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    Wyświetlanie 1-7 z 7
    Tytuł:
    Effect of coexisting sodium ion extractive separation of metal ions with calix[4]arene tetracarboxylic acid
    Autorzy:
    Ohto, K.
    Shioya, A.
    Higuchi, H.
    Oshima, T.
    Inoue, K.
    Powiązania:
    https://bibliotekanauki.pl/articles/346949.pdf
    Data publikacji:
    2002
    Wydawca:
    Politechnika Bydgoska im. Jana i Jędrzeja Śniadeckich. Wydział Technologii i Inżynierii Chemicznej
    Tematy:
    calix[4]arene
    metal separation
    solvent extraction
    coexisting sodium ion
    Opis:
    Solvent extraction of metal ions with calix[4]arene tetracarboxylic acid has been carried out to elucidate effect of coexisting sodium ion. Extraction of metal ions examined, Pb(II), Fe(III), Cu(II), Zn(II), Ni(II), and Co(II), is enhanced by the addition of sodium ion. The enhancement degree of the metal extraction is not necessarily in proportion to the added sodium concentration. The addition of trace amount of sodium ion is necessary to specifically complex for calix[4]arene tetracarboxylic acid and to enhance the extraction ability. However, the addition of excessive amounts of sodium suppresses the extraction of other metal ions, since they act as a competitive ion with other metal ions; The relation between extractive pH1/2 of metal ions and sodium concentration is shown. Mutual separation of metal ions by using additional sodium ion is also investigated. Although complete mutual separation of three metal ions, Pb(II), Cu(II), and Zn(II), has not been achieved, the possibility that the sodium addition will enhance not only the extraction ability but also the separation efficiency is suggested.
    Źródło:
    Ars Separatoria Acta; 2002, 1; 61-70
    1731-6340
    Pojawia się w:
    Ars Separatoria Acta
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Electrochemical Properties of Flexible Anode with SnO2 Nanopowder for Sodium-Ion Batteries
    Autorzy:
    Kim, Huihun
    Sadan, Milan K.
    Kim, Changhyeon
    Choi, Ga-In
    Seong, Minjun
    Cho, Kwon-Koo
    Kim, Ki-Won
    Ahn, Jou-Hyeon
    Ahn, Hyo-Jun
    Powiązania:
    https://bibliotekanauki.pl/articles/2049149.pdf
    Data publikacji:
    2021
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    word
    sodium-ion batteries
    SnO2 anode
    flexible electrode
    nano SnO2 particles
    ether based electrolyte
    Opis:
    Sodium-ion batteries (SiBs) have attracted substantial interest as an alternative to lithium-ion batteries because of the low cost. There have been many studies on the development of new anode materials that could react with sodium by conversion mechanism. SnO2 is a promising candidate due to its low cost and high theoretical capacity. However, SnO2 has the same problem as other anodes during the conversion reaction, i.e., the volume of the anode repeatedly expands and contracts by cycling. Herein, anode is composed of carbon nanofiber embedded with SnO2 nanopowder. The resultant electrode showed improvement of cyclability. The optimized SnO2 electrode showed high capacity of 1275 mAh g-1 at a current density of 50 mA g-1. The high conductivity of the optimized electrode resulted in superior electrochemical performance.
    Źródło:
    Archives of Metallurgy and Materials; 2021, 66, 4; 931-934
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Changes in ion (K, Ca and Na) regulation, antioxidant enzyme activity and photosynthetic pigment content in melon genotypes subjected to salt stress - a mixture modeling analysis
    Autorzy:
    Erdinc, C.
    Powiązania:
    https://bibliotekanauki.pl/articles/11885877.pdf
    Data publikacji:
    2018
    Wydawca:
    Uniwersytet Przyrodniczy w Lublinie. Wydawnictwo Uniwersytetu Przyrodniczego w Lublinie
    Tematy:
    Turkey
    arid habitat
    semi-arid habitat
    plant cultivation
    muskmelon
    Cucumis melo
    plant genotype
    antioxidant enzyme
    photosynthetic pigment content
    calcium ion
    potassium ion
    sodium ion
    salt stress
    Opis:
    The present study aimed to identify the response of melon accessions and cultivars to salt stress in terms of ion exchange, enzyme activity, lipid peroxidation and photosynthetic pigment contents by mixture modelling. In mixture modeling, it is expected that the data set demonstrates a heterogeneous structure. This heterogeneity is characterized as unobservable heterogeneity. The data set’s heterogeneity produces severe deviations in the parameter assessments and the standard deviations. Heterogeneity is overcome when the data set separates itself into homogeneous sub-populations. Mixture modeling was performed using the Mclust mixture cluster program of the statistical software package R 5.2.3. Sub-populations were constructed by evaluating genotypes according to studied traits and correlation analysis was performed using the SPSS software package. The seedlings of 13 melon genotypes were harvested two weeks after salt application (0 mM or 50 mM NaCl) when symptoms of salt stress were observed. Nutrient contents and ratios (K, Ca, Na, K : Na and Ca : Na); superoxide dismutase (SOD), catalase (CAT) and ascorbate peroxidase (APX) activities malondialdehyde (MDA) chlorophyll a, chlorophyll b, total chlorophyll and carotenoid contents were measured. Mixture modeling and correlation analysis were used in evaluating the experimental data sets. Differences in responses to salt application were observed among genotypes. While all genotypes exhibited negative responses in terms of K : Na ratio, which is an important parameter of salt tolerance, the smallest decreases in K : Na ratios were observed in the YYU-11 (–57.09%) and YYU-4 (–58.78%) genotypes, indicating them to be the most tolerant to salt stress. In general, enzyme activity decreased in response to salt application, although the responses varied among genotypes, especially with regard to CAT and APX activity. The YYU-29 genotype was notable as the genotype with the highest K : Na ratio (1.79) as well as the smallest change in MDA content under salt stress.
    Źródło:
    Acta Scientiarum Polonorum. Hortorum Cultus; 2018, 17, 1; 165-183
    1644-0692
    Pojawia się w:
    Acta Scientiarum Polonorum. Hortorum Cultus
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    The effect of Al(III) and Fe(III) ions on the flotation behavior of Kfeldspar with sodium oleate as the collector
    Autorzy:
    Chen, Yi
    Zhou, Jikui
    He, Guichun
    Hu, Hongxi
    Liu, Chao
    Yang, Jiping
    Lyu, Xianjin
    Powiązania:
    https://bibliotekanauki.pl/articles/27323648.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    K-feldspar flotation
    aluminum ion
    iron ion
    sodium oleate
    action mechanism
    Opis:
    The present study investigates the effects and mechanisms of aluminum (Al(III)) and iron (Fe(III)) ions on the flotation efficiency of potassium feldspar (K-feldspar) within oleate collector systems. The study employs micro-flotation experiments, solution chemistry calculations, zeta potential measurements, and FT-IR and XPS analyses to demonstrate that Al(III) and Fe(III) ions can significantly improve the flotation recovery of K-feldspar by altering its surface charge, bonding properties, and adsorption modes. The study also develops adsorption models for the flotation of K-feldspar activated by Al(III) and Fe(III), revealing the synergistic impacts of metal ion hydrolysis products and sodium oleate in the formation of hydrophobic complexes.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 6; art. no. 174724
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of manganese ions addition orders on the flotation behavior of scheelite
    Autorzy:
    Lu, Kuanwei
    Chen, Rong
    Zhang, Ying
    Luo, Hongying
    Yang, Hu
    Cai, Jiaozhong
    Powiązania:
    https://bibliotekanauki.pl/articles/1845215.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    manganese ion
    addition order
    scheelite
    sodium silicate
    flotation
    Opis:
    In this study, the effect of MnCl2 on scheelite flotation with sodium oleate (NaOL) as a collector and sodium silicate as a depressant was assessed by a combination of flotation experiments, Fouriertransform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and solution chemistry. The flotation experiments confirmed that the addition of MnCl2 before sodium silicate showed an adverse effect on flotation and the recovery of scheelite gradually decreased as the amount of MnCl2 was increased. When MnCl2 was added afte r sodium silicate, the recovery of scheelite gradually increased with an increase in the amount of MnCl2. The results of FTIR, XPS, and solution chemistry indicated that MnCl2 acted on the surface of scheelite in the form of manganese ions. When MnCl2 was added before sodium silicate, manganese ions adsorbed on the surface of scheelite reacted with sodium silicate to form a hydrophilic silicate, which covers the surface of scheelite and blocks the adsorption of NaOL. However, when MnCl2 was added after sodium silicate, manganese ions are continued to be adsorbed on the surface of scheelite, which increases the cations on the surface of scheelite, and hence the condition becomes conducive for the interaction between scheelite and NaOL.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2020, 56, 5; 860-873
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    The Method of Removal Yttrium (III) and Ytterbium (III) From Dilute Aqueous Solutions
    Autorzy:
    Lobacheva, O.
    Dzhevaga, N.
    Danilov, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/123428.pdf
    Data publikacji:
    2016
    Wydawca:
    Polskie Towarzystwo Inżynierii Ekologicznej
    Tematy:
    ion flotation
    sodium dodecyl sulfate
    distribution coefficient
    separation coefficient
    removal
    Opis:
    Yttrium (III) and ytterbium (III) cations ion flotation from diluted aqueous solutions in the presence of chloride ions using sodium dodecyl sulfate as collector agent were studied. Y (III) and Yb (III) distribution and recovery coefficients as a function of aqueous phase рН value at different sodium chloride concentrations were received. Yttrium (III) and ytterbium (III) chloro and hydroxo complexes instability constants were calculated. The calculation of separation coefficient at рН specified values depending on chloride ion concentration was conducted. Maximum separation coefficient was observed when chloride concentration of 0.01 M is 50 at рН 7.8. Ksep is minimal in nitrate medium ans is 3 at рН 7.0. At sodium chloride concentration of 0.05 М Ksep is 9 at рН 7.8.
    Źródło:
    Journal of Ecological Engineering; 2016, 17, 2; 38-42
    2299-8993
    Pojawia się w:
    Journal of Ecological Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Determination of moxifloxacin hydrochloride in AVELOX pharmacological formulations using modified potentiometer sensors
    Oznaczanie chlorowodorku moksyfloksacyny w formulacjach farmakologicznych AVELOX przy użyciu zmodyfikowanych czujników potencjometrycznych
    Autorzy:
    Kumar, Sachin
    Sindhu, Sushil K.
    Kumar, Praveen
    Sharma, Amit
    Sagadevan, Suresh
    Powiązania:
    https://bibliotekanauki.pl/articles/2088258.pdf
    Data publikacji:
    2021
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Chemii Przemysłowej
    Tematy:
    AVELOX
    moxifloxacin HCL
    ion-selective electrodes
    sodium tetraphenylborate
    phosphomolybdic acid
    phosphotungstic acid
    poly(vinyl chloride)
    potentiometry
    moksyfloksacyna HCL
    elektrody jonoselektywne
    tetrafenyloboran sodu
    kwas fosfomolibdenowy
    kwas fosfowolframowy
    poli(chlorek winylu)
    potencjometria
    Opis:
    Three different carbon paste (CP), silk-screen (SP) and poly (vinyl chloride) (PVC) modified electrodes were obtained to verify the reliability of AVELOX, the generic name of which is Moxifloxacin HCl (AV-MOXH). The sensing membranes were containing AVELOX ion associated complexes with sodium tetraphenylborate (NaTPB), phosphomolybdic acid (PMA), phosphotungstic acid (PTA), and ammonium reineckate (RN) as electroactive materials. All three electrodes gave fast, viable, and near-Nernstian linear responses over a relative wide concentration range that ranged from 1.010-6 to 1.010-2 mol/L AV-MOXH at 25°C with a monovalent cationic decrease. The sensors demonstrated a good discernment of AV-MOXH from numerous inorganic and organic compounds such as glucose, sucrose, Na+, Ca+, etc. Additionally, the isothermal coefficients along with selectivity coefficients were calculated. The modified Screen Printed Electrode sensor appeared to be highly sensitive for the determination of AV-MOXH. The electrode response was observed in pH range 2–6 for ISPE electrodes and IPVC electrodes and 3–7 for ICPE electrodes under various temperature conditions. The short response time, lifetime validity, recovery, and all the methods of validation such as limit of detection and limit of quantification were estimated. The potentiometric method turned out to be suitable for determining AV-MOXH in pharmacological formulations, and the findings obtained are comparable to the “HPLC official method” in terms of the agreement. As a result, the postulated potentiometric approach was verified in accordance with IUPAC guidelines.
    Otrzymano trzy różne elektrody modyfikowane pastą węglową (CP), sitodrukiem (SP) i polichlorkiem winylu (PVC), w celu oceny skuteczności działania leku AVELOX (nazwa rodzajowa Moxifloxacin HCl, AV-MOXH). Membrany czujników zawierały kompleksy jonu AVELOX z tetrafenyloboranem sodu (NaTPB), kwasem fosfomolibdenowym (PMA), kwasem fosfowolframowym (PTA) i soli Reineckego (RN) jako materiałami elektroaktywnymi. Wszystkie trzy elektrody dały szybkie i bliskie zależności liniowe Nernsta w zakresie stężeń AV-MOXH od 1.0-10-6 do 1.0-10-2 mol/l (w 25°C). Elektrody wykazały dobrą selektywność w oznaczaniu AV-MOXH względem wielu jonów i związków organicznych i nieorganicznych, jak glukoza, sacharoza, Na+, Ca+ itp. Dodatkowo obliczono współczynniki izotermiczne oraz współczynniki selektywności. Zmodyfikowany czujnik z elektrodą sitodrukową okazał się być bardzo czuły do oznaczania AV-MOXH. Badania prowadzono w zakresie pH 2–6 w przypadku elektrod ISPE i IPVC oraz 3–7 w przypadku elektrod ICPE w różnych temperaturach. Oszacowano czas odpowiedzi elektrod, ich czas życia, możliwość regeneracji, odzysk oraz granicę wykrywalności i granicę oznaczalności. Metoda potencjometryczna okazała się być odpowiednia do oznaczania AV-MOXH w preparatach farmakologicznych, a uzyskane wyniki są porównywalne z „oficjalną metodą HPLC”.
    Źródło:
    Polimery; 2021, 66, 11-12; 589--601
    0032-2725
    Pojawia się w:
    Polimery
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-7 z 7

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