Temat: heavy metals adsorption - Katalog OPAC zbiorów

Skocz do pozycji: 1.

Tytuł:: Synthesis of hydrogel nanocomposites and their application in removing dyes and impurities
Synteza nanokompozytów hydrożelowych i ich zastosowanie do usuwania barwników i zanieczyszczeń
Autorzy:: Ebrahimi, Rajabali
Taherkhani, Mahboubeh
Powiązania:: https://bibliotekanauki.pl/articles/24202832.pdf
Data publikacji:: 2023
Wydawca:: Sieć Badawcza Łukasiewicz - Instytut Chemii Przemysłowej
Tematy:: acrylic hydrogel
nanocomposites
sonification
heavy metals adsorption
dye adsorption
hydrożele akrylowe
nanokompozyty
sonifikacja
adsorpcja metali ciężkich
adsorpcja barwników
Opis:: Polyacrylate hydrogels containing starch, ZnSe and Fe3O4 nanoparticles were obtained. The polymerization process was carried out in an ultrasonic field. The structure (SEM, FTIR, XRD), swelling properties and the ability of hydrogels to adsorb dyes (methylene blue, methyl orange, methyl red and Eriochrome Black T) and heavy metals (Cu2+) from wastewater were investigated. Hydrogels containing AgCl nanoparticles were also obtained, which, due to their antibacterial properties, can be potentially used in medicine.
Otrzymano hydrożele poliakrylanowe zawierające nanocząstki skrobi, ZnSe i Fe3O4. Proces polimeryzacji prowadzono w polu ultradźwiękowym. Zbadano strukturę (SEM, FTIR, XRD), właściwości pęczniejące oraz zdolność hydrożeli do adsorpcji barwników (błękit metylenowy, oranż metylowy, czerwień metylowa i czerń eriochromowa T) oraz metali ciężkich (Cu2+) ze ścieków. Otrzymano również hydrożele zawierające nanocząstki AgCl, które ze względu na właściwości antybakteryjne mogą znaleźć potencjale zastosowanie w medycynie.
Źródło:: Polimery; 2023, 68, 5; 276--285
0032-2725
Pojawia się w:: Polimery
Dostawca treści:: Biblioteka Nauki

Artykuł

Zmień widok

na półce

Skocz do pozycji: 2.

Tytuł:: Analysis of the Possibility of Heavy Metal Ions Removal from Aqueous Solutions on Fruit Pomace
Autorzy:: Krasowska, Małgorzata
Kowczyk-Sadowy, Małgorzata
Szatyłowicz, Ewa
Obidziński, Sławomir
Powiązania:: https://bibliotekanauki.pl/articles/24201639.pdf
Data publikacji:: 2023
Wydawca:: Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:: fruit pomace
adsorption
heavy metals
Opis:: Pomace from apples, grapes, blackcurrants, and oranges is a waste product of fruit processing, which is formed during the production of juices. Pomace is a rich source of biologically active compounds such as polyphenols, carotenoids, or vitamins. They also contain pectin, cellulose, lignin, proteins, and minerals. All these components, apart from having many beneficial properties for human health, also show sorption properties towards heavy metal ions. Therefore, this study aimed to evaluate the possibility of removing lead (II) and cadmium (II) ions from aqueous solutions by adding apple, grape, black currant, and orange pomace as well as to determine the adsorption efficiency of selected heavy metals. The studies were carried out in model systems. The results of the research showed that lead (II) and cadmium (II) ions are adsorbed on fruit pomace. The highest removal of cadmium (II) ions was observed in orange pomace and of lead (II) ions in apple pomace. The maximum tested cadmium ions absorption capacity was: 0.117235 mg/g in the case of freeze-dried apple pomace; 0.08618 mg/g in the case of freeze-dried currant pomace; 0.21915 m/g in the case of freeze-dried grape pomace and 0.29549 mg/g in the case of freeze-dried orange pomace. On the other hand, the maximum absorption of lead ions was: 0.457 mg/g in the case of freeze-dried apple pomace; 0.442 mg/g in the case of freeze-dried currant pomace; 0.3445 mg/g in the case of freeze-dried grape pomace and 0.421 mg/g in the case of freeze-dried orange pomace. On the basis of the performed measurements, it can be concluded that the tested waste can potentially be used as a cheap biosorbent for removing heavy metal ions from dilute aqueous solutions.
Źródło:: Journal of Ecological Engineering; 2023, 24, 3; 169--177
2299-8993
Pojawia się w:: Journal of Ecological Engineering
Dostawca treści:: Biblioteka Nauki

Artykuł

Zmień widok

na półce

Skocz do pozycji: 3.

Tytuł:: Removal of Heavy Metals from Aqueous Solutions with the Use of Lignins and Biomass
Autorzy:: Miros-Kudra, Partycja
Sobczak, Paulina
Kopania, Ewa
Powiązania:: https://bibliotekanauki.pl/articles/2171985.pdf
Data publikacji:: 2022
Wydawca:: Sieć Badawcza Łukasiewicz - Instytut Biopolimerów i Włókien Chemicznych
Tematy:: heavy metals
adsorption
biosorbents
lignin
Opis:: The overproduction of pollutants resulting from the development of industry causes the deposition of large amounts of toxic and carcinogenic substances, including heavy metals, in the aquatic ecosystem and other ecosystems. This is a civilisation problem of the present times, posing a serious threat to the natural environment, including humans. For this reason, it has recently become extremely important to develop effective methods to minimise the concentration of heavy metal ions in the aquatic systems and thus reduce their negative impact on the environment. One such technique is adsorption, which is believed to be an effective method of removing contaminants such as heavy metal ions from aqueous solutions. Looking at the available literaturę of the last few years, it can be concluded that adsorbents of natural origin are becoming more and more important. These are agricultural waste, all kinds of biomass, and waste from various industries. The study attempts to present and evaluate the sorption capacity of materials of natural origin, including oat bran, chitosan, alginate, tree bark, coconut fibre, and lignin. The use of such biosorbents is more friendly for the environment compared to their synthetic counterparts and perfectly fits the concept of sustainable development and the circular economy.
Źródło:: Fibres & Textiles in Eastern Europe; 2022, 2 (151); 99--111
1230-3666
2300-7354
Pojawia się w:: Fibres & Textiles in Eastern Europe
Dostawca treści:: Biblioteka Nauki

Artykuł

Zmień widok

na półce

Skocz do pozycji: 4.

Tytuł:: Investigation of the process of adsorption of heavy metals in coastal sands containing micro-plastics, with special attention to the effect of aging process and bacterial spread in micro-plastics
Autorzy:: Seyfi, Sara
Katibeh, Homayoun
Heshami, Monireh
Powiązania:: https://bibliotekanauki.pl/articles/2073767.pdf
Data publikacji:: 2021
Wydawca:: Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:: adsorption
aging
heavy metals
Erythrobacter
microplastics
Opis:: The chief purpose of this study is to investigate the process of adsorption of heavy metals in sands containing microplastics due to aging and bacterial culture. For this purpose, first, the experiment’s conditions were determined by reviewing previous studies and examining the effects of factors on the duration of bacterial culture and UV radiation. Finally, the test conditions were determined as follows: 25 g of adsorbent in 250 ml solution containing 50 mg/l of lead, cadmium, copper, zinc, chromium, and nickel, 750 micrograms of microplastic, bacterial culture time two days, aging time with UV light 14 days. Results of the study show that the addition of virgin microplastics has little effected on increasing the adsorbent strength, except in the case of nickel which reduces adsorption strength. The aging process increases the absorption of all studied metals by up to 60%. Bacterial culture without an aging process reduces the absorption of nickel and cadmium. Simultaneous use of bacterial culture and aging increases the adsorption power by up to 80% for all metals.
Źródło:: Archives of Environmental Protection; 2021, 47, 3; 50--59
2083-4772
2083-4810
Pojawia się w:: Archives of Environmental Protection
Dostawca treści:: Biblioteka Nauki

Artykuł

Zmień widok

na półce

Skocz do pozycji: 5.

Tytuł:: Combined Adsorption of the Copper and Chromium Cations by Clinoptilolite of the Sokyrnytsya Deposit
Autorzy:: Sabadash, Vira
Gumnitsky, Jaroslaw
Lyuta, Oksana
Powiązania:: https://bibliotekanauki.pl/articles/123357.pdf
Data publikacji:: 2020
Wydawca:: Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:: copper
chromium
heavy metals
adsorption
zeolite
Opis:: In the paper, the assessment of the impact of heavy metals on water objects, namely copper and chromium was performed, and the methods for their neutralization were defined. A scientifically grounded method for the selection of natural zeolite for the purification of wastewater from heavy metals has been developed, provided that they are jointly present. The physicochemical characteristics of two metals related to heavy metals are presented: copper and chromium. The methods for determining the sorption capacity of natural zeolite for copper and chromium compounds, as well as the methods of analytical control of the wastewater components were presented. The results of the experimental studies on the combined adsorption of copper and chromium cations by natural zeolite under static conditions were presented. The changes in the chemical composition of the zeolite surface as a result of heavy metal sorption have been investigated. The influence of the nature of the ions and the pH of the adsorption medium on the selectivity of the heavy metal ions extraction by zeolite was analyzed. A diagram of the composition of the solution, depending on the pH values, was constructed. The pH of the beginning of deposition of the corresponding heavy metal hydroxides on the zeolite surface was calculated. While analyzing the results of experimental studies on the combined adsorption of copper and chromium ions, it was found that the copper ions are significantly better adsorbed by the sorbent than the chromium ions. Despite the same concentration of the chromium and copper ions in solution, Cu²⁺ is extracted selectively. As can be seen from the results of experimental studies, the concentration of copper on the surface of the sorbent increases from 0.628% mass at a concentration of 0.01 g/dm³ to 47.380% mass at a concentration of 1 g/dm³. The studies on the static activity of clinoptilolite for the copper and chromium ions indicate a simultaneous mechanism of the process, which involves ion exchange and physical adsorption. The concentration of the chromium ions on the surface of the sorbent after adsorption depends on the increase of the concentration of Cr³⁺ in the original solution to a lesser extent. The results of the studies on the combined adsorption of the Cu²⁺ and Cr³⁺ ions indicate the possibility of their chromatographic separation, which makes their further use possible.
Źródło:: Journal of Ecological Engineering; 2020, 21, 5; 42-46
2299-8993
Pojawia się w:: Journal of Ecological Engineering
Dostawca treści:: Biblioteka Nauki

Artykuł

Zmień widok

na półce

Skocz do pozycji: 6.

Tytuł:: The kinetics, thermodynamics and equilibrium study of nickel and lead uptake using corn residues as adsorbent
Autorzy:: Tejada-Tovar, Candelaria
Villabona-Ortíz, Ángel
Gonzalez-Delgado, Angel Darío
Powiązania:: https://bibliotekanauki.pl/articles/1844359.pdf
Data publikacji:: 2021
Wydawca:: Instytut Technologiczno-Przyrodniczy
Tematy:: adsorption
corn wastes
heavy metals
kinetics
thermodynamics
Opis:: Agricultural residues rich in lignocellulosic biomass are low-cost and sustainable adsorbents widely used in water treatment. In the present research, thermodynamics, kinetics, and equilibrium of nickel(II) and lead(II) ion biosorption were studied using a corncob (Zea mays). The experiments were performed in a batch system evaluating the effect of temperature and dose of adsorbent. Langmuir and Freundlich isotherms were used to study the equilibrium. Thermodynamic and kinetic parameters were determined using kinetic models (pseudo-first order, pseudo-second order, Elovich). Biosorbent characteristics were studied by Fourier-transform infrared spectroscopy, Scanning Electron Microscopy and Energy-dispersive X-ray spectroscopy. It was found that the hydroxyl, carboxyl, and phenolic groups are the major contributors to the removal process. Besides, Pb(II) ions form micro-complexes on the surface of the biomaterial while Ni(II) ions form bonds with active centers. It was found that the highest Ni(II) removal yields were achieved at 0.02 g of adsorbent and 70°C, while the highest Pb(II) removal yields were achieved at 0.003 g and 55°C. A maximum Ni(II) adsorption capacity of 3.52 mg∙g–1 (86%) and 13.32 mg∙g–1 (94.3%) for Pb(II) was obtained in 250 and 330 min, respectively. Pseudo-first order and pseudo-second order models best fit experimental data, and Langmuir and Freundlich models well describe the isotherm of the process. Thermodynamic parameters (ΔH0, ΔG0, ΔS0) suggest that the adsorption process of both cations is exothermic, irreversible, and not spontaneous.
Źródło:: Journal of Water and Land Development; 2021, 48; 197-204
1429-7426
2083-4535
Pojawia się w:: Journal of Water and Land Development
Dostawca treści:: Biblioteka Nauki

Artykuł

Zmień widok

na półce

Skocz do pozycji: 7.

Tytuł:: Potassium Hydroxide Activated Peanut Shell as an Effective Adsorbent for the Removal of Zinc, Lead and Cadmium from Wastewater
Autorzy:: Maki, Rusol
Qasim, Bashar
Powiązania:: https://bibliotekanauki.pl/articles/2202316.pdf
Data publikacji:: 2023
Wydawca:: Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:: adsorption
activated peanut shell
heavy metals
wastewater
Opis:: The toxic heavy metals, as non-biodegradable pollutants, have become a serious threat to aquatic environment. This study aimed to assess the efficiency of the low cost, available and environment-friendly peanut shell as an effective adsorbent for the removal of Zn, Pb and Cd from wastewater. The peanut shell was prepared by carbonization by pyrolysis process at 550 °C, activated with 7M potassium hydroxide(KOH) at 750 °C, and then characterized by using Scanning Electron Microscopy (SEM), and Fourier Transform Infrared spectroscopy (FTIR), X-ray diffraction (XRD) and Brunauer-Emmett-Teller (BET) surface area analysis. The optimum conditions for metal ions adsorption were investigated as a function of various parameters. The optimum conditions included: pH of 6, initial metal concentrations of 20 mg/l for Pb and Zn as well as 40 mg/l for Cd, adsorbent mass of 2 g, optimum temperature of 45 °C and the preferable contact time of 60 min. The removal percent for the studied metal ions exceeded 98%. The adsorption isotherm showed that the Langmuir model was the best fitted model for the metal ions adsorption onto activated peanut shell surface, and the kinetic of adsorption followed the pseudo-first order model. The obtained results showed that the KOH-activated peanut shell possess higher adsorption efficiency for the removal of the studied metal ions from wastewater.
Źródło:: Journal of Ecological Engineering; 2023, 24, 1; 66--78
2299-8993
Pojawia się w:: Journal of Ecological Engineering
Dostawca treści:: Biblioteka Nauki

Artykuł

Zmień widok

na półce

Skocz do pozycji: 8.

Tytuł:: Surface modified bentonite mineral as a sorbent for $Pb^{2+}$ and $Zn^{2+}$ ions removal from aqueous solutions
Autorzy:: Selim, K.haled A.
Rostom, Merit
Youssef, Mohhamed A.
Abdel-Khalek, Nagui A.
Abdel-Khalek, Mohhamed A.
Hassan, El-Sayed R. E.
Powiązania:: https://bibliotekanauki.pl/articles/1450133.pdf
Data publikacji:: 2020
Wydawca:: Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:: Ca-montmorillonite
adsorption
heavy metals
surface modification
rheology
Opis:: Environmental pollution by lead ($Pb^{2+}$) and zinc ($Zn^{2+}$) ions has become an important issue due to its harmful effects on human health and environment. This work aims to evaluate the application of surface modified Egyptian bentonite mineral by acid activation using $H_2SO_4$ and thermal treatment as an adsorbent to remove lead ($Pb^{2+}$) and zinc ($Zn^{2+}$) ions from aqueous solution. X-ray diffraction (XRD), Fourier Transformed Infrared Spectroscopy (FTIR) and Scanning Electron Microscope (SEM) techniques were used to investigate the modified bentonite. The impact of organic and inorganic dispersants on rheological characteristics of bentonite suspensions was investigated. Adsorption of $Pb^{2+}$ and $Zn^{2+}$ ions using modified bentonite mineral was performed with different adsorbent doses and pH values. Removal efficiencies of lead and zinc are 99.67% and 99%, respectively with adsorbent dose of 25 g/l at pH of 6.2.
Źródło:: Physicochemical Problems of Mineral Processing; 2020, 56, 6; 145-157
1643-1049
2084-4735
Pojawia się w:: Physicochemical Problems of Mineral Processing
Dostawca treści:: Biblioteka Nauki

Artykuł

Zmień widok

na półce

Skocz do pozycji: 9.

Tytuł:: Polyurethane Loaded with Vegetable Activated Carbon for Heavy Metals Removal from Water
Autorzy:: El Malti, Wassim
Hamieh, Mostafa
Noaman, Amer
El-Dine, Rim Nasser
Hijazi, Akram
Al-Khatib, Wassef
Powiązania:: https://bibliotekanauki.pl/articles/1955582.pdf
Data publikacji:: 2021
Wydawca:: Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:: activated carbon
adsorption
banana stem
heavy metals
polyurethane
Opis:: The heavy metals pollutants resulting from industrial wastewater are a major environmental problem due to their toxicity and non-biodegradability. Their removal became a trending environmental subject. The preparation of low-cost and eco-friendly adsorbents for industrial wastewater treatment has been widely investigated. Furthermore, the use of polymeric material for this purpose is highly increasing. In this study, banana stem agro-waste was valorized by preparing and characterizing its derived activated carbon used as a filler to improve the adsorption performance of polyurethane foams. The loaded polyurethane was synthesized in the shape of pellets, characterized by SEM, and tested in removing Pb2+ and Cu2+ from aqueous solutions. The effects of activated carbon filler concentration, number of filtering passes, and pH were examined. The loaded polyurethane demonstrated a good adsorption capacity that was enormously improved compared to the unloaded polymer. 77% Pb2+ and 40% Cu2+ removal were reached after one filtering pass only. The optimum pH was determined to be 4. After the 10th pass, and at any pH, almost 100% of the studied metals were eliminated. Rapid and straightforward selectivity and seawater deionization tests were carried out and confirmed the capacity performance of the prepared pellets in removing different aqueous ions.
Źródło:: Journal of Ecological Engineering; 2021, 22, 9; 99-110
2299-8993
Pojawia się w:: Journal of Ecological Engineering
Dostawca treści:: Biblioteka Nauki

Artykuł

Zmień widok

na półce

Skocz do pozycji: 10.

Tytuł:: The use of agro-industrial residues of coffee (Coffea arabica) for the removal of mercury from water
Autorzy:: Tejada-Tovar, Candelaria N.
Rocha-Caicedo, María M.
Paz-Astudillo, Isabel C.
Powiązania:: https://bibliotekanauki.pl/articles/2203551.pdf
Data publikacji:: 2023
Wydawca:: Instytut Technologiczno-Przyrodniczy
Tematy:: agro-industrial residue
bio-adsorption
encapsulation
heavy metals
isotherms
Opis:: Contamination of water bodies by heavy metals is a continuously growing environmental issue. High concentrations of mercury (Hg) in river waters are a recognized environmental problem, because it is one of the most toxic heavy metal ions as it causes damage to the central nervous system. Its negative impact has led to the development of different methods for the treatment of effluents contaminated with Hg(II). The aim of this article is to evaluate the use of coffee (Coffea arabica) residues as adsorbent of Mercury in an aqueous solution. Four kinetic models, including intraparticle diffusion, pseudo-first-order, pseudo-second-order, and Elovich kinetic models were applied to explore the internal mechanism of mercury adsorption. Results indicate that the pseudo-first-order and pseudo-second-order models could accurately describe the adsorption process. It means that chemical adsorption play an important role in the adsorption of mercury by activated carbon. Meanwhile, the external mass transfer process is more effective in controlling the activated carbon mercury adsorption according to the fitting result of the pseudo-first-order model. The fitting to Langmuir’s model suggested that the material surface is energetically homogeneous. The technique of contaminated biomass encapsulation proved to be safe for short-term disposal when metal recovery is not desired.
Źródło:: Journal of Water and Land Development; 2023, 56; 164--171
1429-7426
2083-4535
Pojawia się w:: Journal of Water and Land Development
Dostawca treści:: Biblioteka Nauki

Artykuł

Zmień widok

na półce

Skocz do pozycji: 11.

Tytuł:: Analysis of adsorption of heavy metals from water solutions by wood of selected domestic species using X-Ray Fluorescence (XRF)
Autorzy:: Balicka, Adrianna
Szadkowski, Jan
Powiązania:: https://bibliotekanauki.pl/articles/2200144.pdf
Data publikacji:: 2020
Wydawca:: Szkoła Główna Gospodarstwa Wiejskiego w Warszawie. Wydawnictwo Szkoły Głównej Gospodarstwa Wiejskiego w Warszawie
Tematy:: X-Ray Fluorescence Spectroscopy
wood shaving
adsorption
heavy metals
Opis:: Analysis of adsorption of heavy metals from water solutions by wood of selected domestic species using X-Ray Fluorescence (XRF).The aim of this study was to analyze the absorption of three specific heavy metals from model water solution by wood species from domestic Polish forests. This paper focuses on XRF method to determine metal content in samples. European aspen (Populus tremula L.) and Black locust (Robinia pseudoacacia L.) have been chosen. Firstly, shavings were prepared and soaked with standard solutions of lead (II) nitrate, cadmium nitrate and mercury (II) chloride for 7 days. Then, the material was dried and reduced to ashes using muffle furnace. Finally, content of absorbed metal was marked (XRF) and analyzed with a view to initial contents of metal ions in standard solutions. It was established, that the higher the concentration of mercury in standard solution is, the higher impulse counts is obtained for European aspen. This reversal of the dependence is noticeable for second analyzed species.
Badanie adsorpcji metali ciężkich z modelowych roztworów wodnych przez drewno wybranych gatunków krajowych za pomocą Spektrometrii Fluorescencji Rentgenowskiej (XRF). Celem wykonanych badań było sprawdzenie poziomu adsorpcji wytypowanych metali ciężkich tj. ołowiu, kadmu oraz rtęci, przez dwa gatunki rodzime topolę (Populus tremula L.) oraz robinię akacjową (Robinia pseudoacacia L.). W fazie przygotowawczej materiał został znacznie rozdrobniony i rozdzielony na kilka frakcji. Działanie to miało na celu zwiększenie powierzchni adsorpcji badanego drewna. Azotan kadmu (II), azotan ołowiu oraz chlorek rtęci (II) zostały rozpuszczone w destylowanej wodzie w takich proporcjach, aby stworzyć po cztery roztwory – każdy o innym stężeniu. Wybrana frakcja wiórów została poddana obróbce termicznej w wodzie destylowanej w celu usunięcia zawartego powietrza. Następnie frakcję podzielono na próbki 1 gramowe. Drewno nasiąkało w modelowych roztworach przez ok. 168 godzin. Finalnie zostało ono odsączone, wysuszone i spopielone w piecu muflowym. Tak przygotowane próbki zostały poddane badaniu z wykorzystaniem spektrometrii fluorescencji rentgenowskiej (XRF). Urządzenie analizowało zawartość metali w pyle za pomocą dwóch różnych programów i trzech czasów naświetlania. Otrzymane wartości analizowano pod kątem ilościowym a nie jakościowym.
Źródło:: Annals of Warsaw University of Life Sciences - SGGW. Forestry and Wood Technology; 2020, 111; 73--82
1898-5912
Pojawia się w:: Annals of Warsaw University of Life Sciences - SGGW. Forestry and Wood Technology
Dostawca treści:: Biblioteka Nauki

Artykuł

Zmień widok

na półce

Skocz do pozycji: 12.

Tytuł:: Modification of Salix americana willow bark for removal of heavy metal ions from aqueous solutions
Autorzy:: Rypińska, Iwona
Biegańska, Marta
Powiązania:: https://bibliotekanauki.pl/articles/779386.pdf
Data publikacji:: 2014
Wydawca:: Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:: waste
adsorption
heavy metals
willow bark
methods of modification
Opis:: Salix americana willow bark is a waste arising in the process of wicker decortication that so far has not found Any practical application. The bark can adsorb metal ions, because in its composition among others are phenolic groups which may be involved in the removal of metal ions from water solutions. The results of sorption of copper(II) and zinc(II) on modifi ed willow bark of Salix americana were presented. The bark was modifi ed with nitric and sulfuric acids at concentrations ranging from 5 to 15%. The best adsorption results were obtained using 15% nitric acid for modifi cation. Adsorption of metal ions from aqueous solutions at concentrations raging from 20 to 100 mg/dm3 was studied. It was found that an increase in the initial concentration of copper(II) and zinc(II) resulted in an increase in their adsorption on the modifi ed cortex.
Źródło:: Polish Journal of Chemical Technology; 2014, 16, 4; 41-44
1509-8117
1899-4741
Pojawia się w:: Polish Journal of Chemical Technology
Dostawca treści:: Biblioteka Nauki

Artykuł

Zmień widok

na półce

Skocz do pozycji: 13.

Tytuł:: MgFe-doubled layers hydroxide intercalated with low cost local adsorbent using for removal of lead from aqueous solution
Autorzy:: Abdul-Hameed, Hayder M.
Al Juboury, Maad F.
Powiązania:: https://bibliotekanauki.pl/articles/292557.pdf
Data publikacji:: 2020
Wydawca:: Instytut Technologiczno-Przyrodniczy
Tematy:: adsorption
agriculture waste
composite adsorbent
heavy metals
leaf date palm
Opis:: A new composite adsorbent was prepared by modifying low cost local adsorbent (LCL) using MgFe layered double hydroxide (LDH). This low cost local adsorbent was also prepared from the activation of date palm leaf derived from agricultural waste. In comparison to the low LCL, the adsorption capacity of the new composite adsorbent (LCL/MgFe-LDH) was improved. This was measured in terms of its ability to remove lead from wastewater. The Scanning electron microscope (SEM), Energy dispersive spectroscopy (EDS), Fourier-transform infrared spectroscopy (FTIR) and the specific surface area by the (Brunauer, Emmett and Teller) theory (BET) tests were conducted for the characterisation of LCL and LCL/MgFe-LDH. The behaviour of the lead adsorption processes by using LCL/MgFe-LDH as adsorbent was investigated in batch experiments by examining different values of solution pH, contact time, adsorbent dose and initial Pb²⁺ concentration. High removal efficiency was exhibited by LCL/MgFe-LDH, a value almost double that of LCL. This was attributed to the increase in surface area of LCL/MgFe-LDH (79.7 m²·g^–1) in contrast to the surface area of LCL (24.5 m²·g^–1). The Freundlich equations and pseudo-second-order kinetics model were appropriate for the provision of adsorption equilibrium data for Pb²⁺ on adsorbents. These results reveal the great potential of the new composite adsorbent (LCL/MgFe-LDH) if applied to the absorption of heavy metal ions.
Źródło:: Journal of Water and Land Development; 2020, 45; 10-18
1429-7426
2083-4535
Pojawia się w:: Journal of Water and Land Development
Dostawca treści:: Biblioteka Nauki

Artykuł

Zmień widok

na półce

Skocz do pozycji: 14.

Tytuł:: Controlled synthesis of iron oxide nanoparticles used as an efficient heavy metal ions adsorbent
Kontrolowana synteza nanocząstek tlenków żelaza stosowanych jako efektywny adsorbent jonów metali ciężkich
Autorzy:: Bobik, M.
Korus, I.
Brachmańska, M.
Powiązania:: https://bibliotekanauki.pl/articles/127234.pdf
Data publikacji:: 2015
Wydawca:: Towarzystwo Chemii i Inżynierii Ekologicznej
Tematy:: adsorption
heavy metals
magnetite
nanoparticles
adsorpcja
metale ciężkie
magnetyt
nanocząstki
Opis:: In this paper a few attempts of iron oxide nanoparticles synthesis via chemical co-precipitation are presented. Iron(II) and (III) salts were used as a precursors and aqueous ammonia as a precipitation medium. In the literature it was proved that there are some factors, like reaction temperature, base amount (pH of the reaction mixture) or the concentration of iron salts, which affects characteristics of formed nanoparticles such as their size distribution. The aim of presented research was to select such reaction parameters which would lead to the production of the most effective sorbent for few heavy metal ions, such as: Cr(VI), Pb(II), Cr(III), Cu(II), Zn(II), Ni(II) and Cd(II). The synthesis of nanoparticles were carried out for three temperatures (30, 60, 90ºC) and three ammonia volumes (8, 10, 15 cm3) for each temperature. Furthermore the influence of iron salts molar ratio Fe(II) : Fe(III) in the reaction mixture on resulting sorbent was examined. Because the syntheses were lead in the oxidizing environment, in order to compensate partial oxidation of Fe(II) to Fe(III), a few molar ratios Fe(II) : Fe(III) beyond the stoichiometric value (which is 1 : 2 for magnetite Fe3O4) were investigated. Additionally for the magnetite synthesized in the selected conditions the effect of pH on the sorption of heavy metal ions were examined. The pH conditions were estimated to not exceed 7 in order to avoid metal precipitation.
W pracy przedstawiono próby syntezy nanocząstek tlenków żelaza poprzez ich chemiczne współstrącanie. Jako medium strącające zastosowano wodę amoniakalną. W literaturze udowodniono wpływ takich czynników, jak temperatura reakcji, ilość zasady czy też stężenie soli żelaza Fe(II) i Fe(III) w mieszaninie reakcyjnej na charakterystykę, między innymi wielkość, powstających nanocząstek. Celem niniejszej pracy było dobranie takich parametrów reakcji, aby w efekcie uzyskać najbardziej efektywny sorbent względem jonów kilku metali ciężkich: Cr(VI), Pb(II), Cr(III), Cu(II), Zn(II), Ni(II) i Cd(II). Przeprowadzono syntezę nanocząstek w kombinacji trzech temperatur: (30, 60, 90ºC) oraz trzech objętości amoniaku: (8, 10, 15 cm3). Ponadto sprawdzono, jaki wpływ na powstający sorbent ma stosunek molowy jonów żelaza Fe(II) : Fe(III) w mieszaninie reakcyjnej. Biorąc pod uwagę fakt, iż synteza przeprowadzana była przy dostępie tlenu, w celu kompensacji częściowego utlenienia jonów żelaza Fe(II) do Fe(III), wyjściowy stechiometryczny stosunek tych jonów, który dla magnetytu (Fe3O4) wynosi 1:2, obniżono do kilku wartości poniżej 1 : 2. Dodatkowo dla magnetytu zsyntezowanego w wybranych, optymalnych, warunkach przeprowadzono próbę wpływu pH na sorpcję jonów metali. W celu uniknięcia możliwości wytrącania się osadów maksymalne pH ustalono na nieprzekraczające wartości 7.
Źródło:: Proceedings of ECOpole; 2015, 9, 2; 413-424
1898-617X
2084-4557
Pojawia się w:: Proceedings of ECOpole
Dostawca treści:: Biblioteka Nauki

Artykuł

Zmień widok

na półce

Skocz do pozycji: 15.

Tytuł:: Prediction of Co(II) and Ni(II) ions removal from wastewater using artificial neural network and multiple regression models
Autorzy:: Allahkarami, E.
Igder, A.
Fazlavi, A.
Rezai, B.
Powiązania:: https://bibliotekanauki.pl/articles/109455.pdf
Data publikacji:: 2017
Wydawca:: Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:: artificial neural network
nonlinear multi-variable regression
heavy metals
adsorption
Opis:: In this research, carboxymethyl chitosan-bounded Fe3O4 nanoparticles were synthesized and used for removal of Co(II) and Ni(II) ion metals from wastewater. The capability of magnetic nanoparticles for metal ions removal was investigated under different conditions namely pH, initial concentration of metal ions and adsorbent mass. The assessment of adsorbent performance for metal ions removal under different conditions requires cost and time spending. In this regard, the capability of artificial neural network (ANN) and nonlinear multi-variable regression (MNLR) models were investigated for predicting metal ions removal. The values of operational parameters such as pH, contact time, initial concentration of metal ions and adsorbent mass were applied for simulation by means of ANN and MNLR. A back propagation feed forward neural network, with one hidden layer (4:8:2), was proposed. Two criteria, including mean square error (MSE) and coefficient of determination (R2) were used to evaluate the performance of models. The results showed that two models satisfactorily predicted the adsorbed amount of metal ions from wastewater. However, the ANN model with higher R2 and lower MSE than the MNLR model had better performance for predicting the adsorbed amount of metal ions from wastewater.
Źródło:: Physicochemical Problems of Mineral Processing; 2017, 53, 2; 1105-1118
1643-1049
2084-4735
Pojawia się w:: Physicochemical Problems of Mineral Processing
Dostawca treści:: Biblioteka Nauki

Artykuł

Zmień widok

na półce

Informacja

Wyszukujesz frazę "heavy metals adsorption" wg kryterium: Temat

Źródło danych

Dostawca treści

Kolekcja

Rok wydania

Wydawca

Temat

Autor

Typ dokumentu

Język