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Wyświetlanie 1-10 z 17
Tytuł:
Pyromorphite formation from montmorillonite adsorbed lead
Autorzy:
Bajda, Tomasz
Marchlewski, Tomasz
Manecki, Maciej
Powiązania:
https://bibliotekanauki.pl/articles/2086508.pdf
Data publikacji:
2011
Wydawca:
Polskie Towarzystwo Mineralogiczne
Tematy:
sorption
desorption
immobilization
crystallization
apatite
smectite
Opis:
The reaction of Pb-adsorbed montmorillonite with aqueous solutions of PO4 and Cl ions results in the decrease in phosphate concentration associated with the formation of a new phase – pyromorphite Pb5(PO4)3Cl. Pyromorphite crystals range in size from hundreds of nm to several tens of μm, depending on the PO4, K, and Ca concentrations in the reacting system. A strong ion-exchange effect of K+ and Ca2+ cations on desorption of Pb2+ from Pb-adsorbed montmorillonite was observed. Also, a high concentration of cations leads to a rapid desorption of Pb and the formation of fine pyromorphite crystals. In contrast, low PO4, K and Ca concentrations result in the formation of relatively large euhedral crystals. Final Pb concentrations are much lower in experimental sets than in control experiments with no phosphate present.
Źródło:
Mineralogia; 2011, 42, 2/3; 75--91
1899-8291
1899-8526
Pojawia się w:
Mineralogia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Pyromorphite formation from montmorillonite adsorbed lead
Autorzy:
Bajda, T.
Marchlewski, T.
Manecki, M.
Powiązania:
https://bibliotekanauki.pl/articles/2086540.pdf
Data publikacji:
2011
Wydawca:
Polskie Towarzystwo Mineralogiczne
Tematy:
sorption
desorption
immobilization
crystallization
apatite
smectite
Opis:
The reaction of Pb-adsorbed montmorillonite with aqueous solutions of PO4 and Cl ions results in the decrease in phosphate concentration associated with the formation of a new phase – pyromorphite Pb5(PO4)3Cl. Pyromorphite crystals range in size from hundreds of nm to several tens of μm, depending on the PO4, K, and Ca concentrations in the reacting system. A strong ion-exchange effect of K+ and Ca2+ cations on desorption of Pb2+ from Pb-adsorbed montmorillonite was observed. Also, a high concentration of cations leads to a rapid desorption of Pb and the formation of fine pyromorphite crystals. In contrast, low PO4, K and Ca concentrations result in the formation of relatively large euhedral crystals. Final Pb concentrations are much lower in experimental sets than in control experiments with no phosphate present.
Źródło:
Mineralogia; 2011, 42, 2/3; 75--91
1899-8291
1899-8526
Pojawia się w:
Mineralogia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Degradation of nanoclay-filled polylactide composites
Autorzy:
Rapacz-Kmita, A.
Stodolak-Zych, E.
Dudek, M.
Szaraniec, B.
Rozycka, A.
Mosialek, M.
Mandecka-Kamien, L.
Powiązania:
https://bibliotekanauki.pl/articles/110832.pdf
Data publikacji:
2013
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
nanocomposite materials
food packaging
polymer
smectite clay
Opis:
Nanoclay-filled polylactide (PLA 3051D) composite materials were tested in this study and their capacity for degradation was investigated. Activated and lyophilized smectite clay was used. The filler, its morphology, and grain size distribution were characterized by the use of transmission electron microscopy, scanning electron microscopy, and the dynamic light scattering technique. Samples of pure polylactide and polylactide filled with 3% wt., 5% wt., and 10% wt. of nanoclay in subsequent series were obtained by injection molding. The optimum amount of the filler in the nanocomposites was evalu-ated based on an assessment of mechanical properties as well as capacity to degrade. The 3% wt. mass fraction of nanofiller in the polylactide matrix was found to be the most effective in enhancement of both tensile strength (RM) and Young’s Modulus (E). It was also reported that polylactide nanocomposites filled with 3% wt. of smectite clay were characterized by the highest decrease in molecular mass of the matrix polymer after degradation tests (6 weeks incubation in water at 80°C). The observed decrease in degradation time and the overall changes distinguished in the nanocomposite structure suggest the poten-tial for application of the material in the packaging industry.
Źródło:
Physicochemical Problems of Mineral Processing; 2013, 49, 1; 91-99
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Sferule z granicy Kreda-Paleogen (Lechówka, Polska) – wstępne dane
Spherules from the Cretaceous–Paleogene boundary (Lechówka, Polska) – preliminary data
Autorzy:
Brachaniec, Tomasz
Szopa, Krzysztof
Karwowski, Łukasz
Krzykawski, Tomasz
Salamon, Mariusz
Brom, Krzysztof
Powiązania:
https://bibliotekanauki.pl/articles/1033022.pdf
Data publikacji:
2015
Wydawca:
Polskie Towarzystwo Meteorytowe
Tematy:
Cretaceous–Paleogene boundary
impact origin
smectite
spherule
spinel
Opis:
Samples of boundary clay from Cretaceous–Paleogene deposits from Lechówka, Poland were examined for spherules to confirm the impact origin of the sediment. The chemical composition of investigated spherules show similarities to material from the K–Pg boundary from Stevns Klint. The impact genesis of the spherules is confirmed by the presence of nickel-rich spinel grains on their surfaces. The deposits with spherules are built by smectite with Al and Mg enrichment. This cheto smectite is forming as a result of the weathering of the impact glass.
Źródło:
Acta Societatis Metheoriticae Polonorum; 2015, 6; 17-22
2080-5497
Pojawia się w:
Acta Societatis Metheoriticae Polonorum
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characterization of barren, granitic soils from the Nubian Desert (SW Egypt) by 57Fe Mössbauer spectroscopy
Autorzy:
Hassan, Kamaleldin M.
Gunnlaugsson, Haraldur P.
Powiązania:
https://bibliotekanauki.pl/articles/127629.pdf
Data publikacji:
2013
Wydawca:
Polskie Towarzystwo Mineralogiczne
Tematy:
Egipt
granites
soils
Mössbauer
Fe oxides
vermiculite-chrorite
smectite
Opis:
57 Fe Mössbauer spectroscopy - a versatile technique involving the recoil-free, resonant absorption and emission of nuclear gamma (γ) rays by the iron-57 isotope in natural iron in solids - has been used to provide quantitative information about the mineral host, occupation sites and oxidation states of iron atoms in geological samples. This technique has been applied to the bulk chemistry of a barren soil (Soil A) derived from an aluminous-type granite and another barren soil (Soil B) derived from a sodic-type granite located ~ 100 kilometers apart in the Nubian Deseit in the currently hyper arid south-west of Egypt and which exhibit distinct chemical and mineral differences. The analyses indicate different mineral hosts for the iron in these samples, namely, vermiculite-chlorite plus some hematite in Soil A and hematite and goethite plus minor aegirines in Soil B. Each soil has distinct intensities of oxidized iron (89% for Soil A and 100% for Soil B) and these differences reflect changes in soil sources and processes.
Źródło:
Mineralogia; 2013, 44, 1/2; 39-50
1899-8291
1899-8526
Pojawia się w:
Mineralogia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Bentonite from the Central Slovakia Volcanic Field – A prospective raw material for Polish industry
Autorzy:
Górniak, Katarzyna
Szydłak, Tadeusz
Gaweł, Adam
Klimek, Agnieszka
Tomczyk, Anna
Motyka, Jerzy
Bahranowski, Krzysztof
Powiązania:
https://bibliotekanauki.pl/articles/127637.pdf
Data publikacji:
2017
Wydawca:
Polskie Towarzystwo Mineralogiczne
Tematy:
commercial bentonite
Central Slovakia Volcanic Field
petrography
smectite
microscopic imaging
Opis:
This paper summarizes information about recently worked bentonite deposits in Slovakia and presents the results of studies on bentonite from the Central Slovakia Volcanic Field (CSVF). The authors compared the mineralogy of commercial bentonites exploited in the Stara Kremnička (Jelšový potok), Kopernica, and Hliník nad Hronom deposits. X-ray diffraction (XRD), chemical analyses and microscopy showed that the main component is montmorillonite (37–88%), followed by opal C/CT (5–25%), clinoptilolite (up to 15%), feldspars (3–12%), quartz (up to 8%), biotite (2–5%), and kaolinite (up to 2%). The microscopic imaging provided information valuable for the technological assessment of bentonites, particularly the evaluation of mineralogy determined by XRD. The low variability of the mineral composition of commercial bentonites exploited in the western CSVF, together with the significant reserves and localization of deposits close to the Polish–Slovak state border prove that this raw material deserves more attention from Polish industry.
Źródło:
Mineralogia; 2017, 48, 1/4; 23-38
1899-8291
1899-8526
Pojawia się w:
Mineralogia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characterization and treatment of clayey waste using a sulfuric acid roasting-water leaching process for the extraction of lithium
Autorzy:
Obut, Abdullah
Aktosun, Zeynep
Girgin, İsmail
Deveci, Hacı
Yörükoğlu, Abdulkerim
Powiązania:
https://bibliotekanauki.pl/articles/2146902.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
Kırka boron plant
lithium
smectite
sulfuric acid roasting
water leaching
Opis:
In this study, a detailed characterization of the clayey waste of the Kırka boron plant was undertaken before the development of a sulfuric acid roasting-water leaching process for the extraction of lithium from this waste. The effects of roasting temperature (650-800°C) and sulfuric acid/waste ratio (90-260 kg H2SO4/1000 kg waste on a dry basis) on the extraction of lithium were investigated. By roasting the waste sample, which contained 0.37% Li2O with dolomite, smectite and borax as the main phases, at temperatures between 650°C and 800°C in the absence of sulfuric acid as the additive, CaMgSiO4 was found to form as the dominant phase after the decomposition of dolomite and smectite present in the sample. On the other hand, the X-ray diffraction analyses of the waste sample subjected to sulfuric acid treatment without roasting showed the in-situ formation of various hydrated calcium sulfate phases for all sulfuric acid/waste ratios tested. Besides, at the highest acid/waste ratio of 260, a hydrated magnesium sulfate phase was also identified in the sample. The application of the sulfuric acid roasting-water leaching process under the optimum roasting temperature of 750°C and the acid/waste ratio of 180 was found to lead to a lithium extraction of 85.7%. The applied sulfuric acid roasting-water leaching process appeared to be an attractive process with its attributes including low roasting temperature, high extraction percentage and no requirement for gypsum as the external sulfation agent.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 4; art. no. 149635
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
K-Ar dating of bentonite diagenesis in accretionary-wedge turbidites : case study from Western Outer Carpathians
Autorzy:
Świerczewska, A.
Paul, Z.
Banaś, M.
Tokarski, A. K.
Powiązania:
https://bibliotekanauki.pl/articles/191676.pdf
Data publikacji:
2015
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
Bentonites
illite-smectite
K-Ar dating
accretionary-wedge turbidites
Western Outer Carpathians
Opis:
Sixteen bentonite layers of Eocene–Oligocene age were sampled at thirteen sites in accretionary-wedge turbidite sequences, in the three innermost nappes of the Western Outer Carpathians. K-Ar dating was carried out for five of these layers to obtain the maximum burial ages. All of the ages obtained are older than the stratigraphic ages of the host strata. This relationship is due to significant contamination of the bentonites with non-authigenic minerals. This contamination resulted from rapid sedimentation during synsedimentary folding, which is a common feature in accretionary wedges. It follows that the K-Ar dating of bentonite layers in the turbidite sequences of accretionary wedges should be largely restricted to the very distal facies of turbidites or to pelitic intercalations within the turbidites.
Źródło:
Annales Societatis Geologorum Poloniae; 2015, 85, 1; 177-185
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fate of swelling clay minerals during early diagenesis: a case study from Gdańsk Bay (Baltic Sea)
Autorzy:
Kisiel, Marta
Skiba, Michał
Damrat, Mateusz
Kuligiewicz, Artur
Maj-Szeliga, Katarzyna
Makiel, Magdalena
Zajączkowski, Marek
Salata, Dorota
Powiązania:
https://bibliotekanauki.pl/articles/24264694.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
Smectite
chlorite
illite
reverse weathering
brackish environment
contemporary sediments
O-D method
Opis:
The aim of the study was to recognize the early diagenetic transformations of clay minerals likely taking place in the brackish environment of Gdańsk Bay (Baltic Sea). The Vistula River loads and sediments of the Vistula delta front and prodelta were studied. The mineral compositions of the clay fractions were determined by X-ray diffractometry. The average layer charge (LC) of the expandable interlayers was determined using the O-D vibrational spectroscopy method. The major element content of the studied clays was determined by inductively coupled plasma optical emission spectrometry. The <0.2 μm clay fraction, separated from the river sediments, contained illite-smectite mixed layered minerals, rich in high-charge, dioctahedral smectite (Ilt-Sme), illite, and kaolinite. The same clay fraction, separated from the delta-front sediments, was also composed mainly of Ilt-Sme, illite, kaolinite, and hydroxy-interlayered minerals. The <0.2 μm clay fraction from the prodelta sediments was depleted in Ilt-Sme and enriched in illite and chlorite, relative to the clays from both the river and the delta-front sediments. The LCs (0.45 to 0.56 per formula unit) were higher for clays from the river and the delta front sediments, relative to the clays from the prodelta. The <0.2 μm clay fractions from the prodelta sediments were enriched in MgO, Fe2O3, and K2O, relative to the fine clay fraction from the river. The results indicated that the smectite component of Ilt-Sme, deposited by the Vistula in Gdańsk Bay, underwent chloritization and likely illitization. The chloritization most likely proceeded via formation of hydroxy-interlayers within the smectite. Illite-like minerals, formed at the expense of the smectite with high LC, due to selective adsorption and fixation of K+ from seawater.
Źródło:
Annales Societatis Geologorum Poloniae; 2023, 93, 3; 305--322
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Porównanie właściwości adsorbentów: smektynu dwuoktanościennego i aktywowanego węgla leczniczego w terapii ostrej biegunki u dzieci
Dioctahedral smectite vs. activated charcoal in the treatment of acute diarrhoea in children
Autorzy:
Czerwionka-Szaflarska, Mieczysława
Adamska, Inga
Gawryjołek, Julia
Powiązania:
https://bibliotekanauki.pl/articles/1032459.pdf
Data publikacji:
2013
Wydawca:
Medical Communications
Tematy:
activated charcoal
children
diarrhea
smectite
treatment
biegunka
dzieci
aktywowany węgiel leczniczy
smektyn dwuoktanościenny
leczenie
Opis:
Acute infectious diarrhea is one of the most common causes of morbidity in the pediatric population, mostly of viral etiology. The disease is usually of self-limited course, and as treatment relievers are recommended. The most important part of the treatment are oral rehydration solutions. In the adjuvant treatment may be considered, inter alia, the use of adsorbents. In Poland, the most widely used adsorbents include activated charcoal and activated smectite. The binding capacity for bacterial toxins of the activated charcoal is not completely established, there is no clinical evidence of this action. In clinical studies the ability of smectite to adsorb viruses and bacterial toxins has been confirmed. Protective effect of smectite for stomach and intestines mucous membrane has also been well documented – because of these unique properties, smectite can be classified as second-generation adsorbent. According to current recommendations of ESPGHAN and ESPID from 2008, smectite is the only adsorbent of proven security, that used together with oral rehydration solutions increases the chances of reducing the duration of diarrhea.
Ostra biegunka infekcyjna jest jedną z najczęstszych przyczyn zachorowań w populacji dziecięcej, najczęściej o etiologii wirusowej. Choroba ma zazwyczaj przebieg samoograniczający się, a w terapii zalecane są leki objawowe. Za najważniejszy element leczenia uznaje się stosowanie doustnych płynów nawadniających. W leczeniu uzupełniającym można rozważyć między innymi stosowanie adsorbentów. W Polsce najczęściej stosowanymi adsorbentami są aktywowany węgiel leczniczy i smektyn dwuoktanościenny. Zdolność wiązania toksyn bakteryjnych przez węgiel leczniczy nie jest w pełni udowodniona, nie ma badań klinicznych potwierdzających to działanie. W badaniach klinicznych potwierdzono zdolność smektynu dwuoktanościennego do adsorbcji wirusów i toksyn bakteryjnych. Udokumentowano również wielokierunkowe działanie ochronne smektynu dwuoktanościennego na błonę śluzową żołądka i jelit – z uwagi na te unikalne właściwości smektyn może być kwalifikowany jako adsorbent drugiej generacji. Zgodnie z aktualnymi zaleceniami ESPGHAN i ESPID z 2008 roku smektyn dwuoktanościenny jest jedynym adsorbentem o udowodnionym bezpieczeństwie stosowania, który zastosowany równolegle z doustnymi płynami nawadniającymi zwiększa szanse na skrócenie czasu trwania biegunki.
Źródło:
Pediatria i Medycyna Rodzinna; 2013, 9, 1; 57-59
1734-1531
2451-0742
Pojawia się w:
Pediatria i Medycyna Rodzinna
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-10 z 17

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