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Wyszukujesz frazę "kinetic studies" wg kryterium: Temat


Wyświetlanie 1-2 z 2
Tytuł:
Nano sized carbonized waste biomass for heavy metal ion remediation
Autorzy:
Mahajan, Garima
Sud, Dhiraj
Powiązania:
https://bibliotekanauki.pl/articles/779542.pdf
Data publikacji:
2014
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
nitrogenous waste materials
carbon
heavy metal ions
kinetic studies
Delbergia sisso pods
Opis:
Utilization of agricultural waste material with approach to enhance the heavy metal remediation properties by carbonizing the biomass at nano size particles has been explored in present investigation from aqueous solutions. In this study the lignocellulosic, nitrogenous agricultural waste biomass Delbergia sissoo pods (DSP) has been tried for sequestering of Cd (II), Pb (II) and Ni (II) metal ions from aqueous solutions. Batch experiments were performer for removal of targeted metal ions keeping in consideration the preliminary affecting parameters such as effect of adsorption dose, pH, initial metal ion concentration, stirring speed and contact time. The sorption studies were analyzed by using, Freundlic isotherm and Langmuir isotherm models. The kinetics of the process was evaluated by pseudo pseudo-fi rst order and pseudo second order kinetic models. Studies reveal that the equilibrium was achieved with in 30 min of the contact time at optimized parameters. Analytical studies of biosorbent were done by means of FT-IR, SEM and XRD. Desorption experiments were carried out using HCl solution with a view to regenerate the spent adsorbent and to recover the adsorbed metal ions.
Źródło:
Polish Journal of Chemical Technology; 2014, 16, 4; 6-13
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
DETERMINATION OF FLUCONAZOLE AND ITS OXIDATION PRODUCTS WITH KINETIC EVALUATION UNDER POTASSIUM PERMANGANATE TREATMENT IN ACIDIC SOLUTIONS BY ULTRA PERFORMANCE LIQUID CHROMATOGRAPHY-TANDEM MASS SPECTROMETRY
Autorzy:
Hubicka, Urszula
Krzek, Jan
Żmudzki, Paweł
Żuromska-Witek, Barbara
Motyl, Dariusz
Kryczyk, Agata
Powiązania:
https://bibliotekanauki.pl/articles/895338.pdf
Data publikacji:
2019-02-28
Wydawca:
Polskie Towarzystwo Farmaceutyczne
Tematy:
stability
fluconazole
oxidation studies
kinetic evaluation
UPLC/MS
Opis:
For the determination of fluconazole (FLU) oxidation stability under permanganate treatment at the acidic pH, a sensitive, reproducible, and stability-indicating ultra-performance liquid chromatography–mass spectrometry (UPLC/MS) method was developed. Three additional products (tR = 5.79, 6.98, 7.54) were observed besides the FLU (tR = 6.22). The proposed method was used to study the kinetics of FLU oxidative degradation. An oxidation process followed kinetics of the second-order reaction. The degradation rate constant and the corresponding half-life obtained for the FLU oxidative degradation were 0.5626 h-1 and 16.69 h, respectively. The putative oxidation products were characterized and their fragmentation pathways, on a basis of MS/MS data, were proposed.
Źródło:
Acta Poloniae Pharmaceutica - Drug Research; 2019, 76, 1; 19-27
0001-6837
2353-5288
Pojawia się w:
Acta Poloniae Pharmaceutica - Drug Research
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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