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Wyszukujesz frazę "inter-diffusion" wg kryterium: Temat


Wyświetlanie 1-2 z 2
Tytuł:
Diffusion Path in Ternary One-Phase Systems: An Overview
Autorzy:
Serafin, D.
Nowak, W. J.
Wierzba, P.
Wędrychowicz, S.
Wierzba, Bartek
Powiązania:
https://bibliotekanauki.pl/articles/175705.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
inter-diffusion
up-hill diffusion
diffusion path
Opis:
In this article, the fundamental questions concerning the diffusion path, in particular, what is the shape of diffusion path in ternary systems and how to approximate it from the initial concentration profile, will be answered. The new rules were found which allow for determining the diffusion path from a known initial concentration of the components. This approximation will allow for designing new materials without a time-consuming numerical simulation of the full system of equations. It is shown that the difference in intrinsic diffusion coefficients determines the up-hill diffusion.
Źródło:
Advances in Manufacturing Science and Technology; 2020, 44, 1; 1-8
0137-4478
Pojawia się w:
Advances in Manufacturing Science and Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Properties of water hydrating the galactolipid and phospholipid bilayers: a molecular dynamics simulation study
Autorzy:
Markiewicz, Michał
Baczyński, Krzysztof
Pasenkiewicz-Gierula, Marta
Powiązania:
https://bibliotekanauki.pl/articles/1038986.pdf
Data publikacji:
2015
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
molecular modelling
hydrogen bonds
water diffusion
water dipole orientation
inter-lamellar water
Opis:
Molecular dynamics simulations of 1,2-di-O-acyl-3-O-β-D-galactopyranosyl-sn-glycerol (MGDG) and 1,2-dioleoyl-sn-glycero-3-phosphatidylcholine (DOPC) bilayers were carried out to compare the effect of the lipid head group's chemical structure on the dynamics and orientational order of the water molecules hydrating the bilayer. The effect of the bilayers on the diffusion of water is strong for the neighbouring water molecules i.e., those located not further than 4 Å from any bilayer atom. This is because the neighbouring water molecules are predominantly hydrogen bonded to the lipid oxygen atoms and their mobility is limited to a confined spatial volume. The choline group of DOPC and the galactose group of MGDG affect water diffusion less than the polar groups located deeper in the bilayer interface, and similarly. The latter is an unexpected result since interactions of water with these groups have a vastly different origin. The least affected by the bilayer lipids is the lateral diffusion of unbound water in the bilayer plane (x,y-plane) - it is because the diffusion is not confined by the periodic boundary conditions, whereas that perpendicular to the plane is. Interactions of water molecules with lipid groups also enforce certain orientations of water dipole moments. The profile of an average water orientation along the bilayer normal for the MGDG bilayer differs from that for the DOPC bilayer. In the DOPC bilayer, the ordering effect of the lipid head groups extends further into the water phase than in the MGDG bilayer, whereas inside the bilayer/water interface, ordering of the water dipoles in the MGDG bilayer is higher. It is possible that differences in the profiles of an average water orientation across the bilayer in the DOPC and MGDG bilayers are responsible for differences in the lateral pressure profiles of these bilayers.
Źródło:
Acta Biochimica Polonica; 2015, 62, 3; 475-481
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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