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    Wyświetlanie 1-6 z 6
    Tytuł:
    Sorption of Cr(VI) onto hdtma modified zeolitic tuffs
    Sorpcja Cr(VI) na tufach zeolitowych modyfikowanych HDTMA
    Autorzy:
    Sobolewska, Paulina
    Chojnacka, Maria
    Kramski, Dawid
    Warchoł, Jolanta
    Powiązania:
    https://bibliotekanauki.pl/articles/1819520.pdf
    Data publikacji:
    2020
    Wydawca:
    Towarzystwo Chemii i Inżynierii Ekologicznej
    Tematy:
    hexavalent chromium
    HDTMA-Br modified zeolites
    clinoptilolite
    phillipsite
    sorption equilibrium
    chrom sześciowartościowy
    zeolity modyfikowane HDTMA-Br
    klinoptylolit
    filipsyt
    równowaga sorpcji
    Opis:
    The removal of Cr(VI) from aqueous solutions was investigated using clinoptilolite and phillipsite-chabazite rich tuffs. These minerals were modified using hexadecyltrimethyl – ammonium bromide (HDTMA-Br) and used for Cr(VI) ions removal. The physicochemical characteristics of zeolitic minerals were revealed by XRD, XRF, BET and FT-IR techniques. The uptake capacities of modified zeolites were compared in batch sorption experiments. To predict the sorption isotherms and to determine the characteristic parameters for process design, three isotherm models the Freundlich, the Langmuir, and the Bilangmuir, were applied to experimental data. The data obtained reveal homogeneous Cr(VI) sorption on one kind of active sites on PC-HDTMA surface and heterogeneous sorption on two kinds of active sites on CL-HDTMA surface.
    Źródło:
    Ecological Chemistry and Engineering. A; 2020, 27, 1-2; 1-9
    1898-6188
    2084-4530
    Pojawia się w:
    Ecological Chemistry and Engineering. A
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Can the effects of chromium compounds exposure be modulated by vitamins and microelements?
    Autorzy:
    Sijko, Monika
    Janasik, Beata
    Wąsowicz, Wojciech
    Kozłowska, Lucyna
    Powiązania:
    https://bibliotekanauki.pl/articles/2086573.pdf
    Data publikacji:
    2021-08-05
    Wydawca:
    Instytut Medycyny Pracy im. prof. dra Jerzego Nofera w Łodzi
    Tematy:
    zinc
    folic acid
    selenium
    hexavalent chromium
    vitamin E
    vitamin C
    Opis:
    Chromium (Cr) is a very common element. It occurs in 2 oxidation states, Cr(III) and Cr(VI). Although Cr(III) is not considered an element essential for mammals, it raises lots of controversy due to its role in the body. While Cr(III) action should be considered an effect of pharmacological action, Cr(VI) is included in the first group of carcinogens for humans. Moreover, it induces numerous pathological changes in the respiratory, urinary, reproductive and digestive systems. In addition, Cr(VI) is used in many industry branches, causing millions of workers all over the world to be exposed to Cr(VI) compounds. A considerable number of the occupationally exposed individuals are in favor of a deep analysis of the mechanisms of Cr(VI) action and a search for a way to reduce its negative impact on the human body. Numerous reactive oxygen species inducing oxidative stress and causing various damage are produced during Cr(VI) reduction in the cells. A good balance between antioxidants and pro-oxidants can reduce Cr(VI)-induced damage. The influence of vitamins and microelements on the adverse Cr(VI) effects has no systematic research results summary. Therefore, this work focuses on the role of dietary antioxidants such as vitamins and microelements in the prevention of Cr(VI) adverse health effects. Numerous studies have revealed a protective influence of vitamins (mainly vitamins E and C) as well as microelements (especially selenium) on the reduction of Cr(VI)-induced adverse changes. A potential protective effect of these ingredients may be useful in occupational groups that are particularly exposed to Cr(VI). However, more research in this area is required.
    Źródło:
    International Journal of Occupational Medicine and Environmental Health; 2021, 34, 4; 461-490
    1232-1087
    1896-494X
    Pojawia się w:
    International Journal of Occupational Medicine and Environmental Health
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Fate and Management of Pollution of Hexavalent Chromium Cr(VI) and Heavy Metals in the Zarqa River Basin in Jordan
    Autorzy:
    Shammout, Maisa'a W.
    Shatanawi, Muhammad
    Awwad, Akl M.
    Powiązania:
    https://bibliotekanauki.pl/articles/2026728.pdf
    Data publikacji:
    2022
    Wydawca:
    Polskie Towarzystwo Inżynierii Ekologicznej
    Tematy:
    Zarqa River Basin
    industrial activity
    water pollution
    hexavalent chromium
    Cr(VI)
    heavy metals
    decision maker
    Opis:
    This paper focused on the fate of pollution and management of hexavalent chromium Cr(VI) and heavy metals in the Zarqa River Basin in Jordan. The Zarqa River basin was selected in this research because it contains the majority of Jordanian industries, which are the main source of pollutants including Cr(VI) and heavy metals. This will help in assisting water resource management organizations in decision making when coping with pollution. Industries related to sources and impacts of Cr(VI) and heavy metals were identified, and the administration measures were highlighted according to their role in improving water quality. An analysis of water samples along the Zarqa River was conducted between 2016-2019 to evaluate the heavy metals concentrations and compare the results with the Jordanian standards. Findings showed that Cr(VI) was below the allowable limits (<5 μg/l), and the heavy metals were within the allowed limits set forth in the Jordanian Standard. The ranges of water analysis values (μg/L) were; DO 4640–6480, Fe <40–80, Mn 20–128, Co <20–30, Pb 80–190, Zn 70–100, and Cu <80–190, Al 700–730, V <70–100, B <300–351, Si 1100–1800, Ni 30, and Cd <10. These findings indicated that the quality of the Zarqa River would not cause hazardous effects. However, this was not the case few years ago due the current protection measures. At present some industries have been relocated from the Zarqa Basin to an area that does not pose any environmental hazards, while the rest of industries remained in the basin, but they have established an on-site treatment plant for industrial waste under the control of Jordanian government, and the enforcement of the environmental protection law. These measures must be monitored and updated by decision makers in a sustainable manner to prevent any water pollution.
    Źródło:
    Journal of Ecological Engineering; 2022, 23, 2; 108-115
    2299-8993
    Pojawia się w:
    Journal of Ecological Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Use of dead and living fungal biomass for removal of hexavalent chromium
    Autorzy:
    Holda, A.
    Mlynarczykowska, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/109742.pdf
    Data publikacji:
    2016
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    hexavalent chromium
    Aspergillus niger
    biosorption
    bioaccumulation
    Opis:
    The removal of hexavalent chromium from aqueous solution was carried out in batch experiments using dead and living biomass of Aspergillus niger. The effects of the operating parameters such as influent Cr(VI) concentration, influent pH and biomass concentration on the Cr(VI) reduction were investigated. The results indicates that the removal rate of Cr(VI) increased with a decrease in pH or with increase of Cr(VI) and biomass concentrations. For chromium bioaccumulation along with nutrients the process is the most intensive within the first 5 days of mycelium formation. For biosorption, the greatest binding of this metal is achieved within the first 4 days of the process.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2016, 52, 2; 551-563
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Removal of hexavalent chromium from aqueous solution by adsorption on γ-alumina nanoparticles
    Autorzy:
    Golestanifar, H.
    Haibati, B.
    Amini, H.
    Dehghani, M. H.
    Asadi, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/207945.pdf
    Data publikacji:
    2015
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    adsorption
    alumina
    aluminum
    chemicals removal
    water treatment
    chromium
    chromium compounds
    nanoparticles
    sorption
    alumina nanoparticles
    hexavalent chromium
    adsorpcja
    aluminium
    usuwanie chemikaliów
    uzdatnianie wody
    chrom
    związki chromu
    nanocząstki
    sorpcja
    nanocząstki tlenku glinu
    chrom sześciowartościowy
    Opis:
    The use of γ-alumina (γ-Al2O3) nanoparticles as adsorbent to remove Cr(VI) from aqueous solution was investigated using batch experiments. Adsorption experiments were carried out for various initial doses of Al2O3, initial concentrations of chromium(VI), contact times and pH. The structure and morphology of the sorbent was characterized by XRD, SEM, and TEM techniques. Results demonstrated that the removal efficiency of chromium(VI) was increased by increasing the contact time, initial concentration, and pH. The results of the study showed that adsorption of chromium by γ-alumina nanoparticles reached equilibrium after 60 min and after that a little change of chromium removal efficiency was observed. Furthermore, kinetics of chromium sorption was well fitted by pseudo-second order kinetic model, and well explained by the Freundlich isotherm (R2 > 0.992). Overall, alumina nanoparticles recognized as an effective sorbent to remove chromium(VI) from aqueous solutions.
    Źródło:
    Environment Protection Engineering; 2015, 41, 2; 133-145
    0324-8828
    Pojawia się w:
    Environment Protection Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Equilibrium and kinetic studies of Cr (VI) removal from synthetic wastewater by Acroptilon repense flower powder
    Autorzy:
    Ghaneian, M. T.
    Ehrampoush, M. H.
    Arany, A. M.
    Jamshidi, B.
    Dehvari, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/778278.pdf
    Data publikacji:
    2013
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    Acroptilon repens
    biosorbent
    Hexavalent Chromium
    adsorption kinetic and isotherm
    Opis:
    In this study the removal of Cr (VI) from synthetic wastewater was investigated using Acroptilon repens (Russian Knapweed) flower powder under various conditions (pH, contact time and initial concentration of Cr). The capacity of chromium adsorption at equilibrium conditions by this biosorbent was increased by adsorbate concentration. The results also showed that the removal efficiency of Cr (VI) was increased by increasing the contact time. By increasing the initial concentration of Cr (VI) solution, chromium removal was reduced. The suitability of adsorbents and their constants was tested or evaluated with the Langmuir, Freundlich and Temkin isotherms models. The results indicated that the Freundlich and Langmuir models (R2 > 0.99) gave a better concordance to the adsorption data in comparison with the Temkin equation (R2 = 0.97). The adsorption of Cr (VI) followed the pseudo-second-order kinetics (R2 = 0.991). The study showed that Acroptilon repens flower powder can be used as an effective lignocellulosic biomaterial and biosorbent for the removal of Cr (VI) from wastewater.
    Źródło:
    Polish Journal of Chemical Technology; 2013, 15, 2; 40-47
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-6 z 6

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