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Tytuł:
Numerical Modelling of Phase Diagrams of Copper Alloys for Optimization of Semi-Solid Forming
Autorzy:
Madetko, Arkadiusz
Sołek, Krzysztof
Drożdż, Paweł
Powiązania:
https://bibliotekanauki.pl/articles/28099580.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Czasopisma i Monografie PAN
Tematy:
thixoforming
thermodynamic calculations
copper alloys
phase diagram
Opis:
Processing of metal alloys in semi-solid state is a way of producing many near net-shape parts and nowadays is commercially successful. Particular behaviour of alloys in the partially liquid state, having non-dendritic microstructure, is a base for thixoforming processing. Processing materials in the semi-solid state concerns alloys with relatively wide solidification range. Thermodynamic modelling can be used as a one of a potential tools that allow to identify alloys with proper temperature range. It means that the key feature of alloys suitable for thixoforming is a widely enough melting range, allowing for precise control of material temperature. The data gathered from thermodynamics calculations can also pay off in the industrial thixoforming processes design. The goal of this paper is to identify copper alloys which can be successfully shaped in the semi-solid state. Apart to thermodynamic calculations, the observations on high temperature microscope was carried out. During experiments the solidus, liquidus and also deformation temperatures can be determined. An experimental work allows confirming results obtained within the confines of thermodynamic calculations and firstly to determine the deformation temperatures which are the optimal for shaping processes. The basic achievement of this work is an identification of copper alloy groups possible for shaping in the semi-solid state. At the first part of the paper, the basic criteria of suitable alloys were described. Next, both the solid fraction curves for copper alloys with different alloying elements using ProCAST software and the phase diagrams were determined to identify the solidification temperature ranges of these alloys. In the second part of these paper, the identification of the deformation temperatures was carried out with use of high temperature microscope observation.
Źródło:
Archives of Metallurgy and Materials; 2023, 68, 2; 689--696
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Performance of cryogenic oxygen production unit with exhaust gas bleed for sewage sludge gasification and different oxygen purities
Autorzy:
Kaszuba, Maja
Ziółkowski, Paweł
Mikielewicz, Dariusz
Powiązania:
https://bibliotekanauki.pl/articles/27312208.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Czasopisma i Monografie PAN
Tematy:
thermodynamic analysis
oxy-combustion of syngas
BECCS
cryogenic air separation
penalty production
oxygen production
Opis:
The paper presents a thermodynamic analysis of the integration of a cryogenic air separation unit into a negative CO2 emission gas power plant. The power cycle utilizes sewage sludge as fuel so this system fits into the innovative idea of bioenergy with carbon capture and storage. A cryogenic air separation unit integrated with the power plant was simulated in professional plant engineering and thermodynamic process analysis software. Two cases of the thermodynamic cycle have been studied, namely with the exhaust bleed for fuel treatment and without it. The results of calculations indicate that the net efficiencies of the negative CO2 emission gas power plant reach 27.05% (combustion in 95.0% pure oxygen) and 24.57% (combustion in 99.5% pure oxygen) with the bleed. The efficiencies of the cycle without the bleed are 29.26% and 27.0% for combustion in 95.0% pure oxygen and 99.5% pure oxygen, respectively. For the mentioned cycle, the calculated energy penalty of oxygen production was 0.235 MWh/kgO2 for the lower purity value. However, for higher purity namely 99.5%, the energy penalty of oxygen production for the thermodynamic cycle including the bleed and excluding the bleed was indicated 0.346 and 0.347 MWh/kgO2, respectively. Additionally, the analysis of the oxygen purity impact on the carbon dioxide purity at the end of the carbon capture and storage installation shows that for the case with the bleed, CO2 purities are 93.8% and 97.6%, and excluding the bleed they are 93.8% and 97.8%, for the mentioned oxygen purities respectively. Insertion of the cryogenic oxygen production installation is required as the considered gas power plant uses oxy-combustion to facilitate carbon capture and storage method.
Źródło:
Archives of Thermodynamics; 2023, 44, 3; 63--81
1231-0956
2083-6023
Pojawia się w:
Archives of Thermodynamics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Processing of phosphorites with extraction of phosphorus, obtaining calcium carbide and ferroalloy
Autorzy:
Shevko, Victor M.
Uteyeva, Raisa A.
Badikova, Alexandra D.
Tleuova, Saltanat T.
Powiązania:
https://bibliotekanauki.pl/articles/27323638.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
phosphorite
thermodynamic modeling
electrical melting
phosphorus
calcium carbide
ferroalloy
Opis:
The article considers the results of studying the thermodynamic computer modeling of the interaction of phosphorite (Karatau basin, Kazakhstan) with carbon and coke performed using the HSC-10 software package and electric smelting of the phosphorite with coke and steel shavings in an arc furnace. The modeling allowed us to determine the equilibrium extraction degrees of phosphorus into gas (Р2, Р4), silicon into ferroalloy in the form of iron silicides (FeSi2, FeSi, Fe3Si, Fe5Si3, Si) and calcium into CaС2. At temperatures above 1500 °C, regardless of the amount of iron, the extraction degree of phosphorus into gas is more 99%. The resulting ferroalloy contains 21.2-23.8% of Si, 1.6-2.8% of Al; the calcium carbide has a capacity of 288-325 dm3/kg. The extraction degree of silicon into the alloy was 89.8%, calcium in CaC2 – 72.5%, phosphorus into gas – 99.4%. The ferroalloy, formed at the electric smelting of the Chulaktau phosphorite together with coke and steel shavings and containing 24.9-29.8% of Si, is FS25 grade ferrosilicon, and the formed calcium carbide has a capacity of 278-290 dm3/kg and belongs to the third and second grades. The developed technology makes it possible to increase the degree of phosphorites’ comprehensive use two times (up to 87.5%).
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 6; art. no. 174463
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Theoretical and experimental substantiation of obtaining an alloy from flotation tailings of lead-zinc sulfide ore
Autorzy:
Shevko, Victor M.
Makhanbetova, Baktygul A.
Aitkulov, Dosmurat K.
Powiązania:
https://bibliotekanauki.pl/articles/2200342.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
lead-zinc ore
cinder
enrichment tailings
thermodynamic modeling
electric melting
ferrosilicon
lead-zinc sublimates
Opis:
The article presents the results of thermodynamic and experimental research on the processing of cinders from the firing of Shalkiya deposit lead-zinc ore tailings with the production of siliceous ferroalloys. Thermodynamic modeling carried out using the HSC-6.0 complex based on the Gibbs energy minimization principle showed that the interaction occur with the formation of CaSiO3, FeSiO3, MgSiO3, K2OˑSiO2, FeSi, Fe5Si3, SiC, Fe3Si, Si, SiOg, FeSi2.33, FeSi2, CaSi, Zn, Zng, Pb, Pbg; an increase in the iron amount in the system allows increasing the silicon extraction degree into the alloy at 1800°C to 76%, to reduce the silicon concentration in the alloy from 41 to 24%; FS25 grade ferrosilicon formed at 1752-1867°C in the presence of 88-100% iron, and FS45 grade ferrosilicon – at 1863-1900°C and 20-22.4% iron. Electric melting of a charge containing 63.83% calcined cinder of tailings, 19.15% coke, and 17.02% steel chips allows to obtain FS45 grade ferrosilicon (44.1-43.9% Si) with the extraction of 69.7% silicon and sublimates with the content of 32-38% zinc and lead. The results obtained allow complex processing of lead-zinc sulfide ore tailings with the extraction of not only non-ferrous metals, but also silicon in the ferroalloy.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 1; art. no. 161853
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermodynamic Phase Diagram and Phonon stability, Electronic and Optical Properties of FeVSb: A DFT study
Autorzy:
Bagheri, A.
Boochani, A.
Masharian, S. R.
Jafarpour, F. H.
Powiązania:
https://bibliotekanauki.pl/articles/2203753.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
DFT
thermodynamic phase diagram
phonon
electronic properties
optical properties
Opis:
Mechanical, electronic, thermodynamic phase diagram and optical properties of the FeVSb half-Heusler have been studied based on the density functional theory (DFT) framework. Studies have shown that this structure in the MgAgAs-type phase has static and dynamic mechanical stability with high thermodynamic phase consistency. Electronic calculations showed that this compound is a p-type semiconductor with an indirect energy gap of 0.39 eV. This compound’s optical response occurs in the infrared, visible regions, and at higher energies its dielectric sign is negative. The Plasmon oscillations have occurred in 20 eV, and its refraction index shifts to zero in 18 eV.
Źródło:
Archives of Metallurgy and Materials; 2023, 68, 1; 331--338
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
45 Years of Deliberations on the Thermo-Mechanical Interpretation of Friction and Wear. Part I: The Macroscopic Interpretation of the Tribological Process 4
45 lat rozważań o cieplno-mechanicznej interpretacji tarcia i zużywania. Część I: interpretacja makroskopowa procesu tribologicznego
Autorzy:
Sadowski, Jan
Powiązania:
https://bibliotekanauki.pl/articles/2134813.pdf
Data publikacji:
2022
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
thermodynamic system
friction couple
friction area
extensive parameters
wear
dissipation heat
work of mechanical dissipation
enthalpy
internal energy
specific work of wear
first law of thermodynamics
system termodynamiczny
para tarciowa
strefa tarcia
parametr ekstensywny
praca tarcia
zużywanie
ciepło dyssypacji
praca dyssypacji mechanicznej
entalpia
energia wewnętrzna
praca właściwa zużycia
pierwsza zasada termodynamiki
Opis:
This first part will consider the friction couple or its part, identified with the open thermodynamic system. Dependences among extensive parameters and energetic interactions in the system and its boundaries with the environment are described in analytical terms. The dimensions of the energy dissipation zone, where the friction of solids takes place, are established. The thermo-mechanical nature of the tribological process is demonstrated. The wear conditions and distribution of energy generated by its particular elements are determined. A new quantity is introduced – the specific work of wear, which characterises the wear resistance of the tribological system and its parts. The effect of the reciprocal cover of solids’ friction surfaces on the energy balance structure in calorimetric testing is analysed. The concept of generalised wear is introduced and standardised. The discussion is restricted to processes at the macroscopic level of matter organisation.
Przedmiotem rozważań w pierwszej części pracy jest para tarciowa lub jej fragment utożsamiona z systemem termodynamicznym otwartym. Opisano analitycznie zależności między parametrami ekstensywnymi i oddziaływaniami energetycznymi w systemie i na jego graniach z otoczeniem. Ustalono wymiary strefy dyssypacji energii, w której zachodzi tarcie ciał stałych. Wykazano cieplno-mechaniczną naturę procesu tribologicznego. Ustalono warunki zachodzenia zużywania i rozdziału energii rozproszonej przez poszczególne jego elementy. Wprowadzono nową wielkość – pracę właściwą zużycia, charakteryzującą odporność na zużywanie systemu tribologicznego i jego elementów. Zanalizowano wpływ wzajemnego przykrycia powierzchni tarcia ciał na strukturę bilansu energii w badaniach kalorymetrycznych. Wprowadzono pojęcie zużycia uogólnionego i jego standaryzację. Rozważania ograniczono do procesów zachodzących na makroskopowym poziomie hierarchicznym organizacji materii.
Źródło:
Tribologia; 2022, 2; 55--66
0208-7774
Pojawia się w:
Tribologia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption of CO2 by surface modified coal-based activated carbons: kinetic and thermodynamic analysis
Autorzy:
Xinzhe, Liu
Mingyang, Zhang
Juan, Chen
Zhengyu, Hu
Shuaifei, Xian
Mingxuan, Tang
Chenchen, Zhang
Powiązania:
https://bibliotekanauki.pl/articles/2174813.pdf
Data publikacji:
2022
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
Surface modification
CO2 adsorption capacity
adsorption kinetics
thermodynamic parameters
Opis:
The effects of different surface modifiers on the CO2 adsorption capacity of coal-based activated carbons were studied, and the diffusion behavior, adsorption kinetics and thermodynamic parameters of CO2 in activated car-bons were analyzed. The results show that compared with ethylene glycol, 1,2-propylenediamine and zinc chloride, potassium hydroxide and sodium hydroxide can greatly improve CO2 adsorption capacity. The adsorption rate is faster, and the adsorption capacity is larger, with the maximum CO2 adsorption capacity being 33.54 mL/g. Fick’s law can well describe the diffusion behavior of CO2 in activated carbon. The addition of a surface modifier can increase the diffusion coefficient. The diffusion of CO2 in activated carbon falls into the category of crystal diffusion. The adsorption kinetics of CO2 before and after surface modification follow the Bangham equation. During the adsorption process, δ H < 0, δ G < 0, δ S < 0. Surface modification can reduce adsorption heat and promote adsorption, and the adsorption process is dominated by physisorption.
Źródło:
Polish Journal of Chemical Technology; 2022, 24, 3; 19--28
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analiza termodynamiczna i ekonomiczna hierarchicznej dwuobiegowej elektrowni jądrowej z dwustopniowym rozprężaniem i dwustopniowym sprężaniem w obiegu Joule’a w zakresie wysokich temperatur
Autorzy:
Bartnik, Ryszard
Powiązania:
https://bibliotekanauki.pl/articles/2096866.pdf
Data publikacji:
2022
Wydawca:
Nowa Energia
Tematy:
analiza termodynamiczna
elektrownia jądrowa
wysokie temperatury
thermodynamic analysis
nuclear power plant
high temperatures
Opis:
W pracach [1, 2, 3] przedstawiono termodynamiczną i ekonomiczną analizę innowacyjnej, hierarchicznej elektrowni jądrowej z jednym, chłodzonym helem wysokotemperaturowym reaktorem HTGR (rys. 1). W elektrowni realizowane są dwa obiegi Joule’a, jeden wysokotemperaturowy, drugi niskotemperaturowy. Oba obiegi charakteryzują się pojedynczymi stopniami rozprężania i sprężania helu. W niniejszej pracy przedstawiono natomiast analizę termodynamiczną i ekonomiczną elektrowni z dwoma wysokotemperaturowymi reaktorami HTGR (rys. 2).
Źródło:
Nowa Energia; 2022, 1; 82-94
1899-0886
Pojawia się w:
Nowa Energia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analiza termodynamiczna i ekonomiczna hierarchicznej elektrociepłowni gazowo-gazowej sprzęgniętej ze sprężarkową pompą ciepła
Autorzy:
Bartnik, Ryszard
Powiązania:
https://bibliotekanauki.pl/articles/31804076.pdf
Data publikacji:
2022
Wydawca:
Nowa Energia
Tematy:
analiza termodynamiczna
analiza ekonomiczna
elektrociepłownia gazowa
sprężarkowa pompa ciepła
thermodynamic analysis
economic analysis
gas power plant
compressor heat pump
Opis:
W pracy [1] przedstawiono analizę termodynamiczną i ekonomiczną hierarchicznych elektrowni i elektrociepłowni gazowo-gazowych (rys. 1). W [2] zaprezentowano ich pracę trójgeneracyjną z wykorzystaniem ziębiarek cieplnych i sprężarkowych.
Źródło:
Nowa Energia; 2022, 4; 86-100
1899-0886
Pojawia się w:
Nowa Energia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analiza termodynamiczna i ekonomiczna wpływu objętości akumulatora ciepła na jednostkowy koszt produkcji ciepła w elektrociepłowni gazowo-parowej
Autorzy:
Bartnik, Ryszard
Buryn, Zbigniew
Hnydiuk-Stefan, Anna
Powiązania:
https://bibliotekanauki.pl/articles/31804085.pdf
Data publikacji:
2022
Wydawca:
Nowa Energia
Tematy:
analiza termodynamiczna
analiza ekonomiczna
akumulator ciepła
produkcja ciepła
elektrociepłownia gazowo-parowa
thermodynamic analysis
economic analysis
heat accumulator
heat production
gas-steam combined heat and power plant
Opis:
Wysoka cena gazu ziemnego (szczególnie obecnie podyktowana imperialną polityką Niemiec i Rosji), którego koszt może zatem nawet przekraczać 70-75% rocznych kosztów działania elektrociepłowni gazowo-parowych [6], powoduje często nieopłacalność ekonomiczną ich zastosowania (rys. 4, 5). Opłacalność tę można poprawić przez zastosowanie w nich akumulatorów ciepła (rys. 5). Dzięki nim w sezonie ogrzewczym w szczycie potrzeb Krajowego Systemu Elektroenergetycznego (KSE) produkowana będzie w elektrociepłown dodatkowa ilość energii elektrycznej, a w sytuacji zmniejszonego na nią zapotrzebowania w dolinie obciążenia KSE będzie miało miejsce jej obniżenie.
Źródło:
Nowa Energia; 2022, 3; 64-79
1899-0886
Pojawia się w:
Nowa Energia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Constructional changes of pneumopercussion machines for improving their efficiency
Autorzy:
Antonchik, Volodymyr
Zabolotnyi, Kostiantyn
Hankevich, Valentyn
Maltseva, Vira
Kuts, Oleksandra
Dyczko, Artur
Powiązania:
https://bibliotekanauki.pl/articles/27324346.pdf
Data publikacji:
2022
Wydawca:
Instytut Techniki Górniczej KOMAG
Tematy:
pneumopercussion machines
thermodynamic processes
hammer
compressed air
Opis:
Pneumopercussion machines (pneumatic impact machines) are widely used in all areas of human activity. Also, they are widely used in the mining industry. Unfortunately, their operation is characterized by a low efficiency of compressed air energy usage. In some cases, this level of efficiency is calculated as 15-20%. Such a situation increases the cost of drilling operations significantly. In this article, due to an implementation of a new construction of the equipment, the efficiency of the pneumopercussion machines was increased. This problem is solved by combining the most effective thermodynamic processes of compressed air in the working chambers of machines. Also, a new technical solution for the construction of pneumopercussion machines is suggested by the Authors. The proposed new design is realized by a combination of the most effective thermodynamic processes in the chambers of pneumatic impact machines. A new pneumatic hammer is presented, which allows to reduce compressed air consumption twice during an operation on the surface (in comparison with hammers available on the market). The operation of pneumopercussion machines and the method of calculating geometric parameters are described. The economic performance of the equipment confirms the correctness of the proposed technological solutions.
Źródło:
Mining Machines; 2022, 40, 4; 206--215
2719-3306
Pojawia się w:
Mining Machines
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Energy Infiltration Effect and Energy Body : a Unique Criterion for Building Thermal Insulation
Efekt infiltracji energii i bryła energetyczna : osobliwe kryterium ciepłochronności budynków
Autorzy:
Bieranowski, Piotr
Powiązania:
https://bibliotekanauki.pl/articles/2073835.pdf
Data publikacji:
2022
Wydawca:
Wojskowa Akademia Techniczna im. Jarosława Dąbrowskiego
Tematy:
heat transfer coefficient
heat accumulation
resistance
thermodynamic criterion
współczynnik przenikania ciepła
akumulacja ciepła
rezystancja
kryterium termodynamiczne
Opis:
This publication is provided with the author’s suggestions regarding modification of the basic criterion – heat transfer coefficient. According to the author, the basic criterion of building thermal protection should be extended in such a manner that it will be simple and easy to evaluate a building’s capacity to recover thermal energy accumulated in the wall structure.
W publikacji zamieszczono autorskie propozycje modyfikacji podstawowego kryterium, jakim jest współczynnik przenikania ciepła. Zadaniem autora powinno się rozbudować podstawowe kryterium ochrony cieplnej budynków, tak, aby w podstawowy i łatwy sposób można było ocenić zdolność obudowy budynku do odzysku energii cieplnej – zakumulowanej w konstrukcji ściany.
Źródło:
Problemy Mechatroniki : uzbrojenie, lotnictwo, inżynieria bezpieczeństwa; 2022, 13, 1 (47); 79--92
2081-5891
Pojawia się w:
Problemy Mechatroniki : uzbrojenie, lotnictwo, inżynieria bezpieczeństwa
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Modeling, exergy analysis and optimization of cement plant industry
Autorzy:
Abutorabi, Hossein
Kianpour, Ehsan
Powiązania:
https://bibliotekanauki.pl/articles/2106427.pdf
Data publikacji:
2022
Wydawca:
Politechnika Koszalińska. Wydawnictwo Uczelniane
Tematy:
exergy
organic Rankine cycle
thermodynamic analysis
cement plant
egzergia
organiczny cykl Rankine'a
analiza termodynamiczna
cementownia
Opis:
This study investigates the recovery of wasted heat in the cement plant industries (Neka Cement Factory) in order to reduce the use of fossil fuels and greenhouse gas emissions. Cement is the most widely used man-made material. The global cement industry produces about 3.3 billion tons of cement annually. A lot of energy is needed to produce cement. About 200 kg of coal is used to produce each ton of cement. The cement industry also produces about five percent of the world's greenhouse gases. The method studied in this research is based on heat recovery from boilers installed at the outlet of a clinker cooler and a preheater in a cement factory. Due to the low temperature of the gases available, three different fluids, i.e. water, R134a and R245fa were considered as the operating fluids. Also, energy and exergy analyses are performed in a Rankin cycle and the selection of optimal parameters is considered by using genetic algorithm. The results of this study showed that water with optimized parameters leads to an increase in the production capacity from 5 to 9 MW. However, fluid R134a with optimized parameters leads to a 4% increase in exergy losses and it also increases the production capacity from 5 to 9 MW.
Źródło:
Journal of Mechanical and Energy Engineering; 2022, 6, 1; 55--66
2544-0780
2544-1671
Pojawia się w:
Journal of Mechanical and Energy Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermodynamic Analysis and Mathematic Modeling of Waste Sludge from Drinking Water Treatment Plants
Autorzy:
Azeddine, Fantasse
El Khadir, Lakhal
Ali, Idlimam
Powiązania:
https://bibliotekanauki.pl/articles/2026746.pdf
Data publikacji:
2022
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
drinking water sludge
sludge valorization
wastewater management
thermodynamic analysis
isosteric heat
Opis:
Water treatment annually produces a huge amount of Drinking Water Treatment Sludge (DWTS) wastes. The latter causes environmental problems in Morocco in terms of energy and pollution. Therefore, cost-effective and eco-friendly solutions for managing them should be proposed in order to reduce the frequency of storage along with transportation costs. In this paper, a thermodynamic analysis of DWTS wastes was conducted based on the isosteric heat and compensation theory. Different results concerning the mineralogical identification of sludges were established. Findings revealed that the by-product of water purification was mainly composed of aluminum, silica and iron hydroxides, with pH varying between 6.23 and 6.85. The suspended matter was between 18.3 and 19.6 m/l. The volatile matter of the three sludge samples was between 18 and 21%. The measured dry matter content was between 13.41 and 15.23%. The experimental tests were performed under temperatures from 45 and 60 °C, the experimental data of the sorption curves were fitted by using several models of correlation. Furthermore, the analysis showed that the Peleg’s model perfectly described the isotherm curves in the activities ranging from 0 to 90%. The net isosteric heats of sorption of the three hydroxide sludge from the Moroccan treatment station: $S_k$, $S_m$ and $S_s$, were determined for desorption and adsorption. Moreover, it was revealed that the equilibrium water content rising lead contributed to the reduction of the net isosteric heat and the entropy of sorption. Finally, the enthalpy-entropy compensation showed that the sorption mechanism involved was enthalpy driven.
Źródło:
Journal of Ecological Engineering; 2022, 23, 2; 140-149
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermodynamic Analysis of Precipitation Process of Complex Carbonitride TixV1-xCyN1-y in HSLA-Type Steel
Autorzy:
Wojtacha, Anna
Opiela, Marek
Powiązania:
https://bibliotekanauki.pl/articles/2201794.pdf
Data publikacji:
2022
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
carbonitride
thermodynamic model
HSLA-type steel
microstructure
Opis:
The paper presents a detailed analysis of the MX-type interstitial phase precipitation process and a thermodynamic analysis of the TixV1-xCyN1-y carbonitride precipitation in austenite. The subject of research analysis was the newly developed HSLA-type steel containing 0.175% C, 1.02% Si, 1.87% Mn, 0.0064% N, 0.22% Mo, and microadditions 0.022% V and 0.031% Ti. Analysis of the process of precipitation of MX interstitial phases under thermodynamic equilibrium conditions proved that the first phase that precipitates in the austenite of the tested steel is TiN-type nitride. The onset temperature of this phase was 1450°C. Subsequently, carbides of the TiC-type, VN-type nitrides and VC-type carbides, for which the precipitation onset temperatures were 1180°C, 870°C and 775°C will be released, respectively. The analysis of the precipitation process of the complex carbonitride in austenite under thermodynamic equilibrium conditions was based on the Hillert and Staffansson model, developed by Adrian, with the use of the CarbNit computer program. The beginning of carbonitride precipitation with the stoichiometric composition Ti0.985V0.015C0.073N0.927 occurred at the temperature of 1394°C. At 850°C practically all of the Ti is bound in the carbonitride of the stoichiometric composition Ti0.883V0.117C0.378N0.622. At the same temperature, a significant part of microaddition V will be dissolved in austenite, which means that vanadium will have a lesser effect on the formation of a fine-grained austenite structure, but more strongly on the precipitation hardening of steel by the dispersion VN and V particles (C,N) released during the cooling of the products.
Źródło:
Advances in Science and Technology. Research Journal; 2022, 16, 4; 64--73
2299-8624
Pojawia się w:
Advances in Science and Technology. Research Journal
Dostawca treści:
Biblioteka Nauki
Artykuł

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