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    Wyświetlanie 1-7 z 7
    Tytuł:
    The use of the steric effect of the carrier molecule in the polymer inclusion membranes for the separation of cobalt(II), nickel(II), copper(II), and zinc(II) ions
    Autorzy:
    Radzyminska-Lenarcik, E.
    Ulewicz, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/778754.pdf
    Data publikacji:
    2015
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    polymer inclusion membrane
    separation ions
    steric effect
    copper(II)
    cobalt(II)
    nickel(II)
    cadmium(II)
    zinc(II)
    alkylimidazole
    Opis:
    In this study, palladium-modified nickel foam substrate was applied to examine ethanol oxidation reaction (EOR) in 0.1 The transport of cobalt(II), nickel(II), copper(II), and zinc(II) ions from chloride solutions across polymer inclusion membranes (PIMs), which 1-heptylimidazole (1̲) or 1-heptyl-2-methylimidazole (2̲) or 1-heptyl-4-methylimidazole (3̲) as the ion carrier was reported. The steric effect for carriers 2̲&enspand 3̲&enspdecreases the transport of all ions except Cu(II). The initial fluxes of metal ions transport across PIMs with the 1̲- 2̲&enspdecrease in the sequence: Cu(II) > Zn(II) > Co(II) > Ni(II), whereas for 3 they were Cu(II) > Zn(II) > Ni(II) > Co(II). The highest recovery values were obtained for Cu(II), this being 99 and 85% for carrier 1̲&enspand 2̲, respectively. In both membranes the degree of deposition of the Zn(II) ions was comparable. Zn(II), Co(II) and Cd(II) ions, which form complexes with coordination numbers 4 and 6, are more easily recovered with the use of carriers 2̲&enspand 3̲. Ni(II) ions, which form complexes with coordination number 6 only, practically remain in the feeding phase. PIMs with alkylimidazoles were characterized by non-contact atomic force microscopy.
    Źródło:
    Polish Journal of Chemical Technology; 2015, 17, 2; 51-56
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    The use of 1-alkylimidzoles for selective separation of zinc ions in the transport process across a polymeric inclusion membrane
    Autorzy:
    Radzyminska-Lenarcik, E.
    Ulewicz, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/110913.pdf
    Data publikacji:
    2014
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    polymer inclusion membrane (PIM)
    separation ions
    cobalt(II)
    nickel(II)
    zinc(II)
    alkylimidazole
    Opis:
    The transport of Zn(II) ions from different aqueous nitrate(V) source feeding phases (cMe = 0.001 mol/dm3, pH 6.0) across polymer inclusion membranes (PIMs) doped with 1-alkylimidazole as an ion carrier was reported. Alkyl substituents in position 1 of imidazole ring have an effect on hydrophobic properties of the carriers and the initial flux of the transported metal ions. The membranes were characterized by an atomic force microscopy (AFM). The results show that the Zn(II) ions could effectively be separated from other transition metal cations such as Co(II) and Ni(II) from different equimolar ion mixtures. Also, the thermal stability of PIM doped with 1-decylimidazole was studied in replicate experiments. The highest separation coefficients for the Zn(II)/Co(II) and Zn(II)/Ni(II) systems, equal to 9.4 and 11.9 were recorded for the equimolar Zn(II)-Co(II)-Ni(II) mixture for 1-hexylimidazole as a carrier, while using 1-decylimidazole resulted in the highest values of initial flux of the Zn(II) ions transport across the polymeric membrane.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2014, 50, 1; 131-142
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Separation of Co(II), Cu(II), Ni(II) and Mn(II) from synthetic hydrochloric acid leaching solution of spent lithium ion batteries by solvent extraction
    Autorzy:
    Nguyen, Viet Nhan Hoa
    Lee, Man Seung
    Powiązania:
    https://bibliotekanauki.pl/articles/1449331.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    spent lithium-ion batteries
    divalent metal ions
    solvent extraction
    separation
    Opis:
    Spent lithium ion batteries contain valuable critical metals such as cobalt, copper, lithium and nickel. In order to develop a process for the separation of the divalent metal ions from spent lithium ion batteries, solvent extraction experiments were performed by employing synthetic hydrochloric acid leaching solution. The synthetic solution contained Cu(II), Co(II), Mn(II) and Ni(II) and its acidity was 3 M HCl. Extraction with Aliquat 336 led to selective extraction of Cu(II) with a small amount of Co(II). After adding NaCl to the Cu(II) free raffinate to enhance the complex formation of Co(II), Co(II) was selectively extracted into Aliquat 336 together with Mn(II). The small amount of Mn(II) in the loaded Aliquat 336 was scrubbed by pure Co(II) solution. After adjusting the pH of the raffinate to 3, 91,3% of Mn(II) was selectively extracted over Ni(II) by the mixture of D2EHPA and Alamine 336. In this extraction, the mole fraction of D2EHPA in the mixture affected the extraction of Mn(II). McCabe-Thiele diagrams for the extraction of Cu(II) and Co(II) were constructed. Batch simulation experiments for the three stage counter-current extraction verified the selective extraction of the target metal ions in each extraction step. Namely, the total extraction percentage of Cu(II) and Co(II) was 71.6% and 98.8% respectively. Most metals in the loaded organic phase were stripped completely with the appropriate agents (1.0 M $H_2SO_4$ for Cu(II), 0.1 M H2SO4 for Co(II) and 0.3 M $HCl$ for Mn(II) stripping). A process was proposed to separate the metal ions by solvent extraction.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2020, 56, 4; 599-610
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Selective transport of copper(II) ions across polymer inclusion membrane with aromatic β–diketones as carriers
    Autorzy:
    Radzymińska-Lenarcik, E.
    Witt, K.
    Bożejewicz, D.
    Powiązania:
    https://bibliotekanauki.pl/articles/110355.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    β-diketone
    polymer inclusion membrane
    metal ions separation
    copper(II)
    cobalt(II)
    nickel(II)
    Opis:
    The transport of Cu(II) ions from an equimolar mixture of Co(II), Ni(II), and Cu(II) ions as well as from solutions containing only Cu(II) ions in the feed phase through polymer inclusion membranes (PIMs) with aromatic β–diketones as carriers has been investigated. The polymer membranes consisted of polyvinylchloride (PVC) as the support, bis(2-ethylhexyl)adipate (ADO) as plasticizer, and aromatic β–diketones (benzoylacetone (1) and dibenzoylmethane (2)) as ion carriers. The transport selectivity of PIMs with 1 and 2 was: Cu(II) > Co(II) > Ni(II). The highest recovery factors of Cu(II) ions were observed for 1 (94.0%), whereas for Co(II) and Ni(II) the factors were 21.4 and 7.3%, respectively. The Cu(II)/Co(II) and Cu(II)/Ni(II) selectivity coefficients were equal to 8.9 and 33.7 (for 1), 6.4 and 28.3 (for 2), respectively.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 3; 741-750
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Nickel-cobalt separation by solvent extraction method
    Autorzy:
    Radzyminska-Lenarcik, E.
    Wasilewska, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/115651.pdf
    Data publikacji:
    2015
    Wydawca:
    Fundacja na Rzecz Młodych Naukowców
    Tematy:
    separation ions
    solvent extraction
    cobalt(II)
    nickel(II)
    alkylimidazole
    separacja jonów
    ekstrakcja rozpuszczalnikowa
    kobalt(II)
    nikiel(II)
    alkiloimidazol
    Opis:
    Separation of cobalt(II), and nickel(II) ions from nitrate solutions using liquid-liqiud extraction process was reported. The measurements were run at 25oC and at fixed ionic strength equal to 0.5 (KNO3,HNO3). Initial concentrations of Co(II) and Ni(II) nitric acid in the aqueous phase were constant (0.01 M and 0.15 M, respectively). Both 1-hexylimidazole (1), and 1-hexyl-2-methylimidazole (2), both in dichloromethane were used as extractants. Their concentrations in organic phase were varied from 0.01 to 0.25 M. Cobalt(II) in an aqueous solution forms both tetrahedral and octahedral complexes. Nickel(II) forms only a six-coordinate complexes. These general differences help to provide the basis for the various separation processes currently used for cobalt-nickel separation. The steric effect for extractant 2 facilitates the extraction of tetrahedral Co(II) complexes. Extraction percent (%E) of cobalt(II) and nickel(II) in the systems studied were calculated. The percentage extraction increases for increasing values of pH of aqueous phase and is the highest for pH = 7.2. In the aqueous phase, of which the pH = 7.2, there remain 75%Ni(II) and 40% Co(II) for extractant 1 and the respective values for extractant 2 are 85% Ni(II) and 20% Co(II). The steric effect increases selectivity coefficients Co(II)/Ni(II). The highest selectivity coefficients for both extractants were obtained at a pH of aqueous phase = 6.2; their values were 5 and 8.9 for extractants 1 and 2, respectively.
    Źródło:
    Challenges of Modern Technology; 2015, 6, 3; 20-23
    2082-2863
    2353-4419
    Pojawia się w:
    Challenges of Modern Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Application of polymer inclusion membranes doped with 1-hexyl-4-methylimidazole for pertraction of zinc(II) and other transition metal ions
    Autorzy:
    Ulewicz, M.
    Radzyminska-Lenarcik, E.
    Powiązania:
    https://bibliotekanauki.pl/articles/110567.pdf
    Data publikacji:
    2015
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    polymer inclusion membrane
    PIM
    metal ions separation
    zinc(II)
    transition metal ions
    imidazole derivatives
    Opis:
    Transport of Zn(II) from unary aqueous chloride solutions and from solutions which contain mixtures of Cd(II), Co(II) and Ni(II) ions in source phases (cMe = 0.001 mol/dm3, pH = 6.0) across polymer inclusion membranes (PIMs) doped with 1-hexyl-4-methylimidazole as ion carrier was studied. The use of 1-hexyl-4-methylimidazole enables the separation of 98.5% Zn(II) from a unary solution and 96.9% from a quaternary solution of Zn(II)-Cd(II)-Co(II)-Ni(II) after running the process for 24 hours. Using that ion carrier, the metals are transported in the following order: Zn(II) > Cd(II) > Ni(II) > Co(II), and the selectivity coefficients of Zn(II)/Cd(II), Zn(II)/Ni(II), and Zn(II)/Co(II) are 12.9, 23.4 and 40.8, respectively. Findings of atomic force microscopy (AFM) examinations as well as thermograms of a polymer inclusion membrane containing 1-hexyl-4-methylimidazole are also presented. A membrane with 1.0 mol/dm3 of carrier has a porosity of 15.8%, and roughness of 6.6 nm. The membranes remain thermally stable at temperatures up to 200oC. The findings were compared with earlier-reported results for 1-hexylimidazole.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2015, 51, 2; 447-460
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Application of macrocycle compounds for metal ions separation and removal - a review
    Autorzy:
    Walkowiak, W.
    Ulewicz, M.
    Kozłowski, C. A.
    Powiązania:
    https://bibliotekanauki.pl/articles/346971.pdf
    Data publikacji:
    2002
    Wydawca:
    Politechnika Bydgoska im. Jana i Jędrzeja Śniadeckich. Wydział Technologii i Inżynierii Chemicznej
    Tematy:
    macrocycles
    crown ethers
    lariat ethers
    metal ions
    separation
    Opis:
    A review is presented on macrocyclic compounds novel reagents for metal ions separation and removal in solvent extraction, transport through liquid membranes, and flotation processes. As macrocyclic compounds were used such chemicals as non-ionizable crown ethers, ionizable crown ethers (lariat ethers), calixarenes, and acyclic polyethers. Many literature data as well our own recent research data will be reported on metal ions removal and separation.
    Źródło:
    Ars Separatoria Acta; 2002, 1; 87-98
    1731-6340
    Pojawia się w:
    Ars Separatoria Acta
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-7 z 7

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