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Wyświetlanie 1-15 z 17
Tytuł:
$[FeCl_{4}]¯$ Ionic Liquid Based Ferrofluids
Autorzy:
Parnica, J.
Kesa, P.
Kovac, J.
Timko, M.
Antalik, M.
Powiązania:
https://bibliotekanauki.pl/articles/1368745.pdf
Data publikacji:
2014-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
87.64.kp
75.50.Bb
47.65.Cb
75.50.Mm
Opis:
Magnetic ionic liquids derived from hydrochloride methyl ester alanine amino acids (AA) and $FeCl_{3}$ were synthesized in ethanol and their magnetic properties were investigated. Iron (III) chloride forms ionic liquid in ethanol at saturated concentrations by the transfer of Cl¯ anion from one molecule of $FeCl_{3}$ to the other molecule with the creation of tetrachloro ferrate anion $[FeCl_{4}]$¯ as well as dimer $[Fe_{2}Cl_{7}]$¯. Raman scattering indicates that after addition of hydrochloride methyl ester alanine to ethanol solutions of $FeCl_{3}$ increase the intensities of signal at the frequencies at 318 $cm^{-1}$ and 380 $cm^{-1}$ as markers for the presence of $[FeCl_{4}]$¯ and $[Fe_{2}Cl_{7}]$¯ complexes. The magnetization at room temperature showed in both samples a linear dependence on the applied magnetic field. On the other hand, in the Raman scattering experiments the magnetization is smaller for $FeCl_{3}$ sample in the presence of methyl ester alanine.
Źródło:
Acta Physica Polonica A; 2014, 126, 1; 276-277
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Effect of Polymer Immobilization on Magnetic Properties of Magnetosomes
Autorzy:
Timko, M.
Džarová, A.
Kovač, J.
Kopčanský, P.
Gojzewski, H.
Powiązania:
https://bibliotekanauki.pl/articles/1535115.pdf
Data publikacji:
2010-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.30.Cr
75.30.Gw
75.50.Mm
75.50.Tt
75.60.Ej
Opis:
The anisotropy of several PVA/magnetosomes magnetically textured films has been investigated from the point of view of magnetic properties. The thin film synthesized under the influence of a magnetic field (99 mT) shows the typical behavior of an anisotropic material. On sample textured in magnetic field the magnetisation loop measurements were performed in dependence on the direction of the external magnetic field with respect to the texture axis. The results of hysteresis measurements show that the magnetic field applied during the synthesis promotes an orientation of the chains of magnetosomes and permanently textured film is obtained after solidification. The obtained values for magnetic remanence and coercivity were dependent on the external magnetic field orientation and the alignment effect of particle moments may be clearly seen which is in agreement with the theoretical model of magnetic particle chains.
Źródło:
Acta Physica Polonica A; 2010, 118, 5; 995-997
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study of Composites Consisting of High-T$\text{}_{c}$ Superconductor and Fine Magnetic Particles
Autorzy:
Timko, M.
Kopčanský, P.
Kováč, J.
Koneracká, M.
Plecháček, V.
Powiązania:
https://bibliotekanauki.pl/articles/2013009.pdf
Data publikacji:
2000-03
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
74.72.Hs
75.50.Tt
Opis:
The composite systems as a mixture of fine magnetic particles of Fe$\text{}_{3}$O$\text{}_{4}$ and superconducting powder such as Bi$\text{}_{1.8}$Pb$\text{}_{0.2}$Sr$\text{}_{2}$Ca$\text{}_{2}$Cu$\text{}_{3}$O$\text{}_{10+x}$ were prepared. The influence of internal magnetic field (generated by magnetic particles) on the superconducting properties of prepared composites were studied as a function of concentration of magnetic particles and their magnetic state. The observed data both of the shielding and the Meissner effect were compared with corresponding linear combination of pure signals of magnetite and superconductor, respectively. The large differences were observed for demagnetized samples. It means that result must be discussed in the frame of the distribution of internal magnetic field created by the magnetic particles.
Źródło:
Acta Physica Polonica A; 2000, 97, 3; 389-392
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Characterization of Magnetoferritin
Autorzy:
Mitróová, Z.
Melníková, L.
Kováč, J.
Timko, M.
Kopčanský, P.
Powiązania:
https://bibliotekanauki.pl/articles/1429123.pdf
Data publikacji:
2012-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.30.Cr
75.50.Ee
75.60.Ej
75.50.Tt
Opis:
The paper presents detailed experimental study of synthesis and characterization a bioinorganic magnetic molecule - magnetoferritin. Magnetoferritin with loading of iron ions per protein molecule in the range from 300 to 3000 was prepared. Size distribution analysis (transmission electron microscopy, dynamic light scattering) shows spherical nanoparticles with particle size distribution from 2 to 12 nm, and hydrodynamic diameter from 12 to 25 nm. The thermomagnetic curves measured after cooling the sample in zero field (zero-field cooling) and under the presence of the measurement field (field cooling) show superparamagnetic behavior with the blocking temperature $T_{b}$ from 22 to 60 K and the magnetization loops measured below $T_{b}$ (at 2 K) show the hysteresis with coercive field from 20 to 30 kA/m depending on the concentration of the magnetic nanoparticles.
Źródło:
Acta Physica Polonica A; 2012, 121, 5-6; 1318-1320
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Magnetic Charcoal Supporting Silver as a Water Disinfectant
Autorzy:
Valušová, E.
Antalík, M.
Pristaš, P.
Javorský, P.
Kováč, J.
Timko, M.
Powiązania:
https://bibliotekanauki.pl/articles/1201874.pdf
Data publikacji:
2014-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.05.Ni
75.60.Ej
75.47.Lx
81.05.U-
92.40.qc
Opis:
We investigated the magnetic behavior of charcoal composite with incorporated magnetite and silver ions. The magnetization curve measured at 282 K showed saturation magnetization of 8 emu/g. By benefiting from a mechanical process, the magnetic activated carbon, supporting silver ions (MCAG), acts as a magnetic filter uptaking the bacteria. This idea was confirmed by the DGGE analysis in which the bacterial DNA was detectable in the sediment after the treatment.
Źródło:
Acta Physica Polonica A; 2014, 126, 1; 226-227
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Magnetic Properties of Bacterial Nanoparticles
Autorzy:
Timko, M.
Džarová, A.
Kováč, J.
Kopčanský, P.
Gojzewski, H.
Szlaferek, A.
Powiązania:
https://bibliotekanauki.pl/articles/1810601.pdf
Data publikacji:
2009-01
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
47.65.Cb
51.60.+a
75.30.Gw
75.50.Tt
75.60.Nt
75.60.Ej
75.75.+a
Opis:
The objective of this study is to prepare and study magnetic properties of biological magnetic nanoparticles (magnetosomes) as a product of biomineralization process of magnetotactic bacteria Magnetospirillum sp. AMB-1. From temperature dependence of remanent magnetization and coercive field the Verwey transition is clearly seen at 105 K as a consequence of the large anisotropy along the chains of magnetosomes.
Źródło:
Acta Physica Polonica A; 2009, 115, 1; 381-383
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Magnetic Birefringence Study of the Magnetic Core Structure of Ferritin
Autorzy:
Koralewski, M.
Pochylski, M.
Mitróová, Z.
Melníková, L.
Kováč, J.
Timko, M.
Kopčanský, P.
Powiązania:
https://bibliotekanauki.pl/articles/1428622.pdf
Data publikacji:
2012-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
78.20.Ls
87.15.-v
87.85.jf
Opis:
Magnetically induced optical birefringence (Δ n) was measured for magnetoferritin and horse spleen ferritin aqueous suspensions. The Δ n for magnetoferritin was described in the frame of the Langevin formalism taking into account distribution of core diameter. The established average magnetic dipole moment and core diameter is equal to about 460 $μ_{B}$ and 3 nm, respectively. It was shown that magnetic birefringence and the Cotton-Mouton constant can be powerful parameters in identification of the magnetic core structure of ferritin, especially useful in biomedicine.
Źródło:
Acta Physica Polonica A; 2012, 121, 5-6; 1237-1239
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Viscosity Dependence of a Magnetic Fluid Nanoparticles Concentration
Autorzy:
Tóthová, J.
Kováč, J.
Kopčanský, P.
Rajňák, M.
Paulovičová, K.
Timko, M.
Józefczak, A.
Powiązania:
https://bibliotekanauki.pl/articles/1201929.pdf
Data publikacji:
2014-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
07.55.Jg
75.50.Mm
83.85.Jn
Opis:
In this work we have studied the effect of temperature on the viscosity of magnetic fluids (MFs) based on the transformer oil ITO 100. The volume concentration of suspended magnetic particles (MPs) changed from 0.25 to 1%. Rheological characterization of MFs was performed using a vibroviscometer at working frequency of 30 Hz. The temperature dependence of the viscosity was measured in the temperature range from 20 up to 50 °C. The magnetization of different concentrations of MPs in MFs was determined by using the vibrating sample magnetometer.
Źródło:
Acta Physica Polonica A; 2014, 126, 1; 278-279
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Magnetic Properties and Sorption Activity of Mechanically Activated Magnetite $Fe_3O_4$
Autorzy:
Baláž, P.
Timko, M.
Kováč, J.
Bujňáková, Z.
Ďurišin, J.
Myndyk, M.
Šepelák, V.
Powiązania:
https://bibliotekanauki.pl/articles/1535173.pdf
Data publikacji:
2010-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.60.Ej
61.05.cp
76.80.+y
Opis:
It is known that the action of mechanical forces on solids (mechanical activation and/or mechanochemistry) leads to changes of their properties and reactivity. We have studied the physico-chemical and sorption properties of magnetite $Fe_3O_4$ (Kiruna, Sweden) mechanically activated in a planetary mill. Several methods such as X-ray diffractometry, Mössbauer spectroscopy, magnetometry, specific surface area measurement as well as arsenic sorption tests have been applied. By X-ray diffractometry strong amorphisation of magnetite has been evidenced. In parallel, specific surface area increased from 0.1 $m^2//g$ for the reference (non-milled) sample to the values 0.5-6.1 $m^2//g$ for milled samples. The Mössbauer spectrum of the reference sample is well fitted with two subspectra corresponding to tetrahedrally (A) and octahedrally (B) coordinated iron cations in the spinel structure of $Fe_3O_4$. In mechanically activated samples (B)-site subspectrum becomes asymmetric, while (A)-site spectrum remains more or less unchanged. The more covalent character of the Fe(A)-O bond compared to the Fe(B)-O bond can explain qualitatively why the spin-density transfer from (A) to (B) in the spinel structure is more effective than vice versa. The value of the saturation magnetization at room temperature was 67.4 ≈ 43.6 emu/g which is significantly lower than that of the bulk particles 92 emu/g. This reduction may be attributed to the surface disorder or spin canting at the particle surface. During the milling process the coercivity value increases from 150 Oe up to 460 Oe with milling time. This increase can be related to the fact that magnetic anisotropy may increase when particle size decreases. The sorption activity of $Fe_3O_4$ was enhanced as a consequence of its disordering: 88% of $As^{3+}$ was captured for the mechanically activated sample in comparison with 0% for the non-milled one.
Źródło:
Acta Physica Polonica A; 2010, 118, 5; 1005-1007
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Magnetic Properties of Milled and Thermal Relaxed YBa$\text{}_{2}$ (Cu$\text{}_{1-x}$Fe$\text{}_{x}$)$\text{}_{3}$O$\text{}_{y}$
Autorzy:
Timko, M.
Kováč, J.
Sargánková, I.
Zentková, M.
Mihalik, M.
Maťaš, S.
Čiasnohová, A.
Powiązania:
https://bibliotekanauki.pl/articles/1955517.pdf
Data publikacji:
1997-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
74.90.+n
74.10.+v
74.70.-b
Opis:
The influence of the mechanical milling and subsequent thermal relaxation on magnetic and superconducting behaviour of YBa$\text{}_{2}$(Cu$\text{}_{1-x}$Fe $\text{}_{x}$)$\text{}_{3}$O$\text{}_{y}$ system has been studied. Two methods of heat treatment were used: Set I - slow cooling from 980°C in flowing O$\text{}_{2}$ and Set II - reducing at 770°C in flowing Ar$\text{}_{2}$ followed by reoxidation in flowing O$\text{}_{2}$ below 400°C. The transition to superconductivity, diamagnetic response, critical current density and the effective magnetic moment in the normal state have been estimated. Our measurements indicate that the reducing atmosphere preparation is less detrimental on superconducting properties. The results are discussed in terms of occupancy Cu sites by Fe and redistribution of oxygen atoms.
Źródło:
Acta Physica Polonica A; 1997, 91, 2; 355-358
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Physical Properties of Magnetite Nanoparticles Covered by 11-Mercaptoundecanoic Acid
Autorzy:
Timko, M.
Kopčanský, P.
Antalik, M.
Simsikova, M.
Valusova, E.
Molcan, M.
Kováč, J.
Powiązania:
https://bibliotekanauki.pl/articles/1429127.pdf
Data publikacji:
2012-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
47.65.Cb
85.70.-w
75.30.Cr
75.47.Lx
Opis:
We have investigated the magnetic behavior of magnetite nanoparticles covered by the 11-mercaptoundecanoic acid around magnetite core prepared by a standard co-precipitation method. The particles show superparamagnetic behavior at room temperature, with transition to a blocked state at blocking temperature 91 K estimated from zero field cooled and field cooled at 500 Oe experiment. The hysteresis loop measured at 293 K showed magnetization 32.8 emu/g at 50 kOe without any coercivity. The mean particle size (7.1 nm) was determined by fitting a magnetization curve obtained at 295 K assuming a log-normal size distribution.
Źródło:
Acta Physica Polonica A; 2012, 121, 5-6; 1321-1323
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
AC Magnetic Susceptibility of Ferrofluids Exposed to an External Electric Field
Autorzy:
Rajňák, M.
Dolník, B.
Kováč, J.
Paulovičová, K.
Mitróová, Z.
Kurimský, J.
Cimbala, R.
Kopčanský, P.
Timko, M.
Powiązania:
https://bibliotekanauki.pl/articles/1032260.pdf
Data publikacji:
2017-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
47.65.Cb
75.75.Fk
75.78.-n
83.60.Np
Opis:
It is known that ferrofluid superparamagnetic nanoparticles response to external magnetic fields, often resulting in the formation of elongated clusters along the field. This has a notable impact on dielectric properties of ferrofluids. Here we report on indications of a contrary effect when the magnetic susceptibility of ferrofluids based on transformer oil is influenced by an external electric field. This effect is associated with structural changes in the ferrofluids induced by the external electric fields. Particularly, we focus on a steady state electric field effect, which gives rise to forces acting on the magnetite nanoparticles, leading to the formation of aggregates. In this condition we have measured the ferrofluid AC magnetic susceptibility in parallel and perpendicular configuration of magnetic and electric fields at room temperature. The measurements in both configurations yielded a noticeable decrease in the real susceptibility values with increasing electric field intensity. The result is believed to be caused by the reduction in the total magnetic moment of the ferrofluid. This can be a consequence of the superspin interactions in the aggregates, minimizing the aggregate's energy. Finally, we highlight the necessity of NMR and small angle scattering of polarized neutrons investigations in order to obtain exact information on the magnetic structure induced by the electric forces.
Źródło:
Acta Physica Polonica A; 2017, 131, 4; 887-889
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Influence of Morphology on Magnetic Properties of Magnetosomes
Autorzy:
Hashim, A.
Molčan, M.
Kovač, J.
Varchulová, Z.
Gojzewski, H.
Makowski, M.
Kopčansky, P.
Tomori, Z.
Timko, M.
Powiązania:
https://bibliotekanauki.pl/articles/1428653.pdf
Data publikacji:
2012-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
47.65.Cb
51.60.+a
75.30.Gw
75.50.Tt
75.60.Nt
75.60.Ej
Opis:
Cultivation process was changed three times. The culture medium was enriched by more amount ferric quinate (FQ magnetosomes sample) and more amounts Wolfe's vitamin solution (WVS magnetosomes sample) comparing to normal culture medium (NP magnetosomes sample). NP sample of magnetosomes shows zero coercivity and behaves superparamagnetically. The increase of coercivity (6.5 Oe for WVS and 20 Oe for FQ) may be caused by higher value of shape anisotropy and reveals stronger magnetic correlations between particles of magnetite chains.
Źródło:
Acta Physica Polonica A; 2012, 121, 5-6; 1250-1252
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Radiation Stability of the BSA Modified Biocompatible Magnetic Fluid
Autorzy:
Tomašovičová, N.
Haysak, I.
Kováč, J.
Kubovčíková, M.
Závišová, V.
Timko, M.
Okunev, A.
Zorkovská, A.
Kopčanský, P.
Powiązania:
https://bibliotekanauki.pl/articles/1368667.pdf
Data publikacji:
2014-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.50.Mm
61.30.Gd
64.70.Md
Opis:
The aim of the presented work was to investigate the stability of biocompatible magnetic fluid, i.e. water-based magnetic fluid containing magnetite nanoparticles stabilized by surfactant sodium oleate and modified by bovine serum albumin (BSA) after electron irradiation. Samples with the same concentration of $Fe_{3}O_{4}$ but different mass ratio BSA/$Fe_{3}O_{4}$ (w/w=0.25, 1.0 and 2.5) were studied. The electron irradiation caused about 10% reduction of the saturation magnetization in the samples with w/w BSA/$Fe_{3}O_{4}$ ratio of 0.25 and less than 5% in the samples with w/w BSA/$Fe_{3}O_{4}$ ratio of 1 and 2.5.
Źródło:
Acta Physica Polonica A; 2014, 126, 1; 262-263
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Magnetic Properties of Magnetite Formed by Biomineralization and Chemical Synthesis
Autorzy:
Timko, M.
Džarová, A.
Kopčanský, P.
Závišová, V.
Koneracká, M.
Kováč, J.
Šprincová, A.
Vaclavíková, M.
Ivaničová, L.
Vávra, I.
Powiązania:
https://bibliotekanauki.pl/articles/1813922.pdf
Data publikacji:
2008-01
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.75.+a
47.65.Cb
87.83.+a
Opis:
In this work, the magnetic properties of biologically produced magnetite (magnetosomes) by biomineralization process were compared to those of chemically synthesized $Fe_3O_4$. The coercivity of 185 Oe in magnetosomes is connected with the fact that the mean diameter is larger than critical size for transition from superparamagnetic to ferromagnetic behavior. A sharp magnetic transition at 105 K (Verwey transition) is clearly present in magnetosomes while in opposite, this transition is missing in $Fe_3O_4$.
Źródło:
Acta Physica Polonica A; 2008, 113, 1; 573-576
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 17

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