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    Wyświetlanie 1-4 z 4
    Tytuł:
    Calculation of Diffusion Coefficients for Oxidation of ferrocene derivative synthesized at two different electrodes using Rotating Disk Electrode (RDE)
    Autorzy:
    Nacer, S.N.
    Khelef, A.
    Lanez, T.
    Powiązania:
    https://bibliotekanauki.pl/articles/411798.pdf
    Data publikacji:
    2013
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    Rotating Disk Electrode (RDE)
    diffusion coefficient
    ferrocene derivative
    half-wave potential
    Randles-Sevcik equation
    Opis:
    The electrochemical behavior of N'-Ferrocenylmethyl-N'-Phenylbenzohydrazide synthesized is studied by Rotating Disk Electrode (RDE) Voltammetry to study the kinetics of oxidation and the effect of hydrazide group on ferrocene in organic medium. Thus, two different electrodes (Pt and Gc) were used in ordre to determine this latter. According to the ferrocene taken as a witness the hydrazide group related to the ferrocene made oxydation more difficult. This ferrocenic derivative showed an electrochemical stability, a reversible electrochemical system and an electronic attractor effect of these substitutional ferrocene groups. Finally, we calculated some electrochemical parameters which were: the diffusion coefficients (D), the layer thickness in addition to the electron transfer rate.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2013, 9, 1; 39-47
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Dynamic Mode of Copper Recovery from the Post-Processing Slags
    Autorzy:
    Wołczyński, W.
    Bydałek, A. W.
    Migas, P.
    Tarasek, A.
    Najman, K.
    Powiązania:
    https://bibliotekanauki.pl/articles/352769.pdf
    Data publikacji:
    2018
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    post-processing slag
    complex reagent
    copper recovery
    arc furnace
    rotating tilted electrode
    Opis:
    The post-processing slags containing about 0.8 wt.% of copper were subjected to the treatment of a complex reagent. The chemical composition of the complex reagent has been elaborated and patented in frame of the Grant No. PBS3/A5/45/2015. The slags had an industrial origin and were delivered by the Smelter and Refinery Plant, Głogów, as a product of the direct-to-blister technology performed in the flash furnace assisted by the arc furnace. An agglomeration of copper droplets suspended in the liquid slag, their coagulation, and deposition on the bottom of furnace were observed after the treatment this post-processing slag by the mentioned reagent. The treatment of the post-processing slags by the complex reagent was performed in the arc furnace equipped with some additional electrodes situated at the furnace bottom (additional, in comparison with the arc furnace usually applied in the Smelter and Refinery Plant, Głogów). The behaviour of the copper droplets in the liquid slag within the competition between buoyancy force and gravity was studied from the viewpoint of the required deposition of coagulated copper droplets. The applied complex reagent improves sufficiently the surface free energy of the copper droplets. In the result, the mechanical equilibrium between coagulated copper droplets and surrounding liquid slag is properly modified. Eventually, sufficiently large copper droplets are subjected to a settlement on the furnace bottom according to the requirements. The agglomeration and coagulation of the copper droplets were significantly improved by an optimized tilting of the upper electrodes and even by their rotation. Moreover, the settlement was substantially facilitated and improved by the employment of both upper and lower system of electrodes with the simultaneous substitution of the variable current by the direct current.
    Źródło:
    Archives of Metallurgy and Materials; 2018, 63, 4; 1923-1930
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Electrochemical Method of Copper Powder Synthesis on Rotating Electrode in the Presence of Surfactants
    Autorzy:
    Wojtaszek, K.
    Cebula, F.
    Partyka, B.
    Deszcz, P.
    Włoch, G.
    Socha, R. P.
    Woźny, K.
    Żabiński, Piotr
    Wojnicki, Marek
    Powiązania:
    https://bibliotekanauki.pl/articles/2203711.pdf
    Data publikacji:
    2023
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    copper powder
    electrochemical synthesis
    rotating electrode
    ethylene glycol
    Opis:
    This paper presents a method of synthesizing copper powders by electrochemical method with the use of a rotating working electrode. The influence of the rotation speed of the working electrode, the current density, the concentration of copper ions, and the addition of ethylene glycol on the shape, size, and size distribution of the obtained powders were investigated. Properties of the synthesized powders were characterized by scanning electron microscopy (SEM) and X-ray powder diffractometry (XRD). It has been shown that it is possible to obtain copper powders with a size of 1 µm by an electrochemical method using the rotary cathode, in sulphate bath with addition of ethylene glycol as a surfactant. Increasing current density causes a decrease in the average size of the obtained powder particles. The addition of 2.5% of ethylene glycol prevents the formation of dendritic powders. The change in the concentration of copper ions in the range from 0.01 to 0.15 mol/dm3 in the electrolyte did not show any significant effect on the size of obtained particles. However, higher concentrations of copper limiting the presence of dendritic-shape particles. Changing the speed of rotation of the electrode affects both the size and the shape of synthesized copper powder. For the rotational speed of the electrode of 115 rpm, the obtained powders have a size distribution in the range of 0-3 µm and an average particle size of 1 µm. The particles had a polygonal shape with an agglomeration tendency.
    Źródło:
    Archives of Metallurgy and Materials; 2023, 68, 1; 375--386
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    The Effect of Hydrazide group on the oxydation of ferrocene at two different electrodes using Rotating Disk Electrode (RDE) in organic medium
    Autorzy:
    Nacer, S. N.
    Lanez, T.
    Powiązania:
    https://bibliotekanauki.pl/articles/412271.pdf
    Data publikacji:
    2013
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    Rotating Disk Electrode (RDE)
    diffusion coefficient
    ferrocene derivative
    half-wave potential
    Opis:
    Through this work we adopted Rotating Disk Electrode (RDE) Voltammetry to study the kinetics of oxidation and the effect of hydrazide group on ferrocene in organic medium. Thus, two different electrodes (Pt and Ge) were used in order to determine this latter. According to the ferrocene taken as a witness the hydrazide group related to the ferrocene made oxidation more difficult. This ferrocenic derivative showed an electrochemical stability, a reversible electrochemical system and an electronic attractor effect of these substitutional ferrocene groups. Finally, we calculated some electrochemical parameters which were: the diffusion coefficients (D), the layer thickness in addition to the electron transfer rate.
    Źródło:
    International Letters of Chemistry, Physics and Astronomy; 2013, 7, 1; 1-7
    2299-3843
    Pojawia się w:
    International Letters of Chemistry, Physics and Astronomy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-4 z 4

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