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Wyszukujesz frazę "partial melting" wg kryterium: Temat


Wyświetlanie 1-2 z 2
Tytuł:
Thermal metamorphic evolution of the Pułtusk H chondrite breccia – compositional and textural properties not included in petrological classification
Autorzy:
Krzesinska, A. M.
Powiązania:
https://bibliotekanauki.pl/articles/2060180.pdf
Data publikacji:
2016
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
meteorite
H chondrite
parent body metamorphism
petrologic classification
partial melting
spinel group minerals
rutile in chondrites
Opis:
The thermal history that chondrites experienced on their parent body is an aspect of their petrological classification. However, in the classification scheme, metamorphic conditions are generally limited to the peak metamorphic temperature attained, while it is known that reconstruction of the genuine thermal evolution of any rock requires identification of various metamorphic factors, definition of the temperature-time path during metamorphism and characterization of the processes responsible for heating. Study of the brecciated Pułtusk H chondrite shows that the meteorite comprises both low and high petrologic type material and should be classified as a H3.8–6 chondrite. Based on the textures and mineral and chemical composition, the thermal metamorphic history of the breccia is reconstructed and it is shown to be inconsistent with the petrologic classification; the textural maturation and degree of compositional equilibrium in the meteorite do not correspond to the temperatures attained. The metamorphic conditions are shown to be a function of the primary composition of the accreted minerals and of two metamorphic phases, progressive and retrogressive. First, a prograde phase led to textural maturation and equilibration of the chemical composition of silicates and oxides. The peak metamorphic temperatures were at least ~700ºC for the type 3.8. and 4 material, and up to ~1000ºC in H6 clasts i.e., sufficient to locally give rise to partial melting. The following retrograde metamorphism led to compositional re-equilibration of minerals and textural re-equilibration of minerals with partial melts. The cooling rate during retrograde metamorphism down to at least ~700ºC was low, which allowed potassium feldspar to form patches in Na-plagioclase and pseudobrookite-armalcolite breakdown to form an association of ilmenite and rutile. The two-phase metamorphic evolution of the Pułtusk breccia was the most likely the result of impact heating, which affected the parent body in its very early history.
Źródło:
Geological Quarterly; 2016, 60, 1; 211--224
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Discrimination of Selected Cold-Pressed and Refined Oils by Untargeted Profiling of Phase Transition Curves of Differential Scanning Calorimetry
Autorzy:
Islam, Mahbuba
Magdalena, Montowska
Emilia, Fornal
Jolanta, Tomaszewska-Gras
Powiązania:
https://bibliotekanauki.pl/articles/16538550.pdf
Data publikacji:
2023-08-02
Wydawca:
Instytut Rozrodu Zwierząt i Badań Żywności Polskiej Akademii Nauk w Olsztynie
Tematy:
authentication
plant oils
chemometrics
multivariate data analysis
melting profiles
orthogonal partial least squares-discriminant analysis
differential scanning calorimetry
Opis:
The authenticity assessment of edible oils is crucial to reassure consumers of product compliance. In this study, a new approach was taken to combining untargeted profiling by using differential scanning calorimetry (DSC) with chemometric methods in order to distinguish cold-pressed oils (flaxseed, camelina, hempseed) from refined oils (rapeseed, sunflower, soybean). The whole spectrum of DSC melting profiles was considered as a fingerprint of each oil. Flaxseed and hempseed oils exhibited four endothermic peaks, while three peaks with one exothermic event were detected for camelina seed oil. In the case of refined oils, two endothermic peaks were detected for rapeseed oil, three for sunflower oil and four for soybean oil. Thermodynamic parameters, such as peak temperature, peak heat flow and enthalpy, differed for each type of oil. Principal component analysis (PCA) and orthogonal partial least squares-discriminant analysis (OPLS-DA) were used for processing data consisting of the whole spectrum of heat flow variables of melting phase transition. PCA demonstrated a clear separation between refined and cold-pressed oils as well as six individual oils. The OPLS-DA showed a distinct classification in six classes according to the types of oils. High OPLS-DA coefficients including R2X(cum)=0.971, R2(cum)=0.916 and Q2X(cum)=0.887 indicated good fitness of the model for oil discrimination. Variables influence on projection (VIP) plot indicated the most significant variables of the heat flow values detected at temperatures around −29°C, −32°C, −14°C, −10°C, −24°C and −41°C for the differentiation of oils. The study ultimately demonstrated great potential of the untargeted approach of using the whole melting DSC profile with chemometrics for the discrimination of cold-pressed and refined oils.
Źródło:
Polish Journal of Food and Nutrition Sciences; 2023, 73, 3; 224-232
1230-0322
2083-6007
Pojawia się w:
Polish Journal of Food and Nutrition Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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