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Wyświetlanie 1-15 z 109
Tytuł:
Preparation of iron oxide nanocatalysts and application in the liquid phase oxidation of benzene
Autorzy:
Lokhat, D.
Oliver, M.
Carsky, M.
Powiązania:
https://bibliotekanauki.pl/articles/779676.pdf
Data publikacji:
2015
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
Iron oxide nanocatalyst
benzene
oxidation
phenol
liquid phase
Opis:
A series of iron oxide nanocatalysts were prepared using an ultrasonically assisted co-precipitation technique. Molybdenum promoted Fe3O4 and Fe2O3 were prepared from the original materials by wet impregnation using a solution of ammonium molybdate. The catalysts were tested in the liquid phase oxidation of benzene at atmospheric pressure and at 60°C using molecular oxygen. Phenol yields between 7% and 14.5% were obtained. The major products were pyrogallol and catechol.
Źródło:
Polish Journal of Chemical Technology; 2015, 17, 2; 43-46
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Simultaneous measurement of evaporating fuel spray using laser induced exciplex fluorescence
Autorzy:
Martine--Martínez, S.
Sánchez-Cruz, F. A
Rodríguez-Morales, G.
Riesco-Ávila, J. M.
Gallegos-Munoz, A.
Powiązania:
https://bibliotekanauki.pl/articles/243044.pdf
Data publikacji:
2007
Wydawca:
Instytut Techniczny Wojsk Lotniczych
Tematy:
thermal engine
direct injection
liquid phase
vapour phase
penetration length
Opis:
A macroscopic analysis of experimental measurements offuel sprays penetration on evaporating conditions using the Laser Induced Fluorescence Planar technique is presented. A pure fuel and tracers have been used to determine the two-phase process of the spray by characterizing the wavelengths they display when excited by a laser beam. An experimental set-up based on a single cylinder engine [1, 2], an Nd:YAG laser, an image acquisition system and a system of injection common rail have been used to carry out the experimental processes. Experimental results show the behaviour of the vapour phase and liquid phase in the spray under different thermodynamic conditions and injection parameters in the combustion chamber, particularly the work-fluid density and the injection pressure were observed. The measurement of these parameters is of interest to design the combustion chamber geometry and the piston bowl features of modern direct injection Diesel engines. In particularly, the sschematic diagram and main components of the equipment, cross-sectional view of the cylinder head, experimental layout of PLIEF imaging tests and images, examples of the liquid phase and vapour phase penetration, maximum penetration of the liquid and vapour phase as function of the work fluid density, Maximum penetration of the phase as function of the work fluid density, maximum penetration of the liquid and vapour phase as function of the injection pressure are presented in the paper.
Źródło:
Journal of KONES; 2007, 14, 2; 315-326
1231-4005
2354-0133
Pojawia się w:
Journal of KONES
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
New approach to the determination of phase equilibrium in the Zn-Te system
Autorzy:
Moskvin, P.
Olchowik, J.
Olchowik, G.
Zdyb, A.
Gulkowski, S.
Sadowski, W.
Powiązania:
https://bibliotekanauki.pl/articles/1934011.pdf
Data publikacji:
2011
Wydawca:
Politechnika Gdańska
Tematy:
phase equilibria
solubility
liquid phase epitaxy
II-VI semiconductor compound
Opis:
The polyassociative model of the liquid phase was applied to describe the phase equilibrium in the Zn-Te system. The thermodynamic functions describing the formation of liquid associates were obtained, taking into account the experimental data on the p-T-x equilibrium in the system. The model of polyassociative solutions with the parameters obtained in this work satisfactorily describes the p-T-x diagram of the system. The numerical results of the analysis of the phase equilibrium confirmed the possibility of applying the polyassociative model to the Zn-Te system in a wide temperature range.
Źródło:
TASK Quarterly. Scientific Bulletin of Academic Computer Centre in Gdansk; 2011, 15, 2; 209-217
1428-6394
Pojawia się w:
TASK Quarterly. Scientific Bulletin of Academic Computer Centre in Gdansk
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Polyassociative model of A2B6 semiconductor melt and p-T-x phase equilibria in Zn-Cd-Te system
Autorzy:
Moskvin, P.
Antonov, M.
Olchowik, G.
Olchowik, J.
Zdyb, A.
Gulkowski, S.
Sadowski, W.
Powiązania:
https://bibliotekanauki.pl/articles/1934030.pdf
Data publikacji:
2011
Wydawca:
Politechnika Gdańska
Tematy:
phase equilibria
solubility
liquid phase epitaxy
semiconducting II-VI materials
Opis:
This work presents a numerical analysis of p-T-x phase equilibrium in the Zn-Cd-Te ternary system in the framework of the polyassociative solution model. On the basis of the experimental data on p-T-x phase equilibrium in the ternary system, thermodynamic functions describing the formation of liquid associates were found. It was shown that the results of the mixing of components in the Zn-Cd-Te ternary melt are related to the occurrence of ZnCdTe and ZnCdTe3 associates. Dissociation parameters of these complexes were calculated and subsequently used in order to efficiently describe p-T-x phase equilibrium of the system in a wide temperature range.
Źródło:
TASK Quarterly. Scientific Bulletin of Academic Computer Centre in Gdansk; 2011, 15, 1; 121-130
1428-6394
Pojawia się w:
TASK Quarterly. Scientific Bulletin of Academic Computer Centre in Gdansk
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Laccase activity and stability in the presence of menthol-based ionic liquids
Autorzy:
Feder-Kubis, Joanna
Bryjak, Jolanta
Powiązania:
https://bibliotekanauki.pl/articles/1039478.pdf
Data publikacji:
2013
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
laccase
ionic liquid
two-liquid-phase system
enzyme stability
inactivation kinetics
Opis:
Laccases attract attention due to their potential for manufacturing pharmaceutical intermediates from a wide array of phenolic and non-phenolic substrates that are sparingly soluble in water. Because of the high polarity of ionic liquids (ILs), they can dissolve polar and nonpolar compounds and are claimed as "green" alternative for volatile organic solvents. The main aim of this work was to find water-immiscible ILs suitable for Cerrena unicolor laccase. For that five ILs with bis(trifluoromethanesulfonyl)imide anions coupled with cations derived from natural alcohol - (1R,2S,5R)-(-)-menthol were synthesized, namely: (I) 3-butyl-1-[(1R,2S,5R)-(-)-menthoxymethyl]imidazolium, (II) 1-[(1R,2S,5R)-(-)-menthoxymethyl]-3-heptylimidazolium, (III) 1-[(1R,2S,5R)-(-)-menthoxymethyl]-3-methylpyridinium, (IV) heptyl[(1R,2S,5R)-(-)-menthoxymethyl]dimethylammonium, and (V) decyl[(1R,2S,5R)-(-)-menthoxymethyl]dimethylammonium ions. Laccase activity was tested in buffer saturated with ILs whereas stability tests in biphasic systems lasted 5 days. It was shown that ILs I, III-V did not significantly alter laccase activity (being 90-123% respective to the buffer) whereas IL II decreased reactivity in 20%. Stability tests revealed that ILs I, IV and V increased enzyme stability even more than in the buffer. For mathematical formalization of inactivation courses, isoenzyme model was applied but this model fitted experimental data only for sets obtained in the buffer (control) and in the presence of IL II. In the other cases, first-order reaction model was sufficient. This shows that ILs, even at very low concentrations, influence conformational stability of proteins, which is dependent on the cation structure. In general, the imidazolium (I) and ammonium (IV) salts with shorter alkyl chains supported laccase activity and stability.
Źródło:
Acta Biochimica Polonica; 2013, 60, 4; 741-745
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of Microwave Sintering on Properties and Microstructure of Ferromanganese Alloy Powders
Autorzy:
Lei, L.
Libo, Z.
Linqing, D.
Hongbo, Z.
Guo, C.
Jinhui, P.
Qin, G.
Powiązania:
https://bibliotekanauki.pl/articles/947519.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
microwave sintering
ferromanganese powder
densification
liquid phase
process conditions
Opis:
Microwave sintering process was employed to agglomerate ferromanganese alloy powders. The effects of sintering temperature, holding time and particle size composition on the properties and microstructure of sintering products were investigated. The results was shown that increasing sintering temperature or holding time appropriately is beneficial to increase the compressive strength and volume density. SEM and EDAX analysis shows that the liquid phase formed below the melting point in the sintering process, which leads to densification. XRD patterns indicate that the main reaction during microwave sintering is the decarbonization and carburization of iron carbide phase. The experiment demonstrate that the optimum microwave sintering process condition is 1150°C, 10 min and 50% content of the powders with the size of –75 μm.
Źródło:
Archives of Metallurgy and Materials; 2018, 63, 2; 547-553
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Simultaneous extraction of vanadium and chromium from vanadium slag using low-pressure liquid phase oxidation method
Autorzy:
Xia, J.-P.
Zheng, S.-L.
Wang, S.-N.
Liu, B.
Zou, X.
Powiązania:
https://bibliotekanauki.pl/articles/110818.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
vanadium slag
low pressure leaching
liquid phase oxidation
kinetics
Opis:
A low-pressure liquid oxidation method was proposed and proven to be effective to extract vanadium and chromium simultaneously from the vanadium slag in concentrated NaOH aqueous solutions. The effect of temperature, NaOH mass concentration, liquid-to-solid mass ratio, stirring speed and pressure on the extraction of vanadium and chromium in NaOH aqueous solutions were systematically investigated. Under the optimal reaction conditions (temperature of 473 K, liquid-to-solid mass ratio of 6:1, stirring speed of 700 rpm, NaOH mass concentration of 50%, pressure of 1 MPa and reaction time of 180 min), the vanadium and chromium recovery reached 95% and 90%, respectively. It was found that the reaction temperature and NaOH concentration were important factors for the extraction of vanadium and chromium. The kinetics of the decomposition of vanadium slag in concentrated NaOH aqueous under low pressure was analyzed using the shrinking core model, and the results indicated that the extraction of vanadium and chromium were both governed by the internal diffusion step, with apparent activation energies calculated to be 26.22 and 32.79 kJ/mol, respectively.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 2; 609-619
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Modelling of thin Si layers growth on partially masked Si substrate
Autorzy:
Gułkowski, S.
Olchowik, J.M.
Jóźwik, I.
Moskvin, P.P.
Powiązania:
https://bibliotekanauki.pl/articles/1933182.pdf
Data publikacji:
2008
Wydawca:
Politechnika Gdańska
Tematy:
epitaxial lateral overgrowth
liquid-phase epitaxial growth
computer simulations
Opis:
This paper presents a numerical simulation of epitaxial lateral overgrowth of silicon layers from the liquid phase of an Sn solvent. A two-dimensional diffusion equation has been solved and the concentration profiles of Si in a Si-Sn rich solution during the growth have been constructed. The epilayer thickness and width have been obtained from the concentration near the interface.
Źródło:
TASK Quarterly. Scientific Bulletin of Academic Computer Centre in Gdansk; 2008, 12, 1-2; 121-126
1428-6394
Pojawia się w:
TASK Quarterly. Scientific Bulletin of Academic Computer Centre in Gdansk
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Modelling of the interface evolution during Si layer growth on a partially masked substrate
Autorzy:
Gulkowski, S.
Olchowik, J.
Cieślak, K.
Moskvin, P.
Powiązania:
https://bibliotekanauki.pl/articles/1934033.pdf
Data publikacji:
2011
Wydawca:
Politechnika Gdańska
Tematy:
epitaxial lateral overgrowth
liquid-phase epitaxial growth
computer simulations
Opis:
High-quality thin Si layers obtained from the solution by epitaxial lateral overgrowth (ELO) can play a crucial role in photovoltaic applications. The laterally overgrown parts of the layer are characterized by a lower dislocation density than that of the substrate. The height and width of the layer depend on several factors, such as the technological conditions of liquid phase expitaxy (LPE), growth temperature, cooling rate and the geometry of the system (mask filling factor). Therefore, it is crucial to find the optimal set of technological parameters in order to obtain very thin structures with a maximum width (high aspect ratio). This paper presents a computational study of Si epilayer growth on a line-pattern masked silicon substrate from Si-Sn rich solution. To solve this problem, a mixed Eulerian-Lagrangian approach was applied. The concentration profile was calculated by solving the two-dimensional diffusion equation with appropriate boundary conditions. The growth velocity was determined on the basis of gradients of concentration in the border of the interface. Si interface evolution from the opened window was demonstrated.
Źródło:
TASK Quarterly. Scientific Bulletin of Academic Computer Centre in Gdansk; 2011, 15, 1; 91-98
1428-6394
Pojawia się w:
TASK Quarterly. Scientific Bulletin of Academic Computer Centre in Gdansk
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of sodium sulfide waste water recycling on the separation of chalcopyrite and molybdenite
Autorzy:
Wu, D.
Peng, H.
Abdalla, M.
Powiązania:
https://bibliotekanauki.pl/articles/110657.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
vanadium slag
low pressure leaching
liquid phase oxidation
kinetics
Opis:
The effect of sodium sulfide waste water recycling on the separation of chalcopyrite and molybdenite was investigated in this work. The waste water, which was separated from the slurry after selective flotation, was recycled in the flotation system. This operation significantly improved the subsequent flotation of chalcopyrite and saved the reagent. The results showed that the depression efficiency of sodium sulfide gradually disappeared in the recycling tests due to the consumption. The consumption of sodium sulfide in the separation was not only caused by the adsorption on mineral surfaces but also resulted from the precipitation of metal ions which released from minerals. These effects decreased the solution reducibility and the adsorption of hydrosulfide ions, finally resulting in the less depression for chalcopyrite flotation. After adding a certain amount of sodium sulfide to the recycling, the depression of chalcopyrite performed well and the pulp potential maintained at a relatively lower level. Moreover, the pulp potential was an available parameter to control the flotation separation of chalcopyrite and molybdenite, which made the method easily applied to industry.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 3; 629-638
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The influence of chosen calculation parameters on the total volume of the LNAPL product estimated in a mathematical model
Autorzy:
Knez, J.
Knez, D.
Powiązania:
https://bibliotekanauki.pl/articles/298805.pdf
Data publikacji:
2014
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
light non-aqueous phase liquid LNAPL
groungwater flow simulation
oil derivative product
two-phase modelling
parameters characterizing liquid phase
Opis:
There is a number of mathematical models applied to simulate the migration of oil-derived pollution, with the LNAPL (Light non-aqueous phase liquid) volumes in the saturation and aeration zones being analysed in two-phase modeling. A number of hydrogeological parameters and the parameters describing the second phase consisting of oil derivatives are assumed for the sake of the simulation. A part of the data predetermined for the mathematical model is applied on the basis of direct investigations in the field or laboratory, whereas some data are based on a literature analysis or are used by analogy to similar areas. The model data should be additionally verified and validated in the mathematical model. In the case of the LNAPL remediation system being simulated, it is the parameters related to the ground-water environment and the parameters defining the free product of oil that are very important in determining the volume of the recovered LNAPL. With a good deal of data applied for the remediation process simulation one may expect model solutions of different levels of reliability.
Źródło:
AGH Drilling, Oil, Gas; 2014, 31, 4; 463-469
2299-4157
2300-7052
Pojawia się w:
AGH Drilling, Oil, Gas
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Decomposition Pathways for Aqueous Hydroxylammonium Nitrate Solutions: a DFT Study
Autorzy:
Izato, Y.
Koshi, M.
Miyake, A.
Powiązania:
https://bibliotekanauki.pl/articles/357968.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
hydroxylamine nitrate
reaction pathway
liquid-phase reaction
density functional theory
Opis:
Hydroxylammmonium nitrate (hydroxylamine nitrate, HAN) is one of the most promising candidates as a replacement for commonly used liquid mono-propellants such as hydrazine. The reaction pathways involved in the initial and the catalytic decomposition of HAN in aqueous solution were determined using quantum chemistry calculations incorporating solvent effects. Optimized structures were obtained for the reactants, products and transition states at the ωB97XD/6-311++G(d,p)/SCRF = (solvent = water) level of theory and the total electron energies of these structures were calculated at the CBS-QB3 level of theory. In the initial decomposition, the ion-neutral NH3OH+-HNO3 reaction, the neutral-neutral NH3O-HNO3 reaction and the HNO3 self-decomposition pathways were all found to have reasonable energy barriers, with values of 91.7 kJ/mol, 88.7 kJ/mol and 89.8 kJ/mol, respectively. The overall reaction resulting from any of these pathways can be written as: HAN → HONO + HNO + H2O. The ionic reaction is dominant during the initial decomposition of HAN in aqueous solution because NH3OH+ and NO3– are the major species in such solutions. We also developed six catalytic mechanisms and each of these schemes provided the same global reaction: NH2OH + HONO → N2O + 2H2O. The t-ONONO2 oxidizing scheme is the most plausible based on the energy barrier results.
Źródło:
Central European Journal of Energetic Materials; 2017, 14, 4; 888-916
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Densification and Mechanical Properties of 439L Steel Composites Blended with Fifteen Micron-Size Silicon Carbide Particles
Autorzy:
Lee, Sang Woo
Shin, Hyunho
Rhee, Kyong-Yop
Powiązania:
https://bibliotekanauki.pl/articles/351985.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
439L steel
silicon carbide
composites
densification
liquid phase sintering
Opis:
439L stainless steel composites blended with fifteen micron SiC particles were prepared by uniaxial pressing of raw powders at 100 MPa and conventional sintering at 1350°C for 2 h. Based on the results of X-ray diffraction analysis, dissolution of SiC particles were apparent. The 5 vol% SiC specimen demonstrated maximal densification (91.5%) among prepared specimens (0-10 vol% SiC); the relative density was higher than the specimens in the literature (80-84%) prepared by a similar process but at a higher forming pressure (700 MPa). The stress-strain curve and yield strength were also maximal at the 5 vol% of SiC, indicating that densification is the most important parameter determining the mechanical property. The added SiC particles in this study did not serve as the reinforcement phase for the 439L steel matrix but as a liquid-phase-sintering agent for facilitating densification, which eventually improved the mechanical property of the sintered product.
Źródło:
Archives of Metallurgy and Materials; 2019, 64, 3; 883-888
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
An obtaining of nanoheteroepitaxial structures with quantum dots for high effective photovoltaic devices, investigation of their properties
Poluchenie nanogeteroehpitaksialnykh struktur s kvantovymi tochkami dlja vysokoehffektivnykh solnechnykh ehlementov, issledovanie ikh svojjstv
Autorzy:
Maronchuk, I.
Bykovsky, S.
Bondarec, S.
Velchenko, A.
Powiązania:
https://bibliotekanauki.pl/articles/792288.pdf
Data publikacji:
2014
Wydawca:
Komisja Motoryzacji i Energetyki Rolnictwa
Tematy:
nanoheteroepitaxial structure
quantum dot
liquid phase
substrate
photovoltaic device
investigation
property
semiconductor compound
Źródło:
Teka Komisji Motoryzacji i Energetyki Rolnictwa; 2014, 14, 1
1641-7739
Pojawia się w:
Teka Komisji Motoryzacji i Energetyki Rolnictwa
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Textural, surface, thermal and sorption properties of the functionalized activated carbons and carbon nanotubes
Autorzy:
Nowicki, P.
Szymanowski, W.
Pietrzak, R.
Powiązania:
https://bibliotekanauki.pl/articles/779561.pdf
Data publikacji:
2015
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
carbonaceous adsorbents
oxidation
nitrogenation
surface functional groups
thermogravimetric study
adsorption from liquid phase
Opis:
Two series of functionalised carbonaceous adsorbents were prepared by means of oxidation and nitrogenation of commercially available activated carbon and multi-walled carbon nanotubes. The effect of nitrogen and oxygen incorporation on the textural, surface, thermal and sorption properties of the adsorbents prepared was tested. The materials were characterized by elemental analysis, low-temperature nitrogen sorption, thermogravimetric study and determination of the surface oxygen groups content. Sorptive properties of the materials obtained were characterized by the adsorption of methylene and alkali blue 6B as well as copper(II) ions. The final products were nitrogen- and oxygen-enriched mesoporous adsorbents of medium-developed surface area, showing highly diverse N and O-heteroatom contents and acidic-basic character of the surface. The results obtained in our study have proved that through a suitable choice of the modification procedure of commercial adsorbents it is possible to produce materials with high sorption capacity towards organic dyes as well as copper(II) ions.
Źródło:
Polish Journal of Chemical Technology; 2015, 17, 4; 120-127
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 109

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