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Wyszukujesz frazę "ion equilibrium" wg kryterium: Temat


Wyświetlanie 1-12 z 12
Tytuł:
Study of uni-univalent H+/K+ and uni-bivalent H+/Mg2+ ion exchange reactions using nuclear grade resin Indion-223
Autorzy:
Singare, P. U.
Mohammed, A. K. L.
Dixit, N. N.
Powiązania:
https://bibliotekanauki.pl/articles/411848.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
ion exchange equilibrium
nuclear grade resins
cation exchange
enthalpy change
equilibrium constant
Indion-223
Opis:
In the present paper the uni-univalent and uni-bivalent ion exchange reactions were investigated using nuclear grade anion exchange resin Indion-223 in H+ form. For both H+/K+ uni-univalet ion exchange reactions and H+/Mg2+ uni-bivalet ion exchange reactions, the equilibrium constant K values increases from 0.01710 to 0.02374 and from 0.000177 to 0.000333 respectively as the reaction temperature rises from 35.0 °C to 45.0 °C. The increase in K values with temperature suggest endothermic ion exchange reactions having the enthalpy change values of 22.72 and 51.46 kJ/ mol respectively. The results of such studies will help in selection of suitable ion exchange resins in order to bring about efficient separation of different ionic species present in the waste water effluents released from nuclear as well as chemical process industries.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 14, 2; 231-239
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Relacja zawartości potasu do magnezu w roślinności łąkowej i w glebie jako wskaźnik środowiskowych przemian na użytkach zielonych
Potassium to magnesium ratio in meadow vegetation and soil as an indicator of the environmental changes in grasslands
Autorzy:
Sapek, B.
Powiązania:
https://bibliotekanauki.pl/articles/338416.pdf
Data publikacji:
2008
Wydawca:
Instytut Technologiczno-Przyrodniczy
Tematy:
K/Mg
gleba łąkowa
roślinność łąkowa
równowaga jonowa
użytki zielone
zawartość potasu i magnezu
content of elements
grassland plants
ion equilibrium
K/Mg ratio
meadow soil
Opis:
Na podstawie dostępnych wyników badań na dwóch długoletnich, ścisłych doświadczeniach łąkowych na glebie mineralnej przedstawiono propozycję wykorzystania ilorazu zawartości potasu i magnezu (K/Mg) w roślinności łąkowej i glebie jako wskaźnika przemian, jakie mogą zachodzić z upływem lat na użytku zielonym w warunkach stałego poziomu nawożenia mineralnego. Wyniki oznaczeń zawartości potasu i magnezu w roślinności i glebie oraz odczynu gleby w ciągu ponad 20 lat badań umożliwiły ocenę dynamiki zmian tego wskaźnika. Mimo stałego poziomu nawożenia, w tym również potasem, wykazane zmiany wartości K/Mg z upływem lat świadczą o braku równowagi jonowej w pobieraniu składników przez roślinność łąkową. W warunkach stwierdzanego niedoboru potasu oraz magnezu w polskich glebach, zwłaszcza zakwaszonych, duże i wzrastające w czasie wartości K/Mg wskazują na potrzebę wzbogacania takich gleb w magnez oraz ograniczania możliwości jego wymywania, a także na konieczność zrównoważonego nawożenia potasem użytków zielonych.
A proposition was presented to use the potassium to magnesium ratio in plants and soil as an indicator of changes that might occur with time in grassland at constant mineral fertilization. The elaboration was based on results of a study on two long-term exact meadow experiments on mineral soil. Results of potassium and magnesium analyses in plants and soil as well as the determination of soil pH for more than 20 years enabled the estimation of the dynamics of proposed indicator. Despite constant fertilization, including fertilisation with potassium, the temporal changes of K/Mg ratio evidenced the lack of ionic equilibrium of the elements taken up by plants. In view of the recognised deficit of potassium and magnesium in Polish soils, especially in acid soils, high and still increasing K/Mg ratios point to the need of enriching such soils with magnesium and limiting the possibilities of its leaching. In such cases, balanced fertilisation of grasslands with potassium is indispensable.
Źródło:
Woda-Środowisko-Obszary Wiejskie; 2008, T. 8, z. 2b; 139-151
1642-8145
Pojawia się w:
Woda-Środowisko-Obszary Wiejskie
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The main hydrogeochemical processes affecting the composition of certain naturally carbonated waters of southwestern Poland
Autorzy:
Kiełczawa, B.
Powiązania:
https://bibliotekanauki.pl/articles/2059141.pdf
Data publikacji:
2011
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Polska
Kłodzko Region
groundwater
ion exchange
water-rock interaction
mineral equilibrium
Opis:
Kłodzko region is a historical region in southwestern Poland, cutting into the territory of the Czech Republic. In geological terms, it contains (within the Polish borders) the Upper Nysa Kłodzka Graben and the Orlica-Śnieżnik Metamorphic Unit. The region abounds in naturally carbonated waters, whose composition is dominated by HCO-3, Na+, Ca2+ and Mg2+ ions. This study concerns the chemical composition of waters from particular intakes situated in Kudowa-Zdrój, Jeleniów, Duszniki-Zdrój, Polanica-Zdrój and Gorzanów. Chemical data were analysed mathematically and by hydrochemical modelling performed with the help of the AquaChem5.1 and PhreeqC codes. The chemical composition of the waters studied is shaped chiefly by hydrolysis of aluminosilicates. The major ion composition is also influenced by ion exchange (adsorption and desorption) with and dissolution of carbonate minerals. Analysis of saturation indexes showed that these waters are in equilibrium with kaolinite. Generally speaking, the chemical composition of waters in this region is determined by dissolution and precipitation of carbonates (mostly secondary) and aluminosilicates in the presence of carbon dioxide, as well as by ion exchange.
Źródło:
Geological Quarterly; 2011, 55, 3; 203-212
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mathematical models of ion transport through cell membrane channels
Autorzy:
Miękisz, Jacek
Gomułkiewicz, Jan
Miękisz, Stanisław
Powiązania:
https://bibliotekanauki.pl/articles/748548.pdf
Data publikacji:
2014
Wydawca:
Polskie Towarzystwo Matematyczne
Tematy:
ion channels, ion transport, Poisson-Nernst-Planck equations, non-equilibrium statistical mechanics, Kawasaki dynamics, driven lattice gases
Opis:
We discuss various models of ion transport through cell membrane channels. Recent experimental data shows that sizes of some ion channels are compared to those of ions and that only few ions may be simultaneously in any single channel. Theoretical description of ion transport in such channels should therefore take into account stochastic fluctuations and interactions between ions and between ions and channel proteins. This is not satisfied by macroscopic continuum models based on the Poisson-Nernst-Planck equations. More realistic descriptions of ion transport are offered by microscopic molecular and Brownian dynamics. We present a derivation of the Poisson-Nernst-Planck equations. We also review some recent models such as single-file diffusion and Markov chains of interacting ions (boundary driven lattice gases).Such models take into account discrete and stochastic nature of ion transport and specifically interactions between ions in ion channels.
Źródło:
Mathematica Applicanda; 2014, 42, 1
1730-2668
2299-4009
Pojawia się w:
Mathematica Applicanda
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermodynamics of uni-univalent H+/K+ and uni-bivalent H+/Ca2+ ion exchange reactions using nuclear grade resin Indion-223
Autorzy:
Singare, P. U.
Mohammed, A. L. K.
Dixit, N. N.
Powiązania:
https://bibliotekanauki.pl/articles/412388.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
ion exchange
nuclear grade resins
cation exchangers
enthalpy change
standard equilibrium constant
Indion-223
Opis:
The present paper deals with the thermodynamic of uni-univalent and uni-bivalent ion exchange reactions using nuclear grade anion exchange resin Indion-223. It was observed that with rise in temperature the equilibrium constants K values for H+/K+ uni-univalet ion exchange reaction increases from 0.01710 to 0.02374. Similarly for H+/Ca2+ uni-bivalet ion exchange reaction the equilibrium constants K values increases from 0.000397 to 0.000639. The increase in K values with rise in temperature for both the reactions indicates its endothermic nature having the enthalpy change values of 22.72 and 38.92 kJ/ mol respectively. The technique used here can be extended further to standardise the process parameters in order to bring about the efficient separation of the desired ionic species from the solution.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 14, 2; 190-198
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparative study of uni-univalent H⁺/Na⁺ and uni-bivalent H⁺/Ca²⁺ ion exchange reactions using nuclear grade resin Indion-223
Autorzy:
Singare, P. U.
Mohammed, A. L. K.
Dixit, N. N.
Powiązania:
https://bibliotekanauki.pl/articles/411747.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
ion exchange reactions
nuclear grade resins
cation exchange resins
enthalpy
equilibrium constant
Indion-223
Opis:
The present paper deals with the ion exchange equilibrium studies of uni-univalent and uni-bivalent ion exchange reactions using nuclear grade anion exchange resin Indion-223 in H⁺ form towards Na⁺ and Ca²⁺ ions in the solution. It was observed that with rise in temperature the equilibrium constants K values for H⁺/Na⁺ uni-univalet ion exchange reaction increases from 0.01389 to 0.01855. Similarly for H⁺/Ca²⁺ uni-bivalet ion exchange reaction the equilibrium constants K values increases from 0.000397 to 0.000639. The increase in equilibrium constant values with rise in temperature indicate endothermic ion exchange reactions having the enthalpy change values of 25.55 and 38.92 kJ/ mol respectively.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 14, 2; 127-135
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ion exchange equilibrium studies of uni-univalent H+/Na+ and uni-bivalent H+/Mg2+ ion exchange reactions using nuclear grade resin Indion-223
Autorzy:
Singare, P. U.
Mohammed, A. L. K.
Dixit, N. N.
Powiązania:
https://bibliotekanauki.pl/articles/412153.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
cation exchange
nuclear grade resins
ion exchangers
change in enthalpy
equilibrium constant in standard state
Indion-223
Opis:
In the present investigation the uni-univalent and uni-bivalent ion exchange reactions were studied using nuclear grade anion exchange resin Indion-223 in H+ form. It was observed that for H+/Na+ uni-univalet ion exchange reaction, with rise in temperature the equilibrium constants K values increases from 0.01389 to 0.01855. Similarly increase in K values was observed from 0.000177 to 0.000333 for H+/Mg2+ uni-bivalet ion exchange reaction. The increase in equilibrium constant values with rise in temperature indicate endothermic ion exchange reactions having the enthalpy change values of 25.55 and 51.46 kJ/ mol respectively. It is expected that the present study will provide valuable information in order to decide about the selection of those resins for efficient separation of various ionic species present in the industrial waste water effluents.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 14, 2; 199-207
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermodynamic study to evaluate the selectivity behaviour of nuclear grade resin Indion-223 towards some univalent ions
Autorzy:
Singare, P. U.
Mohammed, A. L. K.
Dixit, N. N.
Powiązania:
https://bibliotekanauki.pl/articles/412486.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
uni-univalent ion exchange reactions
ionic selectivity
nuclear grade resins
cation exchangers
enthalpy change
equilibrium constant
Indion-223
Opis:
The present paper deals with the application of thermodynamic concept in understanding the preferential selectivity of nuclear grade anion exchange resin Indion-223 in H+ form towards Na+ and K+ ions in the solution. In the study it was observed that the equilibrium constants K values for H+/Na+ and H+/K+ uni-univalet ion exchange reactions increases from 0.01389 to 0.01855 and from 0.01710 to 0.02374 respectively as the temperature increases from 35.0 °C to 45.0 °C. The increase in K values with rise in temperature suggests endothermic ion exchange reactions having the enthalpy change values of 25.55 and 22.72 kJ/ mol respectively. Based on difference in K values and enthalpy values for the two uni-univalent ion exchange reactions, the preferential selectivity of the resin for the univalent ions in the solution was predicted. From the results of present study, it appears that the experimental technique used here can be applied further to understand the ionic selectivity of different industrial grade ion exchange resins. It is expected that such studies will provide valuable information in order to decide about the selection of those resins for efficient separation of various ionic species present in the industrial waste water effluents.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 15; 22-29
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on Halide Ions Selectivity of Industrial Grade Anion Exchange Resin Auchlite A-378
Autorzy:
Singare, P. U.
Patange, A. N.
Powiązania:
https://bibliotekanauki.pl/articles/412220.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
selectivity
ion exchange reactions
halide ions
industrial grade resins
anion exchange resins
enthalpy
equilibrium constant
Auchlite A-378
Opis:
The thermodynamic approach was applied to predict the trend selectivity of industrial grade anion exchange resin Auchlite A-378 in chloride form towards iodide and bromide ions in the solution. The study was conducted by performing the Clˉ/Iˉ and Clˉ/Brˉ uni-univalent ion exchange reactions under gradually increasing temperature conditions. The thermodynamic equilibrium constants K values were used to calculate the enthalpies of the two uni-univalent ion exchange reactions. It was observed that the K values for Clˉ/Iˉ ion exchange reaction were higher than Clˉ/Brˉ exchange reaction under identical experimental conditions. Also the enthalpy values for the two uni-univalent ion exchange reactions were calculated as -39.51 and -18.38 kJ/mol respectively. The high K and low enthalpy values obtained for Clˉ/Iˉ ion exchange reaction is responsible for higher selectivity of the resin towards iodide ions as compared to that towards bromide ions, when both the ions are present in the same solution.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 11, 1; 44-50
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on Halide Ions Selectivity of Nuclear Grade Anion Exchange Resin Auchlite ARA-9366
Autorzy:
Singare, P. U.
Patange, A. N.
Powiązania:
https://bibliotekanauki.pl/articles/412305.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
selectivity
ion exchange reactions
halide ions
nuclear grade resins
anion exchange resins
enthalpy
equilibrium constant
Auchlite ARA-9366
Opis:
The selectivity behaviour of nuclear grade anion exchange resin Auchlite ARA-9366 in chloride form towards iodide and bromide ions in the solution was studied. The trend in selectivity of the resin was predicted on the basis of thermodynamics of Clˉ/Iˉ and Clˉ/Brˉ uni-univalent ion exchange reactions. It was observed that the equilibrium constants K values for Clˉ/Iˉ ion exchange reaction were higher than that calculated for Clˉ/Brˉ exchange under identical experimental conditions. Also the enthalpy values for the two uni-univalent ion exchange reactions were calculated as -47.87 and -36.14 kJ/mol respectively. The high K and low enthalpy values obtained for Clˉ/Iˉ ion exchange reaction as compared to that obtained during Clˉ/Brˉ exchange supports higher selectivity of the resin towards iodide ions as compared to that towards bromide ions, when both the ions are present in the same solution.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 11, 1; 67-73
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ion-exchange reaction thermodynamics to study the selectivity behaviour of nuclear and non-nuclear grade anion exchange resins
Autorzy:
Singare, P. U.
Patange, A. N.
Powiązania:
https://bibliotekanauki.pl/articles/412083.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
ionic selectivity
uni-univalent exchange
thermodynamic equilibrium constant
enthalpy
nuclear grade ion exchange resin
Auchlite ARA-9366
Auchlite A-378
Opis:
In the present investigation, attempts were made to understand the difference in bromide ion selectivity of the two closely related anion exchange resins Auchlite ARA-9366 and Auchlite A-378 in chloride form. The selectivity difference was predicted based on the thermodynamic equilibrium constants and enthalpy values of Clˉ/Brˉ ion exchange reactions performed by using the two resins. During Clˉ/Brˉ exchange reactions, with rise in temperature from 30.0 °C to 45.0 °C, the equilibrium constant (K) values were observed to decreases from 8.15x10-2 to 6.06x10-2 for Auchlite ARA-9366 resins and from 2.16x10-2 to 1.10x10-2 for Auchlite A-378 resins. The decrease in K values with rise in temperature, indicate exothermic ion exchange reactions having enthalpy values of -36.14 and -18.38 kJ/mol respectively. The high K and low enthalpy values obtained for Auchlite ARA-9366 resins indicate their greater selectivity for the bromide ions in the solution as compared to Auchlite A-378 resins.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 6; 8-15
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermodynamics of Ion-exchange reaction in predicting the ionic selectivity of Auchlite ARA-9366 and Auchlite A-378 anion exchange resins
Autorzy:
Singare, P. U.
Patange, A. N.
Powiązania:
https://bibliotekanauki.pl/articles/412499.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
ionic selectivity
uni-univalent exchange
thermodynamic equilibrium constant
enthalpy
nuclear grade ion exchange resin
Auchlite ARA-9366
Auchlite A-378
Opis:
The paper deals with predicting the iodide ion selectivity of nuclear and non-nuclear grade anion exchange resins. The ionic selectivity prediction was made on the basis of thermodynamic data of Clˉ/I ˉ ion exchange reaction. It was observed that with rise in temperature from 30.0 °C to 45.0 °C, the equilibrium constant (K) values were observed to decreases from 59.77x10-2 to 23.77x10-2 for Auchlite ARA-9366 resins and from 9.01x10-2 to 4.05x10-2 for Auchlite A-378 resins. The decrease in K values with rise in temperature, indicate exothermic ion exchange reactions having enthalpy values of -47.87 and -39.51 kJ/mol respectively. The high K and low enthalpy values obtained for Auchlite ARA-9366 resins indicate their greater selectivity for the iodide ions in the solution as compared to Auchlite A-378 resins, when both the resins are present in chloride form.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 6; 1-7
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-12 z 12

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