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Wyszukujesz frazę "ions flotation" wg kryterium: Temat


Wyświetlanie 1-12 z 12
Tytuł:
New method for removal of radioactive particles from waste water after decontamination
Nowa metoda usuwania radioaktywnych zanieczyszczeń z roztworów poakcyjnych
Autorzy:
Maciejewski, P.
Zielonka, Z.
Wrzesiński, J.
Powiązania:
https://bibliotekanauki.pl/articles/373385.pdf
Data publikacji:
2011
Wydawca:
Centrum Naukowo-Badawcze Ochrony Przeciwpożarowej im. Józefa Tuliszkowskiego
Tematy:
Ba-133
Cs 137
flotacja jonowa
jonizowalny eter lariatowy
Sr-85
Cs-137
ions flotation
proton-ionizable crown ether
Opis:
A terrorist attack involves the release and dispersion of radioactive material among civilian population or over vital area causes a permanent radioactive contamination, which should be removed in decontamination process. Finally, after this procedure, a large amount of radioactive waste water is made, which should be collected and stored in a special nuclear waste stockpile. We present results of experimental work, which was focused on removal of radioactive substances from waste water from decontamination process after using .dirty bomb.. The ion flotation process was used to remove radioisotopes from slightly salty (
Atak terrorystyczny z użyciem substancji radioaktywnych wymaga podjęcia odpowiednich działań zmierzających do dekontaminacji skażonych powierzchni. Istotą działania jest mechaniczne usuniecie substancji radioaktywnych z użyciem wodnych roztworów związków powierzchniowo czynnych, co jednak skutkuje postawianiem dużych objętości radioaktywnych ścieków (roztworów poakcyjnych). Rozwiązaniem problemu może być zastosowanie szybkiej i efektywnej metody wydzielania substancji promieniotwórczych z roztworów wodnych, tj. flotacji jonowej. W pracy przedstawiono wyniki badań wydzielania radioizotopów Ba-133, Sr-85 i Cs-137 z rozcieńczonych, zasolonych NaNO3 (1.0 10[^-3] M) roztworów wodnych z użyciem nowej grupy związków makrocyklicznych, tj. jonizowanych eterów lariatowych o stężeniu 1 10[^-5] M w obecności niejonowego roztworu spieniacza . Tritonu X-100 (1 10[^-5] M). Stężenie każdego radioizotopu w mieszaninie wynosiło 1 10[^-5] M i założenia odpowiadało składem radioaktywnym ściekom po dekontaminacji obiektów po ataku bombą radiologiczną. Na bazie uzyskanych wyników zaproponowano zastosowanie "modułu flotacyjnego", który umożliwiłby szybkie usuwanie zanieczyszczeń promieniotwórczych z roztworów poakcyjnych, a przez to zasadniczą redukcje objętości ścieków radioaktywnych.
Źródło:
Bezpieczeństwo i Technika Pożarnicza; 2011, 2; 51-58
1895-8443
Pojawia się w:
Bezpieczeństwo i Technika Pożarnicza
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electrokinetic and flotation behavior of rutile in the presence of lead ions and aluminium ions
Autorzy:
Cheng, Hongwei
Liu, Changmiao
Guo, Zhenxu
Feng, Ansheng
Wei, Min
Lv, Zihu
Wu, Dongyin
Zhao, Dengkui
Powiązania:
https://bibliotekanauki.pl/articles/110558.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
lead ions
aluminium ions
rutile
flotation
Opis:
The effects of Pb(II) ions and Al(III) ions on the electro kinetic and flotation behavior of rutile were investigated by micro-flotation tests, zeta potential measurements and solution chemistry analysis. Micro-flotation results indicate that the Pb(II) ions can effectively improve the flotation recovery of rutile while the Al(III) ions significantly inhibit the flotation of rutile. Zeta potential measurements reveal that a collector styrene phosphoric acid (SPA) can adsorb on the rutile surface after the addition of Pb(II) ions, but hardly adsorb on the rutile surface after the addition of Al(III) ions. Pb(II) ions adsorb on the rutile surface in the form of Pb(OH)+ and Pb(OH)2(s), and the latter one is the main reason that activates rutile flotation. Al(III) ions adsorb on the rutile surface mainly in the form of Al(OH)3(s), which prevent the direct interaction between the rutile and the collector, resulting in a decrease of rutile flotation recovery.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 2; 458-466
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of seawater main components on frothability in the flotation of Cu-Mo sulfide ore
Autorzy:
Laskowski, J. S.
Castro, S.
Ramos, O.
Powiązania:
https://bibliotekanauki.pl/articles/109747.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
seawater
froth stability
Cu-Mo flotation
magnesium ions
molybdenite flotation
Opis:
The main problem in the flotation of Cu-Mo sulfide ores in seawater is poor floatability of molybdenite at pH>9.5. Froth stability plays a very important role in determining concentrate grade and recovery in flotation operations and in this paper both floatability and frothability have been tested. The frothability have been studied by measuring froth equilibrium layer thickness in a modified laboratory flotation cell. Two chemical aspects of seawater need to be considered: the content of NaCl (around 87% of salinity), and the concentration of secondary ions (around 13%) (sulfate, magnesium, calcium, bicarbonate ions, etc.). Seawater, NaCl solutions, and seawater’s ions were found to depress frothability. The effect of pH on frothability over the pH range from 9.5 to 11, which is very strong in freshwater, becomes negligible in seawater and the tested electrolyte solutions. The analysis of the relationship between the mechanisms of molybdenite depression and the loss of frothability in seawater implies that the effects of the studied ions on molybdenite floatability and on pulp frothability are different. While depression of molybdenite floatability could be tracked down to magnesium hydroxide precipitation as a main culprit, the depression of frothability is a much more complicated issue.
Źródło:
Physicochemical Problems of Mineral Processing; 2014, 50, 1; 17-29
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study of flotation behavior and mechanism of cervantite activation by copper ions
Autorzy:
Wang, J.
Wang, Y.
Fu, K.
Xu, L.
Wang, Z.
Sun, H.
Xiao, J.
Powiązania:
https://bibliotekanauki.pl/articles/110228.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
flotation
cervantite
copper ions
activation mechanism
Opis:
Copper-ion activation plays a highly important role in cervantite (Sb2O4) flotation. Without metal-ion activation, cervantite cannot be floated by sodium oleate. In this study, flotation tests were conducted to study the effect of Cu2+ on the flotation behaviours of cervantite and quartz (SiO2) as the main gangue mineral. Metal-ion adsorption capacities, zeta potentials, solution chemistry and X-ray photoelectron spectra were analyzed to study the adsorption behavior and mechanism of copper ions and sodium oleate interaction with the minerals surfaces. The results demonstrate that under weakly acidic conditions, cervantite can be flotated and separated from quartz by the addition of copper ions. The reason is that copper ions can be selectively adsorbed on the cervantite surface under weakly acidic conditions, thereby promoting the adsorption of sodium oleate onto the cervantite surface by chemical adsorption. Conversely, copper ions are weakly adsorbed on quartz surfaces below pH 6.1, and sodium oleate cannot be adsorbed on quartz surfaces by chemical adsorption. The hydroxy copper species are integral to the selective activation of cervantite over quartz.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 3; 814-825
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study of process water effect on the activation of sphalerite during differential flotation of Pb-Cu-Zn
Autorzy:
Gutiérrez Pérez, Victor Hugo
Olvera Vázquez, Seydy Lizbeth
Santos Madrid, Rocio
Regino Piña, Rafael
Cruz Ramírez, Alejandro
Rivera Salinas, Jorge Enrique
Alaniz Hernández, Daniel Israel
Powiązania:
https://bibliotekanauki.pl/articles/2146897.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
sphalerite activation
process water
differential flotation
copper ions
lead ions
Opis:
This work was aimed to analyze the effect of concentration of Cu.2+ and Pb.2+ ions in flotation process water with sphalerite activation, the analysis was performed at Cozamin Mining flotation circuit. This analysis demonstrated that (i) it was possible to determine the relationship between Sodium Cyanide and Ammonium Bisulfite used as depressants and Cu.2+ and Pb.2+ contents in the process water. (ii) It also proved the relationship between lead and iron content in the head with the Pb.2+ ions in process water. According to the data gathered and analysis performed, (iii) it was also determined that it was possible to reuse process water as long as the use of Ammonium Bisulfite was reduced and recommended replacing the use of Sodium Cyanide with Zinc Sulfate (ZnSO4) as a depressant of Sphalerite. Additionally, the concentration of Cu.2+ and Pb.2+ ions in the water should be controlled in a range of 10 to 20 ppm and 0.10 to 0.20 ppm, respectively.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 3; art. no. 146906
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption behavior of calcium ions and its effect on cassiterite flotation
Autorzy:
Chen, Yumeng
Feng, Dongxia
Tong, Xiong
Powiązania:
https://bibliotekanauki.pl/articles/110731.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
cassiterite
calcium ions
adsorption
flotation
salicylhydroxamic acid
Opis:
Naturally, most of the cassiterite co-exists with sparingly soluble calcite, which makes it difficult to be fully utilized. Due to the adsorption of calcium ions dissolved from calcite, surface properties of cassiterite and its floatability can be influenced. Adsorption tests show calcium ions can adsorb on cassiterite surface. In the presence of Ca2+, the zeta potentials of cassiterite shift to more positive values and the isoelectric point of cassiterite increases from pH 4.4 to pH 4.9. XPS results show that after calcium ions treatment, a strong calcium spectral peak at 347.65 eV is detected on the cassiterite surface and the chemical circumstance of oxygen atoms is changed. The presence of Ca2+ can significantly depressed the flotation behavior of cassiterite with salicylhydroxamic acid (SHA) as collector. Its recovery is decreased by 26.03% compared to that without Ca2+ at SHA dosage of 8.0×10-4 mol/dm3. When increasing SHA concentration to 9.0×10-4 mol/dm3 and above, the depression effect is partly compensated and the recovery rises by about 20%. Contact angle values of cassiterite measured by the bubble method correspond well to the flotation performance. Hence the depression mechanism of Ca2+ in cassiterite flotation can be interpreted in two aspects: 1) the consumption of SHA due to complexation reactions in pulp; 2) a decrease of effective adsorption site for SHA on cassiterite because of the adsorption of Ca2+.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 1; 258-267
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence and mechanism of Zn2+ on fluorite/calcite in sodium hexametaphosphate flotation system
Autorzy:
Ruitao, Liu
Dan, Liu
Ruofan, Sun
Daqian, Wang
Wenkang, Zhang
Yuebing, Liu
Shuming, Wen
Powiązania:
https://bibliotekanauki.pl/articles/2175451.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
fluorite
calcite
sodium hexametaphosphate
flotation
metal ions
Opis:
Fluorite and calcite have similar surface properties and natural floatability, so their flotation separation has always been a problem faced by the beneficiation industry. The key to flotation separation is the choice of depressants. Sodium hexametaphosphate (SHMP) has a good effect on fluorite calcite selective inhibition. In this paper, the effects of Zn2+ on the selective inhibition of SHMP in the flotation process of fluorite and calcite were studied through single mineral and artificial mixed mineral flotation experiments. Solution chemical calculation, X-ray photoelectron spectroscopy (XPS), Fourier Transform Infrared spectroscopy (FT-IR) and Time of Flight Secondary Ion Mass Spectrometry (ToF-SIMS) analyses investigated the mechanism of action of Zn2+, which had the most significant negative effect on the selective inhibition of SHMP. The results show that the main components of SHMP inhibiting minerals are HPO42- and H2PO4-, which can react with Ca active sites on the mineral surface to form hydrophilic Ca(H22PO4)2 and CaHPO4, while Zn2+ The presence of HPO42- in solution resulted in the formation of stable ZnHPO4 complexes, thereby weakening the inhibitory effect of SHMP on minerals.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 6; art. no. 151676
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of monovalent and divalent ions in coal gasification brine on the froth entrainment and flotation kinetics of anthracite coal
Autorzy:
Zheng, Kaidi
Bu, Xiangning
Zhou, Shaoqi
Zhang, Jing
Shao, Huaizhi
Sha, Jie
Xie, Guangyuan
Powiązania:
https://bibliotekanauki.pl/articles/1845216.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
coal gasification brine
salts ions
coal flotation
entrainment
flotation kinetics
DLVO theory
Opis:
Water plays a critical role in various stages of flotation, which brings a lot of pressure to the flotation processing plants resided in dry areas. In this regard, it will be of significance to explore the feasibility of using wastewater resources in mineral flotation. Coal gasification brine (CGB) that contains a high concentration of salts becomes the subject of interest of this study. In this study, a synthetic CGB solution, which was prepared by adding NaCl, MgCl2, and CaCl2 to ultrapure water based on the composition of salts in a real CGB, was used in the flotation of anthracite coal. The comparison results based on the first-order model showed that flotation in the presence of the synthetic CGB solution gave a higher flotation selectivity (SI =7.086) than that of flotation in ultrapure water (SI=3.545). Water recoveries and average bubble sizes in the froth showed that the addition of the three salt ions (Na+, Mg2+, and Ca2+) was conducive to diminishing the entrainment of gangue materials as a result of the reduction of water reporting to the froth. Additionally, the zeta potentials and induction time measurements indicated that only divalent ions of Ca2+ and Mg2+ significantly compressed the double electrical layer and enhanced the attachment between bubbles and coal particles according to DLVO theory, which was further confirmed by the calculation of interaction energy between coal and bubbles. The findings of the present work may promote the use of CGB as a potential water resource in coal flotation.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 5; 960-974
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Activation of quartz flotation by Cu2+, Ni2+ in the sodium ethylxanthogenate (EX) system
Autorzy:
Liu, Yang
Tong, Xiong
Xie, Rui-Qi
Xie, Xian
Song, Qiang
Fan, Pei-Qiang
Powiązania:
https://bibliotekanauki.pl/articles/24085981.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
quartz
flotation
ions activation
sodium ethylxanthogenate
adsorption mechanism
Opis:
During the flotation of metal sulfide minerals, due to the interference of unavoidable ions, the quartz also partially floats in some cases. The studies on the mechanism of quartz being activated and floating up are still insufficient. In this study, the influence of the Cu2+ and Ni2+ unavoidable ions on the floatation of quartz was studied by micro-flotation experiments, adsorption detection, zeta potential measurement, solution composition calculation, infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS) analyses, and atomic force microscopy (AFM) observation. This provides a theoretical reference for further understanding the mechanism of sodium ethylxanthogenate and quartz surface, as well as the development of a new quartz depressant. The results of flotation showed that after activation by Cu2+ (1×10-4 mol/dm3) and Ni2+ (5×10-5 mol/dm3), the quartz was captured by sodium ethylxanthogenate (EX: 1.4×10-4 mol/dm3) under alkaline conditions (pH=10), while the best recoveries were obtained as 80% and 43%, respectively. The results of adsorption and zeta potential measurements showed that the precipitation rate of Cu2+ was greater than that of Ni2+ under alkaline conditions. Additionally, both Cu2+ and Ni2+ electrostatically adsorbed on the quartz surface and changed the zeta potential of quartz. The solution composition calculation further showed that Cu(OH)+, Cu(OH)2(s), and Ni(OH)+, Ni(OH)2(s) were the main components in the solution under alkaline conditions. The FT-IR and XPS analyses and AFM observations demonstrated that Cu and Ni species adsorbed on O atoms on the quartz surface, providing active sites for EX adsorption, and EX combines with Cu and Ni species on the quartz surface to generate -O-Cu-EX and -O-Ni-EX complexes. Finally, the quartz floated up due to the formation of hydrophobic products and firm adsorption.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 2; art. no. 166368
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mechanism of Ca2+/Fe3+-based synergistic activation of quartz
Autorzy:
Liu, Rongxiang
Yang, Zhanfeng
Li, Jie
Li, Qiang
Wang, Zhenjiang
Luo, Xiaofeng
Powiązania:
https://bibliotekanauki.pl/articles/2200345.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
quartz
flotation
co-activation
metal ions
sodium dodecyl sulfonate
Opis:
Although the flotation behaviors of iron concentrate and quartz are significantly different, quartz is the primary factor that affects the quality of iron concentrate. The flotation mechanism of quartz in the presence of mixed cationic Ca2+/Fe3+-co-activated SDS catcher was studied by conducting flotation tests with pure quartz mineral. The solution chemical calculation method, zeta potential calculation method, Fourier transform infrared (FT-IR) spectroscopy technique, X-ray photoelectron spectroscopy (XPS) technique, and other techniques were used to conduct the studies. The results showed that the maximum Ca2+/Fe3+-based synergistic activation of the flotation recovery process could be achieved in a certain range of pH values when three different activators were added sequentially. Analysis of the zeta potential values revealed that the Ca2+/Fe3+-activated quartz surface improved the extent of positive electricity generated and enhanced the SDS adsorption ability of the quartz surface. Results obtained using the FT-IR technique revealed that Ca2+/Fe3+ exerted a synergistic effect, and the adsorption process exploited the single oxygen bond interactions in the monovalent hydroxyl complex Ca(OH)+ and the double oxygen bond interactions in the Fe(OH)3 precipitates. Results obtained using the XPS technique revealed that the synergistic effect exerted by Ca2+/Fe3+ was significantly stronger than that exerted by Ca2+ or Fe3+ alone. The stable Fe-based six-membered chelate ring was formed on the surface of quartz when Fe3+ was the activator, and the chain-like Ca-based complex was formed when Ca2+ was the activator. The adsorption process on the surface of quartz proceeded following chemical as well as physical adsorption pathways. The results revealed that Ca(OH)+ and Fe(OH)3 played prominent roles during the activation of quartz surfaces in the presence of Ca2+/Fe3+.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 1; art. no. 162262
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Możliwości sterowania kinetyką wydzielania z roztworu pojedynczych jonów w procesie jednoczesnej flotacji kilku jonów metali
Possibilities of ion separation kinetics control during simultaneous flotation of several metalions
Autorzy:
Kawalec-Pietrenko, B.
Rybarczyk, P.
Powiązania:
https://bibliotekanauki.pl/articles/2072227.pdf
Data publikacji:
2013
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
flotacja jonowa
flotacja precypitacyjna
stała szybkości
jony metali
ion flotation
precipitate flotation
rate constant
metal ions
Opis:
Zbadano wpływ pH surówki flotacyjnej, stężenia kolektora i prędkości przepływu powietrza na przebieg flotacji jonowej i precypitacyjnej mieszaniny Al(III), Cu(II) i Zn(lI). Najwyższe wartości stałych szybkości flotacji badanych metali uzyskano dla procesów prowadzonych dla pH około 8, tj. w warunkach flotacji precypitacyjnej. Wykazano, że stałe szybkości flotacji badanych metali są proporcjonalne do prędkości przepływu powietrza flotującego w potędze około 0,8.
Influence of the initial solution pH, collector concentration and air velocity on the course of Al(III), Cu(II) and Zn(II) ion and precipitate flotation was investigated. The highest values of flotation rate constants for aluminum, copper and zinc were observed for the precipitate flotation when a value of the initial solution pH was about 8. It was concluded that flotation rate constants for investigated metals were proportional to air velocity in the power of about 0.8.
Źródło:
Inżynieria i Aparatura Chemiczna; 2013, 5; 433--434
0368-0827
Pojawia się w:
Inżynieria i Aparatura Chemiczna
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Principles and applications of solvent sublation - a review
Autorzy:
Sobianowska, K.
Walkowiak, W.
Kozłowski, C.
Powiązania:
https://bibliotekanauki.pl/articles/346991.pdf
Data publikacji:
2010
Wydawca:
Politechnika Bydgoska im. Jana i Jędrzeja Śniadeckich. Wydział Technologii i Inżynierii Chemicznej
Tematy:
solvent sublation
ion flotation
adsorptive bubble separations
metal ions
organic compounds
Opis:
This article reviews more than 50 references covering the solvent sublation as one of the adsorptive bubble separation methods for organic and inorganic coumpounds removal from aqueous solutions, which were published last 50 years. The solvent sublation is very simple, effective and fast process for removal and separation of chemical compounds from dilute aqueous solutions and can be treated as preconcentration method in their analytical determination. This review concerns the fundamentals of solvent sublation process and desribes the factors determinating the process (temperature, composition of initial aqueous solution, pH, ionic strength, surfactants and ligands presence, organic solvent presence with additives and gas bubble generation). The examples of metal ions selective removal (Table 1) and organic coupounds removal (Table 2) are shown.
Źródło:
Ars Separatoria Acta; 2009-2010, 7; 23-38
1731-6340
Pojawia się w:
Ars Separatoria Acta
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-12 z 12

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