- Tytuł:
- Search for the possibility of utilizing the differences in complex-forming capacities of alkylimidazoles for selective extraction of some metal ions from aqueous solutions
- Autorzy:
- Radzymińska-Lenarcik, E.
- Powiązania:
- https://bibliotekanauki.pl/articles/778263.pdf
- Data publikacji:
- 2008
- Wydawca:
- Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
- Tematy:
-
ekstrakcja selektywna
alkiloimidazol
jony metali przejściowych
selective extraction
alkyl imidazole derivatives
transition metals ions - Opis:
- Alkyl substituents in position 1 of the imidazole ring distinctly affect the hydrophobic properties of the molecule and strengthen its basicity. Hence, 1-alkylimidazoles have been used as extractants of a number of metal ions. Again, a methyl substituent in position 2 of the imidazole ring raises by an order of magnitude the basicity. At the same time, the substituent impedes the formation of the 2-alkylimidazole complexes with metal ions due to the steric effect. By the substitution of alkyl groups in position 1 or 2 of the imidazole ring it is possible to program the extraction properties of extractants and to control the selectivity of extraction.
- Źródło:
-
Polish Journal of Chemical Technology; 2008, 10, 1; 73-78
1509-8117
1899-4741 - Pojawia się w:
- Polish Journal of Chemical Technology
- Dostawca treści:
- Biblioteka Nauki
Artykuł