- Tytuł:
- Polypropylene Films Studied with Variable Positron Beams
- Autorzy:
-
Dębowska, M.
Coleman, P. G.
Gidley, D. W. - Powiązania:
- https://bibliotekanauki.pl/articles/2007958.pdf
- Data publikacji:
- 1999-04
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
36.10.Dr
61.41.+e
71.60.+z
78.70.Bj - Opis:
- Doppler broadening and positron lifetime spectra have been measured for polypropylene films of constant thickness (≈ 50 μm) and different morphology that crystallized from melt at temperature 0, 100, and 120°C. The S -parameter vs. energy curves do not change in a systematic way with crystallinity of samples. It is supposed that decrease in the fractional free volume for samples of greater crystallinity is not seen in S-values because of their increase resulting from annihilation in defects present both in the crystalline regions and on the lamellae surfaces. Intensities of the components in the positron lifetime spectra: I$\text{}_{2}$ (τ$\text{}_{2}$=1.3 ns) and I$\text{}_{3}$ (τ$\text{}_{3}$≈ 2.3÷2.8 ns) show changes with crystallinity of samples. The evident trend is observed for the longer-lived τ$\text{}_{3}$-component intensity to decrease with crystallinity while the reverse is true for the shorter, fixed τ$\text{}_{2}$-component. The decrease in the intensity of the longer-lived component can result from reduction of the fractional free volume.
- Źródło:
-
Acta Physica Polonica A; 1999, 95, 4; 496-504
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki