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Wyszukujesz frazę "ions removal" wg kryterium: Temat


Wyświetlanie 1-11 z 11
Tytuł:
Membranes obtained on the basis of cellulose acetate and their use in removal of metal ions from liquid phase
Autorzy:
Krason, J.
Pietrzak, R.
Powiązania:
https://bibliotekanauki.pl/articles/778160.pdf
Data publikacji:
2016
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
cellulose acetate membrane
phase inversion
physical and chemical properties
Cu and Fe
ions removal
Opis:
The polymer membranes containing 18 wt% of cellulose acetate and different amounts of polyvinylpyrrolidone (PVP) as a cross-linker agent were used in the process of iron and copper ions removal from liquid phase. Depending on the content of PVP (changed from 1 to 4 wt.%) the membrane surfaces were characterised by different hydrophilic character and showed the dominant presence of surface oxygen-containing groups of acidic character. Irrespectively of the concentrations of solvents from which the metal ions had to be removed, the membranes showed better ability to remove Fe3+ ions than Cu2+ ones, and the membrane resistances decreased with increasing content of PVP. After the filtrations of solutions with iron ions the flux recovery ratio took rather high values; this ratio increased with increasing PVP content in the membrane.
Źródło:
Polish Journal of Chemical Technology; 2016, 18, 2; 104-110
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Multi-variant Sorption Optimization for the Uptake Of Pb(II) Ions by Jamun Seed Waste
Autorzy:
Siyal, A.N.
Memon, S.Q.
Amanullah, M.
Pirzada, T.
Parveen, S.
Powiązania:
https://bibliotekanauki.pl/articles/779346.pdf
Data publikacji:
2013
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
optimization
Pb(II) ions removal
Jamun seed waste
response surface methodology
Factorial Design Approach
Opis:
In the present study, jamun seed waste has been explored for the removal of Pb(II) ions from aqueous solution. The multi-variant sorption optimization was achieved by the factorial design approach. 99.91% of Pb(II) ions was removed from aqueous solution. The results predicted by the model were in good agreement with the experimental results (the values of R2 and R2 adj. were found to be 99.89% and 99.95%, respectively). Langmuir and D-R isotherm studies were carried out to fi nd adsorbent's capacities (183.9 š 0.31 mg/g and 184.5 š 0.16 mg/g respectively), sorption free energy 13.17 š 0.16 and RL values in the range of 0.05-0.77, suggested the favorable chemical and/or ion exchange nature of the sorption process. The FT-IR study was carried out for unloaded and Pb(II) ions loaded jamun seed, indicated, Pb(II) ions associated with nitrogen and oxygen of jamun seed containing moieties during the adsorption process. The proposed method was successfully validated and applied for the treatment of Pb(II) ions contaminating drinking water.
Źródło:
Polish Journal of Chemical Technology; 2013, 15, 1; 15-21
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Crosslinked poly(hydroxybutyl acrylate-co-acrylamide) based hydrogels : synthesis, characterization, and performance evaluation in heavy metal removal
Hydrożele na bazie usieciowanego poli(akrylanu hydroksybutylo-co-akrylamidu) : synteza, charakterystyka i ocena zdolności do usuwania metali ciężkich
Autorzy:
Abdallah, Zahraa Saadi
Mohammed, Ameen Hadi
Powiązania:
https://bibliotekanauki.pl/articles/24202779.pdf
Data publikacji:
2023
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Chemii Przemysłowej
Tematy:
superabsorbent polymer
hydroxybutyl acrylate
acrylamide
adsorption properties
heavy metal ions removal
polimery superchłonne
akrylan hydroksybutylu
akryloamid
właściwości adsorpcyjne
usuwanie jonów metali ciężkich
Opis:
By radical polymerization, two series of superabsorbent hydrogels of hydroxybutyl acrylate and acrylamide copolymers, poly(HBA-co-AAm), were obtained. In the first series, the ratio of hydroxybutyl acrylate to acrylamide was optimized with a constant amount of methylene bisacrylamide (MBA) as a cross-linking agent. In the second series, the amount of MBA was changed at a fixed monomer ratio. The structure of the copolymers was confirmed by the FTIR method. Swelling parameters and mechanical properties were tested. Hydrogels with a high Young’s modulus and a high degree of swelling were selected for the study of adsorption properties towards Co2+, Ni2+ and Cd2+ ions. The influence of basic factors such as adsorbent dose, exposure time and pH on adsorption efficiency was also investigated. The ability to adsorb heavy metal ions changed as follows: Co2+> Ni2+> Cd2+.
Metodą polimeryzacji rodnikowej otrzymano dwie serie superchłonnych hydrożeli kopolimerów akrylanu hydroksybutylu i akryloamidu, poli(HBA-co-AAm), otrzymano. W pierwszej serii optymalizowano stosunek akrylanu hydroksybutylu do akryloamidu przy stałej ilości metylenobisakryloamidu (MBA) jako czynnika sieciującego. W drugiej serii przy ustalonym stosunku monomerów zmieniano ilość MBA. Strukturę kopolimerów potwierdzono metodą FTIR. Zbadano parametry pęcznienia oraz właściwości mechaniczne. Do badań właściwości adsorpcyjnych w stosunku do jonów Co2+, Ni2+ i Cd2+ wytypowano hydrożele o wysokim module Younga i wysokim stopniu pęcznienia. Zbadano również wpływ podstawowych czynników, takich jak dawka adsorbentu, czas ekspozycji i pH na efektywność adsorpcji. Zdolność do adsorpcji jonów metali ciężkich zmieniała się następująco: Co2+> Ni2+> Cd2+.
Źródło:
Polimery; 2023, 68, 2; 86--92
0032-2725
Pojawia się w:
Polimery
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Equilibrium and kinetic studies on the removal of heavy metal ions with natural low-cost adsorbents
Autorzy:
Varank, G.
Demir, A.
Bilgili, M. S.
Top, S.
Sekman, E.
Yazici, S.
Erkan, H. S.
Powiązania:
https://bibliotekanauki.pl/articles/207257.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
adsorbents
adsorption
bentonite
dyes
heavy metals
kinetics
metal ions
water treatment
heavy metal removal
heavy metal ions
heavy metals ions removal
adsorbenty
adsorpcja
bentonit
barwniki
metale ciężkie
kinetyka
jony metali
usuwanie jonów metali ciężkich
uzdatnianie wody
Opis:
Adsorption isotherms and kinetics of the removal of heavy metal ions (Ni, Pb, Zn) from aqueous solutions by natural adsorbents (zeolite, bentonite, clay) were investigated in a lab-scale batch study. The effect of various parameters such as adsorbent dosage, initial concentration of heavy metal ions, temperature, and agitation time were studied to optimise the conditions. Under those optimized conditions (180 rpm agitation rate, 120 min agitation time, pH 4.0, 298 K, 100 mg/dm3 initial adsorbate concentration), the removal percentages of heavy metal ions for natural adsorbents have been determined. The adsorption mechanisms and characteristic parameters of the process were analyzed by two and three parameter isotherm models (Langmuir, Freundlich, Temkin, Redlich-Peterson, Toth and Sips), and kinetic models (Lagergren's pseudo-first order, Ho and McKay's pseudo-second order). Adsorption thermodynamics of heavy metal ions (changes of standard enthalpy, entropy and free energy) on zeolite, bentonite and clay were also studied at 298,318 and 338 K.
Źródło:
Environment Protection Engineering; 2014, 40, 3; 43-61
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Removal of metal ions from aqueous solutions by micellar enhanced ultrafiltration (MEUF)
Autorzy:
Staszak, K.
Redutko, B.
Prochaska, K.
Powiązania:
https://bibliotekanauki.pl/articles/779198.pdf
Data publikacji:
2010
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
usuwanie jonów metali
zwiększenie ultrafiltracji micelarnej
MEUF
removal of metal ions
micellar enhanced ultrafiltration
Opis:
The results of preliminary research on the possibility of removing of chromium(III) and copper(II) ions from micellar solutions in MEUF were described. The effectiveness of metal ions removal in the classical UF and MEUF was compared. It was confirmed that in the classical UF the retention of metal ions is small, independent of the concentration of the feed solution. The cross-flow micellar enhanced ultrafiltration experiments showed the usefulness of this method for the separation of metal ions from micellar solutions. The retention of metal ions in MEUF process is almost total in the case of the solutions of low concentration. However, for more concentrated solutions the retention is much smaller.
Źródło:
Polish Journal of Chemical Technology; 2010, 12, 3; 62-65
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Uptake of copper ion using protonated dry alginate beads from dilute aqueous solutions
Autorzy:
Aracena, Alvaro
Álvarez, César
Jerez, Oscar
Guajardo, Nadia
Powiązania:
https://bibliotekanauki.pl/articles/109473.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
removal mechanism
copper ions
alginate beads
pseudo-first order kinetics model
activation energy
Opis:
This research aimed to identify the copper ion removal mechanism when using protonated dry alginate beads. This mechanism was explained through ion exchange between Cu ions and the protons from the functional groups of the alginate beads. Copper removal increased with stirring velocity, reaching values of 97.5 mg g-1 (97.5×10-3 kg/kg of PDAB) of dry alginate at 200 rev min-1, at a solution pH of 6.0 and a run time of 360 min. For the lowest level of copper concentrations, at 10 mg dm-3 (10×10-6 kg dm-3), full removal was attained. The removal kinetics was represented by a pseudo- first order model. A value of 0.0131 min-1 was found for the velocity constant. Under equilibrium conditions, the experiment data was fit to the Langmuir adsorption model, and the highest removal values were 270.3, 222.2 (222.2×10-3 kg/kg of PDAB) and 49 mg g-1 (49×10-3 kg/kg of PDAB) for pH values of 5.0, 3.5 and 2.5, respectively. These are higher than most sorbents used in the literature for copper removal. Increased temperature leads to higher Cu removal. The activation energy was calculated at 9.3 kJ mol-1 for the temperature range of 283 to 343K. Observations using SEM and composition measurements of the alginate cross-section taken by EDS showed a uniform distribution of the copper concentration through the structure of the alginate beads, independent of the solution pH, contact time and temperature.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 3; 732-744
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Wpływ pola ultradźwiękowego na adsorpcję kationów kadmu
The Effect of Ultrasonic Field on the Adsorption of Cadmium Ions
Autorzy:
Lach, J.
Okoniewska, E.
Stępniak, L.
Ociepa, E.
Powiązania:
https://bibliotekanauki.pl/articles/1819171.pdf
Data publikacji:
2013
Wydawca:
Politechnika Koszalińska. Wydawnictwo Uczelniane
Tematy:
pola ultradźwiękowe
adsorpcja kationów
aqueous solution
activated carbon
sewage sludge
metal ions
removal
surface
Opis:
Adsorption on activated carbon is one of the methods applied for removal of heavy metals from water and wastewater contaminated with these elements. Ion exchange is a predominating mechanism in the process of sorption of ions. In case of sorption of heavy metals cations various surface aggregates are formed. Other processes, such as reduction and oxidation, and precipitation in the pores of insoluble compounds (e.g. hydroxides, carbonates) also occur. The processes behind the formation of aggregates with various degrees of resistance have a particular effect on the selectivity of ion exchange on activated carbons. The chemical composition of activated carbon surface – in particular, the presence of oxygen groups capable of ion exchange – shows the most significant effect during adsorption of heavy metals ions. Typically, the surface of the activated carbons produced with the steam-gaseous method has functional groups both of acidic and alkaline character that are capable of exchanging cations as well as anions. Carbon materials with no functional groups can also sorb protons. This is possible due to the fact that dislocated electrons π in the solutions act as Lewis base. There are a number of methods currently being investigated that would allow for improving the efficiency of adsorption of heavy metals. In the presented work the effect of ultrasonic field on the adsorption of cadmium from the model solutions was analyzed. Various configurations of ultrasonic field applied in the process of adsorption were investigated. Ultrasounds were generated in the UP 400S disintegrator. In the first phase the activated carbon in the form of granules was modified with the ultrasonic field of acoustic power density of 42,5 W/cm2or 85,0 W/cm2, at the amplitude of 30 and 60 µm, and at the exposure time of 5, 10, 15 and 20 min. Modified activated carbons were used for sorption of cadmium ions from the solutions at the initial concentrations ranging from 2,24 do 11,2 mg/dm3. The adsorption of cadmium on the activated carbon modified with ultrasounds (at the amplitude of 30 µm and 60 µm) and at the shortest exposure time (i.e. 5 min.) was higher than on the initial activated carbon. The most favorable results were obtained for the activated carbon modified with ultrasonic field with the acoustic power density of 42,5 W/cm3 and the exposure time of 10 min. The efficiency of cadmium adsorption for the highest concentration increased from 50% (the initial activated carbon) to 63%. Also, the work included the analysis of the effect of ultrasonic field on the cadmium solution with the activated carbon in the form of granules in the first phase of static adsorption. In this case, no significant differences in the adsorption capacities were observed. Also, the effect of ultrasounds on the solution used for the adsorption of cadmium did not have an impact on the efficiency of adsorption. In the final phase of the investigations the effect of sonification on the adsorption of cadmium on the powdery activated carbon was analyzed. The control sample was mechanically mixed for 5 min, and the remaining samples were subjected to the ultrasonic field at various amplitudes but with the same exposure time. The efficiency of adsorption combined with ultrasounds was significantly higher. The final concentrations during the adsorption without ultrasounds were in the range of 0,291 to 1,778 mg/dm3 whereas for the adsorption combined with ultrasounds these concentrations ranged from 0,13 to 0,748 mg/dm3.
Źródło:
Rocznik Ochrona Środowiska; 2013, Tom 15, cz. 3; 2142-2157
1506-218X
Pojawia się w:
Rocznik Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Removal of Fluoride Ions from the Mine Water
Usuwanie jonów fluorkowych z wody kopalnianej
Autorzy:
Krasavtseva, Eugenia
Svetlov, Anton
Goryachev, Andrey
Makarov, Dmitry
Masloboev, Vladimir
Powiązania:
https://bibliotekanauki.pl/articles/318757.pdf
Data publikacji:
2020
Wydawca:
Polskie Towarzystwo Przeróbki Kopalin
Tematy:
wastes
sorbents
fluoride ions
removal
mine water
usuwanie fluoru
ścieki
sorbenty zawierające magnez i wapń
Opis:
Murmansk Region is home to some major mining and mineral sites. One of the most challenging environmental problems in the mining industry is mine water treatment. For example, the rocks of the deposit operated by Lovozero Mining and Mineral Processing Company contain villiomite (NaF). It is highly soluble in water, and the mine waters at the site have a high content of fluoride ions – significantly above the maximum permissible values. Lab-scale experiments were conducted to test various reagents and different initial concentrations of fluoride ions in the treatment of model solutions and mine water. Depending on the initial concentrations, magnesium and calcium-containing sorbents are proposed for the defluorization of water. Using scanning electron microscopy and microprobe analysis, it was found that fluorine can be bound in poorly soluble compounds, such as, for example, fluorite. Pilot trials are planned.
Region Murmański jest regionem silnie uprzemysłowionym, jest lokalizacją wielu kopalń. Jednym z najtrudniejszych problemów środowiskowych w górnictwie jest uzdatnianie wód kopalnianych. Przedstawiono przykład kopalni Lovozero Mining and Mineral Processing. Złoże zawiera villiaumit (NaF). Jest to minerał dobrze rozpuszczalny w wodzie. Wody kopalniane w tym miejscu mają wysoką zawartość jonów fluorkowych - znacznie powyżej maksymalnych dopuszczalnych wartości. Przeprowadzono eksperymenty na skalę laboratoryjną w celu przetestowania różnych odczynników i różnych początkowych stężeń jonów fluorkowych w obróbce roztworów modelowych i wody kopalnianej. W zależności od początkowych stężeń do odfluoryzacji wody proponuje się sorbenty zawierające magnez i wapń. Za pomocą skaningowej mikroskopii elektronowej i analizy mikropróbek stwierdzono, że fluor może wiązać się w słabo rozpuszczalnych związkach, takich jak na przykład fluoryt. Planowane są próby pilotażowe.
Źródło:
Inżynieria Mineralna; 2020, 2, 1; 71-74
1640-4920
Pojawia się w:
Inżynieria Mineralna
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Surfactant assisted removal of Cu(II), Cd(II) and Pb(II) from contaminated soils
Autorzy:
Ramamurthy, A.
Schalchian, H.
Powiązania:
https://bibliotekanauki.pl/articles/207738.pdf
Data publikacji:
2013
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
metal ions
soil pollution
surface active agents
contaminated soils
metal removal
residual contaminants
contaminants removal
surfactants
jony metali
zanieczyszczenie gleby
środki powierzchniowo-czynne
gleba zanieczyszczona
usuwanie metali
zanieczyszczenia resztkowe
usuwanie zanieczyszczeń
Opis:
The study deals with the removal of residual contaminants Cu(II), Cd(II) and Pb(II) from soil using surfactants sodium dodecyl sulfate (SDS), sodium dioctyl sulfosuccinate, and Triton x-100. Surfactants were used with and without chelating agent ethylenediaminetetraacetic acid (EDTA). SDS (10 mM) was the most effective surfactant for removing metals. Replacing distilled water with SDS enhanced metal removal by the factor of 5.5, 28.8, and 29.1 for Cu(II), Cd(II), and Pb(II), respectively. SDS with EDTA was efficient in removing metals. Interaction of metal ions with respect to adsorption and desorption were also studied.
Źródło:
Environment Protection Engineering; 2013, 39, 3; 87-99
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Efficient nitrate adsorption from water by aluminum powder. Kinetic, equilibrium and influence of anion competition studies
Autorzy:
Fakhri, Y.
Kakavandi, B.
Safaei, Z.
Asadi, A.
Mohseni, S. M.
Golestanifar, H.
Powiązania:
https://bibliotekanauki.pl/articles/208008.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
aluminium compounds
kinetic parameters
kinetic theory
negative ions
nitrates
nitrogen removal
particle size
związki glinu
parametry kinetyczne
teoria kinetyczna
jony ujemne
azotany
usuwanie azotu
rozmiar cząstek
Opis:
The feasibility of aluminum powder (with particle size of 75–150 μm) for nitrate removal from aqueous solutions has been investigated. Adsorption was examined in function of initial nitrate concentration, contact time, pH and influence of other interfering anions. Maximum nitrate removal occurred at equilibrium pH of 10. The kinetics of adsorption of nitrate ions was discussed based on three kinetic models, namely: the pseudo-first order, the pseudo-second order and the intraparticle diffusion model. The experimental data fitted the pseudo-second order kinetic model very well; the rate constant was 4x10–4 g/ (mg·min) at the concentration of NO3- of 100 mg/dm3. The adsorption data followed both Langmuir (R2 = 0.808) and Freundlich (R2 = 0.865) isotherms probably due to the real heterogeneous nature of the surface sites involved in the nitrate uptake. The maximum sorption capacity of aluminum powder for nitrate adsorption was found to be ca. 45.2 mg/g at room temperature. The results indicate that aluminum powder is an interesting alternative for nitrate removal from the water.
Źródło:
Environment Protection Engineering; 2018, 44, 3; 19-31
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Zastosowanie koagulantów zawierających żelazo dwu- i trójwartościowe do wspomagania wytrącania związków organicznych oraz skompleksowanych jonów miedzi i cyny ze ścieków przemysłowych
Evaluation of application of coagulants containing divalent and trivalent iron to enhance removal of organic compounds and complexed copper and tin ions from industrial effluents
Autorzy:
Thomas, M.
Białecka, B.
Zdebik, D.
Powiązania:
https://bibliotekanauki.pl/articles/401244.pdf
Data publikacji:
2014
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
produkcja płytek drukowanych
oczyszczanie ścieków
związki kompleksowe
strącanie jonów miedzi i cyny
printed circuits board production
wastewater treatment
complex compounds
removal of copper and tin ions
Opis:
W artykule przedstawiono problematykę dotyczącą parametrów fizyko-chemicznych ścieków surowych pochodzących z produkcji płytek drukowanych. Omówiono skład stosowanych kąpieli technologicznych w aspekcie spełnienia wymagań odnośnie wprowadzania ścieków oczyszczonych do wód, ziemi lub kanalizacji miejskiej. Przedstawiono wyniki prób usuwania związków organicznych oraz skompleksowanych jonów miedzi (II) i cyny (II) i (IV) przy zastosowaniu koagulantów zawierających jony Fe (II) i Fe(III). Na podstawie wyników badań wykazano wysoką skuteczność usuwania związków organicznych oraz związków cyny. Wyjaśniono możliwe przyczyny niskiej skuteczności wytracaniem skompleksowanych jonów miedzi (II).
The article presents the issues concerning physical and chemical parameters of raw sewage from the production of printed circuit boards and the composition of the bath used technology in terms of meeting the requirements for the introduction of treated wastewater into surface waters, ground or the municipal sewage system. Showed test results for the removal of organic compounds and ions complexed copper (II) and tin (II) and (IV) using coagulants containing ions of Fe (II) and Fe (III). The studies showed the high efficiency of removal of organic compounds and tin compounds. Explained the possible causes of the difficulties of precipitation complexed copper ions (II).
Źródło:
Inżynieria Ekologiczna; 2014, 38; 167-180
2081-139X
2392-0629
Pojawia się w:
Inżynieria Ekologiczna
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-11 z 11

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