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Tytuł:
Modification of Polyacrylamide-β-Zeolite Composite by Phytic Acid for the Removal of Lead from Aqueous Solutions
Autorzy:
Faghihian, H.
Farsani, S.N.
Powiązania:
https://bibliotekanauki.pl/articles/779338.pdf
Data publikacji:
2013
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
adsorption
lead
composite
polyacrylamide
phytic acid
Opis:
Polyacrylamide-zeolite composite was prepared by direct polymerization of polyacrylamide in suspension of β-zeolite. Phytic acid was then immobilized on the composite surface. Fourier transform infrared spektrometry (FT-IR), X-Ray Diffraction (XRD) and Thermal gravimetry (TG) techniques were employed to characterize the synthesized adsorbent. The adsorptive features of the composite and the modifi Ed composite were investigated for the removal of Pb2+ from aqueous solution in view of dependency on pH, time, ion concentration, temperature, selectivity, kinetics and reusability. The adsorption isotherms were evaluated with reference to the Langmuir and Freundlich models. Thermodynamic of the system was calculated. ΔG<0 indicated that the adsorption process was spontaneous. Good compatibility of the adsorption kinetics to the pseudo-second-order model predicted that the rate-controlling step was a chemical sorption. The selectivity experiments showed that the adsorbents were selective toward Pb2+ In the presence of Zn2+ and Cd2+. The reusability of the adsorbent was tested for four regeneration cycles.
Źródło:
Polish Journal of Chemical Technology; 2013, 15, 1; 1-6
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Innovative NPK Fertilizers based on Polyacrylamide and Polyvinyl Alcohol with Controlled Release of Nutrients
Autorzy:
Białkowska, Anita
Borycka, Bożena
Bakar, Mohamed
Rzany, Agnieszka
Powiązania:
https://bibliotekanauki.pl/articles/2174821.pdf
Data publikacji:
2022
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
polyacrylamide
fertilizers
polyvinyl alcohol
nutrients release
Opis:
The aim of the present work was the preparation and properties evaluation of two innovative fertilizers based on multicomponent polymers characterized by a controlled release of nutrients. One method was based on a multi-component liquid containing different amounts of microelements NPK 12-5-6 fertilizers with polyacrylamide hydrogel beads. The second method concerned the cross-linking of biodegradable polyvinyl alcohol with multi-component NPK fertilizers. Polyacrylamide-based compositions with the highest amount of NPK salts as well as polyvinyl alcohol-based fertilizers in dense gel form, based on 60 phr crosslinking concentrate have shown optimal properties. Regardless of the type of fertilizers used, their components were released slowly. The obtained fertilizers were classifi ed according to the kinetics of nutrient release. Fertilizers made from polyacrylamide based fertilizers have been classifi ed into a group of controlled release fertilizers (CRF), while those made from biodegradable environmentally friendly polyvinyl alcohol have been defi ned as slow released fertilizers (SRF).
Źródło:
Polish Journal of Chemical Technology; 2022, 24, 3; 14--18
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Selective adsorption of anionic polyacrylamide onto ultra-low ash coal and kaolinite
Autorzy:
Zou, W.
Yu, C.
Sun, C.
Cao, Y.
Powiązania:
https://bibliotekanauki.pl/articles/109333.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
coal
kaolinite
anionic polyacrylamide
adsorption
flotation
Opis:
To study the selectivity of polyacrylamide in the selective floc flotation of fine coal, adsorption of anionic polyacrylamide (PAM A401) onto ultra-low ash coal and kaolinite was studied, including the adsorption thermodynamics, floc size distribution and wettability changes. The thermodynamics of the adsorption process at the low concentration of 0-16 mg/dm3 of PAM A401 were studied at different contact times, doses, temperatures and pH values. Thermodynamic parameters of ΔGo, ΔHo, ΔSo and Ea were evaluated to understand the nature of the adsorption process. The results indicated that PAM A401 was selectively adsorbed onto ultra-low ash coal rather than kaolinite. Physical adsorption was the predominant mechanism, and the adsorption of PAM A401 at 12 mg•dm-3 onto coal was 2.15-fold larger than the adsorption on kaolinite. After the adsorption of PAM A401, the lipophilic hydrophilic ratio (LHR) of coal decreased from 9.23 to 7.28, indicating that the coal became less hydrophobic than before. In contrast, the LHR of kaolinite increased from 1.44 to 1.65. Floc size measurements showed that the d10, d50 and d90 of coal flocculated by PAM A401 (at 12 mg/dm3, pH 6.5) were 3.18, 2.76 and 2.59-fold greater than the corresponding levels of these parameters for kaolinite flocs, respectively.
Źródło:
Physicochemical Problems of Mineral Processing; 2016, 52, 2; 738-753
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of polyacrylamide on the process of removing impurities in the rare earth leachate
Autorzy:
Wu, Xiaoyan
Zhou, Fang
Liu, Chufan
Feng, Jian
Zhang, Zhenyue
Chi, Ruan
Powiązania:
https://bibliotekanauki.pl/articles/1448504.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
polyacrylamide
rare earth leachate
impurity removal
flocs
Opis:
The impurity removal process of the rare earth (RE) leachate is usually accompanied by the formation of flocs, and a certain amount of polyacrylamide flocculant needs to be added in this process. However, few studies have investigated the effect of the flocculant on the impurity removal process. Therefore, this paper compares the influence on the process of removing impurities with or without the adding of polyacrylamide (PAM). The results showed that the addition of PAM had little effect on the removal rate of impurities, but it was conducive to the recovery of RE. When ammonium bicarbonate was firstly adopted to regulate the solution pH to 5.0, and then sodium sulfide was used to adjust the pH to 5.2, and 0.5 mL/100 mL of PAM was added to the leachate, 96% $Al^{3+}$ and 98% $Zn{2+}$ were removed from the leachate, while 95% RE was maintained. In addition, PAM could accelerate the settlement of flocs and then shorten the production cycle. The increase in RE recovery rate may be due to the addition of PAM to shorten the settling time of the flocs, thereby reducing the RE ions adsorbed during the flocculation process and increasing the recovery rate of the RE.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 1; 182-191
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study of flocculation performance and mechanism of ultrafine montmorillonite particles with NPAM
Autorzy:
Wang, Lujun
Min, Fanfei
Chen, Jun
Wang, Ting
Zhou, Zhuang
Powiązania:
https://bibliotekanauki.pl/articles/2146901.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
montmorillonite
flocculant
nonionic polyacrylamide
density functional theory
Opis:
Ultrafine montmorillonite particles are the main clay minerals in industrial wastewater. In order to explore the flocculation performance and mechanism of flocculant with montmorillonite, the effects of nonionic polyacrylamide (NPAM) dosage and molecular weight on flocculation effect were studied using a flocculation sedimentation experiment. The morphology of flocs was observed by metallographic microscope and scanning electron microscope, and the microscopic adsorption mechanism was studied utilizing density functional theory (DFT). The results show that the best reagent system for the montmorillonite sample is that the molecular weight of NPAM is 14 million and the added amount is 100 g/t. The floc size increases with rising NPAM dosage, forming a unique multi-level compact space network structure through polymer bridging. The adsorption energy of acrylamide on the Na-(001) surface of montmorillonite is -108.81 kJ/mol, which is significantly higher than -50.66 kJ/mol on the None-(001) surface. Hydrogen bonding is not the main reason for the adsorption of acrylamide on the montmorillonite surface. NPAM mainly causes the flocculation and sedimentation of montmorillonite through the processes of polymer bridging and electrostatic attraction. This study can provide a theoretical basis for the design and synthesis of new flocculants.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 3; art. no. 147790
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on separation of fine-particle ilmenite and mechanism using flocculation flotation with sodium oleate and polyacrylamide
Autorzy:
Peng, Yang
Xiao, Junhui
Deng, Bing
Wang, Zhen
Liu, Nengyun
Yang, Daoguang
Ding, Wei
Chen, Tao
Wu, Qiang
Powiązania:
https://bibliotekanauki.pl/articles/1450088.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
sodium oleate
polyacrylamide
synergistic effect
ilmenite
flocculation flotation
Opis:
In this paper, sodium oleate, polyacrylamide, soluble starch and sodium carboxymethyl cellulose were used as flocculants to study the flocculation and sedimentation behavior of microfine ilmenite. Sedimentation test shows that sodium oleate and polyacrylamide have good flocculation effect on ultrafine ilmenite. The flocculation rate of ilmenite can be further improved by the combination of sodium oleate and polyacrylamide. It was found that both flocculants could generate chemical adsorption with ilmenite surface, and they all react with $Fe^{3+}$ on ilmenite surface. However, sodium oleate reacts with $Fe^{3+}$ to form a water-insoluble iron oleate precipitate which coats the surface of the ilmenite and hinders the action of polyacrylamide and the remaining $Fe^{3+}$. This problem can be avoided by adding polyacrylamide followed by sodium oleate, and the flotation recovery can be increased significantly.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 1; 161-172
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Viscometric studies of chitosan/polyacrylamide mixtures
Autorzy:
Lewandowska, Katarzyna
Sionkowska, Alina
Krasińska, Katarzyna
Powiązania:
https://bibliotekanauki.pl/articles/1035184.pdf
Data publikacji:
2014
Wydawca:
Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
Tematy:
chitosan
miscibility criteria
polyacrylamide
polymer blends
viscosity interaction parameters
Opis:
Polymer-polymer interactions and miscibility for chitosan (Ch) and partially hydrolysed polyacrylamide (HPAM) have been investigated using dilute solution viscosity. The intrinsic viscosity, [η], and the viscosity interaction parameters, bm, have been determined for the binary (solvent/polymer) and ternary (solvent/polymer A/polymer B) systems. Degree of miscibility of these polymer mixtures was estimated on the basis of two criteria. The final result depends on (i) the applied extrapolation method used for determination of the interaction parameters, (ii) the assumed miscibility criteria, and (iii) the blend composition.
Źródło:
Progress on Chemistry and Application of Chitin and its Derivatives; 2014, 19; 73-78
1896-5644
Pojawia się w:
Progress on Chemistry and Application of Chitin and its Derivatives
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Flocculation efficiency of hybrid polymers with trivalent metal cations
Autorzy:
Schmidt, B.
Powiązania:
https://bibliotekanauki.pl/articles/779472.pdf
Data publikacji:
2018
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
polyacrylamide copolymers
starch
hybrid polymers
trivalent metal cations
flocculants
Opis:
Acrylamide/acrylic acid copolymers (AAm/AA) have been synthesized by microemulsion polymerization in absence and presence of trivalent cations Al+3  and Fe+3 . Starch materials were obtained by introducing cations Al+3  and Fe+3 , in the form of aqueous solutions of sulphates(VI) (modif. starch/Me+3 ), into the oxidized starch (modif. starch). The flocculation performance of obtained polyacrylamide copolymers and the one based on the natural polymer was compared with the performance of the commercial AAm/AA flocculant (CF). All materials were characterized by capillary viscometry, FTIR and DSC methods. An aqueous suspension of talc was used for the flocculation studies. The flocculation effectiveness was evaluated on the basis of reduction of suspension extinction and the sludge volume. It was found that synthesized AAm/AA/Me+3  copolymers and modif. starch/Me+3  materials exhibit better flocculation properties for a model talc suspension than a commercially available floculant.
Źródło:
Polish Journal of Chemical Technology; 2018, 20, 4; 96-101
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Miscibility and interactions in chitosan and polyacrylamide mixtures
Autorzy:
Lewandowska, Katarzyna
Powiązania:
https://bibliotekanauki.pl/articles/1035186.pdf
Data publikacji:
2014
Wydawca:
Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
Tematy:
AFM
FTIR analysis
chitosan
polyacrylamide
polymer blends
surface properties
Opis:
In the present work, the results of Fourier transform infrared (FTIR) and atomic force microscopy (AFM) studies of films of chitosan acetate (ChA), polyacrylamide (PAM), and their mixtures are presented. The morphology of the ChA and PAM films and their mixtures was studied by tappingmode atomic force microscopy (AFM). The topography images were considered by determining the root mean square (RMS) deviation in the image data. The study of mixtures by AFM showed a completely different morphology when compared with pure components. The roughness of mixtures increases with the increase of ChA content but is significantly reduced after UV exposure. This may indicate a strong interaction between the polymeric components. The FTIR spectroscopy also supports the obtained results. The miscibility of polymer mixtures is related to interactions between the functional groups of the polymeric components.
Źródło:
Progress on Chemistry and Application of Chitin and its Derivatives; 2014, 19; 65-71
1896-5644
Pojawia się w:
Progress on Chemistry and Application of Chitin and its Derivatives
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Rheological properties of chitosan blends with partially hydrolyzed polyacrylamide in different solvents
Autorzy:
Lewandowska, Katarzyna
Powiązania:
https://bibliotekanauki.pl/articles/1035377.pdf
Data publikacji:
2012
Wydawca:
Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
Tematy:
apparent shear viscosity
chitosan
polyacrylamide
polymer blends
rheological properties.
Opis:
In the present paper, the results of rheological measurements in solutions of chitosan (Ch) with partially hydrolyzed polyacrylamide (HPAM) are presented. Aqueous acetic acid, lactic acid and aqueous acetic acid/NaCl were used as solvents for chitosan, HPAM and Ch/HPAM solution blends. The criterion of miscibility of solution blends, based on the additivity rule of apparent shear viscosity (ηa) has been discussed. The rheological parameters from power law (Ostwald de Waele model) and activation energy of viscous flow (Ea) have been calculated from the flow curves and Arrhenius plots, respectively. It was found that studied polymer solutions exhibited the non-Newtonian behaviour with shear-thinning and/or shear-thickening areas. The final result depends on the thermodynamic goodness of the solvent and on the blend composition.
Źródło:
Progress on Chemistry and Application of Chitin and its Derivatives; 2012, 17; 53-62
1896-5644
Pojawia się w:
Progress on Chemistry and Application of Chitin and its Derivatives
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Elastyczne podłoża poliakryloamidowe do badań komórkowych
Elastic polyacrylamide substrates for cell studies
Autorzy:
Zamora, K.
Dziob, D.
Nowak, J.
Piekarczyk, W.
Rajfur, Z.
Laska, J.
Powiązania:
https://bibliotekanauki.pl/articles/284999.pdf
Data publikacji:
2014
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Polskie Towarzystwo Biominerałów
Tematy:
podłoża poliakryloamidowe
elastyczność
hydrożele
keratynocyty
polyacrylamide substrates
elasticity
hydrogels
keratinocytes
Opis:
Podłoża do hodowli komórkowej charakteryzują się różnymi właściwościami mechanicznymi, które mogą mieć znaczący wpływ na zachowanie komórek. Szczególnie ciekawy typ podłoży stanowią hydrożele akryloamidowe, zarówno ze względu na łatwość ich syntezy, jak i na fakt, iż poprzez niewielkie zmiany ilości substratów wykorzystywanych w wytwarzaniu tych podłoży, można uzyskać podłoża znacznie różniące się elastycznością. Dodatkową zaletą hydrożeli akryloamidowych jest to, że pomimo znacznych różnic elastyczności, biozgodność i bioaktywność pozostają niezmienione. W niniejszym artykule skupiono się na opisie syntezy podłoży akryloamidowych do hodowli komórkowej, a także na scharakteryzowaniu ich cech mechanicznych i sprawdzeniu wpływu elastyczności podłoży na hodowlę rybich komórek keratynocytowych. Keratynocyty to komórki, których hodowla jest niewymagająca, w porównaniu do innych linii komórkowych, gdyż mogą one być hodowane bez konieczności wykorzystywania drogich pożywek, a także bez konieczności inkubowania w temperaturze 37 stopni Celsjusza. W pracy szczegółowo opisano sposób wytwarzania podłoży akryloamidowych o różnych stopniach elastyczności. Hydrofilowość otrzymanych podłoży sprawdzano metodą goniometryczną poprzez pomiar kąta zwilżania. Istotną częścią eksperymentu było określenie właściwości mechanicznych otrzymanych podłoży poprzez pomiar prędkości rozchodzenia się podłużnej fali ultradźwiękowej. W ten sposób porównano właściwości mechaniczne czterech podłoży różniących się modułem elastyczności. Stwierdzono, iż największe prędkości rozchodzenia się fal dotyczą próbek o najniższym module elastyczności, co świadczy o największym upakowaniu cząsteczek polimeru i pośrednio potwierdza najwyższy stopień usieciowania polimeru. Otrzymane podłoża posłużyły jako matryce do hodowli keratynocytów, których migrację obserwowano pod mikroskopem. Zaobserwowano znaczne różnice w zachowaniu się komórek, szybkości ich migracji oraz przyjmowaniu kształtu wskazującego stresogenne działanie podłoży o niskim module elastyczności rzędu kilku kPa oraz korzystne oddziaływanie podłoży twardych o module elastyczności >30 kPa.
Cell culture substrates show different mechanical properties, that may have significant influence on behavior of cells. Acrylamide hydrogels are particularly interesting substrates, due to both the ease of their synthesis and the fact, that by small changes in the amounts of reactants used in their manufacturing process, one can obtain substrates of significantly different elasticity level. An additional advantage of acrylamide hydrogels is that despite of significant changes in elasticity they exhibit no changes in biological properties. This article is focused on the synthesis of acrylamide substrates for cell culturing, characterization of their mechanical properties, and also on searching the influence of elasticity of the substrates on culture of fish keratinocytes. Keratinocytes are cells, which culture is simplified, compared to other cell lines, since they may be cultured without usually expensive nourishments and the necessity of incubation at 37 degrees of Celsius. The detailed description of the synthesis of acrylamide substrates of different levels of elasticity is given in this paper. Hydrophilicity of the obtained substrates was also investigated by testing the contact angle by goniometric method. An important part of the experiment was determining mechanical properties of the obtained substrates by measuring velocity of propagation of ultrasonic longitudinal wave for substrates of different elasticity modules. In that way comparison of the elasticity of the four different substrates was possible. It has been found, that the largest wave propagation velocity refers to the samples of the lowest elastic modules, what proves the highest degree of cross-linking in these hydrogels. The established substrates were used as matrices for keratinocytes culture, which migration was observed under the microscope. Depending on the substrate significant differences in cell behavior, their migration velocity, and shape changing has been observed. The soft hydrogels with elasticity modulus less than several kPa were stressful for the cells while hard ones with elasticity of >30 kPa were beneficial.
Źródło:
Engineering of Biomaterials; 2014, 17, 124; 11-18
1429-7248
Pojawia się w:
Engineering of Biomaterials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Surface properties of chitosan acetate, polyacrylamide and their mixtures
Autorzy:
Lewandowska, Katarzyna
Powiązania:
https://bibliotekanauki.pl/articles/1035217.pdf
Data publikacji:
2013
Wydawca:
Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
Tematy:
AFM
chitosan acetate
contact angle
polyacrylamide
polymer blends
surface properties
Opis:
The surface properties of chitosan acetate (ChA), polyacrylamide (PAM) and ChA/PAM mixtures have been investigated by the tapping-mode atomic force microscopy (AFM) and monitored by contact angle measurements. Chitosan is blended with polyacrylamide in acetic acid solution and this solution is cast to prepare the mixture film. Measurements of the contact angle for two different liquids (diiodomethane and glycerol) on the surface of chitosan acetate. The surface free energy (γs) as well as dispersive (gsd) and polar (gsp) components were calculated from contact angle values by Owens-Wendt methods using an appropriate computer program. The values of polar and dispersive components of surface free energy show that PAM films are more polar than chitosan acetate films. In the case of ChA/PAM mixtures, the values of surface free energy and polar component are reduced significantly compared with pure polymers. This behavior indicates rather hydrophobic character of this surface. The changes of topography images were considered by determining the root mean square (RMS) deviation in the image data. The study of blends by AFM showed a completely different morphology when compared with pure components. The roughness of blends increases with the increase of ChA content. This may indicates a strong interaction between the polymeric components.
Źródło:
Progress on Chemistry and Application of Chitin and its Derivatives; 2013, 18, 18; 29-34
1896-5644
Pojawia się w:
Progress on Chemistry and Application of Chitin and its Derivatives
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The benefits of synthetic or natural hydrogels application in agriculture : an overview article
Autorzy:
Grabowska-Polanowska, Beata
Garbowski, Tomasz
Bar-Michalczyk, Dominika
Kowalczyk, Agnieszka
Powiązania:
https://bibliotekanauki.pl/articles/2048494.pdf
Data publikacji:
2021
Wydawca:
Instytut Technologiczno-Przyrodniczy
Tematy:
biopolymers
hydrogels
infiltration
polyacrylamide
polyacrylic polymers
superabsorbent polymers
surface runoff
SAP
Opis:
In recent years, a growing problem of water deficit has been observed, which is particularly acute for agriculture. To alleviate the effects of drought, hydrogel soil additives – superabsorbent polymers (SAPs) – can be helpful. The primary objective of this article was to present a comparison of the advantages resulting from the application of synthetic or natural hydrogels in agriculture. The analysis of the subject was carried out based on 129 articles published between 1992 and 2020. In the article, the advantages of the application of hydrogel products in order to improve soil quality, and crop growth. Both kinds of soil amendments (synthetic and natural) similarly improve the yield of crops. In the case of natural origin polymers, a lower cost of preparation and a shorter time of biodegradation are indicated as the main advantage in comparison to synthetic polymers, and greater security for the environment.
Źródło:
Journal of Water and Land Development; 2021, 51; 208-224
1429-7426
2083-4535
Pojawia się w:
Journal of Water and Land Development
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Flocculation properties of Dextran-graft-Polyacrylamide of various internal structure
Właściwości flokulacyjne Dekstranu -graft- Poliakryloamidowego o różnych strukturach wewnętrznych
Autorzy:
Kutsevol, N.
Bezuglyi, M.
Vysotska, V.
Powiązania:
https://bibliotekanauki.pl/articles/388483.pdf
Data publikacji:
2009
Wydawca:
Towarzystwo Chemii i Inżynierii Ekologicznej
Tematy:
dekstran
poliakryloamid
kopolimery szczepione
flokulacja
zawiesina kaolinu
dextran
polyacrylamide
graft copolymers
flocculation
kaolin suspension
Opis:
Two series of Dextran-graft-Polyacrylamide copolymers (D-g-PAA) with polysaccharide backbone having different molecular weights (Mw= 20 000 and Mw= 70 000) and willi 5, 10, 15 or 20 PAA-grafts per one Dextran macromolecule were tested as flocculation aids in the model kaolin suspensions. These copolymers have shown high flocculation efficiency significantly dependent upon their internal structure. The flocculation ability or D-g-P AA samples with the same number or P AA-grafts inversely relates to the spacing or the grafts (ie the length or back-bone between the grafts).
Badano właściwości flokulacyjne kopolimerów dekstran-graft-poliakryloamidowych (DG-PAA) ze szkieletem dekstranowym o dwóch różnych masach molekularnych (Mw = 20 000 i Mw = 70 000) oraz z 5, 10, 15 lub 20 molekułami PAA dołączonymi (zaszczepionymi) do tego makromolekularnego szkieletu. Do pomiarów wykorzystywano zawiesinę kaolinu w wodzie. Kopolimery te miały dużą skuteczność flokulacyjną zależną od ich struktury molekularnej. Zdolność flokulacyjna próbek D-g-PAA, z taką samą liczbą zaszczepionych molekuł P AA, jest odwrotnie proporcjonalna do odległości między molekułami zaszczepionymi do szkieletu molekuły dekstranu.
Źródło:
Ecological Chemistry and Engineering. A; 2009, 16, 1-2; 127-133
1898-6188
2084-4530
Pojawia się w:
Ecological Chemistry and Engineering. A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Rozpuszczalne w wodzie kopolimery dekstran-poliakryloamid i ich pochodne anionowe jako matryce w syntezie in situ nanocząstek metali
Water-soluble branched copolymers dextran-polyacrylamide and their anionic derivates as matrices for metal nanoparticles in situ synthesis
Autorzy:
Bezugly, M.
Kutsevol, N.
Rawiso, M.
Bezugla, T.
Powiązania:
https://bibliotekanauki.pl/articles/1218495.pdf
Data publikacji:
2012
Wydawca:
Stowarzyszenie Inżynierów i Techników Przemysłu Chemicznego. Zakład Wydawniczy CHEMPRESS-SITPChem
Tematy:
kopolimery rozgałęzione
dekstran
poliakryloamid
poli(kwas akrylowy)
nanocząstki
branched copolymers
polyacrylamide
polyacrylic acid
dextran
nanoparticles
Opis:
Przeprowadzono syntezę nanocząstek metali w matrycach wodorozpuszczalnych polimerów o różnej wewnętrznej budowie makromolekularnej. Liniowy poliakryloamid (PAA) i rozgałęzione gwiaździste kopolimery dekstran-szczepiony poliakryloamid (D-g-PAA) i ich pochodne anionowe zastosowano do syntezy in-situ nanoukładów Ag i Pd. Zbadano wpływ charakteru matrycy i budowy wewnętrznej makrocząsteczek w roztworze na tworzenie nanocząstek.
Metal nanoparticles were synthesized in water-soluble polymer matrices with different internal macromolecule structures. Linear Polyacrylamide (PAA) and branched star-like copolymers Dextrangraft- Polyacrylamide (D-g-PAA) and their anionic derivatives were used for in situ synthesis of Ag and Pd nanosystems. The influence of the matrix nature and internal structure of macromolecules in solution on the nanoparticles formation was studied.
Źródło:
Chemik; 2012, 66, 8; 862-867
0009-2886
Pojawia się w:
Chemik
Dostawca treści:
Biblioteka Nauki
Artykuł
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