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    Wyświetlanie 1-5 z 5
    Tytuł:
    Galvanic contacting effect of pyrite on xanthate adsorption on galena surface: DFT simulation and cyclic voltammetric measurements
    Autorzy:
    Ke, B.
    Chen, J.
    Li, Y.
    Chen, Y.
    Powiązania:
    https://bibliotekanauki.pl/articles/110904.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    adsorption
    DFT
    galvanic interaction
    pyrite surface
    galena surface
    cyclic voltammetric measurements
    Opis:
    The effect of galvanic interaction between pyrite and galena on xanthate adsorbing on the galena surface has been investigated by means of density functional theory (DFT) and cyclic voltammetric measurements. The calculated results show that differences in the contact site and contact distance between galena and pyrite can affect the intensity of the galvanic interaction, and the relationship between the intensity of galvanic interaction and the adsorption ability of xanthate on galena surface has been studied in detail. In general, the galvanic interaction between pyrite and galena surface can enhance the adsorption of xanthate on the galena surface. The adsorption energies of xanthate on the galena surface decrease with the decrease of contact distance, and when the contact distance is lower than 4 Å, the adsorption energies decrease significantly at Pb-Pb, Pb-S and S-S sites. In particular, at the contact distance of 3 Å, a sharp decrease of adsorption energy is observed at the Pb-Pb contact site; in this case, the negative shift of the Pb-S bonding range and DOS non-locality at Pb-Pb contact site are significantly greater than that of the S-S or Pb-S contact sites. The cyclic voltammetric measurements reveal that the galvanic interaction between galena and pyrite improves the adsorption of xanthate on galena surface, which is in good agreement with the DFT results.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 3; 826-836
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of pyrite type on the electrochemistry of chalcopyrite/pyrite interactions
    Autorzy:
    Forbes, E.
    Smith, L.
    Vepsalainen, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/110218.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    flotation
    arsenic
    pyrite
    galvanic interaction
    Surface oxidation
    Opis:
    Pyrite is the most common sulphide gangue mineral occurring in base metal sulphide ores around the world. Pyrite is known to galvanically interact with valuable minerals such as chalcopyrite, altering their electrochemical and flotation behaviour. Different types of pyrite are known to vary in texture, chemical composition and electrochemical activity. However, the effect that these differences have on the degree of pyrite interaction with chalcopyrite are not well studied. This work examines two distinct types of pyrite from different deposits that have a similar chemical composition, but vary greatly in texture. It investigates the way in which these pyrites interact with chalcopyrite surfaces, affecting both its electrochemical behaviour and floatability. It was found that the Renison pyrite was characterised by a much higher level of surface activity than the Huanzala pyrite. This was attributed to the elevated levels of arsenic within the mineral’s crystalline matrix.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 4; 1117-1129
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Adsorption mechanism of copper xanthate on pyrite surfaces
    Autorzy:
    Deng, Zhengbin
    Cheng, Wanli
    Tang, Yun
    Tong, Xiong
    Liu, Zhihong
    Powiązania:
    https://bibliotekanauki.pl/articles/1447276.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    pyrite
    cupric xanthate
    cuprous xanthate
    adsorption
    surface
    Opis:
    The ratio of the hydrophobic to hydrophilic species and their distribution on mineral surfaces significantly influences the floatability of sulfide minerals. Through the flotation test, the influence of different reagents on pyrite flotation was examined. The interaction mechanisms between copper xanthate and pyrite were evaluated using advanced analysis technologies, including contact angle measurements, zeta potential analysis, scanning electron microscopy, energy dispersive spectroscopy, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy. The results show that the butyl xanthate in solution reacts with copper sulfate to form cupric xanthate, increasing the consumption of the collector butyl xanthate and resulting in lower floatability of pyrite. Cupric xanthate can be adsorbed on the pyrite surface through bonding with the sulfur sites. The adsorbed cupric xanthate on the pyrite surface undergoes redox reaction. The cupric xanthate is reduced to cuprous xanthate, and the sulfur on the surface will be oxidized. The adsorption products on the pyrite surface contain both cuprous xanthate and cupric xanthate. As the pH of a solution increases, the absolute value of the zeta potential of pyrite surface increased and the surface contact angle increased. Iron xanthate is also formed on the pyrite surface through a chemical reaction between the xanthate ions and pyrite, oxidation of xanthate ions to dixanthogen also takes place. Cuprous xanthate is the main hydrophobic substance on the pyrite surface, which can change the surface electrical properties and wettability of pyrite, and improve hydrophobicity of pyrite.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 3; 46-60
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study on surface modification of cerussite by thermochemical processing with pyrite
    Autorzy:
    Zheng, Yong-Xing
    Ning, Ji-Lai
    Xie, Haiyun
    Lv, Jin-Fang
    Hu, Pan-Jin
    Pang, Jie
    Powiązania:
    https://bibliotekanauki.pl/articles/1448573.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    cerussite
    pyrite
    surface modification
    thermochemical processing
    flotation
    Opis:
    In this paper, surface modification of cerussite by thermochemical processing with pyrite was studied based on microflotation tests, X-ray powder diffractometry (XRD), X-ray photoelectron spectroscopy (XPS) and electron probe microanalysis (EPMA). Microflotation test results showed that the surface modification facilitated flotation of the treated cerussite and improved the flotation recovery to approximately 90%. The results of XRD analyses confirmed that cerussite was transformed into massicot, which then interacted with pyrite to form $PbS$, $PbSO_4$, $PbO•PbSO_4$ and $4PbO•PbSO_4$. XPS analyses results revealed that both $PbS$ and $PbS_2$ were formed on the mineral surface, and the percentage of $PbS$ increased with increasing $FeS_2$/$PbCO_3$ (F/P) mole ratio, which was advantageous for the flotation of the modified cerussite. EPMA analyses showed that particles with layered configurations were obviously formed after thermochemical processing. The thickness of the products at the outer layer of the particles increased when the F/P mole ratio increased. Moreover, the S and O contents in the products increased and decreased, respectively.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 1; 156-167
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Response surface methodology (RSM) for optimization of chalcopyrite concentrate leaching with silver-coated pyrite
    Autorzy:
    Salehi, S.
    Noaparast, M.
    Shafaei, S. Z.
    Powiązania:
    https://bibliotekanauki.pl/articles/110894.pdf
    Data publikacji:
    2016
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    chalcopyrite
    copper extraction
    silver-coated pyrite
    optimization
    response surface methodology
    Opis:
    This study aims to leach copper from chalcopyrite and optimizing the leaching process, using the response surface methodology (RSM). The RSM, a D-optimal design with four factors in three levels was employed to evaluate the effect of particle size, temperature, silver-coated pyrite to chalcopyrite ratio and redox potential parameters on the copper extraction efficiency. A quadratic model was then proposed by the RSM to correlate leaching variables. The tests results indicated that the model was significant with the experimental data at a correlation coefficient (R2) of 0.96. The most important parameters of copper extraction efficiency were particle size and silver-coated pyrite-to-chalcopyrite ratio, and also the squared term of particle size (A2), temperature (B2) and redox potential (D2). In addition, the interaction between redox potential and silver-coated pyrite-to-chalcopyrite ratio (CD) was significant. It was shown that the finer the particle size the faster the leaching rate of copper. It was also indicated that by increasing silver-coated pyrite to chalcopyrite ratio of 6:1 copper recovery increased. The maximum recovery of copper (71%) was obtained for the particle size of -38 μm, 70 °C, 420 mV of redox potential, silver-coated pyrite-to-chalcopyrite ratio of 6 and leaching time of 8 hours.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2016, 52, 2; 1023-1035
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-5 z 5

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