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Wyszukujesz frazę "molybdenite" wg kryterium: Temat


Wyświetlanie 1-12 z 12
Tytuł:
Insights into the depression effect and adsorption mechanism of HACC on chalcopyrite surface in Cu-Mo flotation separation
Autorzy:
Li, Mingyang
Zhang, Pengpeng
Xiangpeng, Gao
Huang, Lingyun
Powiązania:
https://bibliotekanauki.pl/articles/27323662.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
chalcopyrite
molybdenite
flotation
adsorption
depressant
Opis:
In this study, hydroxypropyltrimethyl ammonium chloride chitosan (HACC) was first introduced as a depressant during separating chalcopyrite from molybdenite (Cu-Mo). The selective effects of HACC on the separation of Cu-Mo were conducted by single-mineral flotation experiments. The findings from this study revealed that HACC helped separate Cu and Mo efficiently at pH 6 with 8 mg/dm3 of HACC, resulting in 76.22% and 5.38% of Mo and Cu flotation recovery, respectively. The adsorption mechanism of HACC was investigated via zeta potential, adsorption density, and contact angle measurement along with FT-IR and XPS analyses. The contact angle and adsorption density measurements offer indisputable proof that HACC can adsorb on the surface of chalcopyrite. Furthermore, FT-IR and XPS analyses confirm that N atoms in quaternary ammonium groups of HACC interact with Cu sites on the surface of chalcopyrite. The findings also suggest that HACC adsorbs on the surface without significantly impacting molybdenite. All these results confirm that HACC can be an effective chalcopyrite depressant.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 6; art. no. 172481
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Flotation of molybdenite in the presence of microemulsified collector
Autorzy:
You, X.
Li, L.
Lyu, X.
Powiązania:
https://bibliotekanauki.pl/articles/109765.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
molybdenite
flotation
microemulsified collector
diesel
Opis:
In this paper molybdenite flotation using microemulsified collector was reported. The flotation performance of microemulsified collector and conventional diesel was compared. This study is a prelimi-nary investigation which uses pure molybdenite mineral in a modified Hallimond tube. The pH tests showed that the highest recovery of molybdenite in the presence of diesel and microemulsion was ob-tained at pH=6, reaching the recoveries of 93% and 90%, respectively. In the case of obtaining similar results, it was observed that the microemulsion consumption was lower in comparison to diesel. In the flotation tests with microemulsified collector the recovery slightly decreased because too large collector amount caused formation of more unstable bubbles. The contact angle measurements showed that the microemulsified collector was more effective for increasing the hydrophobicity of molybdenite surface. An adsorption model was proposed and it was suggested that the non-ionic surfactant present in the mi-croemulsified collector formed a continuous bimolecular layer, resulting in the increased surface hydro-phobicity. The accomplishment of this research demonstrated the viability of the use of microemulsified collector in molybdenite flotation, attempting to simplify the molybdenite flotation process, especially replace the conventional emulsified collector with high energy consumption and difficult storage.
Źródło:
Physicochemical Problems of Mineral Processing; 2017, 53, 1; 333-341
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Physico-chemical factors in flotation of Cu-Mo-Fe ores with seawater: a critical review
Autorzy:
Castro, S.
Powiązania:
https://bibliotekanauki.pl/articles/109447.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
pyrite
chalcopyrite
molybdenite
Seawater flotation
Metabisulfite
Opis:
This paper aims to provide a comprehensive review on the physico-chemical factors governing the flotation of Cu-Mo-Fe sulfide ores in seawater, which is different from NaCl or KCl solutions because it contains hydrolysable ions such as Mg2+, Ca2+, HCO3-, CO32-, etc., which can precipitate with lime as hydroxides, Ca, and Mg insoluble salts. Under pH 9.0 Mg2+ ions do not depress molybdenite. However, over the critical pH of precipitation of Mg(OH)2 (pH>10.0), molybdenite is strongly depressed in seawater. This detrimental effect on molybdenite discards the use of lime to depress pyrite in Cu-Mo-Fe ores floated in seawater. In plant practice, the use of sodium metabisulfite (MBS) has replaced lime as a pyrite depressant. It works at pH 6.5-7.0 where the natural floatability of molybdenite is enhanced. Consequently, pH control in rougher and cleaning circuits, and the use of MBS to depress pyrite, have allowed the successful use of non-desalinated seawater in flotation of Cu-Mo-Fe sulfide ores at industrial scale.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 4; 1223-1236
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on flotation behavior and mechanism of separating chalcopyrite and Molybdenite with ethyl mercaptoglycolate as inhibitor
Autorzy:
Yang, Xiao-Feng
Xu-Zhao
Liu, Yao-Yao
Powiązania:
https://bibliotekanauki.pl/articles/24085868.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
ethyl thioglycolate
chalcopyrite
molybdenite
inhibitor
separation
Opis:
The effect of ethyl thioglycolate organic small molecule inhibitors on chalcopyrite molybdenite flotation behaviour is investigated via single mineral micro-flotation tests, zeta potential tests, and X-ray photoelectron spectroscopy (XPS) analysis. Results of the flotation test indicate that ethyl thioglycolate organic small-molecule inhibitors can effectively separate Cu and Mo and selectively inhibit chalcopyrite under weak alkaline conditions. Infrared spectroscopy and XPS analysis show that hydrophilic functional groups C=O and -COOH in the ethyl thioglycolate organic small molecules can chemically adsorb onto the chalcopyrite surface. Moreover, ethyl thioglycolate has no obvious effect on zeta potential of molybdenite. Therefore, ethyl thioglycolate can effectively separate chalcopyrite and molybdenite.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 2; art. no. 162824
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Kinetics of hydrophobic agglomeration of molybdenite fines in aqueous suspensions
Autorzy:
Yang, B.
Song, S.
Lopez-Valdivieso, A.
Powiązania:
https://bibliotekanauki.pl/articles/110890.pdf
Data publikacji:
2015
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
agglomeration rate
molybdenite fines
hydrophobic agglomeration
Opis:
The kinetics of hydrophobic agglomeration of molybdenite fines in aqueous suspensions has been studied in this work. This study was performed on minus 5 μm molybdenite particles through turbid-ity measurements and imaging. The results have showed that stirring strength and kerosene addition greatly affected the agglomeration rate of molybdenite fines in aqueous suspensions. The higher was the stirring strength, the larger the agglomeration rate was. Kerosene addition enhanced not only the agglom-eration rate, but also the agglomerates structure. It was recommended to use radial impeller for the for-mation of hydrophobic agglomeration, because it produced a stronger shear field in impeller zone.
Źródło:
Physicochemical Problems of Mineral Processing; 2015, 51, 1; 181-189
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influencing mechanisms of sodium hexametaphosphate on molybdenite flotation using sea water
Autorzy:
Wang, Lizhangzheng
Li, Yubiao
Fan, Ruihua
Fan, Rong
Powiązania:
https://bibliotekanauki.pl/articles/109351.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
sodium hexametaphosphate
flotation
molybdenite
sea water
mechanism
Opis:
Flotation using sea water has been considered as a promising alternative to concentrate molybdenite (MoS2) under alkaline conditions due to scarcity of fresh water and increasingly strict regulations on the quality of discharged water. However, the MoS2 recovery with sea water during flotation has not been satisfactory, owing to the depressing effects from the hydrophilic metallic species onto MoS2 surface. This study combines experimental and theoretical studies of MoS2 flotation to investigate how the physicochemical properties of MoS2 vary with the addition of a dispersant, sodium hexametaphosphate (SHMP), and in sea and fresh water. Our experimental results show that the addition of SHMP during flotation has increased the recovery of MoS2, via reducing the adsorption of the hydrophilic metallic precipitation onto MoS2 surface. The DLVO calculation confirms that the addition of SHMP increases the floatability of MoS2 by dispersing the formed hydrophilic metallic precipitation (Mg(OH)2 colloids) from the MoS2 surface, via reversing attraction force to repulsion force, thereby improving MoS2 flotation recovery.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 5; 1091-1098
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mechanism and leaching kinetics of molybdenite concentrate in a hydrogen peroxide-acid system
Autorzy:
Aracena, Alvaro
Azocar, Alan
Ibáñez, Juan Patricio
Jerez, Oscar
Powiązania:
https://bibliotekanauki.pl/articles/110193.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
molybdenite concentrate
hydrogen peroxide
kinetics
mechanism of reaction
Opis:
The mechanism and leaching kinetics of a molybdenite concentrate in a H2O2-H2SO4 system were studied. The experimental work was performed in a batch reactor equipped with a condenser, a mechanical agitator and a temperature control system. The effects of the temperature, H2O2 and H2SO4 concentrations, particle size, liquid/solid ratio and agitation speed on the Mo recovery were investigated. The thermodynamic results showed that the leaching mechanism it was governed by several intermediate reactions; however, the influences of sulfuric acid and passivation were not observed in the reaction. The most predominant experimental result was the maximum Mo recovery of 81.3% by leaching 64 μm particles at 333 K (60 °C) for 5400 s (90 min). The molybdenum recovery was generally enhanced by increasing the H2O2 and H2SO4 concentrations. However, at H2SO4 concentrations higher than 1.0 mol/dm3, the Mo recovery decreased. Although the agitation speed affected the Mo recovery considerably, high recoveries could be still obtained without mixing. The experimental results and XRD analysis confirmed the reaction mechanisms. The leaching kinetics were analyzed using a shrinking core model in which the rate was controlled by diffusion through a porous layer with radius ro. The reaction rate orders were 1.0 and 0.2 for the H2O2 and H2SO4 concentrations, respectively, and the rate was inversely proportional to the square of the initial particle radius. The calculated activation energy was 75.2 kJ/mol in the temperature range of 278-333 K (5-60 °C).
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 1; 140-152
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Rhenium abundance in molybdenites : a case study on vein-type Cu-Mo-Au mineralisation in the Qarachilar area, Sungun porphyry Cu and Siah Kamar porphyry Mo deposits, NW Iran
Autorzy:
Simmonds, Vartan
Mathur, Ryan
Selby, David
Powiązania:
https://bibliotekanauki.pl/articles/2058578.pdf
Data publikacji:
2019
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Qarachilar
Sungun
Siah Kamar
Qaradagh Batholith
molybdenite
Re content
Opis:
The vein-type Cu-Mo-Au mineralisation in Qarachilar, the Sungun porphyry Cu deposit (PCD) and the Siah Kamar porphyry Mo deposit (PMD) are all located at the northwestern end of the Neo Tethys-related Urumieh-Dokhtar volcano-plutonic belt of Iran. Re contents of moIybdenite samples from the Qarachilar, Sungun and Siah Kamar deposits are about 112.67-462 ppm, 53.24-252.29 ppm, and 10.44-41.05 ppm, respectively. Re contents of the first two deposits fall in the range of PCDs, while those of the latter are lower and correspond to PMDs. The relatively high Re content of the Qarachilar and Sungun molybdenites can be explained considering the low abundance of molybdenite, a mantle-dominated source for ore materials and the incorporation of oxidized and acidic hydrothermal fluids with high fCl. The high abundance of molybdenite in the Siah Kamar PMD has resulted in volume dilution of Re. Furthermore, occurrence of the main ore within the potassic alteration zone and, hence, the alkaline nature of the responsible fluids in this zone have also affected the Re content of molybdenites. Variations of the Re content in different veins/veinlets showed a negative relationship with the formation temperature of these veins, and a positive/negative relationship with the acidity/alkalinity of the hydrothermal fluids, while the grain size of molybdenites showed a positive relationship.
Źródło:
Geological Quarterly; 2019, 63, 3; 478--492
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Research on optimization method of flotation kinetic model based on molybdenite particle size effect
Autorzy:
Wan, He
An, Yanni
Qu, Juanping
Zhang, Chonghui
Xue, Jiwei
Wang, Sen
Bu, Xianzhong
Powiązania:
https://bibliotekanauki.pl/articles/24085892.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
particle size effect
molybdenite
mathematical model
method of correction
Opis:
Flotation kinetic models can be applied to describe the flotation process and to predict mineral recoveries. However, the size composition of the target minerals in the feed ore fluctuates considerably, resulting in insufficient accuracy with flotation kinetic models. There have been many studies that focus on the investigation of flotation kinetics with different particle sizes, while the optimization methods for flotation kinetic models based on particle size effects have not been reported. In this paper, flotation tests, optical microscope observations, and particle size analysis were used to identify the reasons for the decrease in accuracy of the flotation kinetic model due to changes in the composition of molybdenite particle size. Additionally, an optimization method for the flotation kinetic model was developed based on the particle size effect. The test results show that the accuracy of the flotation kinetic model for fixed particle size minerals is very high, but the predicted results for flotation recoveries of different particle size mineral mixtures have large deviations. The poor accuracy might be due to the autogenous carrier effect caused by the particle size composition fluctuating considerably. The optimization method for the flotation kinetic model is based on the particle size effect. The model can accurately describe the flotation process of molybdenite with different size compositions of molybdenite and predict the flotation recovery of molybdenite.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 2; art. no. 163004
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of seawater main components on frothability in the flotation of Cu-Mo sulfide ore
Autorzy:
Laskowski, J. S.
Castro, S.
Ramos, O.
Powiązania:
https://bibliotekanauki.pl/articles/109747.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
seawater
froth stability
Cu-Mo flotation
magnesium ions
molybdenite flotation
Opis:
The main problem in the flotation of Cu-Mo sulfide ores in seawater is poor floatability of molybdenite at pH>9.5. Froth stability plays a very important role in determining concentrate grade and recovery in flotation operations and in this paper both floatability and frothability have been tested. The frothability have been studied by measuring froth equilibrium layer thickness in a modified laboratory flotation cell. Two chemical aspects of seawater need to be considered: the content of NaCl (around 87% of salinity), and the concentration of secondary ions (around 13%) (sulfate, magnesium, calcium, bicarbonate ions, etc.). Seawater, NaCl solutions, and seawater’s ions were found to depress frothability. The effect of pH on frothability over the pH range from 9.5 to 11, which is very strong in freshwater, becomes negligible in seawater and the tested electrolyte solutions. The analysis of the relationship between the mechanisms of molybdenite depression and the loss of frothability in seawater implies that the effects of the studied ions on molybdenite floatability and on pulp frothability are different. While depression of molybdenite floatability could be tracked down to magnesium hydroxide precipitation as a main culprit, the depression of frothability is a much more complicated issue.
Źródło:
Physicochemical Problems of Mineral Processing; 2014, 50, 1; 17-29
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of superconducting magnetic separation to an artificial mixture of chalcopyrite and molybdenite
Autorzy:
Li, Daokui
Kou, Jue
Sun, Chunbao
Yu, Baoqiang
Wang, Chao
Powiązania:
https://bibliotekanauki.pl/articles/110786.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
magnetic matrices
superconducting magnetic separation
buildup behavior
chalcopyrite and molybdenite separation
Opis:
Superconducting magnetic separation of chalcopyrite and molybdenite was studied, along with the effects of the magnetic flux density, slurry concentration, and pulsation amplitude on the separation. According to the force equilibrium model of magnetic particles that accumulated on magnetic matrices during the superconducting magnetic separation, the saturated buildup of magnetic particles was calculated. The saturated buildup of magnetic particles was an approximate fan ring and had a positive correlation with the background magnetic flux density. Superconducting magnetic separation tests results showed that a Mo concentrate with a Mo grade of 31.86% and recovery of 87.24% and a Cu concentrate with a Cu grade of 30.57% and recovery of 94.76% could be obtained. This verified the feasibility of separating mixed Cu and Mo minerals via superconducting magnetic separation.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 3; 597-604
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Wiek molibdenitów w Polsce w świetle badań izotopowych Re-Os
The age of molybdenites in Poland in the light of Re-Os isotopic studies
Autorzy:
Mikulski, S.Z.
Stein, H.J.
Powiązania:
https://bibliotekanauki.pl/articles/2062033.pdf
Data publikacji:
2012
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
wiek izotopowy Re–Os
molibdenit
procesy pomagmowe
granitoidy
waryscydy
Karkonosze
masyw Strzegom-Sobótka
Sudety
blok przedsudecki
blok małopolski
blok górnośląski
Tatry
Re-Os isotope age
molybdenite
post-magmatic processes
Variscides
granitoids
Karkonosze Massif
Strzegom-Sobótka Massif
Sudetes
Fore-Sudetic Block
Małopolska Block
Upper Silesian Block
Tatra Mts.
Opis:
W artykule przedstawiono wyniki datowań metodą Re–Os wieku molibdenitów związanych z waryscyjskimi intruzjami granitoidowymi w Polsce. W masywie karkonoskim oraz w jego wschodniej osłonie metamorficznej stwierdzono dwa etapy krystalizacji molibdenitów (od 326 ±1 do 310 ±1 mln lat), które odzwierciedlają aktywność pneumatolityczną i hydrotermalną w okresie karbońskim od wizenu/ serpuchowu do moskowu. W masywie Strzegom–Sobótka zarówno molibdenity rozetkowe występujące w formie impregnacji w granitach, jak i molibdenity w przecinających je żyłkach kwarcowych wykazują zbliżony wiek (od 309 ±1 do 296 ±2 mln lat). Krystalizacja molibdenitów w tym masywie była pochodną procesów pomagmowych związanych z powolnym stygnięciem magm odpowiedzialnych za powstanie monzogranitów hornblendowo-biotytowych. Zakres wiekowy krystalizacji molibdenitów ze strefy kontaktu bloku małopolskiego z blokiem górnośląskim mieści się w czasie od 301 ±2 do 296,3 ±1,4 mln lat. Najstarszy wiek izotopowy Re–Os krystalizacji wśród zbadanych dotychczas molibdenitów uzyskano dla próbki molibdenitu pochodzącej z Tatr – 350,5 ±1,2 mln lat. Z kolei najmłodsze wieki krystalizacji molibdenitów stwierdzono w próbkach z kamieniołomu w Siedlimowicach (257 ±1 mln lat) oraz w Miedziance (213 ±1 mln lat). Wieki te wskazują na procesy kataklazy i remobilizacji roztworów hydrotermalnych w młodszych okresach, tj. w późnym permie i triasie. Wyniki badań izotopowych molibdenitów pozwoliły określić relacje czasowe pomiędzy poszczególnymi hydrotermalnymi etapami krystalizacji kruszców i procesami magmowo-tektonicznymi w czasie ok. 140 mln lat, tj. od missisipu (karbon) do noryku (późny trias) w różnych obszarach wystąpień waryscyjskich intruzji granitoidowych w Polsce.
The paper presents the results of molybdenites that closely correlate with the Variscan granite intrusions in Poland. In the Karkonosze Massif and its eastern metamorphic cover, there are two separate stages of Re-Os ages of molybdenite crystallization (326 ±1 to 310 ±1 Ma), which reflect pneumatolitic and hydrothermal activity in the Carboniferous (from the Visean/Serpukhovian to the Moscovian). In the Strzegom–Sobótka Massif, both rosette-like molybdenites disseminated in granitoids and those from the quartz veinlets reveal similar Re-Os ages that range from 309 ±1 to 296 ±2 Ma. Molybdenite crystallization in the Strzegom–Sobótka Massif was related to the post-magmatic processes associated with a slow cooling of magma responsible for the formation of hornblende-biotite monzogranites. The time range of molybdenites crystallization form the contact zone between the Małopolska and Upper Silesian blocks is from 301 ±2 to 296.3 ±1.4 Ma. The oldest Re-Os isotopic age of molybdenite (350.5 ±1.2 Ma) was received for a molybdenite sample from the Polish part of the Tatra Mountains. The molybdenites from the eastern part of the Strzegom–Sobótka Massif (Siedlimowice quarry, 257 ±1 Ma) and from the Miedzianka abandoned Cu (-U) mine (213 ±1 Ma) yielded the youngest Re-Os ages. These ages indicate tectonic reactivation and remobilization of hydrothermal fluids in the Late Permian and Late Triassic. The Re-Os isotopic studies of molybdenites allowed defining the time relation between successive hydrothermal stages of ore precipitation and tectonic-magmatic processes during ca. 140 million years e.g. from the Mississippian (Carboniferous) to the Norian (Late Triassic) in different areas of the occurrence of Variscan granitoid intrusions in Poland.
Źródło:
Biuletyn Państwowego Instytutu Geologicznego; 2012, 452; 199--216
0867-6143
Pojawia się w:
Biuletyn Państwowego Instytutu Geologicznego
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-12 z 12

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