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Wyświetlanie 1-15 z 27
Tytuł:
Synthesis and Characterization of Cu(II), Ni(II) and Co(II) Based Schiff Base Complexes
Autorzy:
Bhalu, A.
Vilapara, K.
Maru, M.
Shah, M.
Powiązania:
https://bibliotekanauki.pl/articles/412444.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
schiff base
metal complexes
Opis:
N-(3-Bromo-4-hydroxy-5-methoxybenzylidene)-4-Bromobenzenamine was synthesized. This was further used to synthesize Co(II), Ni(II) and Co(II) based metal complexes and characterized by FT-IR, Elemental analysis, ESI Mass and UV spectroscopy.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 12; 51-55
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
SELENO-L-METHIONINE MODULATE THE TOXIC EFFECT OF NEW DOXORUBICIN METAL COMPLEXES IN PROKARYOTIC MODEL –ESCHERICHIA COLI RFM443 RECA::LUX
Autorzy:
Matejczyk, Marzena
Świderski, Grzegorz
Lewandowski, Włodzimierz
Powiązania:
https://bibliotekanauki.pl/articles/895497.pdf
Data publikacji:
2019-02-28
Wydawca:
Polskie Towarzystwo Farmaceutyczne
Tematy:
cancer
selenium
metal complexes
Dox
toxicity
Opis:
Abstract: The main problem of modern cancer therapy is their resistance to the drugs used and the toxicity of drugs to healthy cells of the human body. Hope is natural substances that are protective of cells and often support the action of standard anticancer chemotherapy. Among them are selenium compounds. In the present study, we examined the cytotoxic and genotoxic potency of doxorubicin (DOX) metal complexes as new anticancer drug candidates. We also measured the effect of simultaneous administration of seleno –L-methionine as biologically active agent with DOX and its complexes with Mn, Mg, Fe, Co and Ni in prokaryotic model - Escherichia coli RFM443 with plasmid transcriptional fusion of recA promoter and luxCDABE as a reporter gene. The results obtained by us, indicate high biological activity of metal complexes with doxorubicin. The strongest modulatory effect was observed using the DOX complexes with Co and Ni compared to the DOX. The DOX complexes with Mg, Mn and Fe also showed relatively high biological activity. Simultaneous bacteria culture treatment with SeMet decreased the values of the DOX and its metal complexes cyto- and genotoxic parameters. These results encourage further research to assess the value of the doxorubicin metal complexes as new cytostatic drug candidates. While SeMet may be considered as therapeutic option in cancer treatment as modulation agent in anti-cancer therapy.
Źródło:
Acta Poloniae Pharmaceutica - Drug Research; 2019, 76, 1; 115-125
0001-6837
2353-5288
Pojawia się w:
Acta Poloniae Pharmaceutica - Drug Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, physicochemical studies, fluorescence behavior, and anticancer properties of transition metal complexes with the pyridyl ligand
Autorzy:
Azam, Mohammad
Al-Resayes, Saud I.
Powiązania:
https://bibliotekanauki.pl/articles/2174812.pdf
Data publikacji:
2022
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
Pyridyl ligand
metal complexes
anticancer activity
Opis:
A novel series of complexes with the formula [MLCl] [M = Co(II) (1), Ni(II) (2), Cu(II) (3), Zn(II) (4)] arising from Pyridyl ligand, N,N’-bis(1-(2-pyridyl)ethylidene)-2,2-dimethylpropane-1,3-diamine), ligand, L, was synthesized and investigated by elemental analyses, FT-IR, 1H and 13C NMR, Powder XRD, and thermal analyses. TGA analysis indicated that all complexes degraded in three different steps, while the PXRD examination showed well-defined sharp crystalline peaks for the complexes, indicating significant crystallinity. The antiproliferative activity of the ligand and its complexes were also evaluated in vitro against the HeLa (Human Cervical Cancer Cells) and HCT116 (Colon Cancer Cells) cell lines. The findings suggested complex 4 to be potential anticancer agent against these cell lines. In addition, ligand and its complexes also exhibited considerable emission properties.
Źródło:
Polish Journal of Chemical Technology; 2022, 24, 3; 35--40
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ultrafiltration membranes from polysulfone and sulfonated polysulfone in metal ions dialysis enhanced by polyelectrolyte
Autorzy:
Poźniak, G.
Powiązania:
https://bibliotekanauki.pl/articles/346903.pdf
Data publikacji:
2006
Wydawca:
Politechnika Bydgoska im. Jana i Jędrzeja Śniadeckich. Wydział Technologii i Inżynierii Chemicznej
Tematy:
polysulfone
ultrafiltration membrane
metal dialysis
polymer-metal complexes
Opis:
The dialysis of metal ions including Mg(II), Ni(II) and Zn(II) through ultrafiltration membranes made of polysulfone and sulfonated polysulfone was enhanced by sodium salt of poly(acrylic acid) diluted in the receiving compartment. In experiments, concentration of Mg(II), Ni(II) and Zn(II) in the feed solution was equal to 10-3 mol/dm3, concentration of polymer in the receiving solution was equal to 10-2 mol/dm3, and pH = 9. In the presence of complexing polymer, concentration of all metal ions in the receiving solution is higher than 50% for the polysulfone membrane and increases to almost 100% for the sulfonated polysulfone membrane. This effect is due to a cation-exchange property of the sulfonated polysulfone membrane.
Źródło:
Ars Separatoria Acta; 2006, 4; 50-56
1731-6340
Pojawia się w:
Ars Separatoria Acta
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Chelating ability of proctolin tetrazole analogue
Autorzy:
Łodyga-Chruścińska, Elżbieta
Sanna, Daniele
Micera, Giovanni
Chruściński, Longin
Olejnik, Jadwiga
Nachman, Ronald
Zabrocki, Janusz
Powiązania:
https://bibliotekanauki.pl/articles/1041268.pdf
Data publikacji:
2006
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
metallopeptides
metal complexes
proctolin
tetrazole peptide analogue
Opis:
The aim of the investigation was to establish the chelating ability of a new proctolin analogue of the sequence Arg-Tyr-LeuΨ[CN4]Ala-Thr towards copper(II) ions. The insertion of the tetrazole moiety into the peptide sequence has considerably changed the coordination ability of the ligand. Potentiometric and spectroscopic (UV-Vis, CD, EPR) results indicate that the incorporation of 1,5-disubstituted tetrazole ring favours the formation of a stable complex form of CuH-1L. This 4N coordination type complex is the dominant species in the physiological pH range. The tetrazole moiety provides one of these nitrogens. The data indicate that Cu(II) ions are strongly trapped inside the peptide backbone. These findings suggest that Cu(II) can hold peptide chains in a bent conformation. This bent conformation may be essential for bioactivity of the tetrazole peptides.
Źródło:
Acta Biochimica Polonica; 2006, 53, 1; 65-72
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and characterization of transition metal complexes of some novel pyrazolo-chalcone derivatives
Autorzy:
Odedra, Pratap
Rojivadiya, A. J.
Powiązania:
https://bibliotekanauki.pl/articles/1066234.pdf
Data publikacji:
2019
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Pyrazolochalcone derivatives
Thermal gravimetric analysis
Transition metal complexes
Opis:
Some novel pyrazolo-chalcone molecules were synthesized by condensation of pyrzolo aldehyde with appropriate acetophenone. The synthesis of some metal complexes of transition metal was carried out with these pyrazoleo heterocyclic compounds. Each metal complex was synthesized by the reaction of new pyrazolochalcone derivatives with the metal salts such as Co(CH3COO)2·6H2O, Ni(CH3COO)2·6H2O, and Cu(CH3COO)2·2H2O. For the structure elucidation of ligand molecule various spectroscopic techniques such as 1H NMR, IR and mass has been used. The synthesized metal complexes were subjected to thermal study i.e., TGA and DTA in order to check structural conformation of synthesized metal complexes.
Źródło:
World Scientific News; 2019, 131; 242-255
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Safety Properties of New Explosive Coordination Compounds
Autorzy:
Wojewódka, A.
Bełzowski, J.
Powiązania:
https://bibliotekanauki.pl/articles/358028.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
transition metal complexes
5-picrylaminotetrazole
explosives
safety properties
Opis:
The present paper details the synthesis of new explosive complexes of the DDT type and the investigation of their sensitiveness to friction and impact. Fourteen new compounds, specifically nitrate and perchlorate complexes of various transition block metals with 5-(2,4,6-trinitrophenylamino)tetrazole, commonly called picrylaminotetrazole (PAT), were synthesised. The nitrate complexes were obtained in yields varying between 8.1% and 75.1%, whereas the perchlorate complexes had yields between 24.9% and 67.3%, with yields typically near the upper bound of the given ranges for both classes of complexes and the low yields obtained for [Co(PAT)3](NO3)3 and [Cd(PAT)3](ClO4)3 being the exception rather than the rule. The structures of these compounds were unambiguously established via XRF and IR spectroscopy, as well as via elemental analysis. Detailed analyses of the safety properties of these new materials were performed in terms of their sensitiveness to friction and impact. In general, the obtained compounds present relatively low sensitivity to mechanical stimuli, like friction and impact, with the nitrate complexes of Ni and Zn exhibiting high sensitivity to impact (1-2 Nm). The rest of the investigated compounds show low sensitivity to mechanical stimuli, comparable to classical blasting materials like PETN, RDX or HMX. It should be noted that, in general, the nitrates were more sensitive to mechanical stimuli than their perchlorate analogues.
Źródło:
Central European Journal of Energetic Materials; 2017, 14, 2; 351-360
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of the mathematical models of distillation equilibria for designing the differential distillation process
Autorzy:
Sobczak, E.
Ringel, T.
Łataś, R.
Powiązania:
https://bibliotekanauki.pl/articles/346973.pdf
Data publikacji:
2013
Wydawca:
Politechnika Bydgoska im. Jana i Jędrzeja Śniadeckich. Wydział Technologii i Inżynierii Chemicznej
Tematy:
colorants
asymmetric metal complexes
heteroleptic complexes
resistance to UV radiation
acetylacetone
Opis:
This paper presents the development of mathematical models for positive and negative azeotropes in the range of the more volatile concentrations component: x∈[0; az] ∨ [az; 1]. The coefficients of these models, which, on their basis, were determined the relative volatility of α and the azeotrope concentration az, defined with the high accuracy (R2∈[0,926; 0,999]) and presented them to the table for all subjects of distillation systems. Based on these relationships, the integration of the mass balance equations of the distillation differential process d(Sx)=ydS was carried out and determined the dependence of the distillate obtained from 1 mole of pig iron D/S0 from the α, az coefficients and xw, xs concentrations. Based on these dependencies, charts D/S0 were prepared from predefined by the authors parameter t=[0,05; 0,25; 0,5; 0,75] which is the change in the concentration of pig iron in the process of concentration. Dependencies, presented for distillation balances of positive and negative azeotrope, in the tested ranges, for similar values of α, have the same mileage. The calculations were made for the 126 distillation systems.
Źródło:
Ars Separatoria Acta; 2012-2013, 9/10; 103-116
1731-6340
Pojawia się w:
Ars Separatoria Acta
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
New colorant metal complexes, derivatives of 1,2–diazoxy–4–naphthalenesulfonic acid and pentane-2,4-dione. Part I. Preparation and properties
Autorzy:
Wasilewska, A.
Maćkowska, E.
Urbaniak, W.
Powiązania:
https://bibliotekanauki.pl/articles/347021.pdf
Data publikacji:
2013
Wydawca:
Politechnika Bydgoska im. Jana i Jędrzeja Śniadeckich. Wydział Technologii i Inżynierii Chemicznej
Tematy:
colorants
asymmetric metal complexes
heteroleptic complexes
resistance to UV radiation
acetylacetone
Opis:
A vast array of colorants used in various industries include metal complex colorants, which are useful mainly in the textile industry. Substances to be used in fiber dyeing are expected to have optimum properties, therefore, such compounds remain to be of interest to researchers. The results of studies on the possible modifications of known colorants are presented in this paper.
Źródło:
Ars Separatoria Acta; 2012-2013, 9/10; 95-102
1731-6340
Pojawia się w:
Ars Separatoria Acta
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, spectral characterization and biological activity studies of Schiff’s base of 1,5-dimethyl-2-phenyl-2,3-dihydro-1H-pyrazol-4-amine and its metal complexes
Autorzy:
Jadeja, Juvansinh J.
Gondaliya, Mitesh B.
Mokariya, Devang M.
Shah, Manish
Powiązania:
https://bibliotekanauki.pl/articles/1192661.pdf
Data publikacji:
2016
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Schiff Bases
anti-microbial activity
Metal complexes
spectral analysis
Opis:
N,O,O-donating tridentate ligand was prepared by condensed reaction 1,5-dimethyl-2-phenyl-2,3-dihydro-1H-pyrazol-4-amine with derivative of salicylaldehyde and its metal complexes with Zn, Cd and Hg, which is highly stable at room temperature and characterized by Mass spectra, IR, 1H and 13C NMR, ESI-MASS and TGA-DTA. Comparatively studies of anti-microbial and anti-fungal activity of different ligand and its metal complex carried out.
Źródło:
World Scientific News; 2016, 47, 2; 123-150
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ionic liquid assisted olefin reactions
Autorzy:
Thirunarayanan, G.
Muthuvel, I.
Sathiyendiran, V.
Powiązania:
https://bibliotekanauki.pl/articles/1075429.pdf
Data publikacji:
2019
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Ionic liquids
Metal complexes
Nano catalysts
alkene reactions
olefin reactions
Opis:
In this review article the authors studied the ionic liquid assisted various alkene reactions with various metal complex catalysts such as Isomerization, Hydrogenation, Hydroformylation, Metathesis-Oligomerization, Dimerization, Arylation, Cyclization, Polymerization, Epoxidation, Michael addition and Tandem Cross-coupling reactions.
Źródło:
World Scientific News; 2019, 126; 36-64
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, computational, anticancerous and antiproliferative effects of some copper, manganese and zinc complexes with ligands derived from symmetrical 2,2’-diamino-4,4’-dimethyl-1,1’-biphenyl-salicylaldehyde
Autorzy:
Ababneh, Taher S.
El-Khateeb, Mohammad
Tanash, Aissar K.
AL-Shboul, Tareq M.A.
Shammout, Mohammad Jamal A.
Jazzazi, Taghreed M.A.
Alomari, Mohammad
Daoud, Safa
Talib, Wamidh H.
Powiązania:
https://bibliotekanauki.pl/articles/1849324.pdf
Data publikacji:
2021
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
tetradentate schiff base
symmetrical metal complexes
DFT calculation
spectroscopy
anticancerous
antiproliferative
Opis:
Four new symmetrical Schiff bases derived from 2,2’-diamino-4,4’-dimethyl-1,1’-biphenyl-salicylaldehyde have been synthesized and characterized by elemental analysis and different spectroscopic techniques. The reaction of 2,2’-diamino-4,4’-dimethyl-1,1’-biphenyl with two equivalents of 5-tert-butyl-, 3,5-dinitro-, 3,5-dibromo- and 3-tert-butyl-salicylaldehyde yielded 2,2’-bis(5-tert-butyl-salicylideneamino)-4,4’-dimethyl-1,1’-biphenyl (A1) as well as the 3,5-dinitro- (A2), 3,5-dibromo- (A3) and 3-tert-butyl- (A4) substituted derivatives. The tetradentate ligands were then reacted with copper-, manganese- and zinc-acetate producing the tetra-coordinate metal complexes which were characterized by FTIR, UV-Visible spectroscopy, magnetic susceptibility and elemental analysis. Zinc complexes were characterized by 1H-NMR spectroscopy. Density functional theory (DFT) calculations at the B3LYP/6-31G(d) level of theory were carried out to fully optimize and examine the molecular geometries of complexes. Subsequently, IR vibrational and UV-Vis absorption spectra were computed and correlated with the observed values and the results are in good agreement with the experimental data. The anticancerous and antiproliferative activity of the A3 ligand and its metal complexes were determined.
Źródło:
Polish Journal of Chemical Technology; 2021, 23, 1; 7-15
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Formation of Polycomplexes of Poly(Methyl Vinyl Ether-Co-Maleic Anhydride) and Bovine Serum Albumin in the Presence of Copper Ions
Autorzy:
Karahan, M
Mustafaeva, Z
Özeroğlu, C.
Powiązania:
https://bibliotekanauki.pl/articles/778272.pdf
Data publikacji:
2014
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
bovine serum albumin
copper ions
metal complexes
biological processes
biomaterials
polyelectrolyte
Opis:
The binary and ternary complex formations of poly(methyl vinyl ether-co-maleic anhydride) (PMVEMA) with copper ions and with bovine serum albumin (BSA) in the presence of copper ions in phosphate buffer solution at pH = 7 were examined by the techniques of UV-visible, fluorescence, dynamic light scattering, atomic force microscopy measurements. In the formation of binary complexes of PMVEMA-Cu(II), the addition of copper ions to the solution of PMVEMA in phosphate buffer solution at pH = 7 forms homogeneous solutions when the molar ratio of Cu(II)/MVEMA is 0.5. Then the formations of ternary complexes of PMVEMA-Cu(II)-BSA were examined. Study analysis revealed that the toxicities of polymer-metal and polymer-metal-protein mixture solutions depend on the nature and ratio of components in mixtures.
Źródło:
Polish Journal of Chemical Technology; 2014, 16, 3; 97-105
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Zasady Schiffa – interesujący zakres zastosowań w różnych dziedzinach nauki
Schiff bases – interesting range of applications in various fields of science
Autorzy:
Brodowska, K.
Łodyga-Chruścińska, E.
Powiązania:
https://bibliotekanauki.pl/articles/142348.pdf
Data publikacji:
2014
Wydawca:
Stowarzyszenie Inżynierów i Techników Przemysłu Chemicznego. Zakład Wydawniczy CHEMPRESS-SITPChem
Tematy:
zasady Schiffa
kompleksy metali
chemia koordynacyjna
Schiff bases
metal complexes
coordination chemistry
Opis:
Kompleksy metali odgrywają istotną rolę zarówno w rolnictwie, jak również chemii farmaceutycznej i przemysłowej. Zasady Schiffa są produktami kondensacji pierwszorzędowych amin i związków karbonylowych. Związki te oraz ich kompleksy z metalami są coraz częściej stosowane jako katalizatory, polimery i barwniki. W artykule przedstawiono właściwości zasad Schiffa oraz korzyści wynikające z ich stosowania w różnych gałęziach przemysłu.
Metal complexes play an important role in agriculture as well as industrial and pharmaceutical chemistry. Schiff bases are the condensation products of primary amines and carbonyl compounds. Schiff bases and their metal complexes are increasingly being used as catalysts, polymers and dyes. This paper reviews the properties of Schiff bases and benefits of their use in various branches of industry.
Źródło:
Chemik; 2014, 68, 2; 129-134
0009-2886
Pojawia się w:
Chemik
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Antibacterial Activities of Some Transition Metal Schiff Base Complexes
Autorzy:
Islam, M.N.
Shahriar, S.M.S.
Islam, M.K.
Jesmin, M.
Ali, M.M.
Khanam, J.A.
Powiązania:
https://bibliotekanauki.pl/articles/411780.pdf
Data publikacji:
2013
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
antibacterial activity
Schiff base transition metal complexes
minimum inhibitory concentration
Brine shrimp lethality
Opis:
A new series of four transition metal complexes of a Schiff base derived from salicylaldehyde and glycine, viz. [N-salicylidene glycinato diaqua cobalt (II) dimer] (SGCo)2, [N- salicylideneglycinato-di-aqua-nickel(ll)dimer] (SGN)2, [N-salicylideneglycinato-aqua-copper(II)] (SGC) and [N-salicylidene glycinato diaqua zinc(II) dimer] (SGZ)2 have been synthesized and characterized through a rapid, simple, and efficient methodology in excellent yield. These compounds were screened for in vitro antibacterial activities against six pathogenic bacteria, such as Shigella sonnei, Escherichia coli, Bacilus subtilis, Sarcina lutea, Staphylococcus aureus and Pseudomonas arioginosa. The antibacterial activity was determined by the disc diffusion method using DMSO as solvent. The results indicate that (SGC) compound exhibit a significant antibacterial activity, depending on the bacterial strain and (SGCo)2, (SGN)2 and (SGZ)2 compounds show a moderate sensitivity even with higher doses. All these compounds were found to possess cytotoxic effect.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2013, 5; 12-20
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 27

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