopy-energy dispersive X-ray and X-ray diffraction methods the differences in surface structuring of active (Ni₈₀Fe₂₀) and inactive (Ni₇₅Fe₂₅) catalysts were revealed. High methane yield for the former might be explained by defective porous superficial layer of catalyst grains, whereby for the latter the specific surface is diminished due to sintering.
Źródło:
Acta Physica Polonica A; 2018, 133, 4; 1088-1090
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Amino acid substitutions of His296 alter the catalytic properties of Zymomonas mobilis 10232 levansucrase
Autorzy:
Li, Shu
Chen, Ming
Li, Gang
Yan, Yong
Yu, Hai
Zhan, Yu
Peng, Zi
Wang, Jin
Lin, Min
Powiązania:
https://bibliotekanauki.pl/articles/1040841.pdf
Data publikacji:
2008
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
Zymomonas mobilis
His296
levansucrase
levan
transfructosylation activity
hydrolysis activity
Opis:
His296 of Zymomonas mobilis levansucrase (EC 2.4.1.10) is crucial for the catalysis of the transfructosylation reaction. The three-dimensional structures of levansucrases revealed the His296 is involved in the substrate recognition and binding. In this study, nine mutants were created by site-directed mutagenesis, in which His296 was substituted with amino acids of different polarity, charge and length. The substitutions of His296 with Arg or Trp retained partial hydrolysis and transfructosylation activities. The positively charged Lys substitution resulted in a 2.5-fold increase of sucrose hydrolysis. Substitutions with short (Cys or Ser), negatively charged (Glu) or polar (Tyr) amino acids virtually abolished both the activities. Analysis of transfructosylation products indicated that the mutants synthesized different oligosaccharides, suggesting that amino acid substitutions of His296 strongly affected both the enzyme activity and transfructosylation products.
Źródło:
Acta Biochimica Polonica; 2008, 55, 1; 201-206
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Conserved Cys residue influences catalytic properties of potato endo-(1→3)-β-glucanase GLUB20-2
Autorzy:
Witek, Agnieszka
Witek, Kamil
Hennig, Jacek
Powiązania:
https://bibliotekanauki.pl/articles/1040688.pdf
Data publikacji:
2008
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
GLUB20-2
inhibition
endo-(1→3)-β-glucanase
Solanum tuberosum
structure-function relationships
substrate specificity
Opis:
The synthesis and degradation of (1→3)-β-glycosidic bonds between glucose moieties are essential metabolic processes in plant cell architecture and function. We have found that a unique, conserved cysteine residue, positioned outside the catalytic centre of potato endo-(1→3)-β-glucanase - product of the gluB20-2 gene, participates in determining the substrate specificity of the enzyme. The same residue is largely responsible for endo-(1→3)-β-glucanase inhibition by mercury ions. Our results confirm that the spatial adjustment between an enzyme and its substrate is one of the essential factors contributing to the specificity and accuracy of enzymatic reactions.
Źródło:
Acta Biochimica Polonica; 2008, 55, 4; 791-797
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preparation, Characterization and Catalytic Properties of SBA-15-SO₃H Supported Tungstophosphoric Acid for Esterification Reaction
Autorzy:
Erdem, B.
Erdem, S.
Çıtak, A.
Yavru, C.
Öksüzoğlu, R.
Powiązania:
https://bibliotekanauki.pl/articles/1031202.pdf
Data publikacji:
2017-09
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.43.Gt
82.65.+r
Opis:
SBA-15-SO₃H supported tungstophosphoric acid (TPA, H₃PW₁₂O₄₀) mesoporous materials were synthesized by impregnation of TPA into the hydrothermally synthesized SBA-15-SO₃H and the catalytic performances were compared for the esterification reaction. The physical and chemical properties of the catalysts were characterized by XRD, SEM/EDX, FT-IR and N₂ adsorption/desorption techniques. The characterization results show that TPA/SBA-15-SO₃H retained the typical mesoporous structure of SBA-15-SO₃H. The experimental results indicated that TPA/SBA-15-SO₃H is a more efficient catalyst than SBA-15-SO₃H for the esterification reaction. The higher activity of TPA/SBA-15-SO₃H compared with that of SBA-15-SO₃H was consistent with the material having the low pKa value, confirming that the esterification rate was mostly dependent on the acid strength of the additional functional groups of solid acid catalyst. Accordingly, the reason for the catalytic activity difference was simply explicated by the effect of TPA, having low pKa value, affecting the pore structure and the total acidity.
Źródło:
Acta Physica Polonica A; 2017, 132, 3; 1041-1044
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis of the cross-linked humic acid supporting palladium catalyst and its catalytic properties for Heck reaction
Autorzy:
Xu, Q.
Shi, W.
Cui, Y.
Powiązania:
https://bibliotekanauki.pl/articles/779729.pdf
Data publikacji:
2012
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
kwasy humusowe
epichlorohydryna
reakcja Hecka
humic acid
epichlorohydrin
supporting palladium catalyst
Heck reaction
Opis:
Cross-linked humic acid supporting palladium (CL-HA-Pd) catalyst was prepared readily and characterized by infrared analysis (IR) and thermogravimetric analysis (TG). The catalyst could catalyze the Heck reaction of aryl halide or substituted aryl halide with vinyl compounds in N2 atmosphere; the yields were above 95%. The catalyst could be recovered and reused 7 times with the Heck reaction of iodobenzene with acrylic acid, and the yield was above 75.6%. The results showed that the catalyst had high catalytic activity even at low temperature of 62°C or with a small amount of the catalyst.
Źródło:
Polish Journal of Chemical Technology; 2012, 14, 2; 75-79
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Wplyw modyfikacji pozywki na biokatalityczne wlasciwosci drozdzy
Effect of medium modification on bio-catalytic properties of yeasts
Autorzy:
Krzyczkowska, J
Stolarzewicz, I
Bellok, D
Bellok, M
Bialecka-Florjanczyk, E
Powiązania:
https://bibliotekanauki.pl/articles/827844.pdf
Data publikacji:
2008
Wydawca:
Polskie Towarzystwo Technologów Żywności
Tematy:
przemysl spozywczy
procesy biotechnologiczne
drozdze
Rhodotorula glutinis
Pichia jadinii
Saccharomyces cerevisiae
pozywki mikrobiologiczne
wlasciwosci biokatalityczne
Opis:
Drożdże stanowią bogate źródło enzymów wykorzystywanych w procesach biotechnologicznych przemysłu spożywczego. Działanie enzymów polega na katalizowaniu reakcji chemicznych nie tylko w organizmach żywych, ale także i poza nimi, zatem drożdże mogą również spełniać ważną rolę w syntezach chemicznych. Z punktu widzenia przetwarzania produktów spożywczych szczególnie istotne są reakcje estryfikacji i hydrolizy estrów. Celem pracy było określenie wpływu składu pożywki na aktywność katalityczną trzech gatunków drożdży Rhodotorula glutinis, Pichia jadinii i Saccharomyces cerevisiae, na przykładzie reakcji modelowej, jaką jest hydroliza laurynianu fenylu. Badane gatunki drożdży, celem porównania, hodowano w standardowych warunkach (podłoże YPD) oraz na pożywkach wzbogacanych w różne źródła azotu oraz węgla. Najskuteczniejsze w hydrolizie estru, przy udziale w pożywce hodowlanej oliwy z oliwek, były drożdże z gatunku Pichia jadinii, (ok. 50 % przereagowania laurynianu fenylu po 10 h, w porównaniu z 8 % przereagowaniem przy standardowej pożywce YPD), natomiast gatunek Rhodotorula glutinis najskuteczniej hydrolizował badany ester podczas hodowli w obecności mocznika (powyżej 50 % po 5 h w porównaniu z 8 % przy zastosowaniu YPD). W przypadku Saccharomyces cerevisiae, hodowanego w obecności oliwy z oliwek, przereagowanie rzędu 50 % osiągnięto dopiero po 40 h. Można zatem wnioskować, że właściwe modyfikacje pożywki pozwalają na stymulowanie lipolitycznych zdolności poszczególnych gatunków drożdży.
Yeasts constitute a rich source of enzymes used in biotechnological processes in food industry. The activity of enzymes consists in catalyzing chemical reactions not only in live organisms, but, also, outside those live organisms, thus, yeasts can also fulfil an important role in chemical syntheses. From the point of view of food products processing, the reactions of esterification and hydrolysis of esters are particularly essential. The objective of this paper was to determine the impact of medium composition on the catalytic activity of three kinds of yeasts: Pichia jadinii, Rhodotorula glutinis, and Saccharomyce cerevisiae exemplified by a model reaction of hydrolysis of phenyl laurate. The yeasts studied were cultured under the typical conditions (YDP medium) and on media enriched by various sources of nitrogen and carbon. The Pichia jadinii yeasts proved to be most efficient in the hydrolysis of esters with a medium containing olive oil (about 50 % of the conversion of phenyl laurate after 10 h compared to 8 % of conversion using a standard YPD medium). As for Rhodotorula glutinis, the ester studied hydrolyzed most efficiently while being culture with the participation of urea (more than 50 % after the 5 h compared with 8 % with the YPD medium applied). In the case of Saccharomyce cerevisiae, cultured in the presence of olive oil, a level of 50% of the conversion was reached as late as after 40 h. Therefore, it can be concluded that proper modifications of medium allow for the stimulation of lypolytic activity of individual kinds of yeasts.
Źródło:
Żywność Nauka Technologia Jakość; 2008, 15, 5; 299-306
1425-6959
Pojawia się w:
Żywność Nauka Technologia Jakość
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Oktakarboksyftalocyjaniny – związki o interesujących właściwościach spektralnych, fotochemicznych i katalitycznych
Octacarboxyphthalocyanines – compounds of interesting spectral, photochemical and catalytic properties
Autorzy:
Nackiewicz, J.
Suchan, J.
Kliber, M.
Powiązania:
https://bibliotekanauki.pl/articles/142362.pdf
Data publikacji:
2014
Wydawca:
Stowarzyszenie Inżynierów i Techników Przemysłu Chemicznego. Zakład Wydawniczy CHEMPRESS-SITPChem
Tematy:
oktakarboksyftalocyjaniny
synteza
asocjacja
widma UV-Vis
kataliza
octacarboxyphthalocyanines
synthesis
association
UV-Vis spectra
catalysis
Opis:
Przedstawiono metody syntezy oktakarboksyftalocyjanin, MPcOC. Omówiono ich widma absorpcyjne UV-Vis, asocjację oraz wybrane właściwości fotochemiczne i katalityczne. Opisano wpływ czwartorzędowych soli amoniowych na widma UV-Vis i asocjację CuPcOC, fluorescencję roztworów wodnych ZnPcOC oraz aktywność katalityczną CoPcOC w homogenicznym aerobowym utlenianiu L-cysteiny.
The article presents synthesis methods of octacarboxyphthalocyanines, MPcOC. Their UV-Vis absorption spectra, their association and selected photochemical and catalytic properties are also discussed. Moreover, the article describes the impact of quaternary ammonium salts on UV-Vis spectra and CuPcOC association, fluorescence of aqueous solutions of ZnPcOC and catalytic activity of CoPcOC in homogeneous aerobic oxidation of L-cysteine.
Źródło:
Chemik; 2014, 68, 4; 369-376
0009-2886
Pojawia się w:
Chemik
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Ti-MWW catalyst - its characteristic and catalytic properties in the epoxidation of allyl alcohol by hydrogen peroxide
Autorzy:
Wróblewska, A.
Fajdek, A.
Milchert, E.
Grzmil, B.
Powiązania:
https://bibliotekanauki.pl/articles/778365.pdf
Data publikacji:
2010
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
Ti-MWW
katalizatory tytanowo-silikalitowe
glicydol
epoksydacja w fazie ciekłej
nadtlenek wodoru
titanium-silicalites
glycidol
liquid phase epoxidation
hydrogen peroxide
Opis:
Ti-MWW, one of the latest titanium-silicalite catalysts, has been prepared by direct hydrothermal synthesis using hexamethyleneimine as a structure-directing agent. The characteristic of the catalyst was performed by means of the following methods: XRD, SEM, IR, UV-vis and X'Ray microanalysis. The catalytic properties of Ti-MWW have been compared with those of the conventional titanium-silicalites TS-1 and TS-2 in the epoxidation of allyl alcohol with hydrogen peroxide. The process has been described by the following main functions: the selectivity of the transformation to glycidol in relation to allyl alcohol consumed, the conversions of the substrates (allyl alcohol and hydrogen peroxide) and the selectivity of the transformation to organic compounds in relation to hydrogen peroxide consumed.
Źródło:
Polish Journal of Chemical Technology; 2010, 12, 1; 29-34
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, characterization and catalytic properties of SAPO-11 molecular sieve synthesized in hydrothermal media using di-isopropylamine as template
Autorzy:
Chellappa, T.
Costa, M. J. F.
Nascimento, W. A.
Ferreira De Lima, L.
Bassan, I. A.
Tavares, M.
Fernandes, V. J.
Menezes, A.
Guilherme Meira, L.
Telesforo Nóbrega De Medeiros, J.
Maribondo Do Nascimento, R.
Powiązania:
https://bibliotekanauki.pl/articles/200372.pdf
Data publikacji:
2014
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
microporous materials
SAPO-11
characterization
catalytic activity
molecular sieves
Opis:
A microporous SAPO-11 Molecular sieve was successfully synthesized by the hydrothermal method, using a single agent, as an organic template: di-isopropylamine (DIPA). The obtained solid was calcined at 550◦C for three hours, after which the flow of nitrogen was exchanged for that of synthetic air and submitted for another ten hours of calcination, so as to remove the single agent: di-isopropylamine, which after the removal of the template could be observed by the high crystallization of the sample. Furthermore, the molecular sieve was characterized by XRD, SEM, TG-DTG and N2 adsorption desorption (BET analysis). The obtained catalyst proved to have a high potential catalytic activity and selectivity, through the obtained characterization results, exhibiting good hydrothermal stability. The catalytic performance of SAPO-11 was tested by the deactivation/regenerability of the coked sample, furthered by cracking of n-hexane reaction and high olefins selectivity was obtained.
Źródło:
Bulletin of the Polish Academy of Sciences. Technical Sciences; 2014, 62, 3; 481-488
0239-7528
Pojawia się w:
Bulletin of the Polish Academy of Sciences. Technical Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The comparative analysis of catalytic properties of Group 11 elements in NOx reduction by hydrocarbons in the presence of oxygen
Autorzy:
Kruczyński, Stanisław W.
Orliński, Piotr
Ślęzak, Marcin
Powiązania:
https://bibliotekanauki.pl/articles/2087018.pdf
Data publikacji:
2022
Wydawca:
Polska Akademia Nauk. Polskie Naukowo-Techniczne Towarzystwo Eksploatacyjne PAN
Tematy:
diesel engine
NOx reduction
conversion testing
group 11 elements
Opis:
NOx emission reduction in diesel engines can be achieved by using catalytic reactors reducing nitrogen oxides, including NH3-SCR and possibly also HC-SCR reactors. Reactors using ammonia achieve large conversion rates but cause a lot of operational problems. For this reason, the interest in reactors using hydrocarbons and their derivatives to reduce NOx has increased. Such reactors are the ones using metals from Group 11 (coinage metals) such as Cu, Ag and Au placed on an Al2O3-SiO2 carrier as active materials. The article characterizes the porosity and acidity of the carrier surface. Conversion of NO2, NO and propene as well as the formation of CO and N2O depending on the temperature at constant dosing of propene on a carrier covered with Cu, Ag and Au with a metal content of 4 g/dm3 were evaluated. The results of the tests showed that the tested Group 11 elements can be the basis for further experiments related to the development of this exhaust fumes cleaning technology for diesel engines.
Źródło:
Eksploatacja i Niezawodność; 2022, 24, 2; 170--176
1507-2711
Pojawia się w:
Eksploatacja i Niezawodność
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structure Characterization and Catalytic Properties of Cr$\text{}_{2}$O$\text{}_{3}$ Doped with MgO Supported on MgF$\text{}_{2}$
Autorzy:
Goslar, J.
Wojciechowska, M.
Zieliński, M.
Tomska-Foralewska, I.
Przystajko, W.
Powiązania:
https://bibliotekanauki.pl/articles/2043607.pdf
Data publikacji:
2005-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.Fc
68.43.Fg
82.65.+r
Opis:
A characterization of double oxide systems containing Cr$\text{}_{2}$O$\text{}_{3}$ doped with MgO and supported on MgF$\text{}_{2}$ was carried out. The catalysts were prepared by impregnation and co-impregnation methods and characterized by the Brunauer-Emmett-Teller method, EPR, and temperature programmed reduction. The results proved the interactions between supported oxides and the presence of spinel-like phase after treatment at 400ºC. Magnesium oxide clearly influences the catalytic activity as well as selectivity of chromium catalysts supported on MgF$\text{}_{2}$. The MgO-Cr$\text{}_{2}$O$\text{}_{3}$/MgF$\text{}_{2}$ systems were active and selective in the reaction of CO oxidation at the room temperature and in the dehydrogenation of cyclohexene.
Źródło:
Acta Physica Polonica A; 2005, 108, 2; 323-330
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Photosensitization of TiO2 P25 with CdS Nanoparticles for Photocatalytic Applications
Autorzy:
Trenczek-Zając, A.
Banaś, J.
Świerczek, K.
Zazakowny, K.
Radecka, M.
Powiązania:
https://bibliotekanauki.pl/articles/352507.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
semiconductors
X-ray diffraction
transmission electron microscopy TEM
catalytic properties
optical properties
Opis:
A TiO2/CdS coupled system was prepared by mixing the TiO2 P25 with CdS synthesized by means of the precipitation method. It was found that the specific surface area (SSA) of both components is extremely different and equals 49.5 for TiO2 and 145.4 m2·g-1 for CdS. The comparison of particle size distribution and images obtained by means of transmission electron microscopy (TEM) showed agglomeration of nanocomposites. X-ray diffraction (XRD) patterns suggest that CdS crystallizes in a mixture of cubic and hexagonal phases. Optical reflectance spectra revealed a gradual shift of the fundamental absorption edge towards longer wavelengths with increasing CdS molar fraction, which indicates an extension of the absorption spectrum of TiO2. The photocatalytic activity in UV and UV-vis was tested with the use of methyl orange (MO). The Langmuir–Hinshelwood model described well the photodegradation process of MO. The results showed that the photocatalytic behaviour of the TiO2/CdS mixture is significantly better than that of pure nanopowders.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2A; 841-849
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 30

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