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    Wyświetlanie 1-4 z 4
    Tytuł:
    Activated bio-carbons prepared by physical activation of residues after supercritical extractionof raw plants
    Autorzy:
    Bazan-Woźniak, Aleksandra
    Pietrzak, Robert
    Powiązania:
    https://bibliotekanauki.pl/articles/110368.pdf
    Data publikacji:
    2019
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    bio-sorbents
    physical activation
    toxic gas removal
    adsorption from liquid phase
    Langmuir and Freundlich isotherm
    Opis:
    A series of activated bio-carbons has been obtained by physical activation of residues after supercritical extraction of blackberries, raspberries and blackcurrants. The effects of different temperatures of activation and different starting materials on the physicochemical and sorption properties of the bio-carbon samples obtained were evaluated. The physicochemical properties of the activated bio-carbons were characterized by elementary analysis, low-temperature nitrogen sorption and Boehm titration. All materials were tested as adsorbents of pollutants from gas (nitrogen dioxide) and liquid (iodine, methylene blue) phase. The sorption properties of the activated bio-carbons were tested at 23°C. The materials obtained were activated bio-carbons of surface area ranging between 303 and 442 m2/g and showing basic character of the surface. The content of elemental carbon in the obtained samples was in the range of 73.4-82.1 wt. %. The maximum adsorption capacities of the materials towards nitrogen dioxide were 65 mg/g, methylene blue -207 mg/g, and iodine 1001 mg/g. According to the adsorption tests towards nitrogen dioxide, the sorption capacities of the adsorbents studied were increased if a mixture of nitrogen dioxide and air had a humidity of 70 %. The mechanism of methylene blue adsorption involved the formation of adsorptive multilayer. The most effective adsorbent of organic and inorganic pollutants proved to be the activated bio-carbon obtained from the residues after supercritical extraction of blackcurrants.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2019, 55, 6; 1357-1365
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Developing a complex of measures for liquid removal from gas condensate wells and flowlines using surfactants
    Autorzy:
    Volovetskyi, V.B.
    Doroshenko, Ya.V.
    Kogut, G.M.
    Rybitskyi, I.V.
    Doroshenko, J.I.
    Shchyrba, O.M.
    Powiązania:
    https://bibliotekanauki.pl/articles/2175794.pdf
    Data publikacji:
    2021
    Wydawca:
    Stowarzyszenie Komputerowej Nauki o Materiałach i Inżynierii Powierzchni w Gliwicach
    Tematy:
    well
    gas
    flowline
    gas pipeline
    liquid removal
    hydrocarbon extraction
    internal cavity cleaning
    studnia
    gaz
    linia przepływu
    gazociąg
    usuwanie cieczy
    ekstrakcja węglowodorów
    czyszczenie wnęk wewnętrznych
    Opis:
    Purpose: The purpose of this work is to consider the complications that arise while operating gas condensate wells, in particular, the accumulation of hydrocarbon condensate, formation and condensation water at wells and flowlines, to develop a method for removing liquid from wells and flowlines before it entering a gas treatment unit and being treated with surfactants and to develop a method for the foam destruction in the gas-liquid flow. Design/methodology/approach: The operational parameters of gas-condensate wells of the Yuliivske oil and gas condensate field (OGCF) have been analysed. Wells have been identified that are operated in difficult conditions due to the accumulation of the liquid at the bottom hole and in flowlines. The volume of the liquid accumulated at the bottom hole of gas condensate wells is estimated. The quantity of surfactants, the volume and concentration of the solution required to remove the liquid were calculated individually for each well. The program of experimental researches has been made. The efficiency of the application of surfactant solution was experimentally determined and a positive result was achieved in the form of an increase in production by 10%. A new approach to the use of surfactant solution, as well as the foam destruction, has been proposed. The studies were performed within the framework of research and development work by the specialists of the Ukrainian Scientific Research Institute of Natural Gases. Findings: Comprehensive measures are proposed to increase the efficiency of gas condensate wells operation. They are monitoring of operational parameters of wells by pressure and temperature gauges installed at the wellhead and at the inlet gas pipelines of the gas treatment unit; calculation of the volume of accumulated fluid in the wellbore and flowline; installation of a complex of automated feeding a surfactant solution of both in the annulus of the wells and in the flowline. For this purpose, two options for the complex and and have a different principle of operation. To prevent foam from entering the gas treatment unit, a method of its destruction has been proposed. The implementation of the proposed comprehensive measures will allow controlling the well operation mode, timely liquid removal from the well and the flowline and ensure stable hydrocarbon production. Research limitations/implications: The obtained results of laboratory and experimental studies have shown that using a surfactant solution is reasonable to remove the liquid from gas condensate wells. To increase the efficiency of the measure, a new method of feeding surfactant solution was developed by installing a unit for automated feeding (UAF) of a surfactant solution at the mouth. Practical implications: The results of laboratory tests allow using a surfactant solution reasonably in order to remove the liquid from gas condensate wells, as well as possible further destruction of foam in the gas-liquid flow for increasing both the efficiency of the extraction and production volume. Originality/value: On the basis of previously performed experimental research, it has been established that it is advisable to use a surfactant solution to remove the liquid from gas condensate wells and flowlines. A new method of removing liquid from gas condensate wells and flowlines has been developed, as well as a method of destroying foam in a gas-liquid flow, which are original and can be implemented.
    Źródło:
    Archives of Materials Science and Engineering; 2021, 108, 1; 24--41
    1897-2764
    Pojawia się w:
    Archives of Materials Science and Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Development of foam-breaking measures after removing liquid contamination from wells and flowlines by using surface-active substances
    Autorzy:
    Volovetskyi, V. B.
    Doroshenko, Ya. V.
    Stetsiuk, S. M.
    Matkivskyi, S. V.
    Shchyrba, O. M.
    Femiak, Y. M.
    Kogut, G. M.
    Powiązania:
    https://bibliotekanauki.pl/articles/2201061.pdf
    Data publikacji:
    2022
    Wydawca:
    Stowarzyszenie Komputerowej Nauki o Materiałach i Inżynierii Powierzchni w Gliwicach
    Tematy:
    well
    gas
    flowline
    liquid removal
    gas-fluid flow
    foam breaking
    odwiert
    gaz
    linia przepływu
    usuwanie cieczy
    przepływ gaz-ciecz
    Opis:
    Purpose The purpose is to consider the complications that arise during the operation of gas condensate wells, in particular, the accumulation of liquid contamination. Development of new approaches to improve the efficiency of the separation equipment performance of gas gathering and treatment systems when a multiphase flow enters. Development of a foam breaking method in a gas-liquid flow after removal of liquid contaminants from wells and flowlines using surfactants. Design/methodology/approach An analysis was made of the complications that may arise when removing liquid contaminants from wells and flowlines using surfactants. Measures have been developed that will make it possible to timely prevent the ingress of foam into the separation equipment of gas gathering and treatment systems. Using computational fluid dynamics (CFD) modelling, an effective foam-breaking device was developed by supplying stable hydrocarbon condensate. Findings A method to minimize the negative impact of foam on the operation of separation equipment after fluid removal from wells and gas condensate field flowlines using a surfactant solution was elaborated. A method for its breaking was proposed to prevent the flow of foam into the gas processing unit. This method foresees the application of the technological scheme layout for supplying a stable hydrocarbon condensate to a gas-liquid flow entering the separators of the first of separation, both the main line and the measuring line. CFD modelling was used to study the process of foam breaking by feeding hydrocarbon condensate into it. The influence of the hydrocarbon condensate supplying method on gas-dynamic processes (distribution of pressure, velocity, volumetric particles of phases), and the efficiency of foam breaking was estimated. It was established that the supply of hydrocarbon condensate from one branch pipe to the pipeline through which the foam moved did not ensure its complete breaking. To increase the efficiency of foam breaking, a device with designed four nozzles for supplying hydrocarbon condensate was developed. CFD modelling made it possible to substantiate that in this case, a pressure reduction zone appeared at the place of condensate supply. Because of a sharp change in pressure, a strong improvement in the effect of foam breaking occurred. The understanding of the regularities of foam breaking processes by hydrocarbon condensate was obtained, and the design of a device for the complete foam breaking was developed. Research limitations/implications The obtained results of laboratory studies have shown that a sharp decrease in the stability of the foam occurs under the condition of an increase in the volume of stable hydrocarbon condensate added to the studied model of mineralized formation water. Based on the results of CFD modeling, a device for breaking foam by stable hydrocarbon condensate has been worked out, the effectiveness of which will be confirmed experimentally and in field conditions. Practical implications The results of the performed laboratory studies and CFD modelling allow a more reasonable approach to using various available methods and measures to prevent the ingress of foam with a gas-liquid flow into the separation equipment of gas gathering and treatment systems. This approach makes it possible to develop new effective ways and measures to prevent this complication. Originality/value Based on CFD modelling, it was found that when a stable hydrocarbon condensate is supplied into a gas-liquid flow, foam breaks. A method for breaking foam in a gas-liquid flow has been developed, which is original and can be introduced in practice.
    Źródło:
    Journal of Achievements in Materials and Manufacturing Engineering; 2022, 114, 2; 67--80
    1734-8412
    Pojawia się w:
    Journal of Achievements in Materials and Manufacturing Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Właściwości fizykochemiczne i sorpcyjne węgli aktywnych otrzymanych przez aktywację skór owoców cytrusowych oraz niskiej jakości węgla brunatnego
    Physicochemical and sorption properties of activated carbons obtained from citrus fruit peels and low quality lignite
    Autorzy:
    Nowicki, P.
    Kaźmierczak-Raźna, J.
    Pietrzak, R.
    Powiązania:
    https://bibliotekanauki.pl/articles/296829.pdf
    Data publikacji:
    2016
    Wydawca:
    Politechnika Częstochowska. Wydawnictwo Politechniki Częstochowskiej
    Tematy:
    citrus fruit peels
    lignite
    direct activation
    physical activation
    NO2 removal
    H2S removal
    adsorption from liquid phase
    skóry owoców cytrusowych
    węgiel brunatny
    aktywacja bezpośrednia
    aktywacja fizyczna
    usuwanie NO2
    usuwanie H2S
    adsorpcja z fazy ciekłej
    Opis:
    Common citrus fruit peels (banana, grapefruit and orange) as well as low quality lignite were used as precursors for the preparation of cheap activated carbons. In the first step, each of the precursors was air-dried at 110°C, crushed and sieved to the grain size of 5÷6 mm. Next the crushed materials were divided into two parts and subjected to two different treatments: direct activation of the precursors with carbon dioxide or pyrolysis of raw materials followed by physical activation with carbon dioxide. The effect of two variants of thermo-chemical treatment on the elemental composition, textural parameters and acidicbasic character of the surface of adsorbents prepared has been tested. Finally, the activated carbons were tested as adsorbents against two very hazardous and widespread gas pollutants, namely nitrogen dioxide and hydrogen sulphide, as well as toward inorganic and organic liquid pollutants represented by iodine and methylene blue. Depending on the precursor as well as method of preparation, the final products were microporous or mesoporous activated carbons with rather poorly developed surface area ranging from 107 to 527 m2/g and total pore volume from 0.09 to 0.37 cm3/g, showing strongly basic character of the surface. The results obtained have also proved that a proper choice of activation procedure for biomass or low quality lignite allows to produce effective adsorbents with good sorption capacity toward gaseous and liquid pollutants, especially for nitrogen dioxide and iodine.
    W pracy przedstawiono wyniki badań nad otrzymywaniem węgli aktywnych ze skór owoców cytrusowych oraz niskiej jakości węgla brunatnego. Adsorbenty węglowe otrzymano na drodze aktywacji bezpośredniej prekursorów oraz aktywacji fizycznej karbonizatów za pomocą tlenku węgla(IV). Zbadano wpływ wariantu aktywacji na skład elementarny, parametry teksturalne i właściwości kwasowo-zasadowe wytworzonych materiałów węglowych, a także na efektywność usuwania tlenku azotu(IV) i siarkowodoru ze strumienia powietrza oraz jodu i błękitu metylenowego z roztworów wodnych. Na podstawie przeprowadzonych badań stwierdzono, że produkty aktywacji charakteryzują się dość przeciętnie rozwiniętą powierzchnią właściwą mieszczącą się w przedziale od 107 do 527 m2/g i całkowitą objętością porów wynoszącą od 0,09 do 0,37 cm3/g. Wykazano również, że zarówno aktywacja bezpośrednia prekursorów, jak i aktywacja fizyczna karbonizatów za pomocą CO2 prowadzi do uzyskania materiałów o wysokiej zawartości popiołu i wyraźnie zasadowym charakterze powierzchni. Przeprowadzone testy sorpcyjne wykazały ponadto, iż węgle otrzymane poprzez aktywację skór owoców cytrusowych oraz niskiej jakości węgla brunatnego charakteryzują się dobrymi zdolnościami sorpcyjnymi wobec zanieczyszczeń gazowych i ciekłych, w szczególności wobec tlenku azotu(IV) i jodu.
    Źródło:
    Inżynieria i Ochrona Środowiska; 2016, 19, 3; 341-352
    1505-3695
    2391-7253
    Pojawia się w:
    Inżynieria i Ochrona Środowiska
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-4 z 4

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