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Tytuł:
Improving recovery efficiency for pyrite from high sulfur gangue by collaborating vibration energy in fluidized bed
Autorzy:
Zhou, Chenyang
Fan, Xuchen
Dong, Liang
Duan, Chenlong
Zhao, Yuemin
Powiązania:
https://bibliotekanauki.pl/articles/110615.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
vibrated fluidized bed
pyrite recovery
density segregation
high sulfur gangue
dry beneficiation
Opis:
It is of great significance for economic development and environment protection to recover pyrite from high sulfur gangue in China. Due to problem of global water shortage, it is urgent to explore more efficient separation methods without consuming water in mineral processing field. This study has proposed an innovative method for pyrite recovery using vibration fluidized bed based on particle density difference. Detailed separation results depicted that sulfur content of -6+3 mm, -3+1 mm and -1+0.5 mm samples increased to ca. 37%, 33% and 27%. The highest comprehensive recovery rate reached ca. 72%. Compared with recent wet methods, separation results indicated that it was satisfied for pyrite recovery using vibrated fluidized bed. Thus, it is a feasible way for pyrite recovery from high sulfur gangue through the dry method of fluidized bed by collaborating vibration energy.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 1; 70-81
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on surface modification of cerussite by thermochemical processing with pyrite
Autorzy:
Zheng, Yong-Xing
Ning, Ji-Lai
Xie, Haiyun
Lv, Jin-Fang
Hu, Pan-Jin
Pang, Jie
Powiązania:
https://bibliotekanauki.pl/articles/1448573.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
cerussite
pyrite
surface modification
thermochemical processing
flotation
Opis:
In this paper, surface modification of cerussite by thermochemical processing with pyrite was studied based on microflotation tests, X-ray powder diffractometry (XRD), X-ray photoelectron spectroscopy (XPS) and electron probe microanalysis (EPMA). Microflotation test results showed that the surface modification facilitated flotation of the treated cerussite and improved the flotation recovery to approximately 90%. The results of XRD analyses confirmed that cerussite was transformed into massicot, which then interacted with pyrite to form $PbS$, $PbSO_4$, $PbO•PbSO_4$ and $4PbO•PbSO_4$. XPS analyses results revealed that both $PbS$ and $PbS_2$ were formed on the mineral surface, and the percentage of $PbS$ increased with increasing $FeS_2$/$PbCO_3$ (F/P) mole ratio, which was advantageous for the flotation of the modified cerussite. EPMA analyses showed that particles with layered configurations were obviously formed after thermochemical processing. The thickness of the products at the outer layer of the particles increased when the F/P mole ratio increased. Moreover, the S and O contents in the products increased and decreased, respectively.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 1; 156-167
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Efficient sulfidization of lead oxide at high temperature using pyrite as vulcanizing reagent
Autorzy:
Zheng, Y.-X.
Lv, J.-F.
Wang, H.
Wen, S.-M.
Huang, L.
Powiązania:
https://bibliotekanauki.pl/articles/110351.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
lead oxide
sulfidization roasting
pyrite
reaction mechanism
TG
Opis:
A sulfidization roasting-flotation process was usually viewed to be effective in treating the refractory oxide ore. In this paper, pyrite was proposed to be applied as a potential vulcanizing reagent to transform PbO or its surface to PbS based on feasibilities of technology and economy. The evolution process, phase and characteristics of crystal growth were investigated by TG, XRD and SEM-EDS, respectively, to interpret the interaction mechanism of lead oxide and pyrite at high temperature. It was found that the decomposition process of pyrite under argon atmosphere was a slow process of sulfur released from FeS2 to FexS, which made the process easier to be controlled. When PbO was introduced into the system, the initial solid-solid (PbO-FeS2) reaction and prevailing solid-gas (PbO-S2(g)) reaction occurred at about 500 °C and 700 °C, respectively. Combined with the SEM-EDS analyses results, the optimal temperature for the sulfidization of PbO should be in the range of 700-750 °C.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 2; 270-277
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Flotation separation influenced by the rheological properties of diaspore-pyrite mixed pulp
Autorzy:
Zhao, Yongqing
Li, Xianhai
Powiązania:
https://bibliotekanauki.pl/articles/27323666.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
bauxite
diaspore
pyrite
flotation
rheological property
viscosity
Opis:
The effects of pyrite and diaspore with different particle sizes on the rheological properties of pulp with butyl xanthate added as a collector were studied, and the mechanism for rheological pyrite separation from diaspore by flotation was probed. The apparent viscosity of the diaspore pulp with different particle sizes was higher than that of pyrite, especially for -30 μm diaspore. Microfine diaspore was an important component affecting the apparent viscosity and yield stress of the diaspore-pyrite mixed pulp, and the pulp became a non-Newtonian fluid when the mass fraction of fine-grained diaspore in the mixed pulp was high. In this study, sodium hexametaphosphate (SHMP) was used to control the rheology of the mixed pulp and improve the pyrite flotation, and the S (sulfur) recovery rate first increased and then decreased with increasing SHMP concentration. The apparent viscosity of the pulp decreased by 3.01% and the S recovery rate increased by 34.83% when the amount of added SHMP was 0.05 mg/kg. The apparent viscosity with 0.50 mg/kg SHMP was 21.76% lower than that seen with the addition of 0.05 mg/kg SHMP, but the S recovery rate was also reduced by 14.94%. Further research showed that the increased SHMP concentration led to increases in the electronegativities of the particle surface and the repulsive force between particles, which prevented agglomeration of the particles, reduced the apparent viscosity and yield stress of the mixed pulp, promoted collisions between the pyrite particles and the bubbles, and reduced the resistance of the air bubbles to flotation.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 6; art. no. 174305
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ammonium chloride’s weakening effect on the copper activation of pyrite in flotation and the surface regulation mechanism behind it
Autorzy:
Zhang, Shengdong
Chen, Yumeng
Tong, Xiong
Xie, Xian
Lu, Yalin
Powiązania:
https://bibliotekanauki.pl/articles/110323.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
pyrite
depression
cuprammonium solution
pH buffering property
flotation
Opis:
The traditional separation process of pyrite and marmatite is carried out under highly alkaline conditions. Therefore, a large amount of lime is demanded and the zinc recovery cannot be guaranteed. However, under weakly alkaline conditions, copper-activated pyrite has good floatability, which is difficult to separate from marmatite. In this paper, ammonium chloride (NH4Cl) is used for depressing the flotation of copper-activated pyrite to achieve the separation of these two minerals under weakly alkaline environment. The flotation tests show that NH4Cl can significantly reduce the floatability of pyrite in weakly alkaline conditions. The results of adsorption tests and X-ray photoelectron spectroscopy (XPS) analyses indicate that NH4Cl can obviously change the composition of pyrite surface by increasing the content of iron/copper hydroxide and reducing the content of copper sulfides. Calculation of the solution composition demonstrates that the addition of NH4Cl results in the occurrence of Cu(NH3)n2+ and the pH buffering property. Based on these results, it can be concluded that the depression of NH4Cl on copper activated pyrite is mainly derived from two aspects: 1) the pH buffering property of the conjugated acid-base pair (NH4+/NH3) can impede the decline of OH- concentration, which results in more hydroxide adsorbed on pyrite; 2) NH3 (aq) competes with the pyrite surface to consume Cu2+through complexation, which causes a reduction in the amount of copper sulfides formed on the pyrite surface.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 5; 1070-1081
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Framboidy pirytowe jako wskaźniki paleośrodowiska
Pyrite framboids as paleoenvironmental indicators
Autorzy:
Zatoń, M.
Rakociński, M.
Marynowski, L.
Powiązania:
https://bibliotekanauki.pl/articles/2074589.pdf
Data publikacji:
2008
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
framboidy pirytowe
redoks
warunki środowiskowe oksyczne
warunki środowiskowe dysoksyczne
warunki środowiskowe euksyniczne
jura
dewon
Polska
pyrite framboids
redox
euxinia
anoxia
dysoxia
Jurassic
Devonian
Polska
Opis:
The problemof application of pyrite framboids in reconstructions of the redox conditions is presented. The characteristics of pyrite framboids, their origin and principles of application in paleoenvironmental interpretations are given. The pyrite framboid diameter distribution as indicators of redox conditions was presented on the examples of the Middle Jurassic (Upper Bajocian-Lower Bathonian) ore-bearing clays of the Polish Jura, and Upper Devonian (Middle and Upper Famennian) dark grey and black shales from Kowala (Holy Cross Mountains). It has been shown, that during the sedimentation of the ore-bearing clays, the pyrite framboids formed in the sediment, below the oxic water column; however, some episodic oscillation around the dysoxic conditions cannot be entirely excluded. During the sedimentation of the Middle Famennian dark grey shales, the redox conditions at the sea-floor oscillated around dysoxia. In both examples, the framboids are characterized by wide range of their diameters and the presence of large, >10 "my"m, framboids. On the contrary, the Upper Famennian black shales, representing the Hangenberg event, were deposited below the euxinic conditions in the water column. It is indicated by a high frequency of small-size framboids, far below 6 "my"m in diameter, and the lack of the large ones. The overlying shales, on the other hand, show the transition to more oxic conditions. The redox conditions interpreted above are in agreement with the independent biomarker analyses and paleontological observations.
Źródło:
Przegląd Geologiczny; 2008, 56, 2; 158-164
0033-2151
Pojawia się w:
Przegląd Geologiczny
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
An innovative flotation technology for the lime-depressed pyrite recovery from copper sulphide ore via acid mine drainage (AMD) activation
Autorzy:
Yuan, Jiaqiao
Ding, Zhan
Bi, Yunxiao
Li, Jie
Wen, Shuming
Bai, Shaojun
Powiązania:
https://bibliotekanauki.pl/articles/2175438.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
copper sulfide ore
acid mine drainage (AMD)
lime-depressed-pyrite
activator
hydrophilic species
Opis:
In this study, an innovative flotation technology consisted of Cu differential flotation with high alkali lime and pyrite recovery with acid mine drainage (AMD) activation was investigated for the cleaner beneficiation of the copper sulfide ore. Flotation test results showed that H2SO4 -CuSO4 and AMD could effectively activate the pyrite flotation with SBX collector. Moreover, the recovery of S concentrate is increased by 5.33% in the AMD system. Adsorption amount results of SBX collector indicated that the hydrophilic species (Ca2+, CaOH+ and FeOOH) were formed on the pyrite surfaces in the high alkali lime craft (pH=11.3) and degraded the interaction between SBX and pyrite surfaces. AMD can effectively clear off the hydrophilic calcium species and the copper ions originated from the AMD absorb onto the pyrite surfaces, facilitating the SBX collector adsorption. Composition analysis results of tailings water confirmed that the tailing water obtained by the AMD flotation system was more desirable to be recycled in the Cu differential flotation due to its higher pH value (8.7). The present study provides a novel approach for the treatment of AMD, and has the vital practical significance for the emission reduction of AMD and the increase of beneficiation profits.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 6; art. no. 152609
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Investigating the selectivity of calcium hypochlorite for flotation separation of chalcopyrite and pyrite pre-adsorbed collector
Autorzy:
Yang, Wenhui
Qiu, Xianhui
Yan, Huashan
Wu, Hao
Yang, Liu
Lai, Ruisen
Qiu, Tingsheng
Powiązania:
https://bibliotekanauki.pl/articles/2146919.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
pyrite
chalcopyrite
calcium hypochlorite
flotation separation
Opis:
Bulk flotation is usually used in the flotation of Cu-Fe sulfide ore, and the subsequent concentrate is difficult to be separated because the minerals have adsorbed the collector. In this paper, flotation tests showed that calcium hypochlorite (Ca(ClO)2) had a stronger depression effect on pyrite pre-adsorbed sodium butyl xanthate (SBX), while having a negligible depressive effect on chalcopyrite. A copper concentrate with Cu grade of 33.32% and Cu recovery of 94.47% could be obtained from flotation tests of mixed minerals. The depression performance and mechanism of Ca(ClO)2 were studied by contact angle measurements, Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy analyses, the results suggested that Ca(ClO)2 can decomposes SBX on the pyrite surface and oxidizes the mineral surface to form hydrophilic substances, which enhances the hydrophilicity of the pyrite surface. In contrast, Ca(ClO)2 has little effect on chalcopyrite pre-adsorbed SBX, the possible depression model is discussed.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 4; art. no. 150703
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Insight into the effect of galvanic interactions between sulfide minerals on the floatability and surface characteristics of pyrite
Autorzy:
Yang, Bo
Tong, Xiong
Xie, Xian
Huang, Lingyun
Powiązania:
https://bibliotekanauki.pl/articles/1448232.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
galvanic interaction
floatability
pyrite
sulfide minerals
Opis:
Complex sulfide ores are usually found as a mixture of various sulfide and gangue minerals, and froth flotation is the predominant method for the selective separation of sulfide minerals. Adherence and contact between sulfide minerals are inevitable during froth flotation, and galvanic interactions between sulfide minerals will occur because of differences in rest potentials. However, the effect of these galvanic interactions on the selective flotation of sulfide minerals have been rarely studied. In this work, the effect of the galvanic interaction between pyrite and sphalerite on the flotation behavior and surface characteristics of pyrite was investigated by micro-flotation tests, collector adsorption tests, electrochemical techniques and XPS (X-ray photoelectron spectroscopy) surface analysis. The micro-flotation tests indicated that the floatability of pyrite decreased in the pH range of 4.0 to 9.5 and increased under strongly alkaline pH conditions (pH > 10) due to the galvanic interaction. The collector adsorption results demonstrated that the adsorption capacity of the collector on the pyrite surface was significantly reduced because of the galvanic interaction between pyrite and sphalerite. The electrochemical measurements revealed that the decrease in the oxidation current of xanthates to dixanthogen was responsible for the decreasing adsorption capacity of the collector on the pyrite surface. The XPS results indicated that the formation of the $S_O_3^{2-}$ oxidation product on the pyrite surface decreased at a strongly alkaline pH due to the galvanic interaction. Therefore, pyrite floatability improved at an alkaline pH. These results consistently showed that the galvanic interaction between pyrite and sphalerite had an important influence on the floatability and surface characteristics of pyrite.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 2; 24-33
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Flotation kinetics and thermodynamic behavior of chalcopyrite and pyrite in high alkaline systems
Autorzy:
Yan, H.
Yuan, Q.
Zhou, L.
Qiu, T.
Ai, G.
Powiązania:
https://bibliotekanauki.pl/articles/110078.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
flotation kinetics
pyrite
chalcopyrite
flotation separation
high alkaline
microcalorimetry
Opis:
The monomineral flotation test and microcalorimetry were used to study the flotation kinetics and thermodynamic behavior of chalcopyrite and pyrite in high alkaline systems of lime and NaOH. The results showed that in these systems there were less hydrophilic substances on the chalcopyrite surface, so that the apparent activation energy of sodium butyl xanthate (SBX) adsorption on chalcopyrite surface was low. This promoted the adsorption of SBX and increased the flotation rate and recovery of chalcopyrite. In contrast, the hydrophilic Fe(OH)3 and SO42- formed by oxidation on the pyrite surface increased the adsorption activation energy of SBX. Thus, the flotation rate and recovery of pyrite were lower. Moreover, in the lime high alkaline system, the hydrophilic calcium film generated on the pyrite surface further hindered the adsorption of SBX, thereby further inhibiting pyrite in this environment. In other words, the lime high alkaline environment increased the apparent activation energy difference of SBX adsorption between chalcopyrite and pyrite compared to the NaOH system, facilitating the flotation separation of chalcopyrite and pyrite. The results can help with the theoretical research of flotation separation of other minerals, and provide guidance for developing low alkaline and lime-free pyrite depressants.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 3; 901-910
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ocena efektów rekultywacji Kopalni "Staszic" w Rudkach koło Kielc
The assessment of the effects of the reclamation in the mine "Staszic" in Rudki near Kielce
Autorzy:
Warda, A.
Powiązania:
https://bibliotekanauki.pl/articles/385945.pdf
Data publikacji:
2007
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
złoże pirytu
Rudki koło Kielc
rekultywacja
toksyczność
pyrite deposit
Rudki near Kielce
reclamation
toxicity
Opis:
W artykule przedstawiono charakterystykę złoża pirytu i rud żelaza w Rudkach koło Kielc, warunki jego eksploatacji w latach 1933-1974 oraz wywołane przez wydobycie zanieczyszczenie terenu, szczególnie w rejonie osadników poflotacyjnych i składowiska "Serwis". Omówiono sposób przeprowadzenia rekultywacji tego terenu w latach 1970-1973. Pobrane w 2005 r. próbki gruntu ze składowiska "Serwis" pozwoliły na wykonanie analizy skuteczności rekultywacji. W ramach analizy zbadano skład ziarnowy próbek, wyznaczono gęstość właściwą i objętościową, obliczono porowatość oraz straty prażenia, określono zawartość metali ciężkich, odczyn gleby, przewodność elektrolityczną właściwą (jako miarę zasolenia) oraz zawartość siarki całkowitej i węgla, dzięki czemu było możliwe oszacowanie zawartości materii organicznej. Na tej podstawie sformułowano wnioski dotyczące ekstremalnie kwaśnego odczynu gruntów oraz ich zasolenia, co wskazuje na niepełną skuteczność rekultywacji.
The article presents the characteristic of the deposit of pyrite and iron ores in Rudki near Kielce, conditions of its exploitation in 1933-1974 and mining-caused pollution of the region, in particular in the area of the postflotation decantation ponds and repository "Serwis". The way of carrying out reclamation of this area in 1970-1973 was described. Taken in 2005 samples of soil from the repository "Serwis" allowed the analysis of the efficiency of reclamation. In the framework of the analysis the granulation of samples was made, proper density and volume density were determined, as well as the porosity and the loss while roasting, content of heavy metals, pH of soil, proper electrolytic conductivity (as the measure of salinity) and the content of total sulphur and coal, due to which it was possible to estimate the content of organic matter. Based on this the conclusions referring to extremely acid reaction of soils and their salinity were made, indicating an incomplete efficiency of reclamation.
Źródło:
Geomatics and Environmental Engineering; 2007, 1, 3; 181-196
1898-1135
Pojawia się w:
Geomatics and Environmental Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption of yeast dextran on clinochlore surface and the implications for pyrite/clinochlore separation
Autorzy:
Wang, Zhen
Zou, Dan
Zhao, Kaile
Safarov, Sayfidin
Xu, Ying
Powiązania:
https://bibliotekanauki.pl/articles/2146917.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
clinochlore
pyrite
flotation
yeast dextran
adsorption
Opis:
Silicate minerals with a certain degree of flotability are often easy to mix into sulfide ore concentrate in mineral processing industry. In this paper, the adsorption of yeast dextran on clinochlore and its application in pyrite/clinochlore separation were investigated. The adsorbed amount and micro polarity measurement results displayed that the yeast dextran molecules selectively adsorbed onto clinochlore surface compared with pyrite. The adsorbed yeast dextran resulted in the increase in the surface polarity of clinochlore surface, and inhibited the further adsorption of xanthate, thus keep it hydrophilic and depressed. Quantum chemical computation results indicated that yeast dextran was mainly adsorbed on mineral surface by the chelation with the surface metal active sites, and the chelating strength of yeast dextran with three ions was in the sequence of Fe3+ > Mg2+ > Fe2+. While Mg2+, Fe2+ and Fe3+ are the main metal ions on the surface of clinochlore, and Fe2+ is the unique metal ions on pyrite surface. This is the reason of the selectivity of the yeast dextran depressant for pyrite/clinochlore flotation system. The flotation results demonstrated that yeast dextran was qualified to selectively depress clinochlore in pyrite flotation.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 4; art. no. 151635
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mineralogy characteristics, stability conditions, and formation pathways of synthetic pyrrhotite formed by heating pyrite at 700℃
Charakterystyka mineralogiczna, warunki stabilności i ścieżki powstawania syntetycznego pirotynu utworzonego przez ogrzewanie pirytu w temperaturze 700℃
Autorzy:
Wang, Zhehao
Wang, Ling
He, Yuting
Duan, Jiongran
Fan, Bowen
Powiązania:
https://bibliotekanauki.pl/articles/2203296.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Instytut Gospodarki Surowcami Mineralnymi i Energią PAN
Tematy:
synthetic pyrrhotite
pyrrhotite
pyrite
hematite
pirotyn syntetyczny
pirotyn
piryt
hematyt
Opis:
Pyrite is a sulfide mineral and is widely distributed in nature. Pyrite may transform into pyrrhotite when heated at high temperatures. In order to support processing engineering techniques and industrial applications of pyrite and pyrrhotite, it is necessary to investigate synthetic pyrrhotite, which is formed by heating pyrite in air, based on existing research. In this work, the mineralogical characteristics and stability conditions of synthetic pyrrhotite formed by heating pyrite at elevated temperatures were studied. The possible formation pathway was verified using a solid-phase reaction. X-ray-diffraction results revealed that synthetic pyrrhotite differs from natural pyrrhotite in the paragenetic association of minerals. Natural pyrrhotite and magnetite coexist in the natural pyrrhotite sample. Synthetic pyrrhotite formed by heating pyrite at 700℃ for 1 h has the paragenetic association with hematite and a small amount of pyrite and magnetite. All pyrrhotite samples were monoclinic pyrrhotite-4C (Fe7S8) and exhibit minimal differences in terms of lattice parameters. Synthetic pyrrhotite-4C was stable under 0.5–2 h of heating at 700℃ in air. It had the highest relative content by heating for 1 h. It was eventually transformed into hematite with heating periods exceeding 3 h, as was the case for pyrite and magnetite. In air, synthetic pyrrhotite-4C is mainly formed via two pathways: (1) pyrite → pyrrhotite-4C and (2) pyrite → magnetite → pyrrhotite-4C. Pathway (1) is more favorable than pathway (2). This transformation cannot be achieved by the reaction between hematite and sulfur.
Piryt jest minerałem siarczkowym szeroko rozpowszechnionym w przyrodzie. Piryt może przekształcić się w pirotyn podczas ogrzewania w wysokich temperaturach. W celu wsparcia technik inżynierii mineralnej i przemysłowego zastosowania pirytu i pirotynu, konieczne jest zbadanie syntetycznego pirotynu w oparciu o istniejące badania, który powstaje w wyniku ogrzewania pirytu w powietrzu. W pracy zbadano właściwości mineralogiczne i warunki trwałości syntetycznego pirotynu powstałego w wyniku ogrzewania pirytu w podwyższonej temperaturze. Możliwą ścieżkę powstawania zweryfikowano za pomocą reakcji w fazie stałej. Wyniki dyfrakcji rentgenowskiej ujawniły, że syntetyczny pirotyn różni się od naturalnego pirotynu w paragenetycznych asocjacjach minerałów. Naturalny pirotyn i magnetyt współistnieją w próbce naturalnego pirotynu. Syntetyczny pirotyn powstały w wyniku ogrzewania pirytu w temperaturze 700℃ przez 1 godz. wykazuje asocjację paragenetyczną z hematytem oraz niewielką ilością pirytu i magnetytu. Wszystkie próbki pirotynu były jednoskośnym pirotynem-4C (Fe7S8) i wykazują minimalne różnice pod względem parametrów sieci. Syntetyczny pirotyn-4C był stabilny w czasie 0,5–2 godzin ogrzewania w powietrzu w temperaturze 700℃. Najwyższą względną zawartość miał po ogrzewaniu przez 1 godzinę. Ostatecznie został przekształcony w hematyt z okresami ogrzewania przekraczającymi 3 godziny, podobnie jak w przypadku pirytu i magnetytu. W powietrzu syntetyczny pirotyn-4C powstaje głównie dwoma metodami: (1) piryt → pirotyn-4C i (2) piryt → magnetyt → pirotyn-4C. Ścieżka (1) jest korzystniejsza niż ścieżka (2). Tej przemiany nie można osiągnąć w reakcji hematytu z siarką.
Źródło:
Gospodarka Surowcami Mineralnymi; 2023, 39, 1; 23--34
0860-0953
Pojawia się w:
Gospodarka Surowcami Mineralnymi
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Pyrite oxidation inhibition by hydrophobic films for acid mine drainage control at the source
Autorzy:
Wang, Shuncai
Zhao, Yue
Li, Shuang
Powiązania:
https://bibliotekanauki.pl/articles/110200.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
hydrophobic film
pyrite
suppression
linoleic acid
acid mine drainage
Opis:
Acid mine drainage (AMD), which is also known as acid rock drainage (ARD), can cause serious environmental pollution, especially for surrounding aquatic and terrestrial ecosystems due toits low pH, high metal and sulfate concentration. Acid mine drainage is an urgent environmental problem for the worldwide ore mining industry. In this paper, we demonstrated that hydrophobic films can inhibit the oxidation of pyrite-bearing tailings to achieve the control of at-source AMD. The results of chemical leaching testing showed that the hydrophobic films formed by linoleic acid can suppress the oxidation of pyrite-bearing tailings and reduce the AMD production. In addition, the presence of hydrophobic films of linoleic acid on the surface of pyrite-bearing tailings was confirmed by the results from Fourier transform infrared (FTIR) analyses and scanning electron microscopy with energy dispersive spectrometry (SEM / EDS).
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 5; 1132-1140
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Evaluation of pyritic tailings from a copper concentration plant for calcareous sodic soil reclamation
Autorzy:
Tozsin, G.
Arol, A. I.
Cayci, G.
Powiązania:
https://bibliotekanauki.pl/articles/109593.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
waste pyrite
gypsum
pyrite oxidation
column leaching test
sodic soil
reclamation
Opis:
This study was aimed to investigate the feasibility to use waste pyrite and sulphuric acid produced from waste pyrite for the reclamation of calcareous sodic soils. The final aim is to displace Na from an exchange complex and replace it with Ca, leading to a decrease in pH and exchangeable sodium percentage (ESP) and an improvement of soil structure. A fertility of the soil may also be enhanced by this technique since waste pyrite can be rich in several micronutrients. An additional advantage to this strategy is that waste pyrite is inexpensive and readily available in large quantities, by contrast to gypsum. In this study, column-leaching tests were carried out to evaluate a change in soil properties upon addition of gypsum and pyritic tailing amendments from a copper concentration plant. An availability of essential micronutrients for a plant growth (Fe, Cu, Zn and Mn) and hazardous potential of pyritic tailings in terms of heavy metal contamination were taken into account. Gypsum, powder waste pyrite and sulfuric acid produced from waste pyrite were applied to the soil with reference to the gypsum requirement (GR) of the soils. The results showed that application of waste pyrite with a dose of 44.74 megagrams per ha was superior to gypsum of 55.20 Mg/ha dose in terms of exchangeable sodium percentage (ESP) in 42 weeks. In addition, application of all the concentrations of sulfuric acid produced from waste pyrite also decreased the ESP values. The best values with sulfuric acid were obtained with a dose of 35.31 Mg/ha in 26 weeks. It was observed that the content of all micronutrients in the soil increased significantly (P<0.01) with waste pyrite and sulfuric acid applications. The levels of the micronutrients after treatments can be classified sufficient for the plant growth except for the iron level with the minimum dose of sulfuric acid application 17 Mg/ha. The heavy metal content in the soil after treatment with the pyritic tailings was found to be lower than the legal limit values. Thus, waste pyrite can be effectively used since rapid amelioration of calcareous sodic soils is possible with no deleterious heavy metal contamination.
Źródło:
Physicochemical Problems of Mineral Processing; 2014, 50, 2; 693-704
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
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