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Wyszukujesz frazę "heavy metal adsorption" wg kryterium: Temat


Tytuł:
Preparation of carbonaceous heavy metal adsorbent from palm shell using sulfur impregnation
Autorzy:
Sugawara, K.
Wajima, T.
Kato, T.
Sugawara, T.
Powiązania:
https://bibliotekanauki.pl/articles/346975.pdf
Data publikacji:
2007
Wydawca:
Politechnika Bydgoska im. Jana i Jędrzeja Śniadeckich. Wydział Technologii i Inżynierii Chemicznej
Tematy:
palm shell
heavy metal adsorption
carbonaceous adsorbent
pyrolysis
sulfur impregnation
Opis:
We attempt to prepare a heavy metal adsorbent from palm shell with a simple-two step process using pyrolysis and sulfur impregnation. Palm shell was pyrolyzed with three different methods; rapid pyrolysis, slow pyrolysis, and KOH pyrolysis, and the prepared char with high specific surface area was sulfurized with H2S impregnation to obtain the sulfur-impregnated char with the adsorption ability of heavy metals. The pyrolysis char with high specific surface area can be obtained by KOH pyrolysis, which was pre-treated with KOH solution before slow pyrolysis, and can added sulfur into KOH pyrolysis char using H2S gas. The sulfur content of sulfur-impregnated char increased with increasing the time of H2S treatment, and increased the adsorption amount of Pb2+ from aqueous solution. The sulfur impregnated char was more effective for Pb2+ and Zn2+ adsorption than commercial charcoal.
Źródło:
Ars Separatoria Acta; 2007, 5; 88-98
1731-6340
Pojawia się w:
Ars Separatoria Acta
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis of hydroxyapatite derived from agricultural waste and its applications as an adsorbent for heavy metal removal from wastewater
Autorzy:
Kalbarczyk, Marta
Szcześ, Aleksandra
Powiązania:
https://bibliotekanauki.pl/articles/2079904.pdf
Data publikacji:
2019
Wydawca:
Uniwersytet Marii Curie-Skłodowskiej. Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
Tematy:
hydroxyapatite, eggshell, adsorption, heavy metal, wastewater
Opis:
 The presence of heavy metals in aquatic systems can be harmful to living species. Heavy metals are not biodegradable, and their tendency to accumulate in living organisms often causes different, undesirable consequences. Therefore, removing these impurities from wastewater has become one of the key issue related to environmental protection [Babel and Kurniawan 2004].There are many methods developed to remove heavy metals from wastewater and adsorption is one of the most popular one. Despite of the diversity of these technologies there is still a need to develop methods that do not require a large financial input [Hegazi 2013, Renu et al. 2017].The most important features that determine materials used as adsorbent is their low cost, biocompatibility and environmental friendly nature and hydroxyapatite presents all of them. Moreover, hydroxyapatite particles are characterized by high specific surface area and simple method of synthesis. It is also reported that it can be obtained from agricultural waste based on calcium like eggshells [Akram et al. 2014].The aim of this paper is to show and compare different methods of hydroxyapatite synthesis using eggshells as a source of calcium and it sorption capacity due to different metal cations from aqueous solution.
Źródło:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia; 2019, 74, 2; 53-68
2083-358X
Pojawia się w:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorpcja metali ciężkich na tlenku glinu i stabilizacja zużytego adsorbentu przy pomocy technologii SULSTAR
Heavy metals adsorption on aluminium oxide and stabilization of spent adsorbent using a SULSTAR technology
Autorzy:
Rajczykowski, K.
Loska, K.
Powiązania:
https://bibliotekanauki.pl/articles/357174.pdf
Data publikacji:
2016
Wydawca:
Politechnika Śląska
Tematy:
heavy metal adsorption
dangerous wastes stabilization
SULSTAR stabilization
adsorpcja metali ciężkich
stabilizacja odpadów niebezpiecznych
stabilizacja SULSTAR
Opis:
The study aimed to analyze the adsorptive properties of aluminium oxide and effectiveness of stabilization process of spent adsorbent using an innovative technology based on the sulfur polymer called "SULSTAR", developed and patented by company Marbet-Wil in Gliwice. The process of adsorption of the heavy metals was carried out at pH 5 in glass batch reactors for a period of 2 hours. The average amount of lead, adsorbed in the process was 3.30 mg of lead per gram of adsorbent. After adsorption spent aluminium oxide was dried and then used to a stabilization process at a mass ratio 1: 2 (adsorbent: stabilizer). As a result of deterioration process of analysed stabilized adsorbents, the process of stabilization reduced the amount of lead ions released into deteriorating solution up to 88.7% comparing to unstabilized adsorbent, at the lowest pH level. The release of lead ions to deteriorating solutions at higher pH values, thanks to a stabilization process was completely inhibited.
Przeprowadzone badania miały na celu analizę właściwości adsorpcyjnych tlenku glinu oraz skuteczności procesów stabilizacji zużytego adsorbentu przy pomocy innowacyjnej technologii siarkowej SULSTAR, opracowanej i opatentowanej przez firmę Marbet-Wil w Gliwicach. Proces adsorpcji metali ciężkich przeprowadzany był przy pH 5, w szklanych reaktorach okresowych przez okres 2 godzin. Średnia ilość zaadsorbowanego w tym procesie ołowiu wynosiła 3,30 mg ołowiu na gram adsorbentu. Po procesie adsorpcji zużyty tlenek glinu suszono a następnie poddawano procesowi stabilizacji w stosunku masowym 1:2 (adsorbent: stabilizator). W wyniku procesu deterioracji zużytych adsorbentów, wykazano, że proces stabilizacji odpadów zredukował ilość uwalnianych do roztworów deteriorujących jonów ołowiu o 88,7% dla roztworu o najniższym pH, a w przypadku roztworów o wyższym pH ponowne uwalnianie ołowiu zostało całkowicie zahamowane.
Źródło:
Archiwum Gospodarki Odpadami i Ochrony Środowiska; 2016, 18, 2; 67-72
1733-4381
Pojawia się w:
Archiwum Gospodarki Odpadami i Ochrony Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Wykorzystanie odpadów z przemysłu ceramicznego, energetycznego i budowlanego w technologii adsorpcji
Utilization of waste from the ceramic, energy and construction industry in adsorption technology
Autorzy:
Siemiątkowski, G.
Nolepa, A.
Kiprian, K.
Powiązania:
https://bibliotekanauki.pl/articles/392260.pdf
Data publikacji:
2017
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Ceramiki i Materiałów Budowlanych
Tematy:
odpad przemysłowy
wykorzystanie odpadów
proszek ceglany
popiół fluidalny
popiół denny
popiół z bocznikowania
właściwości sorpcyjne
adsorpcja metali ciężkich
industrial waste
waste utilization
brick powder
fluidized fly ash
bottom ash
bypass dust
sorption properties
heavy metal adsorption
Opis:
Artykuł jest opisem doświadczenia mającego na celu weryfikację możliwości wykorzystania pyłów ceglanych, popiołów lotnych i odpadów dennych ze spalania węgla brunatnego czy pyłów z bypassa, pochodzących z linii wypalania klinkieru w technologii adsorpcji metali ciężkich w środowisku wodnym. Wszystkie te materiały nie znajdywały dotychczas użytecznego wykorzystania, stanowiąc istotny balast odpadowy. Osiągnięte wyniki badań należy uznać za bardzo obiecujące. Analizowane odpady w opisanych w artykule warunkach doświadczenia wykazywały bardzo dobre właściwości sorpcyjne – w większości przypadków sięgające co najmniej 82% skuteczności. Na uwagę zasługuje również trwałość wiązań sorpcyjnych. Uzyskana w doświadczeniu desorpcja metali ciężkich w większości przypadków była znikoma. Pozytywne wyniki badań dają nadzieję na rychłe znalezienie użytecznego wykorzystania dla analizowanych odpadów.
The article is a description of the experience aimed at verifying the possibility of using brick dust, fly ash and bottom waste from lignite combustion or bypass dust, which came from the clinker firing line in the technology of adsorption of heavy metals in the water environment. All these materials have not yet found useful use, constituting a significant waste ballast. The research results achieved should be considered very promising. The analyzed waste in the experimental conditions described in the article showed very good sorption properties – in most cases reaching at least 82% of effectiveness. Noteworthy is the durability of sorption bonds. The desorption of heavy metals obtained in the experiment was, in most cases, insignificant. Positive research results give hope for prompt finding of useful use for the analyzed waste.
Źródło:
Prace Instytutu Ceramiki i Materiałów Budowlanych; 2017, R. 10, nr 31, 31; 51-69
1899-3230
Pojawia się w:
Prace Instytutu Ceramiki i Materiałów Budowlanych
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Cyclical metal adsorption and desorption through sludge immobilized in chitosan media
Autorzy:
Kuczajowska-Zadrożna, Małgorzata
Filipkowska, Urszula
Jóźwiak, Tomasz
Szymczyk, Paula
Powiązania:
https://bibliotekanauki.pl/articles/1034744.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
Tematy:
adsorption
chitosan
desorption
heavy metal
immobilization
Opis:
In this research, a cyclical adsorption/desorption of cadmium and zinc from solutions containing a single metal or its mixture in ratio of 1:1 and 1:2 using immobilized activated sludge in the chitosan (ASC) was examined. In the adsorption studies, the optimal dose of ASC was 4 g/L. The highest desorption efficiency was achieved for 1M HNO3. Both adsorption and desorption occurred in accordance with a pseudo-second order reactions which is confirmed by R2 values. Mass of zinc adsorbed and desorbed in one cycle from a solution containing a single metal was 0.78 and 0.40 mmol/g d.w. when cadmium was lower (respectively 0.41 and 0.21 mmol/g d.w.). In subsequent cycles, both metals were adsorbed and desorbed at a lower efficiency. The highest efficiency of desorption was observed for a mixture of Cd:Zn in the ratio of 1:1 and 1:2, respectively 86% and 89% of cycle1, whereas for the zinc it was 70% and 53%. Desorption efficiency of both metals and its mixtures, in subsequent cycles gradually decreased.
Źródło:
Progress on Chemistry and Application of Chitin and its Derivatives; 2016, 21; 135-146
1896-5644
Pojawia się w:
Progress on Chemistry and Application of Chitin and its Derivatives
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Biosorption/desorption of cadmium(ii) and zinc (ii) from aqueous solutions by activated sludge immobilized onto chitosan beads
Autorzy:
Kuczajowska-Zadrożna, Małgorzata
Filipkowska, Urszula
Jóźwiak, Tomasz
Szymczyk, Paula
Powiązania:
https://bibliotekanauki.pl/articles/1035015.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Polskie Towarzystwo Chitynowe
Tematy:
adsorption
chitosan beads
desorption
heavy metal
Opis:
In this study, we evaluated the effectiveness of cadmium and zinc adsorption and desorption from solutions containing single metals and a mixture of metals in the ratio of 1:2 by activated sludge immobilized onto chitosan (ASC). The optimal pH value determined for metals adsorption ranged from pH 5 to pH 6, whereas that established for desorption reached pH 2. In the case of individual metals, the state of adsorption equilibrium in the solution was achieved after 180 min, whereas in the case of a metal mixture – after 270 min. In the case of desorption, the state of equilibrium was achieved after 45 min. It was stated that both adsorption and desorption proceeded according to the pseudo-second order reaction. The study enabled determining the maximum adsorption capacity based on Langmuir, Freundlich and Sips models. The Sips model was found suitable for the description of adsorption of single metals onto ASC, whereas both Sips and Freundlich models – for description of the adsorption of a metal mixture, which was indicated by the determined values of R2 coefficient. The adsorption capacity of ASC determined from Sips model for individual solutions of cadmium and zinc reached 216 and 188.3 mg/g d.m., respectively, whereas that determined for their mixture reached 106 mg/g d.m. for both metals.
Źródło:
Progress on Chemistry and Application of Chitin and its Derivatives; 2015, 20; 142-155
1896-5644
Pojawia się w:
Progress on Chemistry and Application of Chitin and its Derivatives
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Treatment of Laboratory Wastewater by Using Fenton Reagent and Combination of Coagulation-Adsorption as Pretreatment
Autorzy:
Arita, Susila
Agustina, Tuty Emilia
Ilmi, Nurul
Pranajaya, Violanda Dwi Wulandari
Gayatri, Rianyza
Powiązania:
https://bibliotekanauki.pl/articles/2173343.pdf
Data publikacji:
2022
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
laboratory wastewater
fenton reagent
coagulation
adsorption
heavy metal
Opis:
Laboratory wastewater contains organic and inorganic compounds that are harmful to the environment when disposed of without prior treatment. Besides the high COD and BOD values, the laboratory wastewater also contains metals such as iron (Fe), zinc (Zn), copper (Cu), chromium (Cr), and lead (Pb) which is categorized as dangerous waste material and can pollute the groundwater. Although the quantity of wastewater produced by the laboratory is relatively small, it has a real impact on the environment around the laboratory. However, the wastewater has to be treated properly before being discharged into the environment. The aim of the research was to study the laboratory wastewater treatment by using Fenton’s reagent with coagulation and adsorption pretreatment. In the pretreatment with coagulation, three types of coagulants are used, namely PAC (Poly Aluminum Chloride), ACH (Aluminum Chlorohydrate) and Aluminum Sulfate (AS) with their respective concentrations of 10–80 ppm. The highest percentage of average pollutant removal of 58.21% was found when 80 ppm of AS was applied. The pretreatment was continued by adsorption with activated carbon and zeolite adsorbents within 60–120 minutes of mixing time. It was detected that the most optimum adsorbent was activated carbon with average pollutant removal of 50.22% within 1 hour of mixing time. Processing was extended by utilized Fenton’s reagent using a variation of the molar ratio between 1:100 and 1:400. It was obtained that the best molar ratio to degrade the laboratory wastewater is 1:300 with an average removal of pollutant of 43.45%. As a result of laboratory wastewater treatment using combine Fenton’s reagent and coagulation-adsorption pretreatment, an average pollutant removal of 90.81% was obtained. The final content of COD, BOD, TSS, as well as Cu and Pb metal has met the environmental quality standard.
Źródło:
Journal of Ecological Engineering; 2022, 23, 8; 211--221
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Removal Performance of Bio-Sorption on Sunflower Seed Husk for Copper and Lead Ions from Aqueous Solutions
Autorzy:
Abdulhusain, Noor Alaa
Mokif, Layla Abdulkareem
Powiązania:
https://bibliotekanauki.pl/articles/24201773.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
heavy metal
industrial wastewater
adsorption capacity
sunflower seed husk
Opis:
This study was concerned with the feasibility of using sunflower seed husk (waste material from the food industry) as a low-cost and available sorbent material to remove copper and lead ions. Sunflower seed husk was used for the biosorption of heavy metal ions (Pb(II) and Cu(II)) from aqueous solutions. The properties of natural adsorbent were characterized using Fourier transform infrared spectroscopy (FTIR). Pb(II) and Cu(II) adsorption were investigated in batch experiments through several influencing operating parameters, including contact time, sorbent dosage, initial pH, and initial concentration. The Pseudo-first-order and pseudo-second-order models were also applied to the experimental data to determine the adsorption kinetics. The results showed that adsorption of both ions fitted well by pseudo-Second-order, with determination coefficient R2 = 0.99, for both ions with SSE (1.628, 1.345) for Pb(II) and Cu(II), respectively.
Źródło:
Journal of Ecological Engineering; 2023, 24, 5; 110--117
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparative assessment of Al2O3 modified biomasses from agricultural residues for nickel and cadmium removal
Autorzy:
Herrera-Barros, Adriana
Tejada-Tovar, Candelaria
Gonzalez-Delgado, Angel D.
Powiązania:
https://bibliotekanauki.pl/articles/1844335.pdf
Data publikacji:
2021
Wydawca:
Instytut Technologiczno-Przyrodniczy
Tematy:
adsorption
agricultural residues
alumina nanoparticles
cellulose
heavy metal ions
Opis:
The biodiversity of aqueous environments has been affected due to the disposal of wastewater highly contaminated with heavy metal ions, causing much damage to ecosystems. These pollutants are very toxic and bioaccumulate in living organisms. This work attempts to evaluate the adsorption of nickel ad cadmium ions using three biomasses from agricultural residues (corn cob – CC, orange peel – OP, and oil palm bagasse – PB) modified with alumina nanoparticles. The biomasses were characterized via compositional analysis and a point of zero charges to quantify the presence of lignin, cellulose, hemicellulose, and the feasible pH, taking advantage of the biomass charge. After modification with Al2O3 nanoparticles. The resulting adsorbents were characterized via FT-IR analysis to identify the functional groups that most contributed to the adsorption performance. Furthermore, the influence of Al2O3 nanoparticles was analysed on the adsorption capacities of the evaluated biomasses using batch systems at a temperature of 25°C and pH 6. All biomasses displayed a high content of cellulose, estimating a weight percentage of about 19.9%, 14.3%, and 13.1% for PB, OP, and CC samples, respectively. The FT-IR spectrum confirmed hydroxyl and carboxyl functional groups, which contribute to enhancing the adsorption capacities of the modified biomasses. Functional adsorption capacity was observed for all biomasses after modification with Al2O3 nanoparticles, achieving at pH 6.0 a cadmium removal from 92% (CC-Al2O3 and PB-Al2O3) up to 95.8±0.3% (OP-Al2O3). In nickel ions, it was estimated a broader adsorption capacity at pH 6.0 of about 86±0.4% after using the CC-Al2O3 sample, 88±0.1% for the PB-Al2O3 adsorbent, and 98±0.2% for the OP-Al2O3 sample, confirming the suitability of these Al2O3-modified biomasses for the removal of heavy metal ions.
Źródło:
Journal of Water and Land Development; 2021, 49; 29-34
1429-7426
2083-4535
Pojawia się w:
Journal of Water and Land Development
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A Review on Adsorption of Heavy Metals from Wood-Industrial Wastewater by Oil Palm Waste
Autorzy:
Ayob, Syafiqa
Othman, Norzila
Altowayti, Wahid Ali Hamood
Khalid, Faisal Sheikh
Bakar, Norshila Abu
Tahir, Muhammad
Soedjono, Eddy Setiadi
Powiązania:
https://bibliotekanauki.pl/articles/1839174.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
industrial wastewater
heavy metal
adsorption
activated carbon
oil palm waste
Opis:
The use of heavy metals in the manufacturing industry over the past few decades has eventually contributed to a rise in the flow of metallic compounds into wastewater and has raised significant ecological and health threats to living things. Adsorption is an excellent way to treat solid waste effluent, offering significant benefits such as affordability, profitability, ease of operation and efficiency. However, the price of commercial adsorbent namely activated carbon has soared due to its high demand. There is also a green improvement in this method by turning the commercial adsorbent into agricultural waste. In Malaysia, the oil palm waste is such suitable material that can be utilized for making activated carbon, since they are ample and easy to find. Additionally, part of them is agricultural waste that cannot be consumed (i.e. leaves and fronds). Hence, this study aimed to analyse the potential of activated carbon from agricultural waste, namely oil palm waste, in reducing the levels of heavy metals in industrial wastewater.
Źródło:
Journal of Ecological Engineering; 2021, 22, 3; 249-265
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Complex Technology of Sewage Purification from Heavy-Metal Ions by Natural Adsorbents and Utilization of Sewage Sludge
Autorzy:
Zasidko, Iryna
Polutrenko, Myroslava
Mandryk, Oleg
Stakhmych, Yuliia
Petroshchuk, Nataliia
Powiązania:
https://bibliotekanauki.pl/articles/124975.pdf
Data publikacji:
2019
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
heavy metal ions
adsorption
thermal pyrolysis
modifying additive
ceramic mixture
Opis:
The aspects of complex technology of sewage purification and utilization of purification sludge were investigated in the article. The authors substantiated the possibility of purifying sewage from heavy-metal ions by means of zeolite and utilizing sewage sludge in bricks production. The adsorption capacity of the zeolite from Sokyrnytsia deposit was studied for cupric and manganese ions in relation to its fractional composition. The comparative effectiveness studies of heavy metals adsorption by natural zeolite and anthracite were carried out. The optimal sorption parameters of these ions were selected based on the investigation results of their adsorption dynamics in the Cu2+ and Mn2+ solutions. The prospects of sewage sludge utilization by means of its thermal pyrolysis at the temperatures of 600-700°С were studied. The modifying additive was obtained, which can be added to the ceramic mixture and increase the porosity, reduce the density and decrease the thermal conductivity of course solid bricks.
Źródło:
Journal of Ecological Engineering; 2019, 20, 5; 209-216
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Removal of copper, zinc and iron from water solutions by spruce sawdust adsorption
Autorzy:
Kovacova, Zdenka
Demcak, Stefan
Balintova, Magdalena
Powiązania:
https://bibliotekanauki.pl/articles/95649.pdf
Data publikacji:
2019
Wydawca:
Fundacja Ekonomistów Środowiska i Zasobów Naturalnych
Tematy:
adsorption
model solution
spruce sawdust
heavy metal
adsorpcja
rozwiązanie modelowe
trociny świerkowe
metal ciężki
Opis:
The water pollution by toxic elements is one of the major problems threatening human health as well as the quality of the environment. Sorption is considered a cost-effective method that is able to effectively remove heavy metals. During past few years, researches have been researching usage of low-cost adsorbents like bark, lignin, chitosan peat moss and sawdust. This paper deals with the study of copper, zinc and iron adsorption by adsorption of spruce sawdust obtained as a by-product from locally used wood. Raw spruce sawdust was used to remove heavy metal ions from the model solutions with ion concentration of 10 mg/L during 24 hours or 5, 10, 15, 30, 45, 60, 120 min, respectively. Fourier-transform infrared spectroscopy was applied to determine functional groups of sawdust. Sorption efficiency was higher than 67% in short-time experiments and higher than 75% for one day experiments in all tested cations.
Źródło:
Ekonomia i Środowisko; 2019, 3; 64-74
0867-8898
Pojawia się w:
Ekonomia i Środowisko
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Equilibrium and kinetic studies on the removal of heavy metal ions with natural low-cost adsorbents
Autorzy:
Varank, G.
Demir, A.
Bilgili, M. S.
Top, S.
Sekman, E.
Yazici, S.
Erkan, H. S.
Powiązania:
https://bibliotekanauki.pl/articles/207257.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
adsorbents
adsorption
bentonite
dyes
heavy metals
kinetics
metal ions
water treatment
heavy metal removal
heavy metal ions
heavy metals ions removal
adsorbenty
adsorpcja
bentonit
barwniki
metale ciężkie
kinetyka
jony metali
usuwanie jonów metali ciężkich
uzdatnianie wody
Opis:
Adsorption isotherms and kinetics of the removal of heavy metal ions (Ni, Pb, Zn) from aqueous solutions by natural adsorbents (zeolite, bentonite, clay) were investigated in a lab-scale batch study. The effect of various parameters such as adsorbent dosage, initial concentration of heavy metal ions, temperature, and agitation time were studied to optimise the conditions. Under those optimized conditions (180 rpm agitation rate, 120 min agitation time, pH 4.0, 298 K, 100 mg/dm3 initial adsorbate concentration), the removal percentages of heavy metal ions for natural adsorbents have been determined. The adsorption mechanisms and characteristic parameters of the process were analyzed by two and three parameter isotherm models (Langmuir, Freundlich, Temkin, Redlich-Peterson, Toth and Sips), and kinetic models (Lagergren's pseudo-first order, Ho and McKay's pseudo-second order). Adsorption thermodynamics of heavy metal ions (changes of standard enthalpy, entropy and free energy) on zeolite, bentonite and clay were also studied at 298,318 and 338 K.
Źródło:
Environment Protection Engineering; 2014, 40, 3; 43-61
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of modified maize hull for removal of Cu(II) ions from aqueous solutions
Autorzy:
Ghasemi, S. M.
Mohseni-Bandpei, A.
Ghaderpoori, M.
Fakhri, Y.
Keramati, H.
Taghavi, M.
Moradi, B.
Karimyan, K.
Powiązania:
https://bibliotekanauki.pl/articles/208248.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
heavy metal ions
waste water
Cu(II)
ions
adsorption
biomass
jony metali ciężkich
ścieki
biomasa
adsorpcja
Opis:
Discharge of industrial waste containing heavy metals to the environment is a main concern because of their toxicity to many life forms. Adsorption process is one of the conventional methods in order to adsorb heavy metals from wastewater effluents. Therefore, the removal of Cu(II) from aquatic solutions using modified maize hull was investigated. All experiments were performed in batch conditions. The residual Cu(II) concentration was measured by AAS. Upon increasing the adsorbent dosage, pH, and contact time and decreasing Cu(II) concentration, the removal efficiency of Cu(II) ions increased. In optimum conditions, 50% of copper was removed by modified maize hull. The experimental data were best fitted by the Langmuir type 2 model and the adsorption kinetic model followed a pseudo-second order type 1 model. It seems that the use of the modified maize hull to remove Cu(II) ions is very suitable, low-cost, and efficient.
Źródło:
Environment Protection Engineering; 2017, 43, 4; 93-103
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparison of adsorption of Cd(II) and Pb(II) ions on pure and chemically modified fly ashes
Autorzy:
Soco, E.
Kalembkiewicz, J.
Powiązania:
https://bibliotekanauki.pl/articles/185273.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
heavy metal
coal fly ash
adsorption
kinetics
thermodynamics
popioły lotne z węgla kamiennego
adsorpcja
kinetyka
termodynamika
Opis:
The study investigates chemical modifications of coal fly ash (FA) treated with HCl or NH4 HCO3 or NaOH or Na2 edta, based on the research conducted to examine the behaviour of Cd(II) and Pb(II) ions adsorbed from water solution on treated fly ash. In laboratory tests, the equilibrium and kinetics were examined applying various temperatures (293 - 333 K) and pH (2 - 11) values. The maximum Cd(II) and Pb(II) ions adsorption capacity obtained at 293 K, pH 9 and mixing time 2 h from the Langmuir model can be grouped in the following order: FA-NaOH > FA-NH 4 HCO 3 > FA > NaOH2edta > FA-HCl. The morphology of fly ash grains was examined via small-angle X-ray scattering (SAXS) and images of scanning electron microscope (SEM). The adsorption kinetics data were well fitted by a pseudo-second-order rate model but showed a very poor fit for the pseudo- first order model. The intra-particle model also revealed that there are two separate stages in the sorption process, i.e. the external diffusion and the inter-particle diffusion. Thermodynamics parameters such as free energy, enthalpy and entropy were also determined. A laboratory test demonstrated that the modified coal fly ash worked well for the Cd(II) and Pb(II) ion uptake from polluted waters.
Źródło:
Chemical and Process Engineering; 2016, 37, 2; 215-234
0208-6425
2300-1925
Pojawia się w:
Chemical and Process Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł

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