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Tytuł:
Application of geochemical modeling for analysis of changes in groundwater chemistry in karst area (case study from gypsum karst in the Czarny Potok valley, SW Ukraine)
Autorzy:
Solovey, T.
Jóźwiak, K.
Powiązania:
https://bibliotekanauki.pl/articles/87453.pdf
Data publikacji:
2008
Wydawca:
Polskie Towarzystwo Geograficzne
Tematy:
karst processes
geochemical model
Ukraine
Opis:
One of the most up to date scientific problems in recognition of karst processes is quantitave evaluation their activity. Basic and distinctive indicators that describe karst processes activity are intensity and magnitude of chemical denudation (Aksiom S.D., 2002). Not only a tool for describing changes taking place in the observed hydrogeological system will be presented in the paper but tools that allow to predict changes that may take place on the spur of the natural and anthropogenic factors. Only a few methods widely used in hydrogeology are also used in geography. In this paper authors present basis of geochemical modeling that can be widely used. Geochemical modeling can be divided into two main issues: Measurement, assessment and generalization of kinetic and thermodynamic data for solid phases (e.g. minerals), gases and solutions; Use of above data in numerical algorithms describing natural and anthropogenicly changed systems of interaction between water and matrix (Macioszczyk, Dobrzyński, 2006). The practical aspects of geochemical modeling concentrate mainly on creating geochemical models of the environment and its changes. Geochemical modeling has been recently widely used for describing chemical composition of groundwater as well as factors and processes shaping it. A geochemical model is a tool that allow for understanding hydrogeochemical processes taking place in the environment. It is a basis for further analysis of system`s susceptibility for modifications conducted by human as well as it might be an element of the forecast of the risk of environment contamination. The main advantage of geochemical modeling is simplicity of received data interpretation, possibility of groundwater chemistry origin interpretation, predicting chemistry modifications and also forecasting changes in water quality. Geochemical models can be divided into three main groups: Speciation model – it doesn`t include any information about temporal or spatial distribution of processes, it only describe the effect of water – rock – gases interaction in a single point of hydrogeological space; Reaction path model – it delivers information about succeeding changes of the hydrogeological system (spatial variability) that take place as an effect of providing a load of mass and/or energy. The time effect can be modeled with use of reaction rate constant; Reactive transport model – it include data describing temporal and spatial variability of chemical reactions in the system.
Źródło:
Prace Komisji Krajobrazu Kulturowego; 2008, 8; 231-243
1896-1460
2391-5293
Pojawia się w:
Prace Komisji Krajobrazu Kulturowego
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Lead and iron contents in parsley being cultivated in the area of Chrzanów geochemical anomaly
Autorzy:
Mundała, P.
Szwalec, A.
Kędzior, R.
Telk, M.
Machaj, M.
Powiązania:
https://bibliotekanauki.pl/articles/184541.pdf
Data publikacji:
2014
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
parsley
geochemical anomaly
food quality
Opis:
Selected research polygon is located in Trzebinia commune in the mid of the 80 km way from Kraków to Katowice (the Upper Silesia capital). The towns of Trzebinia, Chrzanów within the towns of Krzeszowice, Jaworzno, Mysłowice, have been creating a base of well-connected Kraków-Upper Silesia agglomeration. The inhabitants of Trzebinia commune are flexible on labour market, often commute to work in Kraków or Katowice. They have detached houses with gardens of one or two acres size, where "home-made", fresh, low-processed food could be produced. At the same time the area of Trzebinia Community belongs to Chrzanów geochemical anomaly, which is reflected in high values of cadmium, lead and zinc contents in the soils. This is the result of both natural and anthropogenic factors. The purpose of the paper was to evaluate lead and iron contents in roots and leaves of parsley being cultivated within the area of the anomaly. Considering, there is a positive geochemical anomaly, the lead contents in soil were low - the average value was 88.67 mg kg -1 d.m. and only two contents -218.98 and 119.35 exceeded 100 mg kg -1 d.m. On the other hand the lead contents in parsley roots were high, many times higher than the allowable values. The lead contents in parsley leaves were also high. Phytoaccumulation indices low, only one had the average value, but at their minimal range (1.02 and 10.3 adequately for leaves and roots). Translocation index of lead was close to one. The iron contents in soils were not high and fall within the scope of low and average ranges that occur in Polish soils. The iron contents in leaves were high, attractive from nutrition point of view.
Źródło:
Geology, Geophysics and Environment; 2014, 40, 4; 377-386
2299-8004
2353-0790
Pojawia się w:
Geology, Geophysics and Environment
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Geochemical characteristics of Neogene methane-bearing lignite of the Bełchatów region
Autorzy:
Maruta, M.
Zakrzewski, A.
Powiązania:
https://bibliotekanauki.pl/articles/299185.pdf
Data publikacji:
2017
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
tertiary lignite
geochemical analysis
palaeoenvironment
methane
Opis:
Coal beds could contain various amount of methane. This attribute might be dangerous in shafts or quarrying. Among other things, the works in the coal beds, including drilling, potentially there is a risk of exceeding the methane lower explosive limit. But on the other hand it is a source of unconventional hydrocarbon accumulations. In this paper geochemical characteristic of organic matter of tertiary brown coal from central part of Poland were performed. Geochemical surveys helps to know about genesis of methane from study area. The analysed samples contain various quantity of organic carbon, from 20,74 to 71.93 wt. %. Lignite from examine samples have weak hydrocarbon potential. In tertiary sediments prevails III type of kerogen with admixture of II type of kerogen. The thermal maturity of the tertiary organic matter changes within the interval from 354 to 419 in Tmax scale. Organic matter is immature. The composition of bitumens is different in various part of study area. Elemental analysis confirm that brown coal was comprised mostly by humic-group macerals. Coal samples contain methane with mixed genesis.
Źródło:
AGH Drilling, Oil, Gas; 2017, 34, 1; 81-93
2299-4157
2300-7052
Pojawia się w:
AGH Drilling, Oil, Gas
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Palaeoenvironmental and palaeoclimatic records in the Niedzica Succession sediments (Pieniny Klippen Belt) in the light of geochemical and chemostratigraphical analysis
Autorzy:
Kasperek, Kamila
Powiązania:
https://bibliotekanauki.pl/articles/24202125.pdf
Data publikacji:
2023
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
Pieniny Klippen Belt
geochemical analysis
chemostratigraphical analysis
Opis:
The Middle–Upper Jurassic sediments of the Niedzica-Podmajerz section was the subject of integrated study, including sedimentological, geochemical and stratigraphic analysis. The studied section is located in the Pieniny Klippen Belt area and belongs to the Niedzica unit. The section is characterized by continuous exposure of Jurassic carbonate-silica deposits extending from the Bajocian to Kimmeridgian, showing a transition from crinoidal limestones representing typical neritic facies to pelagic facies, i.e. radiolarites and red nodular limestones. The following lithofacies were distinguished in the studied section: grey crinoidal limestones (Smolegowa Limestone Formation), red crinoidal limestones (Krupianka Limestone Formation), red nodular limestones (Niedzica Limestone Formation), radiolarites (Czajakowa Radiolarites Formation) and red nodular limestones (Czorsztyn Limestone Formation). Based on a multidisciplinary dataset, the palaeoenvironmental interpretation was proposed. The results of magnetic susceptibility (MS), gamma-ray spectrometric measurements, CaCO3 content, δ13C analysis and concentrations of major and trace elements data indicate a rapid change in sedimentary conditions at the Callovian–Oxfordian boundary. Variations of δ13C from the Niedzica-Podmajerz indicate global changes in biological productivity, ocean circulation and burial of organic matter in the Tethys area, analogies of which can be found, for example, in Fatricum Domain in the Tatra Mountains. Records of MS, elements K, Th, Al, as well as Ti/Al and Zr/Al proxies indicate probably a period of increased (Lower Bathonian–Upper Callovian) and decreased (Oxfordian) detrital supply to the sedimentary basin. This process was most likely climatically controlled. The CaCO3 results indicate the variability of carbonate production. The lowest values of calcium carbonate (<20%) in Niedzica-Podmajerz section was recorded in the middle part of the radiolarites of the Czajakowa Radiolarite Formation, corresponding to the phase of the carbonate crisis. From this interval, the amount of carbonates in the rocks gradually increases, indicating a return to carbonate sedimentation. These fluctuations probably reflect changes in the position of the ACD and CCD.
Źródło:
Geotourism / Geoturystyka; 2023, 1-2 (72-73); 34--34
1731-0830
Pojawia się w:
Geotourism / Geoturystyka
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The analysis of the soil gases on the chosen example of oil mine
Autorzy:
Fąfara, Z.
Ilkiv, I.
Przybyłowicz, J.
Powiązania:
https://bibliotekanauki.pl/articles/299060.pdf
Data publikacji:
2015
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
geochemical testing
soil gases
oil mine
geostatistical methods
Opis:
In the autumn of 2014 were performed the geochemical research of the soil gases composition in the area of selected oil mine in southern Poland. For a total were carried out of 75 individual analysis at 55 measuring points. The average depth of the measuring point was about 84.4 cm. The grid selection of the measurement points was made ad hoc, taking into account arrangement the existing mine installation and the location of the abandon wells. Finally, geochemical studies were performed in the vicinity of 6 exploitation wells (1 liquidated, one flowing well and 4 pumped periodically), on the route of transmission pipelines and in the area of group centers. The free choice of the measurement point location was limited by buildings and agricultural crops. In the area of the analyzed deposit were drilled more than 100 wells, most of which were liquidated and usually did not stay after them no trace on the surface. Based on the results of the geochemical research of the soil gases composition there was determined the spatial distribution of the methane concentration in the soil in the nodes of a regular grid by geostatistical methods using kriging. On this bases there were developed the maps of the methane concentration. Generally, on the oil deposit site there were detected two areas with the increased methane concentration in the ground. The distribution of the methane concentration in soil on the first one shows the installation leak in the vicinity of several wells. In the second much smaller area it may suspect that the pipeline transporting crude oil to the group centre is leaky. In the research area are vast cultivated fields of high oxygenation and small wet ground. There are no permanently wetlands areas. This means that in soil occur at most aerobic rot and decay processes, resulting in the production of carbon dioxide but not methane. There is no reason to assume that occur also the natural anaerobic putrefaction processes. Therefore, the detected abnormally high methane concentration in the ground is not of biological origin. To confirm formulated hypothesis should also be do the chromatographic research of C14 carbon isotope content in the taken methane samples from the soil to determine his age and confront it with the age of methane produced from the deposit. In general, the results analysis of the geochemical research of the soil gases composition leads to the conclusion that the rock mass is hermetic from the geological point of view, but there are occasional leaks in the production system of several wells and transmission pipeline, that can remove.
Źródło:
AGH Drilling, Oil, Gas; 2015, 32, 2; 443-455
2299-4157
2300-7052
Pojawia się w:
AGH Drilling, Oil, Gas
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The modified Dräger probe to the geochemical research of the soil gases composition
Autorzy:
Fąfara, Z.
Ilkiv, I.
Sołecki, T.
Powiązania:
https://bibliotekanauki.pl/articles/299193.pdf
Data publikacji:
2015
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
geochemical testing of soil gases composition
oil deposit
Opis:
The Dräger probe in the measurement set to the geochemical research of the soil gases composition is inconvenient to use. It's heavy, which are reąuired to operate at least two people. Cumbersome and time-consuming is to place it into the soil by impact method, and often there is fail to reach the planned measurement depth. For this reason, there was designed and made the new modified Dräger probe. The new probe has significantly lower mass and outer diameter. In principle it should be possible to introduce it into the soil by pushing, which will greatly facilitate and accelerate conducting the geochemical research of the soil gases composition.In the autumn of 2014 has been tested the modified Drager probe. The purpose of this study is to assess it suitability to conduct the geochemical research of the soil gases composition. In total there were performed 374 measurements of the soil gases composition at different depths in the 247 measurement points. In 99 cases (26.5%) there was failed to perform the measurement because the soil gases flow rate through the meter was too little. Pulling probe usually allowed to perform the research - in only 6 measurement points (2.4%), it was impossible. The average depth of the measurement point is equal to 0.78 m.
Źródło:
AGH Drilling, Oil, Gas; 2015, 32, 1; 89-102
2299-4157
2300-7052
Pojawia się w:
AGH Drilling, Oil, Gas
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Estimation of inorganic carbon sources in groundwater recharge by inverse geochemical modelling (Carboniferous aquifer, the Intra-Sudetic Basin, SW Poland)
Autorzy:
Dobrzynski, D.
Powiązania:
https://bibliotekanauki.pl/articles/2060223.pdf
Data publikacji:
2008
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Polska
Sudetes
inverse geochemical modelling
radiocarbon activity
groundwater chemistry
Opis:
Geochemical modelling was applied in quantification of chemical reactions responsible for the chemistry of groundwater in the recharge zone of a Carboniferous aquifer (the Sudety Mts., SW Poland). Calculation of the contribution of dissolved in organic carbon (DIC) sources allowed estimation of the initial radiocarbon activity in the recharge to groundwater. The 14C activity calculated upon the results of geochemical modelling is consistent with the 14C activity measured in groundwater. Geochemical modelling can be applied for estimation of the initial 14C activity in recharge water as well as the 14C activity in groundwater along the flow path. Methods of geochemical modelling have an advantage over empirical methods because they combine the effects of various chemical reactions occurring in the geochemical system.
Źródło:
Geological Quarterly; 2008, 52, 2; 191-191
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Modelowanie geochemiczne narzędziem poznania geochemii systemów wód podziemnych. Przykłady zastosowań, aktualny stan w Polsce
Geochemical modelling-a tool for understanding geochemistry of groundwater systems. Case studies, and present-day state in Poland
Autorzy:
Dobrzyński, D.
Powiązania:
https://bibliotekanauki.pl/articles/2074438.pdf
Data publikacji:
2006
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
geochemia
modelowanie
woda podziemna
geochemical modelling
water chemistry
groundwater
Opis:
Potential of geochemical modelling for groundwater systems, with the most important up-to-date literature was concisely described. Case studies considering different methods of geochemical modelling used for understanding of groundwater systems geochemistry are presented. Most of case studies concern modelling of groundwater in short turn-over time zone in the Sudetes Mts. (SW Poland). Present-day geochemical modelling state-of-art in Poland was discussed and evaluated.
Źródło:
Przegląd Geologiczny; 2006, 54, 11; 976-981
0033-2151
Pojawia się w:
Przegląd Geologiczny
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ecological analysis of heavy metal and radioactivity potential of Holocene sediments in Iznik Lake
Autorzy:
Yumun, Zeki U.
Kam, Erol
Powiązania:
https://bibliotekanauki.pl/articles/146352.pdf
Data publikacji:
2019
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
Iznik Lake
heavy metals
radionuclides
geochemical analyses
radionuclide determination
Opis:
In this study, the heavy metal and radioactive properties of Iznik Lake were investigated. Concentration values of the first (Ag, Bi, Mo, Sn, Se, Zn, As, B, Cd, Co, Cr, Cu, Ni, Pb, Pt and Sb) and second (Na, Mg, K, Ca, P, S, Fe, Al and Mn) group of elements in borehole 1 (BH-1) drilling did not show much variation from the top to the bottom of the drilling. Concentration values of the fi rst group of elements in borehole 2 (BH-2) drill samples decreased at higher levels of drilling. In addition, natural and anthropogenic radionuclides were measured by gamma spectrometry, and the results of environmental natural radioactivity of Iznik Lake and its surroundings were determined. In the measurement results, Ra-226 was found to be below the world average value at all locations. It is assumed that the determination of K-40 values above the average values was due to agricultural activities carried out intensively in the study area. Th-232 values were found to be below the world average value in drilling samples; Cs-137 values were below the background level in all samples. According to these results, the study area does not contain any unnatural radioactivity.
Źródło:
Nukleonika; 2019, 64, 3; 103-109
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Formy występowania wybranych metali w żużlach hutniczych na tle ich właściwości geochemicznych
Forms of occurrence of selected metals in metallurgical slags in comparison with their geochemical properties
Autorzy:
Jonczy, I.
Powiązania:
https://bibliotekanauki.pl/articles/216013.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Instytut Gospodarki Surowcami Mineralnymi i Energią PAN
Tematy:
żużel hutniczy
metal
właściwości geochemiczne
metallurgical slag
geochemical properties
Opis:
Badania składu chemicznego żużli hutniczych pochodzących zarówno z bieżącej produkcji, jak i składowanych przez wiele lat na zwałowiskach wykazały, że są one bardzo zróżnicowane. Żużle zawierają znaczne ilości metali, w tym metali ciężkich, obok pierwiastków z grupy niemetali i lantanowców. W artykule na podstawie badań mineralogiczno-chemicznych żużli stalowniczych oraz żużli po produkcji stali i rud Zn-Pb, scharakteryzowano formy występowania i powiązania ze składnikami fazowymi wybranych metali: żelaza, manganu, cynku, ołowiu i in. Stwierdzono, że metale w żużlach hutniczych mogą występować w postaci drobnych kropli nie oddzielonych od żużla w procesie hutniczym, tworzyć skupienia polimetaliczne, własne fazy (zwłaszcza tlenkowe) oraz ukrywać się w strukturach faz krzemianowych. Znaczna ilość metali jest rozproszona w szkliwie i substancji amorficznej. Prowadzone badania dostarczają informacji na temat występowania metali w żużlach hutniczych, co jest szczególnie istotne podczas wykonywania prac związanych z gospodarczym wykorzystaniem żużli. Dotyczy to zwłaszcza coraz częściej podejmowanych prób pozyskiwania pierwiastków z żużli hutniczych. Działania te determinują konieczność analizy składu chemicznego i fazowego żużli, gdyż mogą stanowić ważną wskazówkę np. przy opracowywaniu odpowiedniej technologii odzysku pierwiastków.
Research of metallurgical slags chemical composition, originating both from current production as well as gathered in dumping grounds formany years, show that they are very diversified. Slags contain substantial amounts of metals, including heavy metals, apart from elements from groups of non-metals and lanthanoids. In the article occurrence forms and relations with phase components of selected metals (iron, manganese, zinc, lead and others) on the basis of mineralogical and chemical research on slags after steel and ore Zn-Pb production were characterized. It was stated that metals may occur in metallurgical slags as fine drops not separated from slag during a metallurgical process, may form polymetallic aggregates, their own phases (especially oxide ones) and hide in structures of silicate phases. A considerable amount of metals is dissipated in glaze and amorphous substance. The conducted research delivers information on the occurrence of metals in metallurgical slags, which is extremely important during work connected with economic exploitation of slags. It especially refers to increasing attempts of acquiring elements from metallurgical slags. These activities determine the necessity of analyzing chemical and phase composition of slags because they may be an important indication, for instance while working on a proper technology of elements recovery.
Źródło:
Gospodarka Surowcami Mineralnymi; 2012, 28, 1; 63-75
0860-0953
Pojawia się w:
Gospodarka Surowcami Mineralnymi
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Badania specjacji bromu w wodach o zróżnicowanym zasoleniu na podstawie modelowania geochemicznego
The Study of Bromine Speciation in Water of Varying Salinity, Based on Geochemical Modeling
Autorzy:
Winid, B.
Powiązania:
https://bibliotekanauki.pl/articles/1819148.pdf
Data publikacji:
2013
Wydawca:
Politechnika Koszalińska. Wydawnictwo Uczelniane
Tematy:
specjacja bromu
modelowanie geochemiczne
woda
bromine speciation
water
geochemical modeling
Opis:
Chemical analyses usually present the overall concentration of the test element or ion in its most common form. Geochemical modeling allows the calculation of the distribution and concentrations of aqueous species, based on the results of chemical analysis and physical – chemical measurements. The initial characterization of inorganic forms of bromine in groundwater was based on the undertaken geochemical modeling. The studies considered waters of varying mineralization, including varyingious contents of bromine. Fresh water contains small quantities of bromine. The average content of bromine in surface water and active exchange zone groundwater generally does not exceed 0,2 mg/L. The mineralized waters and also some specific therapeutic waters, thermal waters and brines, may contain bromides in amounts greater than in ordinary groundwater. During water treatment processes, the oxidation of bromide can cause the formation of carcinogenic bromate and organic bromine compounds, also mutagenic. The distribution of bromine species in waters of different chemical type and of varied salinity, has been calculated using the program PHREEQC (Parkhurst, Apello 1999). The author used her own research of infiltration of saline water flowing into the Wieliczka salt deposits and also the results of sample analyses of waters with different contents of bromide, both in Poland and the U.S. The study also includes analyses of leachate from three different landfills in the south of Poland. Chemical characteristics were collected from author's own research as well as published data. There were 33 analyses of waters of different chemical characteristic, most of them saline (with chloride ion content larger than 20% milieqvalent). Bromine species were analyzed in terms of salinity and chemical type of water. The calculations also take into consideration the species of bromine which are potentially conducive to the formation of carcinogenic compounds. The quantitative relationship between speciation content and ionic strength, chlorides, bromides and pH was analyzed statistically and presented in the figures. Based on the results of calculations of bromine speciation resulting from geochemical modeling, it can be stated that the main form of bromine occurrence is bromide ion, which accounts for more than 93% of all speculations. In the waters of low ionic strength, it is typically up to 100%. The maximum content of NaBr in the studied waters exceedes 7%. It should be noted that bromide ion is not always present in aqueous solutions. The content of NaBr increases with the ionic strength of the aqueous solution. Other bromine speciations account for only a fraction of a percent. There was no occurrence of bromate BrO3-and the percentage of undissociated forms (HBrO) did not exceed the value of 1E-19, which is about 5.4 E-21 mg/L. Geochemical modeling carried out confirmed the prevalence of bromine in aqueous solution in ionic form (bromide).
Źródło:
Rocznik Ochrona Środowiska; 2013, Tom 15, cz. 3; 2452-2467
1506-218X
Pojawia się w:
Rocznik Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Geochemistry of Middle Jurassic mudstones (Kraków-Częstochowa area, southern Poland): interpretation of the depositional redox conditions
Autorzy:
Szczepanik, P.
Witkowska, M.
Sawłowicz, Z.
Powiązania:
https://bibliotekanauki.pl/articles/2059479.pdf
Data publikacji:
2007
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Middle Jurassic
Częstochowa Clay Formation
palaeoenvironment
geochemical parameters
redox conditions
Opis:
Middle Bathonian iron-bearing dark grey mdstones and claystones from the Kraków-Czestochowa Upland (southern Poland) were subjected to geochemical and mineralogical study in order to evaluate palaeo-redox conditions of their deposition and diagenesis. They are mainly composed of kaolinite, with smaller amounts of other clay minerals and detrital quartz. Organic matter is composed of type III and/or IV kerogen and its d13C is between -23 and -24‰, suggesting a mainly terrigenous source, with a possible admixture of marine input. Most geochemical parameters: (total organic carbon) TOC/S, U/Th, Ni/Co, V/Cr, (Cu+Mo)/Zn ratios, authigenic uranium content, and Fe-TOC-S relationship, indicate deposition under oxygenated bottom water conditions. By contrast, DOP (degree of pyritization) and V/V+Ni indices suggest a dysoxic environment. However, DOP probably reflects redox conditions in the sediment during diagenesis rather than in the over laying water column. The composition of the organic matter and the domination of pyrite euhedra over framboids indicates that the V/V+Ni ratio may not be reliable for determination of redox conditions in the rocks studied. There is no significant difference between the geochemical indices of host rocks with nodules and those with out them.
Źródło:
Geological Quarterly; 2007, 51, 1; 57-66
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Rescue archaeological research on the Dominican Square in Cracow in the light of interdisciplinary studies
Autorzy:
Łyczak, M.
Powiązania:
https://bibliotekanauki.pl/articles/184499.pdf
Data publikacji:
2014
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
medieval architecture
archaeological excavations
cultural layer
petrographic study
geochemical study
Opis:
The rescue excavations associated with the renovation of surfaces surrounding the Dominican Basilica of the Holy Trinity in Cracow were conducted in 2011-2012 in front of the church. This research confirmed the presence of a churchyard cemetery whose origins date back to the 12th century and led to the discovery of previously unknown relics of medieval architecture in the form of two pieces of the masonry foundation of the Gothic chapels and presumably pre-Dominican (or early-Dominican) church of the Holy Trinity as well as undisturbed culture layers from early mediaeval times. The research was carried out in close collaboration with researchers in architecture and art history; it enabled preliminary reconstruction of the plans of the discovered buildings. Petrographic analysis of building material and samples of mortars used provided information on mediaeval construction techniques. Human bone material was analyzed by anthropologists. As a result, the gender, age and health status of members of the mediaeval and modern populations of Cracow buried in the cemetery were determined. Geochemical studies also helped to assess the degree of land contamination related to the presence of the cemetery. A detailed analysis of the cultural layer representing the residue of the open settlement along with its coeval economical structures was carried out. Layer dating was based on a formal analysis of the ceramic material. Osteological research of the animal bone material and palaeobotanical studies of soil samples taken from settlement layers allowed clarification of the nature of the settlement.
Źródło:
Geology, Geophysics and Environment; 2014, 40, 2; 207-218
2299-8004
2353-0790
Pojawia się w:
Geology, Geophysics and Environment
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Zastosowanie metod modelowania hydrochemicznego w ocenie wietrzenia skał klastycznych na przykładzie piaskowca kredowego ze złoża Radków
Hydrochemical methods applied in the assessment of clastic rocks weathering process on the example of Radków sandstone
Autorzy:
Labus, M.
Powiązania:
https://bibliotekanauki.pl/articles/216197.pdf
Data publikacji:
2010
Wydawca:
Polska Akademia Nauk. Instytut Gospodarki Surowcami Mineralnymi i Energią PAN
Tematy:
modelowanie geochemiczne
wietrzenie
piaskowiec
Radków
geochemical modeling
weathering
clastic rock
Opis:
W artykule zawarto przykład modelowania hydrochemicznego procesów wietrzenia skał klastycznych, używanych do celów budowlanych. Metodę przedstawiono na przykładzie kredowego piaskowca ciosowego ze złoża Radków (niecka śródsudecka). Badana skała jest piaskowcem kwarcowym, zawierającym do 11% skaleni potasowych oraz 1,8% minerałów węglanowych. Współczynnik porowatości całkowitej wynosi ponad 20%. Na przebieg procesów wietrzenia wpływa też dominujący udział makroporów właściwych (84%). Do modelowania wykorzystano symulator geochemiczny The Geochemist's Workbench 7. Badania miały na celu przybliżone określenie efektów wpływu niszczących czynników otoczenia (wód opadowych na terenach zurbanizowanych) na skały okruchowe. Model krótkotrwałych reakcji kinetycznych wietrzenia surowca wskazuje, iż zobojętnienie kwaśnego odczynu wód opadowych związane jest z rozkładem minerałów węglanowych, w tym przypadku kalcytu i dolomitu. Rozkład minerałów glinokrzemianowych, podczas symulowanego odparowania roztworu, biorąc pod uwagę początkową ich objętość w skale, jest nieznaczny.
The durability of building stones is controlled mostly by the following properties: mineral composition, texture, pore area parameters, and pore fluid phase composition and its content. Stone elements in building objects might be regarded as open hydrochemical systems, whose initial chemistry is set at deposition stage. Chemistry of the system changes when infiltrating water moves chemical components through pores, and causes either leaching or cementation of grains. The weathering processes could be clearly presented by hydrogeochemical modeling (reactive transport models). The paper presents an example of hydrochemical modeling of weathering processes within the clastic rock, used as a building material. The examined rock is Cretaceous quader sandstone from Radków deposit (intrasudetic basin, Lower Silesia, Poland), widely used in architectural monuments in Central Europe. The rock is quartz sandstone of high porosity of over 20%. Dominating pores are macropores (84%). The modeling was conducted with use of geochemical simulator The Geochemist's Workbench 7, estimated the influence of destroying environmental factor (atmospheric water of urbanized area) for rock. In the model the total pore area is assumed to be saturated by rain water, hence the reactions are related to the external part of a building rock. The time of saturation and evaporation stage is established for a one day (24 hours). Themodeling estimated the influence of destroying environmental factors, i.e. atmospheric water of urbanized area. Model of rock-water interactions showed that the porosity increase is connected to decomposition of carbonate minerals (calcite and dolomite). Decomposition of other minerals (aluminosilicates) starts during the evaporation cycle, but the scale of the phenomenon is insignificant, taking into account the volume of the reactants.
Źródło:
Gospodarka Surowcami Mineralnymi; 2010, 26, 1; 83-92
0860-0953
Pojawia się w:
Gospodarka Surowcami Mineralnymi
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Zastosowanie modelowania geochemicznego do ilościowej oceny denudacji chemicznej
Quantitative estimation of chemical denudation by using geochemical modelling
Autorzy:
Szostakiewicz, M.
Małecki, J.J.
Powiązania:
https://bibliotekanauki.pl/articles/2074430.pdf
Data publikacji:
2006
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
denudacja chemiczna
modelowanie
geochemia
chemical denudation
geochemical modelling
Inner Carpathians
Opis:
Chemical denudation is an essential factor of the circulation of elements on the Earth. Its intensity is related to several processes, of which the most important are dissolution and precipitation of minerals. Chemical denudation considerably bears on physicochemical proprieties of surface waters and groundwaters in the hypergenesis zone. The paper presents the use of geochemical models for quantitative estimation of chemical denudation. The geochemical models allow considering in calculations such parameters as different solubilities of minerals and the reaction of dissolution of carbonates in the presence of carbon dioxide
Źródło:
Przegląd Geologiczny; 2006, 54, 11; 1007-1010
0033-2151
Pojawia się w:
Przegląd Geologiczny
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 117

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