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Tytuł:
Analysis of Stress and Strain Fields in and around Inclusions of Various Shapes in a Cylindrical Specimen Loaded in Tension
Autorzy:
Neimitz, A.
Janus, U.
Powiązania:
https://bibliotekanauki.pl/articles/354166.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
void nucleation
inclusion fracture
critical
Opis:
A numerical analysis is performed of the stress field in and around inclusions of various shapes. Inclusions both stiffer and more compliant than the metal matrix are analysed. The critical stresses required for inclusion fracture are estimated after observation of cavities and inclusions by scanning electron microscopy. Real inclusions were observed after performing uniaxial loading to different amounts of overall strain. The material tested was Hardox-400 steel.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 2A; 569-576
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Voids Nucleation at Inclusions of Various Shapes in Front of the Crack in Plane Strain
Autorzy:
Neimitz, A.
Janus, U.
Powiązania:
https://bibliotekanauki.pl/articles/958206.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
void nucleation
inclusion fracture
critical stress
Opis:
An analysis is presented of the stress field in and around inclusions of various shapes. Results were obtained by the finite element method. Inclusions were located within elementary cells located at the centre of the specimen next to the crack front. The influence of an in-plane constraint on the stress distribution was tested.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 3; 1587-1592
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Investigation on Nucleation Kinetics, Growth and Nonlinear Optical Properties of L-Cystine Hydrochloride Crystal
Autorzy:
Manivannan, D.
Kirubavathi, K.
Selvaraju, K.
Powiązania:
https://bibliotekanauki.pl/articles/1029827.pdf
Data publikacji:
2018-01
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
crystal growth
nucleation kinetics
optical materials
NLO
Opis:
The semiorganic nonlinear optical crystal of amino-carboxyl acid family, L-cystine hydrochloride (LCHCl) was successfully grown from its aqueous solution by the slow evaporation solution growth method. The solubility, metastable zone width and induction period were determined for the first time experimentally and there by the possibility of growing bulk crystals of LCHCl using deionized water as solvent. The induction period was recorded for the different supersaturation ratios (S=1.2, 1.3, 1.4, and 1.5), which reveals that the induction period of LCHCl decreases with increase in supersaturation. The nucleation kinetic parameters such as critical free energy, change of volume free energy, critical radius, number of molecules in the critical nucleus and nucleation rate have been evaluated for LCHCl crystals. The interfacial energy values of LCHCl were determined for different supersaturation ratio by means of varying temperatures. The single crystal X-ray diffraction gives the lattice parameters value of the grown crystals. The second harmonic generation efficiency was confirmed by the Kurtz-Perry powder method. The laser damage threshold energy of the grown crystal indicates that grown crystal has excellent resistance to laser radiation also compared with known other nonlinear optical crystals.
Źródło:
Acta Physica Polonica A; 2018, 133, 1; 63-67
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A model of agglomerate formation during bed wetting in the process of disc granulation
Autorzy:
Obraniak, A.
Gluba, T.
Powiązania:
https://bibliotekanauki.pl/articles/185107.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
aglomeracja
moczenie
nucleation
agglomeration
disc granulation
wetting
Opis:
This paper presents a method for quantitative assessment of the mechanisms of nucleation and granules growth by layering in the process of bed wetting during periodic disc granulation. This study included two initial, consecutive stages of a process with defined time courses. The first phase was a time period, in which only formation of new nuclei took place, while in the second stage simultaneous nucleation and growth of granules as a result of sticking raw material grains to preexisting nuclei occurred. Different kinds of binding liquid were used for bed wetting in each phase. In the first phase, an aqueous solution of dye was used, and pure distilled water in the second stage. The contribution of particular mechanisms to the formation of agglomerates at different time points within the second phase of the process was determined in this study. To do that the results of bed granulometric analysis, mass balance of size fractions and the analysis of contents of a marker (dye) delivered to the bed with the binding liquid during the first phase in agglomerates were used. To assess the concentration of the dye in different size fractions of the batch, spectrophotometric analysis was utilised. The study was performed using UV-VIS JASCO V-630 spectrophotometer equipped with an integrating sphere. The sieve analysis, spectrophotometric studies and mass balance were used to determine changes in the weight of the dye containing nuclei and of the nuclei containing no dye. The aforementioned analyses were also used to assess changes in the weight of formed granules and of raw material particles attached to nuclei during simultaneous nucleation and growth of granules.
Źródło:
Chemical and Process Engineering; 2012, 33, 1; 153-165
0208-6425
2300-1925
Pojawia się w:
Chemical and Process Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Influence of Steric Stabilization on Process of Au, Pt Nanoparticles Formation
Autorzy:
Luty-Błocho, M.
Powiązania:
https://bibliotekanauki.pl/articles/356030.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
gold
platinum
nanoparticles
kinetic
nucleation growth
steric stabilization
Opis:
Nanoparticles are very fascinating area of science not only due to their unique properties but also possibility of producing new more complex materials, which may find an application in modern chemistry, engineering and medicine. In process of nanoparticles formation very important aspect is a rate of individual stage i.e. reduction, nucleation and autocatalytic growth, because this knowledge allows for proper materials design, morphology manipulation, stability. The last one aspect can be realized using proper electrostatic, steric and electrosteric stabilization. However until now nobody reports and measures kinetic rates of all stages during process of particles formation in the presence of steric stabilizers. Thus, the main contribution of this paper is determination of individual rate constants for nanoparticles formation in the presence of steric stabilizers and their comparison to the system without stabilizer. For this purpose, an aqueous solution of Au(III) and Pt(IV) ions were mixed with steric stabilizers like PVA and PVP, and reduced using L-ascorbic acid as a mild and sodium borohydride as a strong reductant. As a results stable nanoparticles were formed and process of their formation was registered spectrophotometrically. From obtained kinetic curves the values of observed rate constants for reduction metal ions, slow nucleation and fast autocatalytic growth were determined using Watzky-Finke model. It was found that the addition of polymer affects the rate of the individual stages. The addition of steric stabilizers to gold ions reduced with L-ascorbic acid causes that the process of nucleation and autocatalytic growth slows down and the value of observed rate constants for nucleation changes from 3.79·10-3 (without polymer) to 7.15·10-5 s-1 (with PVA) and for growth changes from 1.15·103 (without polymer) to 0.48·102 s-1 M-1 (with PVA). However, the rate of the reduction reaction of Au(III) ions is practically unchanged. In case of using strong reductant the addition of polymer effects on the shape of kinetic curve for reduction of Au(III) and it suggests that mechanism is changed. In case of Pt(IV) ions reduction with L-ascorbic acid, the process speeds up a little when PVA was added. Determined values of observed rate constants for nucleation and growth platinum nanoparticles decrease twice comparing to the system without polymer. The reduction of Pt(IV) ions with sodium borohydride accelerates when PVP was added and slows down when PVA was used. Moreover, the size of obtained colloidal gold and platinum was also analysed using DLS method. Obtained results (rate constants) may be useful in the process of nanomaterials synthesis, in particular in microflow.
Źródło:
Archives of Metallurgy and Materials; 2019, 64, 1; 55-63
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fatigue damage mechanisms and damage evolution near cyclically loaded edges
Autorzy:
Ebner, R.
Gruber, P.
Ecker, W.
Kolednik, O.
Krobath, O.
Jesner, G.
Powiązania:
https://bibliotekanauki.pl/articles/200051.pdf
Data publikacji:
2010
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
fatigue damage
crack nucleation
plastic strains
residual stress
Opis:
A combined experimental and numerical approach was applied to develop a basic understanding of the fatigue damage process taking place at edges exposed to cyclic mechanical loads. A recently developed cyclic edge-loading test was used in order to simulate the fatigue loading of the edges of manufacturing tools and to study the microscopic damage mechanisms. Accompanying finite element calculations were performed to provide a better understanding of the loading conditions at edges subjected to cyclic mechanical loads. A comparison of the numerical simulation with the experimental results revealed good accordance. Main results of the investigations are the distribution of plastic strains and their evolution with increasing number of cycles, the distribution of the residual stresses, the localisation and the evolution of damage at the microscale (microcracks and voids), and the localisation and growth of fatigue cracks. Micro-damage develops in the entire plastically deformed region. Fatigue crack nucleation was mainly found in deformation bands and fatigue crack growth was only observed near the transition region between the extensively and the slightly plastically deformed zone not at the loaded area but at the side area. The reason for that phenomenon is the formation of tensile residual stresses in this region which is favouring fatigue crack growth.
Źródło:
Bulletin of the Polish Academy of Sciences. Technical Sciences; 2010, 58, 2; 267-279
0239-7528
Pojawia się w:
Bulletin of the Polish Academy of Sciences. Technical Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of hindered amine light stabilizers on the resistance of polypropylene towards ionizing radiation
Autorzy:
Przybytniak, G.
Mirkowski, K.
Rafalski, A.
Nowicki, A.
Legocka, I.
Zimek, Z.
Powiązania:
https://bibliotekanauki.pl/articles/148686.pdf
Data publikacji:
2005
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
polypropylene
stabilizers
HALS
electron beam
apparent viscosity
nucleation agent
Opis:
The influence of hindered amine light stabilizers (HALSs) on physical and mechanical properties of irradiated and non-irradiated isotactic polypropylene (PP) was studied. The stabilizers under investigation were: Tinuvin 765 (T765) and Tinuvin 622 (T622) - derivatives of 1,2,2,6,6-pentamethyl piperidine and Chimassorb 944 (C944) - a derivative of 2,2,6,6-tetramethyl piperidine. It was found that the stabilizers reduce the amount of peroxyl radicals in the amorphous phase of PP. The irradiation with electron beam causes a drop of apparent viscosity both in the original and in the modified PP however the effect is smaller in the presence of HALSs. Admixture of T622 and T765 stabilizers increases the crystallization temperature of non-irradiated PP by about 8 10°C (measured by DSC) what results from the facilitated formation of a large number small microcrystals. It was concluded that HALSs initiate two opposite tendencies - chemical protection against damage initiated by free radicals and, simultaneously, physical enhancement of sensitivity towards irradiation by the increase of nucleation density. In the studied systems, the presence of maleic anhydride does not improve compatibility between the polymeric matrix and HALSs.
Źródło:
Nukleonika; 2005, 50, 4; 153-159
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of heterogeneous nucleation on thermodynamic properties of isotactic polypropylene
Autorzy:
Barczewski, M.
Dobrzyńska-Mizera, M.
Trzeciak, M.
Powiązania:
https://bibliotekanauki.pl/articles/778993.pdf
Data publikacji:
2013
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
isotactic polypropylene
PP
heterogeneous
nucleation
modification
sorbitol
DMTA
DSC
Opis:
In this paper we have investigated the effect of 1,2,3-trideoxy-4,6:5,7-bis-O-[(4-propylphenyl)methylene]-nonitol sorbitol used in varying amounts (0.01 - 1 wt %) on isotactic polypropylene (iPP) matrix. We have used dynamic mechanical thermal analysis (DMTA) and differential scanning calorimetry (DSC) to study glass transition temperatures and crystallinity as a function of the nucleating agent concentration. Isotactic polypropylene samples showed a strong dependency on amount of α nucleating agent used. An increasing content of sorbitol based nucleating agent led to an increase of crystallization temperature upon cooling from the melt at constant rate and a decrease of the glass transition temperatures.
Źródło:
Polish Journal of Chemical Technology; 2013, 15, 4; 71-74
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Amyloidy i prionoidy – czy jest już czas, żeby się obawiać?
Amyloids and prionoids – is there a time to be afraid?
Autorzy:
Liberski, Paweł P.
Powiązania:
https://bibliotekanauki.pl/articles/1053678.pdf
Data publikacji:
2013
Wydawca:
Medical Communications
Tematy:
priony
prionoidy
amyloidy
nukleacja
oligomery
prions
prionoids
amyloids
nucleation
oligomers
Opis:
The new era has come to microbiology as we have realized that the unconventional viruses of kuru, Creutzfeldt-Jakob disease (CJD), Gerstmann-Sträussler-Scheinker syndrome (GSS), scrapie, and bovine spongiform encephalopathy (BSE) are infectious amyloid proteins and that these transmissible spongiform dementias are brain amyloidoses. This quotation from a Nobel laureate, D. Carleton Gajdusek, illustrates the best the content of this paper. Amyloid is a generic term, which embraces the fibrillary cross-β-sheet quaternary structure of any protein. All amyloids, irrespective of their amino acid sequences, are formed through nucleation/polymerization reactions in which oligomeric structures (small aggregates) composed of a limited number of a given protein moiety (a seed) nucleates other moieties. As a result, the β-pleated secondary structure predominates. Such proteins are called “prionoids” as opposed to “real” prions, which are infectious, or transmissible, in a microbiological sense; they spread between individuals and cause macro-epidemics, such as kuru, BSE and iatrogenic CJD. In this review, prions and prionoids, and their inter-relatedness, will be discussed.
Nadeszła nowa era mikrobiologii, kiedy zrozumieliśmy, że niekonwencjonalne wirusy kuru, choroby Creutzfeldta--Jakoba (CJD) i zespołu [obecnie „choroby”] Gerstmanna-Sträusslera-Scheinkera (GSS), scrapie, encefalopatii gąbczastej bydła (BSE) są infekcyjnymi białkami amyloidowymi i że pasażowalne encefalopatie gąbczaste są amyloidozami mózgu. Ten cytat z wypowiedzi laureata Nagrody Nobla D. Carletona Gajduska znakomicie ilustruje całość zagadnienia. Amyloid to nazwa ogólna określająca włókienkową czwartorzędową strukturę białka. Wszystkie amyloidy, niezależnie od sekwencji aminokwasów tworzących je białek, tworzą się w wyniku reakcji nukleacji/polimeryzacji, w której agregaty (oligomery), składające się z niewielkiej liczby cząsteczek białka (jądro, seed), nukleują cząsteczki białka prekursorowego, co prowadzi do zmiany konformacji przestrzennej w kierunku harmonijki-β. Choroby wywołane przez takie białka nazywa się prionoidami. „Prawdziwe” priony różnią się zasadniczo od wszystkich innych prionoidów − priony są zakaźnie w sensie mikrobiologicznym, szerzą się między osobnikami, wywołując makroepidemie, takie jak kuru, vCJD, BSE i jatrogenne przypadki CJD. W niniejszym artykule zostaną omówione podstawowe prionoidy − choroby Alzheimera i Parkinsona – oraz relacja łącząca je z chorobami prionowymi.
Źródło:
Aktualności Neurologiczne; 2013, 13, 3; 230-239
1641-9227
2451-0696
Pojawia się w:
Aktualności Neurologiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparative studies of the electroreduction of zinc ions from gluconate solutions
Badania porównawcze katodowej redukcji jonów cynkowych z roztworów glukonianowych
Autorzy:
Rudnik, Ewa
Chat, Karolina
Powiązania:
https://bibliotekanauki.pl/articles/263934.pdf
Data publikacji:
2019
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
electrodeposition
voltammetry
chronoamperometry
polarization
nucleation
osadzanie katodowe
woltamperometria
chronoamperometria
polaryzacja
nukleacja
Opis:
This study considers the role of chloride and sulphate anions in the cathodic reduction of zinc ions from gluconate solutions (chloride, sulphate, chloride-sulphate). Cyclic potentiodynamic and potentiostatic polarization measurements, as well as chronoamperometric experiments, were performed. Electrochemical results were correlated with the speciation of the baths. The experiments revealed the inhibiting effect of sulphate ions on the cathodic process caused by the formation of stable neutral ZnSO4 complex in the sulphate-gluconate bath. It resulted in zinc deposition under a limiting current, with the release of metal cation as a rate-determining step. The less stable ZnGlu+ complex dominated both chloride-containing baths, thus the metal deposition ran under activation control. Independent of the solution composition, the nucleation of zinc occurred according to the instantaneous model.
W artykule przedstawiono rolę anionów chlorkowych i siarczanowych w katodowej redukcji jonów cynku z roztworów glukonianowych (chlorkowy, siarczanowy, chlorkowo-siarczanowy). Przeprowadzono pomiary cyklicznej polaryzacji potencjodynamicznej i potencjostatycznej oraz eksperymenty chronoamperometryczne. Wyniki elektrochemiczne skorelowano ze składem jonowym roztworów. Eksperymenty wykazały hamujący wpływ jonów siarczanowych na proces katodowy w kąpieli siarczanowo-glukonianowej spowodowany tworzeniem się stabilnego obojętnego kompleksu ZnSO4. W rezultacie, w elektrolicie siarczanowym osadzanie cynku zachodziło w warunkach prądu granicznego, a etapem powolnym było uwalnianie jonu metalu z kompleksu. W obecności jonów chlorkowych dominujący kompleks stanowił mniej trwały ZnGlu+, a redukcja jonów cynku zachodziła w warunkach kontroli aktywacyjnej. Niezależnie od składu roztworu stwierdzono natychmiastowe zarodkowanie cynku.
Źródło:
Metallurgy and Foundry Engineering; 2019, 45, 1; 19-31
1230-2325
2300-8377
Pojawia się w:
Metallurgy and Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Boiling heat transfer phenomenon from an isolated nucleation center
Wymiana ciepła przy wrzeniu dla wyodrębionego centrum nukleacji
Autorzy:
Orman, Ł. J.
Powiązania:
https://bibliotekanauki.pl/articles/402086.pdf
Data publikacji:
2016
Wydawca:
Politechnika Świętokrzyska w Kielcach. Wydawnictwo PŚw
Tematy:
boiling heat transfer
nucleation center
wymiana ciepła przy wrzeniu
centrum nukleacji
Opis:
The paper discusses a method of boiling heat transfer investigation from a cavity of given geometrical dimensions. The testing method is described together with literature review on the subject. This experimental concept can be used to provide useful data on the creation and departure frequency of bubbles, thus giving more insight into the boiling phenomenon.
Źródło:
Structure and Environment; 2016, 8, 1; 59-63
2081-1500
Pojawia się w:
Structure and Environment
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The cavitation nuclei transient characteristics of Lennard-Jones fluid in cavitation inception
Autorzy:
Fu, Q.
Zhang, B.
Zhao, Y.
Zhu, R.
Liu, G.
Li, M.
Powiązania:
https://bibliotekanauki.pl/articles/259255.pdf
Data publikacji:
2018
Wydawca:
Politechnika Gdańska. Wydział Inżynierii Mechanicznej i Okrętownictwa
Tematy:
cavitation nuclei
molecular dynamics simulation
Lennard-Jones fluid
cavitation inception
nucleation
Opis:
In the field of ocean engineering, cavitation is widespread, for the study of cavitation nuclei transient characteristics in cavitation inception, we applied theoretical analysis and molecular dynamics (MD) simulation to study Lennard-Jones (L-J) fluid with different initial cavitation nuclei under the NVT-constant ensemble in this manuscript. The results showed that in cavitation inception, due to the decrease of liquid local pressure, the liquid molecules would enter the cavitation nuclei, which contributed to the growth of cavitation nuclei. By using molecular potential energy, it was found that the molecular potential energy was higher in cavitation nuclei part, while the liquid molecular potential energy changes greatly at the beginning of the cavitation nuclei growth. The density of the liquid and the surface layer changes more obvious, but density of vapor in the bubble changes inconspicuously. With the growth of cavitation nuclei, the RDF peak intensity increased, the peak width narrowed and the first valley moved inner. When cavitation nuclei initial size reduced, the peak intensity reduced, the corresponding rbin increased. With the decrease of the initial cavitation nuclei, the system pressure and total energy achieved a balance longer, and correspondingly, they were smaller. In addition, at the beginning of the cavitation nuclei growth, the total energy and system pressure changed greatly.
Źródło:
Polish Maritime Research; 2018, S 2; 75-84
1233-2585
Pojawia się w:
Polish Maritime Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Weryfikacja modeli heterogenicznego zarodkowania ziaren pierwotnych w stopie Al-5Cu
Verification of Models of Heterogeneous Nucleation of Primary Grains in Al-5Cu Alloy
Autorzy:
Górny, M.
Sikora, G.
Powiązania:
https://bibliotekanauki.pl/articles/381989.pdf
Data publikacji:
2014
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
zarodkowanie heterogeniczne
modele zarodkowania
gęstość ziaren pierwotnych
przechłodzenie ciekłego stopu
rozkład statystyczny
heterogeneous nucleation
nucleation models
density of the original grain
supercooling a molten
statistical distribution
Opis:
Gęstość ziaren pierwotnych Nv po krystalizacji zależy od maksymalnego przechłodzenia ΔT ciekłego stopu. Zależność ta może być oparta o różne rozkłady statystyczne: Gaussa, Weibulla, lognormalny oraz zależy od charakterystyki heterogenicznych miejsc zarodkowania oraz ich aktywnej liczby obecnej w ciekłym stopie odlewniczym. Celem niniejszej pracy jest skonfrontowanie wyników doświadczalnych z istniejącymi już modelami Oldfielda, Frasia, lognormalnego oraz wyznaczenie wartości parametrów zarodkowania tych modeli, które są charakterystyczne dla badanego stopu Al-5Cu. Zweryfikowano modele zarodkowania ziaren fazy pierwotnej α(Al) w stopie Al-5Cu w stanie wyjściowym oraz modyfikowanym. Z przeprowadzonej analizy wynika, że model Oldfielda wykazuje dobrą zgodność z wynikami doświadczalnymi, ale tylko dla stanu wyjściowego, podczas gdy modele lognormalny oraz Frasia (oparty na rozkładzie statystycznym Weibulla) są równoważne pod względem dobrego odwzorowania wyników doświadczalnych dla zarodkowania ziaren fazy pierwotnej α(Al) w stopie Al-5Cu zarówno dla stanu wyjściowego jak i modyfikowanego.
The grain density Nv after solidification is a function of maximum undercooling of a liquid alloy ΔT. This relationship may be based on the different statistical distributions: Gaussian, Weibull, Lognormal and depends on the characteristics of heterogeneous nucleation sites present in the liquid alloy. The purpose of this work was a compare the experimental data with the models: Oldfield, Fras and Lognormal and determination the nucleation parameters of these models, which are characteristic for the investigated alloy Al-5Cu. The models of nucleation of primary grains α(Al) in the alloy Al-5Cu was verified for two physicochemical state of liquid metal: base and refined. The analysis shows that the model Oldfield has a good compatibility with experimental results, but only for the base alloy. The lognormal and Fras (based on Weibull's distribution) models are equivalent as regards a good representation of the experimental results of the nucleation of primary grains α(Al) in the alloy Al-5Cu for both physicochemical state.
Źródło:
Archives of Foundry Engineering; 2014, 14, 4 spec.; 31-36
1897-3310
2299-2944
Pojawia się w:
Archives of Foundry Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Optimisation of LT-GaN nucleation layer growth conditions for the improvement of electrical and optical parameters of GaN layers
Autorzy:
Wośko, Mateusz
Powiązania:
https://bibliotekanauki.pl/articles/174388.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
GaN
nucleation
recrystallization
metalorganic chemical vapor deposition
nitrides
LED
MSM
MESFET devices
Opis:
In this work we present the influence of low temperature gallium nitride (LT-GaN) nucleation layer deposition and recrystallization conditions on the electrical and optical properties of buffer and active layer of metal–semiconductor field-effect transistor (MESFET) structure. MESFET structures were used to investigate the properties of bulk materials that determine also the performance of many type GaN based devices, like light emitting diodes (LEDs), high electron mobility transistors (HEMTs) and metal–semiconductor–metal (MSM) detectors. The set of n-GaN/u-GaN/sapphire structures using different nucleation LT-GaN layers thickness and different annealing times was deposited using AIXTRON CCS epitaxial system. In contrast to typical procedure, the high resistive GaN buffer layer was not obtained by intentional Fe/Mg doping, but by specific adjustment of GaN nucleation conditions and recrystallization process parameters that introduce carbon atoms in epitaxial layers, that serve as donors. Generally, low pressure (below 200 mbar) in a reactor chamber, during initial stages of nucleation and recrystallization as well as HT-GaN epitaxy, promotes the growth of high resistive material. Obtained results show that annealing/recrystallization time of LT-GaN has a significant impact on the electrical and optical properties of GaN buffer layers. Longer annealing periods tend to promote crystallization of material with higher electron mobility and higher Si dopant incorporation/activation while maintaining high resistivity in u-GaN buffer area. It was shown that the dimensions of the GaN islands, that could be influenced by the duration of an annealing step of LT-GaN growth, have no impact on the HT-GaN buffer layer coalescence process and material resistivity, but influences mainly electrical properties of active n-GaN layer. Author suggests that the key parameters that are determining the buffer resistivity are the pressure and temperature during LT-GaN annealing and buffer layer coalescence. The influence of GaN island diameters, after LT-GaN annealing, on the u-GaN resistivity was not confirmed.
Źródło:
Optica Applicata; 2019, 49, 1; 167-176
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Strefa metastabilna w krystalizacji
The Metastable Zone of aqueous solutions
Autorzy:
Bogacz, W.
Wójcik, J.
Powiązania:
https://bibliotekanauki.pl/articles/142365.pdf
Data publikacji:
2014
Wydawca:
Stowarzyszenie Inżynierów i Techników Przemysłu Chemicznego. Zakład Wydawniczy CHEMPRESS-SITPChem
Tematy:
strefa metastabilna
krystalizacja przemysłowa
temperatura nukleacji
metastable zone
industrial crystallization
nucleation point
Opis:
Chociaż strefa metastabilna jest istotnym zagadnieniem w krystalizacji przemysłowej, to wciąż jej definicja posiada pewne niejasności. W artykule przedstawiono wyniki badań polegających na określeniu temperatury nukleacji oraz szerokości strefy metastabilnej (przechłodzenie) dla roztworów chlorku potasu, azotanu (V) potasu i siarczanu (VI) potasu przy użyciu kalorymetru reakcyjnego Mettler Toledo RCle.
The Metastable Zone (MSZ) is one of the most essential notions in industrial crystallization. However, its definitions have still some vagueness, and models to estimate the metastable limit (MSL) have not been matured enough to be used in practical operation. This paper presents the results of studies of determination the nucleation point and the MSZW of potassium chloride, potassium nitrate (V) and potassium sulphate (VI) solutions, using the Reaction Calorimeter Mettler Toledo RCle.
Źródło:
Chemik; 2014, 68, 3; 198-204
0009-2886
Pojawia się w:
Chemik
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 34

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