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Wyszukujesz frazę "hydroxamic acid" wg kryterium: Temat


Wyświetlanie 1-6 z 6
Tytuł:
Oil-assisted flotation of fine hematite using sodium oleate or hydroxamic acids as a collector
Autorzy:
Li, H.
Liu, M.
Liu, Q.
Powiązania:
https://bibliotekanauki.pl/articles/109749.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
hematite
sodium oleate
kerosene
Batch Flotation
Octyl hydroxamic acid
Oleoyl hydroxamic acid
Opis:
Micro-flotation and batch flotation tests were carried out on fine (-20 µm) hematite to investigate the influences of non-polar oil when sodium oleate, octyl hydroxamic acid, or oleoyl hydroxamic acid was used as a collector. Both micro-flotation and batch flotation tests were performed using single hematite mineral and/or artificial mixed minerals (hematite:quartz = 1:1), and kerosene was utilized as the neutral oil. The experimental results showed that the addition of a kerosene emulsion benefited hematite recovery in the micro-flotation tests where a froth layer did not exist. In the batch flotation where a froth layer existed, kerosene behaved differently when used in conjunction with the three collectors. Kerosene helped improve the batch flotation when sodium oleate or oleoyl hydroxamic acid was used as a collector. However, it reduced concentrate weight yield, grade and recovery to a noticeable extent when octyl hydroxamic acid was used as a collector, especially at low dosages. In addition, single hematite batch flotation kinetics tests coupled with water recovery measurement were carried out to study the role of kerosene at different collector dosages. It was observed that water drainage and the resulting froth destabilization by kerosene was dominant at low collector dosages, especially in the flotation using octyl hydroxamic acid. At higher collector dosages, the water drainage and froth destabilization effect by kerosene was possibly counter-balanced by the higher hematite surface hydrophobicity and bubble surface tension gradient, which led to more stable froth layer.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 4; 1130-1145
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on a novel hydroxamic acid as the collector of rhodochrosite
Autorzy:
Zhao, G.
Dai, T.
Wang, S.
Zhong, H.
Powiązania:
https://bibliotekanauki.pl/articles/110816.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
flotation
rhodochrosite
hydroxamic acid
DFT
Opis:
A novel collector, tert-butyl benzohydroxamic acid (TBHA), was first introduced in rhodochrosite flotation. The performance of TBHA was investigated by the density functional theory (DFT) calculation along with the micro flotation test, zeta potential determination and XPS analysis, compared with benzohydroxamic acid (BHA). TBHA has stronger affinity to the mineral than BHA in terms of frontier molecular orbital, atomic net charge and bond population. The substitution of tert-butyl group on the benzene ring improves the affinity of the hydroxamic acid to the mineral. TBHA exhibits excellent collecting ability to rhodochrosite with a recovery of about 99% at a concentration of 3.89×10-4 mol/dm3 and pH 6.5. The hydroxamic acid molecules are adhered on mineral surfaces by chemical adsorption, resulting in negative shifts for the zeta potential of rhodochrosite with the presence of the collector. Chemical adsorption can be also confirmed from XPS analyses that the atomic concentration ratios of C and O to Mn on the treated mineral surfaces were increased and the binding energy of Mn3s was decreased. The experimental data achieve excellent agreement with the computational analyses.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 2; 428-439
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Behavior and mechanism of collophane and dolomite separation using alkyl hydroxamic acid as a flotation collector
Autorzy:
Yu, J.
Ge, Y.
Hou, J.
Powiązania:
https://bibliotekanauki.pl/articles/110455.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
hydroxamic acid
collophane
dolomite
separation mechanism
Opis:
Flotation response of collophane and dolomite using alkyl hydroxamic acid (AH) (chelating collector) was investigated in the paper. The experiments were performed using pure and artificially mixed minerals as well as a real phosphate ore. Their separation mechanisms were studied by means of zeta potential measurements, infrared analysis, adsorption measurements, thermodynamics, and quantum chemical calculations. The results indicated that AH exhibited an excellent performance in the flotation separation of collophane from dolomite in neutral medium. The P2O5 grade of the concentrate increased from 19.84% to 30.51% without any other reagents when the pH value was about 7. The zeta potential and adsorption studies showed that the adsorption of AH at the cellophane/aqueous interface was greater than that at dolomite surface, which was the essential reason that separation of collophane from dolomite. The results of Fourier Transform Infrared (FTIR) spectrum and thermodynamics calculation indicated that the adsorption of AH at collophane was attributed to the chemical bonding. Moreover, AH molecule formed O-O five-membered ring with calcium ion on the collophane surface.
Źródło:
Physicochemical Problems of Mineral Processing; 2016, 52, 1; 155-169
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis of a novel hydroxamic acid flotation collector and its flotation separation of malachite against quartz
Autorzy:
Sun, Xin
Huang, Lingyun
Wu, Dandan
Hu, Bo
Zhang, Mei
Li, Yaming
Tong, Xiong
Powiązania:
https://bibliotekanauki.pl/articles/2146909.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
flotation
collector
malachite
hydroxamic acid
direct flotation
adsorption
Opis:
This paper proposes a promising chelating collector, phenyl propyl hydroxamic acid (BPHA), to directly float malachite for the separation of malachite against quartz. The flotation performance and mechanism was investigated via microflotation tests, as well as through contact angle, Scanning Electron Microscopeand Energy Dispersive Spectrometer (SEM–EDS), zeta potential, adsorption capacity, Fourier transform infrared spectroscopy (FT-IR), and X-ray photoelectron spectroscopy (XPS) analyses. The results of microflotation tests showed that BPHA has a strong ability to collect malachite and a significant selectivity against quartz. The contact angle tests showed that BPHA effectively adsorbed onto the mineral surface and could improve the hydrophobicity of the malachite surface. SEM–EDS and adsorption capacity analyses further indicated that BPHA adsorbed onto the surface of malachite. The FR-IR results suggested that BPHA could react with Cu2+ ions and facilitate strong chemical adsorption onto the surface of malachite. Furthermore, zeta potential and XPS analyses provided clear evidence that BPHA exhibited a stronger affinity for malachite and a weaker interaction with quartz.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 4; art. no. 149427
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparing cyclohexyl hydroxamic acid and benzohydroxamic acid in cassiterite flotation under lead nitrate activation
Autorzy:
Yang, Hao
Ou, Leming
Powiązania:
https://bibliotekanauki.pl/articles/27323645.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
adsorption
cassiterite
flotation
lead nitrate
cyclohexyl hydroxamic acid
Opis:
This paper investigates the flotation behavior of Cyclohexyl hydroxamic acid (CHA) and benzhydroxamic acid (BHA) on cassiterite under lead nitrate activation conditions and elucidates the adsorption mechanism of CHA on the cassiterite surface. Microflotation experiments were performed to compare the capturing efficiency of CHA and BHA at pH values ranging from 4 to 12. Results showed that CHA exhibited superior capability in capturing cassiterite compared to BHA. The recovery of cassiterite in the hydroxamic acid-based flotation system correlated positively with the adsorption of hydroxamic acid on the cassiterite surface. Adsorption experiments revealed an increase in adsorption quantity with an increase in hydroxamic acid dosage, with CHA exhibiting significantly higher adsorption amount than BHA on the cassiterite surface. To analyze the adsorption mechanism of CHA on the cassiterite surface, both infrared spectroscopy and X-ray photoelectron spectroscopy (XPS) analysis were conducted, both before and after lead nitrate activation. IR spectra and XPS results indicated that lead ion activation enhanced the adsorption of CHA on the cassiterite surface, resulting in an increased number of active sites for CHA interaction. Additionally, chemisorption of CHA occurred on the cassiterite surface.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 6; art. no. 174673
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of suberoylanilide hydroxamic acid on peripheral blood mononuclear cell cytotoxicity towards tumor cells in canines
Autorzy:
Oyamada, T.
Okano, S.
Powiązania:
https://bibliotekanauki.pl/articles/2087212.pdf
Data publikacji:
2021
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
antitumor effect
canines
cytotoxicity
NKG2D receptor
peripheral blood mononuclear cell
suberoylanilide hydroxamic acid
Źródło:
Polish Journal of Veterinary Sciences; 2021, 24, 1; 35-41
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-6 z 6

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