- Tytuł:
-
Synteza i zastosowanie styrylopochodnych arenów, karbazolu i ferrocenu w projektowaniu e-stereoregularnych krzemoorganicznych materiałów hybrydowych
Synthesis and application of styryl derivatives of arenes, carbazol and ferrocene for designing e-stereoregular organosilicon hybrid materials - Autorzy:
- Majchrzak, Mariusz
- Powiązania:
- https://bibliotekanauki.pl/articles/1413279.pdf
- Data publikacji:
- 2021
- Wydawca:
- Polskie Towarzystwo Chemiczne
- Tematy:
-
kataliza
sprzęganie Suzuki
sililujące sprzęganie
materiały hybrydowe
polimery
catalysis
Suzuki coupling
silylative coupling
hybrid materials
polymers - Opis:
- The potential for expanding the variety of catalytic methods for carbon-carbon bond formation is being currently explored in many research centres all over the world. An increasing use of selected d-block metals as catalysts in the synthesis has brought new methods of functionalization of organic and organometallic compounds of great importance for development of polymer chemistry and organic chemical technology [5, 6]. This work describes very precise and controlled catalytic transformations as useful tools for the synthesis of new E-conjugated organic, organosilicon molecular and polymeric compounds. The combination of Suzuki-Miyaura coupling and silylative coupling reactions as a simple and efficient method is established for designing new E-stereoregular hybrid materials in the presence of well-defined transition metal (TM) catalysts. All presented compounds can be interesting precursors for a further functionalization that may significantly increase the possibility of their application in the design and synthesis of new functional materials.
- Źródło:
-
Wiadomości Chemiczne; 2021, 75, 1-2; 137-162
0043-5104
2300-0295 - Pojawia się w:
- Wiadomości Chemiczne
- Dostawca treści:
- Biblioteka Nauki
Artykuł