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Tytuł:
Zastosowanie żywic epoksydowych jako warstw pro-adhezyjnych w wytwarzaniu kompozytów polimer-metal metodą wtryskiwania
The application of epoxy resins as the pro-adhesion inter-layers in the manufacturing of the polymer-metal composites during injection moulding process
Autorzy:
Trzaska, O.
Dmitruk, A.
Kornacki, Ł.
Wróblewski, R. M.
Kaczmar, J. W.
Powiązania:
https://bibliotekanauki.pl/articles/278260.pdf
Data publikacji:
2014
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Inżynierii Materiałów Polimerowych i Barwników
Tematy:
kompozyt hybrydowy polimer-metal
żywica epoksydowa
adhezja
wtryskiwanie
polymer-metal hybrid composite
epoxy resin
adhesion
injection moulding
Opis:
W artykule przedstawiono zagadnienia związane z kompozytami hybrydowymi polimer-metal wytwarzanymi metodą wtryskiwania. Przedstawiono wpływ przygotowania powierzchni ze stali DC01 na adhezję tworzywa sztucznego do metalu. Najlepsze wyniki uzyskano dla powierzchni stalowych poddanych obróbce fizyczno-chemicznej (obróbka strumieniowo-ścierna przy pomocy cząstek elektrokorundu F 80 oraz trawienie w 15% roztworze kwasu fosforowego (V) - H3PO4). Celem zwiększenia adhezji specyficznej na granicy faz polimer-metal zaproponowano zastosowanie żywic epoksydowych jako warstw pro-adhezyjnych. Najlepsze wyniki uzyskano dla kompozycji epoksydowych poddanych modyfikacji fizycznej (dodatek napełniacza w postaci elektrokorundu szlachetnego białego F 1200 w proporcji 1:1 względem masy żywicy epoksydowej).
The present article is focused on polymer-metal hybrid composites manufactured during injection moulding process. The influence of DC01 steel surface preparation on the polymer to metal adhesion process is discussed. The best results were obtained for the steel surfaces prepared by physical and chemical methods (the sand blasting with the use of the F 80 alumina particles and etching in the 15% solution of phosphoric acid). The epoxy resins were proposed as the pro-adhesion inter-layers to increase the strength of the specific adhesion at the polymer-metal interface. The best results were obtained for the epoxy compositions which had been modified with use physical methods (by adding the F 1200 alumina filler in proportion 1:1 to mass epoxy resin).
Źródło:
Przetwórstwo Tworzyw; 2014, [R.] 20, nr 4 (160), 4 (160); 349-355
1429-0472
Pojawia się w:
Przetwórstwo Tworzyw
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analiza termograwimetryczna w badaniu paliw
Thermogravimetric analysis in the research of fuels
Autorzy:
Wróblewski, R.
Klukowski, M.
Powiązania:
https://bibliotekanauki.pl/articles/378143.pdf
Data publikacji:
2016
Wydawca:
Politechnika Poznańska. Wydawnictwo Politechniki Poznańskiej
Tematy:
termowaga
termograwimetria
paliwa
biomasa
piroliza
Opis:
W artykule przedstawiono charakterystykę wybranych paliw kopalnych: węgla kamiennego i brunatnego oraz wybranych rodzajów biomasy: pelletu drzewnego i ziarna owsa. Omówiono również metodę analizy termograwimetryczej oraz opisano termowagę znajdującą się w Laboratorium Paliw i Przetwarzania Energii Instytutu Elektroenergetyki Politechniki Poznańskiej. W dalszej części pracy przedstawiono wyniki analizy termograwimetrycznej dla wyżej wymienionych typów paliw w postaci krzywych termograwimetrycznych. Analiza ta ma na celu określenie poziomu temperatury procesu pirolizy oraz stopnia konwersji paliw stałych w paliwo gazowe. Badania te są prowadzone pod kontem możliwości poprawy efektywności energetycznej układów wytwarzania energii elektrycznej i ciepła zintegrowanych ze zgazowaniem biomasy.
In the article the characteristics of different types of solid fuels like black coal, brown coal and different types of biomass like wood pellets and oats grain were shown. Moreover, the method of thermogravimetric analysis and thermobalance located at Laboratory of Fuels and Energy Conversion Institute of Electrical Power Engineering Poznan University of Technology were described. In the next part of the thesis results of thermogravimetric analysis of the above types of fuels were presented. This analysis is to determine the level of temperature of pyrolysis process and the degree of conversion of solid fuels in to gas fuel. This research is conducted account of the possibility of improving the energy efficiency of systems of electricity and heat with integrated biomass gasification.
Źródło:
Poznan University of Technology Academic Journals. Electrical Engineering; 2016, 88; 289-300
1897-0737
Pojawia się w:
Poznan University of Technology Academic Journals. Electrical Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Magnetocaloric Effect in Ni-Cu-Mn-Gd-Ga Alloy. XI Symposium of Magnetic Measurements
Autorzy:
Sielicki, K.
Wróblewski, R.
Leonowicz, M.
Powiązania:
https://bibliotekanauki.pl/articles/1402340.pdf
Data publikacji:
2015-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.30.Sg
Opis:
The magnetocaloric effect of the Ni-Cu-Mn-Gd-Ga polycrystalline alloy was investigated. The nominal composition of the alloy was $Ni_{50}Cu_{6.25}Mn_{16.75}Ga_{25}Gd_{2}$ at.%. The X-ray diffraction studies revealed presence of two phases at room temperature. This was confirmed by magnetic measurements conducted in low field of 4 kA/m (50 Oe), which showed two Curie transition temperatures, one in vicinity and the other one well above the room temperature. The analysis of isothermal magnetic curves allowed the calculation of magnetic entropy change ($\Delta S_{M}$). Although the peak value of $| \Delta S_{M}|$ is relatively low, ≈1.1 J/(kg K), it is very broad. The adiabatic temperature change (ΔT) measured near room temperature is ≈0.49 K. Such result is irrespective of the magnetizing-demagnetizing cycle frequency which varied from 2/min to 10/min.
Źródło:
Acta Physica Polonica A; 2015, 128, 1; 120-122
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A Comparative Studies of Magnetocaloric Effect in Ni-Mn-Cu-Ga and Ni-Mn-Pb-Ga Alloys
Autorzy:
Sielicki, K.
Wróblewski, R.
Leonowicz, M.
Powiązania:
https://bibliotekanauki.pl/articles/1388040.pdf
Data publikacji:
2015-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.30.Sg
Opis:
Effect of Pb substitution for Cu on magnetocaloric properties of $Ni₂Mn_{1-x}Cu_xGa$ (x = 0.25, 0.27, 0.29) alloy was investigated experimentally. The magnetic measurements of Ni-Mn-Pb-Ga alloys conducted at low field of 4kA/m (50 Oe) showed that their Curie points are above the room temperature (RT). The analysis of isothermal magnetic curves allowed the estimation of magnetic entropy change $(ΔS_{M})$. The highest calculated value of $|ΔS_{M}|,$ ≈ 12 J/(kgK) and ≈ 1.8 J/(kgK), was registered for alloys containing 6.25 at.% of Cu and 6.75 at.% of Pb, respectively. The adiabatic temperature changes (ΔT) measured near RT are ≈ 0.4 K.
Źródło:
Acta Physica Polonica A; 2015, 127, 2; 644-646
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Z pomocą walczącej Warszawie
Autorzy:
Ruman, Tadeusz.
Powiązania:
Biuletyn Instytutu Pamięci Narodowej 2004, nr 8/9, s. 109-118
Współwytwórcy:
Wróblewski, Jarosław (1971- ). Opracowanie
Ruman, Jan M. Opracowanie
Data publikacji:
2004
Tematy:
Powstanie 1944 r. warszawskie zrzuty lotnicze pamiętniki
Zrzuty lotnicze Warszawa 1944 r. pamiętniki
Pamiętniki żołnierskie polskie 1939-1945 r.
Opis:
Fot.
Dostawca treści:
Bibliografia CBW
Artykuł
Tytuł:
Enancjoselektywna enzymatyczna desymetryzacja katalizowana oksydoreduktazami. Reakcje redukcji. Część 2
Enantioselective enzymatic desymmetrization catalyzed by oxidoreductases. Reduction reactions. Part 2
Autorzy:
Kołodziejska, R.
Karczmarska-Wódzka, A.
Tafelska-Kaczmarek, A.
Studzińska, R.
Wróblewski, M.
Augustyńska, B.
Powiązania:
https://bibliotekanauki.pl/articles/171910.pdf
Data publikacji:
2014
Wydawca:
Polskie Towarzystwo Chemiczne
Opis:
Biotransformation reactions of many organic compounds under the influence of enzymes take place with the high selectivity, rarely achieved by other methods. Ketoesters represent an extensive group of selectively bioreduced compounds. Chiral hydroxyesters and, subsequently, hydroxyacids are valuable intermediates in the syntheses of various biologically active compounds. Acyclic α- and β-ketoesters are transformed to the corresponding (R)- and (S)-hydroxyesters by using a specific dehydrogenases. The whole-cells enzymes, e.g. baker’s yeast, may exhibit a different catalytic activity depending on the substrate structure. Baker’s yeast enzymes selectively reduce the cyclic β-ketoesters providing mainly anti diastereomers due to the lack of rotation around the single α,β carbon-carbon bond. The enzymatic reduction of the esters, cyclopentanone, and cyclohexanone derivatives gave the optically active anti-alcohol enantiomers. The reductive EED of prochiral α-ketoesters, as well as β-ketoesters is an interesting transformation in organic chemistry due to the importance of the resulting chiral α-hydroxy acids and their derivatives used as building blocks. Baker’s yeast-catalyzed reduction of alkyl esters derived from pyruvate and benzoylformate allows the preparation of the (R)-alcohols. Polyketones can also be subjected to the reductive EED to give different compounds bearing the quaternary stereogenic centers which are broadly applied in asymmetric synthesis. In asymmetric synthesis, similarly to carbon-oxygen double bonds, carbon-carbon double bonds of prochiral alkanes can be reduced to obtain the optically active saturated compounds. The reduction of alkenes is catalyzed by both, the whole cells (microorganisms, plant cells) as well as isolated enzymes belonging to the oxydoreductases, so-called ene-reductases. The whole-cell catalysts are suitable, most frequently, for the preparative scale syntheses, but they are less chemoselective in comparison to the isolated reductases. In the case of polyfunctionalized alkenes, microorganisms can cause the additional side reaction reducing the desired product yield.
Źródło:
Wiadomości Chemiczne; 2014, 68, 11-12; 1009-1030
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Magnetic Entropy Changes in Pb Doped Ni-Mn-Cu-Ga Alloys
Autorzy:
Sielicki, K.
Zygmuntowicz, J.
Wróblewski, R.
Leonowicz, M.
Powiązania:
https://bibliotekanauki.pl/articles/354050.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
magnetocaloric effect
magnetic entropy change
Curie temperature
Heusler alloys
Opis:
Effect of Pb addition on magnetocaloric properties of Ni50 Mn18,75 Cu6,25-aPbaGa25 (a = 1, 2, 3, 4, 5) alloys was investigated experimentally. The magnetic measurements conducted at low field of 4 kA/m showed that addition of Pb led to separation of the both transformation temperatures and significantly shifted the structural transition effect towards lower temperatures as well as increased the Curie temperature. The analysis of isothermal magnetic curves allowed for the calculation of magnetic entropychange (ΔSM). Although the peak values of |ΔSM| for alloys containing 4 and 5 at.% Pb, ~3 J/(kg*K) and ~1.5 J/(kg*K) respectively, are low they stretch over the structural transformation and Curie temperature, and are at least 30 K wide at half maximum height.
Źródło:
Archives of Metallurgy and Materials; 2020, 65, 2; 823-825
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Prolina : pospolity aminokwas wyjątkowy katalizator. Część IV, Reakcja Michaela
Proline as a common amino acid and an exceptional catalyst. Part IV, Michael reaction
Autorzy:
Karczmarska-Wódzka, A.
Studzińska, R.
Kołodziejska, R.
Wróblewski, M.
Dramiński, M.
Powiązania:
https://bibliotekanauki.pl/articles/171840.pdf
Data publikacji:
2014
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
prolina
reakcja Michaela
synteza asymetryczna
proline
Michael reaction
asymmetric synthesis
Opis:
In recent years there has been a dynamic development of asymmetric synthesis. Groups of researchers, particularly the one led by Benjamin List and Carlos Barbas, carried out a number of reactions and showed the effectiveness of the use of small organic molecules such as proline as catalysts. Michael addition catalyzed with proline is a particularly interesting reaction because it can be carried out in two aminocatalytic pathways. The analysis of Michael reaction reveals potential for both forms of aminocatalysis: enamine and iminium catalysis (Scheme 1) [1–14]. Presumably Michael reaction proceeds mainly according to enamine mechanism. The use of proline in Michael reaction with imine activated acceptor is slightly effective. So far the researches have shown that the modification of proline molecule or addition of other catalyst is necessary for condensation to appear. Enamine catalysis concerns the activation of carbonyl compound in situ being a donor. There is no need for enolase anion to be created earlier [2, 15–17]. When, as a result of the reaction of a,b-unsaturated carbonyl compound with proline, Michael acceptor activation appears it means that it is enamine mechanism reaction (Scheme 1) [2, 24]. One of the first examples of direct Michael reaction proceeding through enamine transition state is the reaction of cyclopentanone with nitrostyrene (Scheme 6) [20–23]. Other examples of Michael addition of ketone with nitro olefin catalysed by proline are shown in table 2 and 3 [10, 23, 30]. Nitroketones obtained in that way are useful as precursors for different organic compounds [33], also pyrrolidines [34]. Pyrrolidines are pharmacologically active and they selectively block presynaptic dopamine receptors [34] (Scheme 7). Except for Michael intermolecular reaction, intramolecular condensation adducts were also obtained. Michael intramolecular proline-catalyzed condensation in which inactive ketones transform into α,β-unsaturated carbonyl compounds was described (Scheme 9) [35, 36]. These reactions require a stoichiometric amount of a catalyst and a long time of reaction and they give as a result a little enantiomeric excess [11, 24, 35]. In 1991, Yamaguchi and co-workers carried out malonates Michael addition to α, β-unsaturated aldehydes catalyzed by L-proline [24, 39]. The reaction proceeded according to enamine mechanism, for example dimethyl malonate was reacted with hex- 2-enal in the presence of proline to give Michael adduct in 44% yield. To improve the yield an attempt of a slight modification of a proline molecule was made transforming it into proper salt. Proline lithium salt enabled to obtain the condensation product in 93% yield (Tab. 4). Regardless of a used catalyst the products in the form of racemates were obtained. In order to improve enantioselective properties of a catalyst, Michael addition of diisopropyl malonate to cycloheptenone was carried out in chloroform in the presence of different proline salts. Optimal enantioselectivity and yield was obtained by using rubidium salt (Tab. 5–7) [40, 41]. Rubidium prolinate-catalyzed Michael additions are used in industry e.g. for enantioselective synthesis of the selective serotonine reuptake inhibitior (SSRI) (–)-paroxetine (antidepressant) (Scheme 12) [24].
Źródło:
Wiadomości Chemiczne; 2014, 68, 1-2; 49-65
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Prolina : pospolity aminokwas wyjątkowy katalizator. Część III, Reakcja Mannicha
Proline as a common amino acid and an exceptional catalyst. Part III, Mannich reaction
Autorzy:
Studzińska, R.
Karczmarska-Wódzka, A.
Wróblewski, M.
Kołodziejska, R.
Dramiński, M.
Powiązania:
https://bibliotekanauki.pl/articles/172649.pdf
Data publikacji:
2014
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
prolina
reakcja Mannicha
synteza asymetryczna
proline
Mannich reaction
asymmetric synthesis
Opis:
Mannich reaction occuring among ketone, aldehyde, and amine is one of the ways of a synthesis of biologically active compounds. Reactions of this type were carried out in the presence of different catalysts [3–10], however in recent years a lot of attention has been paid to enantioselective Mannich reaction catalyzed with proline. Such reactions were carried out with the use of different compounds containing carbonyl group and the most frequently used amine was p-anisidine. The advantage of the use of p-anisidine is a possibility of conducting the direct Mannich reaction (Scheme 3). In this way β-amino ketones (Tab. 1, 2, 4) [15, 18–20, 23, 24], α-hydroxy-β-amino ketones (Tab. 3) [15, 22], and β-amino alcohols (Tab. 5, 6) [25, 26] were obtained. A possibility of syntheses of β-amino sugars and α-amino acids with their derivatives (Tab. 7) [28, 29] is worth noticing. In a great number of described reactions, the products were obtained with satisfactory yield and enantiomeric excess. Taking into consideration the difficulty of a removal of p-hydroxyphenyl group which protects amine group in the resulting products, the attempts of using different amine compounds in Mannich reactions catalyzed with proline were undertaken. The use of amines blocked by tert-butoxycarbonyl group (Boc) enabled to obtain the products with high yield and ee values (Tab. 12–15) [35–38]. However in the case of the use of Boc the reaction must be carried out in an indirect way (it is necessary to prepare imine blocked by Boc earlier).
Źródło:
Wiadomości Chemiczne; 2014, 68, 1-2; 21-48
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Entropy Change Calculations for Pure Gd and a Ni-Mn-Cu-Ga Heusler Alloy: Constant Field vs. Constant Temperature Experiment
Autorzy:
Ferenc, J.
Kowalczyk, M.
Wróblewski, R.
Cieślak, G.
Sielicki, K.
Leonowicz, M.
Kulik, T.
Powiązania:
https://bibliotekanauki.pl/articles/1402338.pdf
Data publikacji:
2015-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.30.Sg
65.40.gd
Opis:
The magnetocaloric effect may be assessed indirectly by expressing it as the change in magnetic entropy in varying magnetic field, H, as the function of temperature, T. Magnetization, M=f(T,H), may be experimentally acquired from a series of isothermal measurements with variable field, or from a series of constant field measurements with variable temperature. The accuracy of magnetic entropy calculation depends on the number of series in these experiments. The aim of this work is to determine how little data is sufficient to obtain accurate results of magnetic entropy change calculations, on the basis of real, magnetocaloric materials. Pure gadolinium and a Ni-Mn-Cu-Ga Heusler alloy were studied. For both materials, the magnetic entropy change and relative cooling power were calculated from both experiments, with the decreasing number of experimental data. For both materials, the constant field experiment with only 6 field values provided only a 5% error of calculations, as compared to the experiment with 100 field values. The Arrott plots were also drawn for constant field mode with 6 field values, easily indicating the order of transition. Comparison of the calculation results suggests that the constant field mode magnetization measurement may be more accurate and faster than isothermal mode.
Źródło:
Acta Physica Polonica A; 2015, 128, 1; 111-115
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Strategia naukowo-badawcza Centrum Naukowo-Badawczego Ochrony Przeciwpożarowej
Autorzy:
Wróblewski, D.
Klimiuk, J.
Leszczak, M.
Małozięć, D.
Rakowska, J.
Sulak, M.
Surla, Z.
Świetnicki, J.
Turkiewicz, R.
Zboina, J.
Powiązania:
https://bibliotekanauki.pl/articles/373524.pdf
Data publikacji:
2006
Wydawca:
Centrum Naukowo-Badawcze Ochrony Przeciwpożarowej im. Józefa Tuliszkowskiego
Tematy:
misja
CNBOP
działalność
bezpieczeństwo
finanse
gospodarka
mission
activity
safety
finance
economy
Opis:
Omówiono miejsce CNBOP w systemie bezpieczeństwa powszechnego poprzez realizację misji Centrum. Przedstawiono strategię naukowo-badawczą oraz zakres spójności działalności Centrum z rządowymi celami strategicznymi.
In the article there is described position of CNBOP in the common safety system based on realization of statue CNBOP tasks. There is also presented research and scientific strategy and conformity of CNBOP activity with government’s strategic targets.
Źródło:
Bezpieczeństwo i Technika Pożarnicza; 2006, 2/4; 33-38
1895-8443
Pojawia się w:
Bezpieczeństwo i Technika Pożarnicza
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Changes of the Vistula River External Delta in the period of 2009-2014
Zmiany stożka ujściowego Wisły w okresie 2009-2014
Autorzy:
Wróblewski, R.
Rudowski, S.
Gajewski, Ł.
Sitkiewicz, P.
Szefler, K.
Kałas, M.
Koszałka, M.
Powiązania:
https://bibliotekanauki.pl/articles/111466.pdf
Data publikacji:
2015
Wydawca:
Instytut Morski w Gdańsku
Tematy:
zapobieganie powodziom
ujście Wisły
badania batymetryczne
Opis:
Celem pracy jest określenie stanu i zmian rzeźby stożka ujściowego Wisły Przekop, w okresie lat 2009-2014, w relacji do oceny warunków swobodnego spływu wód Wisły. Stanowi to istotny element dla oceny skuteczności zapobiegania powodziom w rejonie Żuław. Podstawę badań stanowią szczegółowe, monitoringowe pomiary batymetrii i morfometrii stożka wraz z kanałem doprowadzającym. Stosowano nowoczesną aparaturę (głównie DGPS RTK i specjalistyczne systemy nawigacyjne oraz echosondę wielowiązkową) zapewniającą uzyskanie cyfrowego modelu powierzchni dna, z decymetrową dokładnością położenia punktów. W kolejnych latach wykonano serię map batymetrycznych dla skali 1:10 000, map rzeźby i map różnicowych zmian rzeźby. Stwierdzone znaczne zmiany charakteru rzeźby (przy względnie niewielkim zmianach konturów stożka), wskazują na ich istotna rolę w kształtowaniu warunków swobodnego spływu wód Wisły.
The aim of this study is to determine the state and changes of the Vistula Canal (Wisła Przekop) external delta relief, in the period of 2009-2014, and in relation to the assessment of the conditions of free runoff of the Vistula River waters. This is an important element for assessing the effectiveness of flood prevention in the area of Żuławy. The basis of the study are detailed bathymetry monitoring and morphometric measurements of the external delta with the supply channel. Modern equipment was used (mainly RTK and DGPS specialist navigation systems and multibeam echosounder), providing the obtainment of a digital model of the seabed surface, with decimeter accuracy of location points. In subsequent years, a series of bathymetric maps for the scale of 1:10 000 was made, as well as relief maps and maps of differential changes of the relief. The observed significant changes in the nature of the relief (with relatively small changes in the contours of the delta), indicate their important role in shaping the conditions of free runoff Vistula waters.
Źródło:
Biuletyn Instytutu Morskiego w Gdańsku; 2015, 30, 1; 16-22
1230-7424
2450-5536
Pojawia się w:
Biuletyn Instytutu Morskiego w Gdańsku
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Tablice miazszosci grubizny drzewa oparte na srednicy pniaka
Autorzy:
Bruchwald, A
Rymer-Dudzinska, T.
Dudek, A.
Michalak, K.
Wroblewski, L.
Zasada, M.
Tomusiak, R.
Powiązania:
https://bibliotekanauki.pl/articles/816262.pdf
Data publikacji:
2002
Wydawca:
Polskie Towarzystwo Leśne
Tematy:
dendrometria
srednica
pniaki
tablice miazszosci
lesnictwo
miazszosc drzew
wzory empiryczne
Źródło:
Sylwan; 2002, 146, 01; 5-16
0039-7660
Pojawia się w:
Sylwan
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Anisotropy of the Magnetocaloric Effect in the $Ni_{49.6}Mn_{27.6}Ga_{22.8}$ Single Crystal
Autorzy:
Wroblewski, R.
Sielicki, K.
Leonowicz, M.
Powiązania:
https://bibliotekanauki.pl/articles/1402315.pdf
Data publikacji:
2015-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
65.40.gd
75.30.Gw
75.30.Sg
Opis:
The magnetocaloric effect anisotropy in the $Ni_{49.6}Mn_{27.6}Ga_{22.8}$ single crystal was investigated. In the examined alloy the structural phase transition and magnetic transition occur at room temperature and around 370 K, respectively. The magnetic entropy change, at those two temperatures, was determined on the basis of isothermal and isofield curves, recorded at fields up to 1200 kA/m (1.5 T) with temperature steps of 2.5 and 5 K. Although the calculated values of magnetic entropy change are relatively small, ≈0.7 J/(kg K), an anisotropy of the magnetocaloric effect is observed with a magnetic field applied along the main crystallographic directions of the single crystal. The magnetic entropy change at the structural phase transition depends on the orientation. The weakest magnetocaloric effect occurs when the field is applied along [1 0 0] direction whereas the highest magnetocaloric effect value is reached along [0 0 1] direction, which is an easy magnetization axis. Such behaviour can be explained with the high magnetocrystalline anisotropy of the martensitic phase. The magnetic entropy change value, at the structural phase transition, obtained for the polycrystalline specimen, is close to that for the [0 0 1] single crystal direction.
Źródło:
Acta Physica Polonica A; 2015, 128, 1; 54-55
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Monitorowanie dachów związane z obciążeniami śniegiem
Monitoring of roofs under snow loads
Autorzy:
Wróblewski, R.
Zając, M.
Kopij, Ł.
Powiązania:
https://bibliotekanauki.pl/articles/160873.pdf
Data publikacji:
2013
Wydawca:
Polski Związek Inżynierów i Techników Budownictwa
Tematy:
dach
konstrukcja dachu
obciążenie śniegiem
monitorowanie
system monitorowania
roof
roof structure
snow load
monitoring
monitoring system
Opis:
Awarie i katastrofy budowlane, choć rzadkie i mało prawdopodobne, to jednak zdarzają się wywołując poważne konsekwencje. Najlepszą gwarancją uniknięcia takiego wydarzenia są odpowiednio sporządzony projekt i prawidłowo wykonana konstrukcja. Zastosowanie systemu monitorowania konstrukcji zwiększa jej bezpieczeństwo poprzez informowanie użytkownika o możliwym zagrożeniu. Monitorowanie związane z obciążeniami śniegiem, jako wyspecjalizowany system, pełni rolę wspomagającą użytkownika w decyzjach związanych z odśnieżaniem dachu, a właściwie najczęściej w decyzji o braku konieczności odśnieżania dając pewność, że decyzja taka jest uzasadniona.
Breakdowns and collapses of structures are incidental and unlikely, but their consequences are serious. A proper design and construction is the best method to avoid these events. Increse of structural safety can be increased by application of structural health monitoring system informing the user on possible disability. Monitoring for snow loadas, as a specialised system, supports the user in making decisions on snow removal from a roof and more precisely and generally in making decisions on not removal of snow giving confidence that the decision is reasonable.
Źródło:
Przegląd Budowlany; 2013, R. 84, nr 11, 11; 16-18
0033-2038
Pojawia się w:
Przegląd Budowlany
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Enancjoselektywna enzymatyczna desymetryzacja katalizowana oksydoreduktazami. Reakcje utleniania. Część 1
Enantioselective enzymatic desymmetrization catalyzed by oxidoreductases. Oxidation reactions. Part 1
Autorzy:
Karczmarska-Wódzka, A.
Kołodziejska, R.
Tafelska-Kaczmarek, A.
Studzińska, R.
Wróblewski, M.
Augustyńska, B.
Powiązania:
https://bibliotekanauki.pl/articles/172799.pdf
Data publikacji:
2015
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
dehydrogenaza
monooksygenaza
reakcja utleniania
dehydrogenase
monooxygenase
oxidation reaction
Opis:
The main advantage of biotransformation involving enzymes, compared to chemical processes, is a highly selective formation of products with precise configuration. Herein we describe enzymes participating in the oxidation processes, especially dehydrogenases and monooxygenases. Dehydrogenases are not only able to catalyze the enantioselective reduction of prochiral ketones, but they can also desymmetrize meso and prochiral diols through the enantioselective oxidation. As a result of this processes, optically active hydroxyketones, hydroxycarboxylic acids, and their derivatives are obtained. Cytochrome P450 monooxygenases (CYPs) constitute a family of heme-containing enzymes which exhibits a variety of catalytic activities. They catalyze different reactions, such as hydroxylation, epoxidation, oxidative deamination, or N- and (S)-oxidation. In the oxidation reaction with monooxygenases, the whole cells are commonly used as catalysts. The use of monooxygenases in the oxidation reaction of prochiral alkanes provides the optically active alcohols. It is very significant that these transformations are still difficult to carry out by chemical methods. Baeyer-Villiger monooxygenases (BVMO EC 1.14.13.X) effectively catalyze the nucleophilic and electrophilic oxidation reactions of various functional groups. BVMO are highly regio- and stereoselective enzymes, and their catalytic potential is used in the synthesis of optically pure lactones and esters. Keywords:
Źródło:
Wiadomości Chemiczne; 2015, 69, 1-2; 35-51
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Acetaminophen (Paracetamol) induced acute liver failure - A social problem in an era of increasing tendency to self-treatment
Autorzy:
Wroblewski, T.
Kobryn, K.
Koziel, S.
Oldakowska-Jedynak, U.
Pinkas, J.
Danielewicz, R.
Ziarkiewicz-Wroblewska, B.
Krawczyk, M.
Powiązania:
https://bibliotekanauki.pl/articles/50483.pdf
Data publikacji:
2015
Wydawca:
Instytut Medycyny Wsi
Źródło:
Annals of Agricultural and Environmental Medicine; 2015, 22, 4
1232-1966
Pojawia się w:
Annals of Agricultural and Environmental Medicine
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Enancjoselektywna enzymatyczna desymetryzacja katalizowana oksydoreduktazami. Reakcje utleniania. Część 2
Enantioselective enzymatic desymmetrization catalyzed by oxidoreductases. Oxidation reactions. Part 2
Autorzy:
Karczmarska-Wódzka, A.
Kołodziejska, R.
Tafelska-Kaczmarek, A.
Studzińska, R.
Wróblewski, M.
Augustyńska, B.
Powiązania:
https://bibliotekanauki.pl/articles/172457.pdf
Data publikacji:
2015
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
dioksygenaza
oksydaza
peroksydaza
reakcja utleniania
dioxygenase
oxidase
peroxidase
oxidation reaction
Opis:
In continuation of our work, we herein describe next enzyme classes applied for oxidation reaction. Dioxygenases, oxidases, and peroxidases are successfully used in the synthesis of desymmetrization products with high yields and enantiomeric excesses. Aromatic dioxygenases, such as toluene dioxygenase (TDO), naphthalene dioxygenase (NDO), and biphenyl dioxygenase (BPDO) found in the prokaryotic microorganisms are enzymes belonging to the dioxygenase class and are the most commonly used in organic synthesis. The α-oxidation of various fatty acids in the presence of an α-oxidase from germinating peas is one of the few examples of oxidases application in asymmetric organic synthesis. The intermediary α-hydroxyperoxyacids can undergo two competing reactions: decarboxylation of the corresponding aldehydes or reduction to the (R)-2-hydroxy acids. In order to eliminate the competitive decarboxylation reaction tin(II) chloride is used as an in situ reducing agent. Peroxidases are the redox enzymes found in various sources such as animals, plants, and microorganisms. Due to the fact that, in contrast to monooxygenases, no additional cofactors are required, peroxidases are highly attractive for the preparative biotransformation. Oxidation reactions catalyzed by (halo)peroxydases are also often used in organic synthesis. N-Oxidation of amines, for instance, leads to the formation of the corresponding aliphatic N-oxides, aromatic nitro-, or nitrosocompounds. From a preparative synthesis standpoint, however, sulfoxidation of thioether is important since it was proven to proceed in a highly stereo- and enantioselective manner. Furthermore, depending on the source of haloperoxidase, chiral sulfoxides of opposite configurations can be obtained.
Źródło:
Wiadomości Chemiczne; 2015, 69, 1-2; 53-64
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The effect of the filled epoxy resin interlayers on the adhesion in polymer-metal hybrid joints
Autorzy:
Trzaska, O.
Kaczmar, J. W.
Wróblewski, R.
Niekrasz, M.
Kornacki, Ł.
Casalegno, V.
Periolatto, M.
Bongiovanni, R.
Powiązania:
https://bibliotekanauki.pl/articles/278268.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Inżynierii Materiałów Polimerowych i Barwników
Tematy:
epoxy resin
polymer-metal hybrid composite
hybrid joints
adhesion promoters
żywica epoksydowa
kompozyt hybrydowy polimer-metal
połączenia hybrydowe
promotory adhezji
Opis:
Two epoxy resin compounds were used as the adhesion interlayers at the interface between an injected glass fibre reinforced thermoplastic polymer PA6GF30 (polyamide 6 with 30% wt. of glass fibres) and steel sheet (DC01 steel, 0.5 mm thick). Both epoxy resins, Epidian62 and Epidian57, were filled with alumina particles (grain size of 3 µm ± 1%) in a volume rate of 100:29 epoxy resin - alumina. Steel sheets with cured layer of epoxy resin compounds were placed in the injection mold, then the PA6GF30 was injected between them. Shear strength tests were basis for the evaluation of the adhesion of the manufactured polymer-metal hybrid joints. SEM and optical microscopy analysis were used to investigate the structure of joints after shear deformation. Conversion rates of epoxy compounds and heat of curing reactions were investigated by using of differential scanning calorimeter (DSC). It was found that the highest strength of these joints was achieved for epoxy compounds based on Epidian62.
Źródło:
Przetwórstwo Tworzyw; 2016, T. 22, Nr 1 (169), 1 (169); 27-35
1429-0472
Pojawia się w:
Przetwórstwo Tworzyw
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Prolina – pospolity aminokwas wyjątkowy katalizator. Część II, Międzycząsteczkowa kondensacja aldolowa
Proline as a common amino acid and an exceptional catalyst. Part II, Intermolecular aldol reaction
Autorzy:
Kołodziejska, R.
Wróblewski, M.
Karczmarska-Wódzka, A.
Studzińska, R.
Dramiński, M.
Powiązania:
https://bibliotekanauki.pl/articles/171560.pdf
Data publikacji:
2013
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
międzycząsteczkowa reakcja aldolowa donor
akceptor
prolina
anti-aldole
intermolecular aldol reaction
donor
acceptor
proline
anti-aldol
Opis:
Proline in organic synthesis is used as a small molecular organocatalyst. In a catalytic act proline, similarly to an enzyme, activates reagents, stabilizes transition state and influences an orientation of substrates [1–12]. Proline works as aldolase I (so called microaldolase I). In comparison with other amino acids it shows exceptional nucleophilicity which makes imines and enamines formation easier. In the intermolecular aldol reaction proline was used for the first time by List and co-workers (Scheme 1) [3, 9, 20]. Since then an immense progress has been observed in this field. Several aldolization reactions were performed in the presence of proline. Reactions of this type proceed between the donor (nucleophile) and the acceptor (electrophile). In aldol reaction the donors can be both ketones and aldehydes which next are condensed with ketones and aldehydes acting as electrophiles (Scheme 2–18; Tab. 1–7) [21–72]. The presence of proline ensures not only high yield of homo- and heteroaldolization but mainly enables conducting enantio- and diastereoselective synthesis. Intermolecular proline-catalyzed aldol condensation proceeds according to enamine mechanism. Anti-aldols, which make a valuable source of intermediates in the synthesis of important biologically active compounds, are mainly obtained in this reaction [35–44, 54, 58, 62, 63, 68, 69, 71].
Źródło:
Wiadomości Chemiczne; 2013, 67, 11-12; 1027-1050
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Blue Laser on High N$\text{}_{2}$ Pressure-Grown Bulk GaN
Autorzy:
Grzegory, I.
Boćkowski, M.
Krukowski, S.
Łucznik, B.
Wróblewski, M.
Weyher, J.
Leszczyński, M.
Prystawko, P.
Czernecki, R.
Lehnert, J.
Nowak, G.
Perlin, P.
Teisseyre, H.
Purgał, W.
Krupczyński, W.
Suski, T.
Dmowski, L.
Litwin-Staszewska, E.
Skierbiszewski, C.
Łepkowski, S.
Porowski, S.
Powiązania:
https://bibliotekanauki.pl/articles/2030423.pdf
Data publikacji:
2001-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Opis:
In this note we report briefly on the details of pulsed-current operated "blue" laser diode, constructed in our laboratories, which utilizes bulk GaN substrate. As described in Ref. [1] the substrate GaN crystal was grown by HNPSG method, and the laser structure was deposited on the conducting substrate by MOCVD techniques (for the details see Sec. 2 and Sec. 4 of Ref.~[1], respectively).
Źródło:
Acta Physica Polonica A; 2001, 100, Supplement; 229-232
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Enancjoselektywna enzymatyczna desymetryzacja katalizowana oksydoreduktazami. Dehydrogenazy w reakcji redukcji. Część I
Enantioselective enzymatic desymmetrization catalyzed by oxidoreductases. Dehydrogenases in reduction reactions. Part I
Autorzy:
Kołodziejska, R.
Karczmarska-Wódzka, A.
Tafelska-Kaczmarek, A.
Studzińska, R.
Wróblewski, M.
Augustyńska, B.
Powiązania:
https://bibliotekanauki.pl/articles/171686.pdf
Data publikacji:
2014
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
redukcja asymetryczna
dehydrogenaza alkoholowa
kofaktor
asymmetric reduction
alcohol dehydrogenase
cofactor
Opis:
Enzymes act as biocatalysts whether are also mediating in all anabolic and catabolic pathways, playing an extremely important role in the cells of all life forms. Catalytic potential of oxidoreductases is most commonly used in reduction reactions. Dehydrogenases and reductases catalyze the reversible desymmetrization reactions of meso and prochiral carbonyl compounds and alkenes. The oxidoreductase- catalyzed reactions require cofactors to initiate catalysis. In most cases, it is nicotinamide adenine dinucleotide (NADH) or its phosphorylated derivative (NADPH), which acts as a hydride donor. The necessity of employing expensive cofactors was, for the long time, one of the main limitations to the use of dehydrogenases. This problem was solved by developing a regeneration system of a cofactor in the reaction environment. Various systems are used for the cofactor recycling. In the case of a carbonyl compound reduction, an irreversible oxidation of formic acid to carbon dioxide is most frequently used. In this paper, selected examples of whole-cell and isolated enzymes applications in the carbonyl compound reduction are discussed. The application of baker’s yeast, microorganisms and dehydrogenases in enantioselective enzymatic desymmetrization (EED) of prochiral ketones leads to a broad spectrum of chiral alcohols used as intermediates in the syntheses of many pharmaceuticals and compounds presenting a potential biological activity.
Źródło:
Wiadomości Chemiczne; 2014, 68, 9-10; 763-782
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Submarine landslides on the slope of a sandy barrier : A case study of the tip of the Hel Peninsula in the Southern Baltic
Autorzy:
Rudowski, R.
Rucińska-Zjadacz, M.
Wróblewski, R.
Sitkiewicz, P.
Powiązania:
https://bibliotekanauki.pl/articles/2059851.pdf
Data publikacji:
2016
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
underwater mass movements
sandspit
digital terrain model (DTM)
side-scan sonar
sub–bottom profiling
Opis:
The aim of the study is to present the occurrence of landslides on the submarine slope of a sandy barrier. The scale and significance of this phenomenon is discussed. The study area is the Hel Peninsula. It is a 35 km long young sandy spit. The landform is prograding into the deep part of Gdańsk Bay, and the underwater extension of its tip is a steep sandy slope. The tip is still poorly investigated, as it was a military area closed to researchers until 2003. The first detailed survey of the tip on the seabed was conducted aboard the research vessel “IMOR”. A multibeam echosounder, a sub-bottom profiler and a side-scan sonar were used, while grab and core samples of sediment were obtained. Many forms, commonly created as the result of underwater mass movement, were recognized and determined (main scarps, main bodies, landslide steps, landslide foots, series of small slides, “sheet” slides and structural slides). On the one hand, the landslide processes that occur in the tip of the Hel Peninsula are related to the natural development of sandy spits. On the other hand, they threaten the shore’s stability. The genesis of the landslides is still not known.
Źródło:
Geological Quarterly; 2016, 60, 2; 407--416
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Prolina – pospolity aminokwas wyjątkowy katalizator. Część I, Biosynteza proliny. Wewnątrzcząsteczkowa kondensacja aldolowa
Proline as a common amino acid and an exceptional catalyst. Part I, Proline biosynthesis. Intramolecular aldol reaction
Autorzy:
Wróblewski, M.
Kołodziejska, R.
Studzińska, R.
Karczmarska-Wódzka, A.
Dramiński, M.
Powiązania:
https://bibliotekanauki.pl/articles/172473.pdf
Data publikacji:
2013
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
biosynteza proliny
mechanizm kondensacji aldolowej
wewnątrzcząsteczkowa reakcja aldolowa
proline biosynthesis
mechanism of aldol reaction
intramolecular aldol reaction
Opis:
In asymmetric synthesis of organic compounds more effective solutions are being looked for which will result in higher yield(s) of product(s) and their high enantioselectivity [1]. One of such solutions is an use of a multilevel and cheap catalyst. Proline used as a catalyst is a substance of natural origin which was synthetically obtained by Willstätter who was carrying out research on hygric acid (Scheme 1) [10]. The cells of many organisms have a suitable enzymatic system essential for proline biosynthesis [15]. So far, three proline biosynthesis pathways have been described: from glutamate (Scheme 3 and 4), ornithine (Scheme 5 and 6), and arginine (Scheme 7) [16–28]. Proline which is obtained as a result of biosynthesis or supplementation is a substrate for many proteins. Characteristic and significant content (about 23%) of this amino acid was observed in collage. In cells proline can play an important role of osmoregulator [31–35] – a protective substance regulating the activity of such enzymes as catalase and peroxidase [36]. Proline as a secondary amine shows exceptional nucleophilicity facilitating imine and enamine formation. Used as a catalyst in aldol reaction makes with substrates like imine or enamine transition state imitating the activity of naturally occurring enzymes for this type of reaction, that is aldolases. In their research Hajos and Parrish, and Eder, Sauer and Wiechert used proline in intramolecular aldol reaction obtaining proper enones (Scheme 9) [60–62]. The process of intramolecular aldol reaction was used for a separation of racemic mixture of diketones (Scheme 10) [63, 64], cyclization of ortho-substituted aromatic aldehydes and ketones (Scheme 11) [65], synthesis of cyclic diketones (Scheme 13) [68] and domino reaction to obtain substituted cyclohexanones from beta-diketones and unsaturated ketones (Scheme 14) [69].
Źródło:
Wiadomości Chemiczne; 2013, 67, 9-10; 801-818
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
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