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Wyszukujesz frazę "phosphate adsorption" wg kryterium: Temat


Wyświetlanie 1-10 z 10
Tytuł:
Kinetyka adsorpcji jonów fosforanowych z wód powierzchniowych z użyciem preparatu Phoslock
Adsorption kinetics of phosphate ions from surface waters using Phoslock
Autorzy:
Jodłowski, A
Gutkowska, E
Dobrzański, M
Powiązania:
https://bibliotekanauki.pl/articles/297068.pdf
Data publikacji:
2012
Wydawca:
Politechnika Częstochowska. Wydawnictwo Politechniki Częstochowskiej
Tematy:
Phoslock
adsorpcja fosforanów
kinetyka
metody rekultywacji
phosphate adsorption
kinetics
remediation methods
Opis:
Phoslock jest adsorbentem produkowanym na bazie glinki bentonitowej modyfikowanej lantanem, który zgodnie z informacjami literaturowymi skutecznie obniża stężenie fosforanów w wodach powierzchniowych. Mechanizm reakcji polega na wiązaniu anionów fosforanowych z jonami lantanu w stosunku 1:1. W artykule zaprezentowano wyniki badań nad kinetyką adsorpcji jonów fosforanowych przy użyciu preparatu Phoslock, wykorzystując podczas ich interpretacji równanie szybkości reakcji rzędu pseudodrugiego. Przedstawiono wyniki badań dotyczące skuteczności działania preparatu Phoslock prowadzone z wykorzystaniem roztworów wodnych odpowiednio przygotowanych w laboratorium oraz porównawczo wody naturalnej pochodzącej ze sztucznego zbiornika Rochna położonego w odległości około 30 km od Łodzi. Proces adsorpcji jonów fosforanowych zachodził intensywniej w roztworze modelowym niż w wodzie naturalnej.
Eutrophication and its harmful effects cause the need for finding methods of slowing, halting or even reversing this process and its consequences. Currently, the most important and most frequently used methods of remediation are these that use compounds that bind/remove phosphorus. Phoslock is an adsorbent based on lanthanum-modified bentonite clay that effectively lowers the phosphate concentration in surface waters. The reaction mechanism involves binding of phosphate anions with the lanthanum ions in a molar ratio of 1:1 and thus forming lanthanum phosphate (rhabdophane). A characteristic feature of this reaction is that the rhabdophane may be formed when concentrations of La3+ and −34PO are low. Research on the use of Phoslock in phosphate reduction revealed that the complex of lanthanum and phosphate may occur in the pH range 5÷9. It was also found that the rate of adsorption rate increased at higher temperatures. This article studied the kinetics of adsorption of phosphate ions with Phoslock described by the equation of reaction rateof pseudo-second order. Article presents results of research on the effectiveness/efficiency of Phoslock when using water properly prepared in laboratory, and comparatively, natural water coming from the artificial lake Rochna which is used for recreational purposes. Lake Rochna is situated about 30 km from the city of Lodz. Results indicate that the process of adsorption of phosphate ions occurred more intensively in the pre-made model water than in natural water.
Źródło:
Inżynieria i Ochrona Środowiska; 2012, 15, 3; 295-305
1505-3695
2391-7253
Pojawia się w:
Inżynieria i Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Efficient phosphate removal in swine wastewatewater using Fe-Mn-modified pyro/hydrochar from swine manure
Autorzy:
Zhu, Fanglun
Zhang, Cheng
Shan, Shengdao
Yuan, Wenqiao
Pawłowski, Artur
Song, Chengfang
Cao, Yucheng
Li, Yongfu
Wangj, Junjie
Qian, Jinyao
Powiązania:
https://bibliotekanauki.pl/articles/2032865.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
phosphate adsorption
pig
water eutrophication
biochar
swine manure
adsorpcja fosforanów
trzoda chlewna
eutrofizacja wód
biowęgiel
obornik świński
Opis:
Phosphorus in wastewater is one of the main causes of water eutrophication. Phosphorus removal from swine wastewater is always a challenge. To achieve on-site recycling of swine farm waste, the low-cost pyro/hydrochars and their Fe-Mn-modified form were prepared from swine manure as an efficient adsorbent for phosphate removal. The results showed that the phosphate removal efficiency of unmodified pyro/hydrochars was less than 7.77%, which was significantly increased to 58.21–83.76% for the Fe-Mn-modified-pyro/hydrochars. The maximum adsorption capacity of pyrochar was found on the Fe-Mn-modified-pyrochar (PC-600M) with a surface area of 102.03 m2/g and a micropore volume of 0.25 cm3/g. The PC-600M exhibited high adsorption capacity (26.07 mg/g) in a low concentration of phosphate (50 mg/dm3), and its removal efficiency reached up to 83.76% within 24 hours. Furthermore, the adsorption of phosphate on biochars without modification (HC-210 and PC-600) was validated using a first-order kinetic model, and the adsorption of phosphate on modified biochars (HC-210M and PC-600M) was well described by the second-order kinetic model and Langmuir isotherm. In addition, there is no significant difference in the adsorption of phosphorus between pyrochars and hydrochars, but the preparation cost of hydrochars is lower than that of pyrochars. It was confirmed that the low-cost Fe-Mn-modified pyro/hydrochar from swine manure had potential for efficient phosphate removal in wastewater treatment and would facilitate value-added utilization of swine manure.
Źródło:
Environment Protection Engineering; 2021, 47, 3; 83-101
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Phosphate removal from aqueous solutions by chitin and chitosan in flakes
Autorzy:
Szymczyk, Paula
Filipkowska, Urszula
Jóźwiak, Tomasz
Kuczajowska-Zadrożna, Małgorzata
Powiązania:
https://bibliotekanauki.pl/articles/1034690.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
Tematy:
adsorption
chitin
chitosan
phosphate
Opis:
The article presents the effectiveness of phosphate adsorption on the flakes of chitin and chitosan. Studies performed determined adsorption capacity of chitin and chitosan, best among the tested adsorption pH and the equilibrium time. Langmuir model was used to describe the results. The highest removal efficiency of phosphorus compounds using chitin was obtained at pH 3 and with chitosan at pH 4. The study of phosphate equilibrium concentration time obtained for both sorbents was carried out at three concentrations of 1, 5 and 10 mg/dm3. The highest sorption efficiency of the phosphate using chitin was achieved after 20 minutes of the process and at the chitosan after 40 minutes. In the case of chitosan after the equilibrium time the effect of partial P-PO4 release was observed, which could be related to the change in pH of the solution by the sorbent. Studies have shown that chitosan is a more effective absorbent for phosphorus compounds. The maximum adsorption capacity of chitosan with phosphate was 6.65 mg/g, and chitin - 2.09 mg/g.
Źródło:
Progress on Chemistry and Application of Chitin and its Derivatives; 2016, 21; 192-202
1896-5644
Pojawia się w:
Progress on Chemistry and Application of Chitin and its Derivatives
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption Kinetics of Edamame Soybean Peel Activated Carbon in Reducing the Level of Phosphate
Autorzy:
Eri, Iva Rustanti
Pramudinta, Namira Kholifatul
Nurmayanti, Demes
Powiązania:
https://bibliotekanauki.pl/articles/2027815.pdf
Data publikacji:
2022
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
adsorption kinetics
activated carbon
phosphate
Opis:
Domestic wastewater, such as detergent wastewater, causes the increase of the phosphate level that strongly contributes to eutrophication. Adsorption is a method that can be used to reduce the levels of phosphate. The natural ingredients that can be made as activated carbon include edamame soybean peel, because it contains a lot of celluloses. This research aimed to analyze the adsorption kinetics and adsorption capacity of edamame soybean peel activated carbon in reducing the phosphate levels. Adsorption was carried out with batch method with various concentrations of adsorbate (2 mg/L, 4 mg/L, and 6 mg/L) and stirring time (3 hours, 6 hours, 9 hours, and 12 hours). The results showed that the highest adsorption capacity was found in 6 mg/L of adsorbate concentration and 6 hours of stirring time. The results were validated by the Langmuir isotherm and pseudo-second-order adsorption kinetics model. The Langmuir isotherm indicated that adsorption occurred in monolayer. The maximum adsorption capacity was 0.43509 mg/g and the constant of adsorption kinetics was 1.5558 g/mg•min. Activated carbon from edamame soybean peel successfully reduced the levels of phosphate. The increase of adsorption capacity was correlated with the increasing concentration of adsorbate and stirring time until the equilibrium.
Źródło:
Journal of Ecological Engineering; 2022, 23, 2; 97-107
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of temperature in removing of anions in solution on biochar using Zea mays stalks as a precursor
Autorzy:
Villabona-Ortiz, Ángel
Tejada-Tovar, Candelaria
Ortega-Toro, Rodrigo
Powiązania:
https://bibliotekanauki.pl/articles/1841960.pdf
Data publikacji:
2021
Wydawca:
Instytut Technologiczno-Przyrodniczy
Tematy:
adsorption
biochar
cornstalks
nitrate
sulfate
phosphate
Opis:
Biochar was prepared from corn (Zea mays) stalks and impregnated with sulfuric acid. The biomass was impregnated for 24 h with a 50% solution of H2SO4 with impregnation ratios 1:2 (B 1:2) and 1:3 p/v (B 1:3); then, it was carbonized in a muffle furnace at 520°C for 30 min with a 10°C per min ramp. The adsorption capacity to remove anions (nitrate, sulfate, and phosphate) in an aqueous solution was evaluated by varying the temperature. The adsorption mechanism was studied by determining the thermodynamic parameters: Gibbs free energy (ΔGº), enthalpy (ΔHº) and entropy (ΔSº) standard. The biochars were characterized by Scanning Electron Microscopy-Energy Dispersive X-Ray Spectroscopy (SEM-EDS) analysis and were found to exhibit a heterogeneous surface and porous nature, with C, O, S, and Si. The experiments in the batch system showed the best performance of B 1: 2 in the removal of the three anions occurred at 303 K, while B 1: 3 had the best performance at 298 K. From the thermodynamic parameters, it was found that the removal processes are endothermic, their mechanism is by chemisorption. It is concluded that synthesized biochar is an excellent alternative to removing nutrient anions present in the solution.
Źródło:
Journal of Water and Land Development; 2021, 50; 64-68
1429-7426
2083-4535
Pojawia się w:
Journal of Water and Land Development
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The mechanism of phosphate bacteria in increasing the solubility of phosphorus in Indonesian Andisols
Autorzy:
Tamad, -
Maas, Azwar
Hanudin, Eko
Widada, Jaka
Powiązania:
https://bibliotekanauki.pl/articles/1844351.pdf
Data publikacji:
2021
Wydawca:
Instytut Technologiczno-Przyrodniczy
Tematy:
adsorption
Andisols
mineralization
phosphate bacteria
solubilisation
Opis:
The purpose of this research was to determine: 1) phosphate bacteria (PB) mechanisms responsible for enhancing the soil’s soluble phosphorus (P), using the processes of inorganic P solubilisation, organic P mineralization, and blocking of soil colloidal adsorption site, and 2) to investigate the factors contributing to this increase. Phosphate bacteria (PB) was inoculated into sterile Andisols in three separate compositions, termed 1 kg P∙kg–1 (2.82 g phosphate rock, 0.5 g Ca3(PO4)2, 0.4 g Al3(PO4)2, or 0.4 g Fe3(PO4)2), organic P (0.5 cm3 para-Nitrophenylphosphate (pNPP) or 0.5 g Na-phytate), and 1 kg P (KH2PO4)∙kg–1, in order to analyse inorganic P solubilisation, organic P mineralization, and evaluate blocking soil colloidal site for adsorption P, respectively. Furthermore, spectrophotometry technique was applied to determine the amount of dissolved P. The PB showed an improvement in inorganic P solubilisation from 147.66 to 194.61 mg P∙kg–1, and also in organic P from 63.6 to 91.7 mg P∙kg–1, compared to control, (31.06 mg P∙kg–1) and (23.7 mg P∙kg–1), respectively. Meanwhile, the micro-organisms were known to decrease P adsorption by 13.43%, beyond the restraint set at 85.34%. Therefore, increased soluble P in Andisols is possibly expressed, using the equation as follows: soluble P (mg P∙kg–1) = 1201.96 + 1.18 inorganic P solubilisation (mg P∙kg–1) + 1.09 organic P mineralization (mg P∙kg–1) – 0.92 adsorption P (mg P∙kg–1) (R2 = 0.99).
Źródło:
Journal of Water and Land Development; 2021, 49; 188-194
1429-7426
2083-4535
Pojawia się w:
Journal of Water and Land Development
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of compound phosphate collector on flotation separation of jamesonite from marmatite and insights into adsorption mechanism
Autorzy:
Huang, Weiqin
Gu, Guohua
Chen, Xiong
Wang, Yanhong
Powiązania:
https://bibliotekanauki.pl/articles/1448921.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
compound phosphate
jamesonite
marmatite
flotation separation
adsorption mechanism
Opis:
Separating jamesonite and marmatite is difficult due to their similar response to traditional collectors. To improve the selectivity of the collector and simplify the reagent system, compound phosphate (MP) as a collector for the separation of jamesonite from marmatite was studied in this study. The flotation tests revealed that, compared with the most used butyl xanthate (BX), MP had the advantages of lower dosage and stronger selectivity under weak acid pulp. Under the optimum flotation conditions, a concentrate with the grade of 31.54% Pb, 6.93% Zn and the recovery of 89.87% Pb, 12.31% Zn could be obtained from mixed binary minerals flotation (mass ratio of 1:1). Adsorption, zeta potential, FT-IR and XPS analysis demonstrated that MP performed strong chemisorption on jamesonite surface while underwent weak physisorption on marmatite, this difference was responsible for the excellent selectivity of MP toward jamesonite flotation and weak collecting capacity to marmatite.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 1; 294-304
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The effect of hydrothermal modification of titanium phosphate on the adsorption affinity towards cadmium ions
Autorzy:
Janusz, Władysław
Khalameida, Svietlana
Skwarek, Ewa
Sydorchuk, Vladimir
Charmas, Barbara
Powiązania:
https://bibliotekanauki.pl/articles/110216.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
titanium phosphate
FTIR-ATR
hydrothermal treatment
adsorption
cadmium ions
Opis:
The effect of hydrothermal treatment of the gel or xerogel oftitanium phosphate (TiP) sample on the surface properties was studied usingthe EDS and FTIR ATR methods. The results show that the hydrothermal treatment of initial titanium phosphate decreases the amount of physically adsorbed water but increases the surface concentration of phosphate groups. Supplementary measurements of electrokinetic properties of modified and hydrothermally modified titanium phosphate samples confirmed an increase of the concentration of acidic groups on theTiP surface. The adsorption affinity of titanium phosphate towards cadmium ions was discussed. It was found that at a low initial concentration of cadmium ions adsorption affinity increases as a resultof hydrothermal treatment of TiP gel.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 6; 1568-1576
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Magnetite Oxide Nanoparticles and Tungsten Oxide Nanoparticles on Phosphate Removal from Aqueous Solutions
Autorzy:
EL-Baz, Amro
Mokhtar, Mona
Abdo, Ahmed
Powiązania:
https://bibliotekanauki.pl/articles/24201790.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
phosphate removal
nanoparticles
Fe3O4 NPs
WO3 NPs
adsorption
desorption
Opis:
Phosphate (P) removal from aqueous solutions were studied by a new mineral adsorbent, tungsten (VI) oxide (WO3) nanoparticles (NPs), which has not been the subject of much research in the field of removing P contaminants from agricultural wastewater. In this paper, P was removed from aqueous solutions by a new mineral adsorbent, WO3 NPs and it was compared with magnetite (iron IV) oxide (Fe3O4) nanoparticles (NPs) under the same ambient operating conditions i.e., The influence of the dosage of adsorbents, initial P concentration, contact time, pH and temperature. The values that achieved the best removal were recorded. It was concluded that the best limits for pH were at 2–3, contact time at 40 minutes, temperature at 45 °C and adsorbent dose at 1.0 g/L. Best results of the variables were applied on samples of real agricultural wastewater, which achieved removal ratio of 77.3% and 75.42% for Fe3O4 and WO3 NPs, respectively. SEM, EDX and FTIR images and analyses were conducted to describe the characteristics of nano-adsorbents used before and after P adsorption in aqueous solutions. The P adsorption kinetics for aqueous solutions were examined by fitting results of the experiment to both the first & second pseudo-kinetically models. The outcome indicated that kinematic data fit better with pseudo-second-order kinetic models. Moreover, the information captured from equilibrium adsorption was analyzed using isothermal methods (by Langmuir & Freundlich Forms). Their results showed that the Freundlich form is considered more suitable than Langmuir form in analyzing the biosorption of P ions. The thermodynamic demeanor of P adsorption by Fe3O4 and WO3 NPs was analyzed and evaluated, and the thermodynamic data analyses confirmed the process of P adsorption was spontaneous. The ΔG° value was negative, while ΔH° and ΔS° values found to be positive, which means that the adsorption of P was a spontaneous, random and endothermic operation. In general, Fe3O4 and WO3 nanoparticles had a high efficiency in removing phosphate from water. In addition, WO3 NPs has been identified as one of the most promising adsorbents due to its rapid and effective adsorption of pollutants.
Źródło:
Journal of Ecological Engineering; 2023, 24, 3; 287--303
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of phosphates on dissolved organic matter release from peat-muck soils
Autorzy:
Sokolowska, Z.
Szajdak, L.
Boguta, P.
Powiązania:
https://bibliotekanauki.pl/articles/24997.pdf
Data publikacji:
2011
Wydawca:
Polska Akademia Nauk. Instytut Agrofizyki PAN
Tematy:
amino acid content
ash
bulk density
calcium form
dissolved organic matter
humic acid
muck
organic matter
peat bog soil
pH
peat soil
peat-muck soil
phosphate
surface property
water adsorption index
Źródło:
International Agrophysics; 2011, 25, 2
0236-8722
Pojawia się w:
International Agrophysics
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-10 z 10

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