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    Wyświetlanie 1-8 z 8
    Tytuł:
    Application of chromatographic plate theory on the weathered crust elution-deposited rare earth ore with carboxylate
    Autorzy:
    Zhang, Zhenyue
    Wang, Guangshuai
    Li, Chunhua
    Chi, Ruan
    Long, Fei
    Chen, Zhuo
    Chi, Xiao Wang
    Liu, Defeng
    Powiązania:
    https://bibliotekanauki.pl/articles/1446022.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    weathered crust elution-deposited rare earth ore
    carboxylate ammonium
    mass transfer
    theory plate
    rare earth
    Opis:
    To improve the leaching process of rare earth and reduce the impurities in the leachate, the carboxylate ammonium, such as ammonium acetate, ammonium citrate and ammonium tartrate, were selected as lixiviant to compare the effects of concentration, flow rate, pH and temperature on leaching mass process of rare earth and aluminum. Meanwhile, the leaching behaviors of rare earth and aluminum leached by three kinds of carboxylate ammonium were analyzed by chromatographic plate theory. The relationship between the flow rate and height equivalent (HETP) could fit well with the Van Deemter equation and there was an optimal flow rate (uopt) for the leaching of the rare earth and aluminum. Besides, the conditions of carboxylate ammonium lixiviant were optimized. The optimum concentrations of ammonium acetate, ammonium tartrate and ammonium citrate were 15 g/L, 25 g/L and 5 g/L respectively, the leaching flow rate was 0.50 mL/min, the pH value was approximatively 7.00 and the leaching temperature was 293 K to 303 K. At these conditions, the mass transfer efficiencies of three ammonium carboxylates for rare earth and aluminum was in the order of ammonium acetate > ammonium tartrate > ammonium citrate. Moreover, the ammonium acetate could commendably inhibit aluminum ions entering the lixivium.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 4; 48-62
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Direct reuse of rare earth oxalate precipitation mother liquor for rare earth leaching
    Autorzy:
    Wu, Xiaoyan
    Zhou, Fang
    Feng, Jian
    Liu, Xueme
    Zhang, Zhenyue
    Chi, Ruan
    Powiązania:
    https://bibliotekanauki.pl/articles/109869.pdf
    Data publikacji:
    2019
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    weathered crust elution-deposited rare earth ore
    oxalic acid
    precipitation
    mother liquor
    Opis:
    In the recovery process of rare earth (RE) from the weathered crust elution-deposited rare earth ore, ammonium sulfate is used as the leaching liquor to leach RE, and then the leachate containing RE3+ can be precipitated by oxalic acid and the RE oxalate precipitation mother liquor is reused for RE leaching process after removing the residual oxalic acid by precipitation with calcium hydroxide. However, the reuse process of precipitation mother liquor cannot proceed in the strong acid and alkali restricted areas and the discharge of mother liquor which contains a large amount of ammonium salt will cause ammonia-nitrogen waste and pollution. In order to realize the reuse of the precipitation mother liquor in this area, the direct reuse of RE oxalate precipitation mother liquor for RE leaching was investigated in this study. The RE oxalate precipitation process and the RE leaching process with oxalic acid were studied. The results showed that the residual oxalic acid concentration in the mother liquor can be controlled lower than 0.8 g/dm3 at pH 2-3 when the RE concentration in the leachate was 0.1- 1.5 g/dm3 and the RE precipitation rate reached to 94%. In addition, RE leaching efficiency was up to 90% while the oxalic acid concentration in the prepared mother liquor was 0.2-0.8 g/dm3, pH 2-3. Therefore, the precipitation mother liquor with oxalic acid concentration less than 0.8 g/dm3 could be directly reused for RE leaching. However, considering the different performance of RE ores, the recommended oxalic acid concentration in the direct used precipitation mother liquor was lower than 0.6 g/dm3.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2019, 55, 3; 760-769
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Mass transfer process of leaching weathered crust elution-deposited rare earth ore with magnesium salts
    Autorzy:
    Chen, Z.
    Zhang, Z.
    He, Z.
    Chi, R.
    Powiązania:
    https://bibliotekanauki.pl/articles/110343.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    mass transfer
    magnesium salts
    theory plate
    weathered crust elution-deposited rare earth ore
    Opis:
    In order to optimize the leaching process of weathered crust elution-deposited rare earth ore with magnesium salts, the influence of different flow rate, concentration of magnesium ions, initial pH of magnesium salts solution and experimental temperature on the mass transfer process of rare earth and aluminum was investigated in the case of using magnesium salts as leaching agent. The relationship between the flow rate μ and the HETP (Height Equivalent of Theoretical Plate) is in accordance with the Van Deemter equation when magnesium salts were used as leaching agent. The optimum condition for rare earth and aluminum were 0.4 cm3/min of flow rate and 0.2 mol/dm3 of magnesium ion concentration of magnesium sulfate, magnesium chloride and magnesium nitrate respectively. Under this condition the mass transfer efficiency of rare earth and aluminum with three kinds of magnesium salts follow the order of Mg(NO3)2>Mg(Cl)2>MgSO4. High temperature contributes to improving the mass transfer efficiency of rare earth and aluminum. Magnesium nitrate as the leaching agent can get the highest leaching mass transfer efficiency of rare earth and magnesium sulfate as the leaching agent can make the impurity leaching and mass transfer efficiency of Al is the lowest.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 3; 1004-1013
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    One step purification of impurities in the leachate of weathered crust elution-deposited rare earth ores
    Autorzy:
    Zhou, F.
    Feng, J.
    Wang, Z.
    Xu, Y.
    Zhang, Z.
    Chi, R.
    Powiązania:
    https://bibliotekanauki.pl/articles/110333.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    leachate
    weathered crust
    rare earth ore
    leachate purification
    precipitation
    Opis:
    It is necessary to control and reduce the high content of Al3+, Cu2+ and Pb2+ ions in the leachate of weathered crust elution-deposited rare earth ore to facilitate the rare earth recovery and the quality of rare earth products. Neither NH4HCO3 nor Na2S are suitable for removal of all impurity ions and meanwhile maintain high rare earth recovery. Conventionally, NH4HCO3 is firstly adopted to remove Al3+, and then Cu2+ and Pb2+ are removed by using Na2S. This two steps purification process is quite long and results in lots of complication in operation. In this paper, a one-step purification by using the compound of NH4HCO3 and Na2S was proposed to remove Al3+, Cu2+ and Pb2+. The results showed that after purification 89% Cu, 92% Pb and 74% Al were removed from the leachate solution by using 0.1 M compound of NH4HCO3/Na2S, while maintaining 89% rare earth. The optimal purification parameters were: volume ratio of NH4HCO3 to Na2S of 9:1, volume ratio of compound to leachate of 0.05:1, precipitation time of 30 min.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 2; 1188-1199
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Process mineralogy of Bayan Obo rare earth ore by MLA
    Autorzy:
    Xu, Caili
    Chi, Ru’an
    Zhang, Yantu
    Zhong, Chengbin
    Ruan, Yaoyang
    Lyu, Renliang
    Zhou, Fang
    Powiązania:
    https://bibliotekanauki.pl/articles/1449295.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    process mineralogy
    rare earth
    Bayan Obo ore
    MLA
    Opis:
    The maximum recovery of rare earth resource from the Bayan Obo ore deposit is a difficult task, especially without the sufficient data of mineralogy. In this paper the mineralogy of Bayan Obo ore deposit by comprehensively research with the application of mineral liberation analyzer (MLA) is reported. The MLA was applied to quantitatively analyze the complicated element/mineral compositions, the REE occurrence, the size distribution and the degree of liberation of the Bayan Obo ore. Mineralogical analysis of the rare earth ore has shown that REEs are present mainly as bastnaesite and monazite-(Ce) to a small extent as parisite-(Ce). 5.85% of the REEs, 34.99% of iron and 0.12% of niobium occur in the ore sample. There are 76.99% of iron occurred in hematite and the remaining iron is mainly distributed in magnetite and goethite. The degree of liberation of bastnaesite and monazite(Ce) was 79.65% and 75.67% respectively when the grinding fineness was 83.57% passing 75 μm sieves. Un-liberated or partly liberated rare earth minerals are associated closely mainly with other rare earth minerals and gangues. These theoretical data could be employed to further comprehensively utilize the rare earth ore.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2020, 56, 4; 737-745
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Seepage process on weathered crust elution-deposited rare earth ores with ammonium carboxylate solution
    Autorzy:
    Zou, Hualiang
    Zhang, Zhenyue
    Chen, Zhuo
    Liu, Defeng
    Chai, Xiuwei
    Zhang, Han
    Chi, Ru-an
    Powiązania:
    https://bibliotekanauki.pl/articles/1449672.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    permeability
    weathered crust elution-deposited rare earth ore
    ammonium carboxylate
    hydrodynamics
    Opis:
    In order to reveal the seepage law of ammonium carboxylate solution in the in-situ leaching process of weathered crust elution-deposited rare earth ores, the effects of concentration, pH, temperature, particle size and porosity on permeability were discussed in this paper. The results shown that the seepage of the leaching agent solutions in the rare earth ore follows Darcy's law and displays a laminar flow under the conditions of this experiment and seepage velocity can be increased by changing leaching conditions. The permeability coefficients are inversely proportional to concentrations of ammonium acetate, ammonium tartrate and ammonium citrate whose concentration is greater than 0.7wt%, because the insoluble complexes formed by the reaction of ammonium citrate with RE3+ at lower concentration n decrease the permeability coefficient. The permeability coefficients of ammonium carboxylate solutions increase firstly and then decrease with the pH increased. The maximum of permeability coefficients of ammonium acetate, ammonium tartrate and ammonium citrate solution were 2.92, 1.91 and 2.70, respectively, while the pH of solution were 5, 6 and 7, respectively. Increasing temperature is beneficial for the seepage of ammonium carboxylate solution in orebody, therefore, it is helpful for leaching operation in summer. Moreover, clay minerals particle size and porosity are the key factors affecting the permeability of ammonium carboxylate solution in orebody. The permeability coefficients of ammonium acetate, ammonium tartrate and ammonium citrate solutions are 2.92×104cm/s,1.90×10-4cm/s and 2.69×10-4cm/s, respectively, at the same temperature of 293K, original particle size and porosity of the ore. Ammonium acetate solution has the best permeability in orebody.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2020, 56, 1; 89-101
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study on fluoride fixation effect of Bayan Obo rare earth iron ore and three sodium agents under microwave irradiation
    Autorzy:
    Guo, Jing
    Wen, Ming
    Li, Jie
    Hong, Xunhai
    Zhang, Wenhao
    Wang, Yonglun
    Powiązania:
    https://bibliotekanauki.pl/articles/2146846.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    Bayan Obo rare earth iron ore
    microwave roasting
    sodium agent fluoride fixation
    Opis:
    To investigate the fluorine fixation of Bayan Obo rare-earth iron ores in beneficiation and metallurgy processes, the effect of three sodium agents, namely, sodium hydroxide, sodium carbonate, and sodium bicarbonate, on fluorine fixation under the action of microwaves was investigated using Xray diffraction, chemical detection, and orthogonal experiments. The effects of different types of sodium, roasting temperatures, sodium ratios, and roasting times on the fluorine fixation rate were evaluated. Results show that compared with conventional roasting, the fluorine fixation efficiency of Bayan Obo rare-earth iron ore under the action of microwave is superior after the formulation of the sodium agent, which is crucial for the study. Among the three sodium agents, the fluorine fixation effect of NaHCO3 can be used as the preferred sodium agent. Orthogonal experiments showed that the factors influencing the magnitude of the fluorine fixation rate are the roasting temperature, sodium agent ratio, and roasting constant temperature time in the order of priority. The optimal conditions for the fluorine fixation process are the microwave roasting temperature of 973.15 K, sodium bicarbonate ratio of 40%, and roasting time of 60 min. The highest fluorine fixation rate of 86.72% can be obtained. The findings of this study can provide a reference for the development of green and economic recovery processes for Bayan Obo rare-earth iron ores.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 1; 63--76
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study on REE occurrence in a Svanbergite and basic ore characteristics
    Autorzy:
    Ma, Keyu
    Zhang, Jie
    Deng, Qiufeng
    Men, Pengpeng
    Zhang, Yusong
    Shi, Xiulin
    Powiązania:
    https://bibliotekanauki.pl/articles/2146882.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    svanbergite
    rare earth elements (REEs)
    occurrence state
    crandallite
    ore characteristics
    Opis:
    Svanbergite in Sichuan Province, China is a special middle-low grade phosphorus ore. It contains rare earth elements (REEs), aluminum, and strontium that can be exploited and utilized. In this study, several methods were used to systematically study the occurrence of REEs in the ore and basic ore characteristics. The ore, which was rich in REEs, Al, and Sr, was classified as marine sedimentary low-grade phosphorus ore. The main ore mineral was crandallite and pyrite, and independent REE minerals were not found. Crandallite was the main carrier mineral of useful elements, including P, REEs, Al, and Sr. REE+ was inferred to mainly exist in crandallite via isomorphism by replacing Ca2+ and H+. The crandallite was mainly characterized as fine-grained, and minerals were closely disseminated. The results from this study will provide a valuable reference for expanding available REE resources and the efficient comprehensive utilization of svanbergite.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 3; art. no. 147377
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
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