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Wyszukujesz frazę "functional nanocomposites" wg kryterium: Temat


Wyświetlanie 1-2 z 2
Tytuł:
Modified titanium dioxide for 3D printing applications
Autorzy:
Sztorch, Bogna
Głowacka, Julia
Hanuszewska, Anna
Romańczuk-Ruszuk, Eliza
Konieczna, Roksana
Przekop, Robert
Powiązania:
https://bibliotekanauki.pl/chapters/2204277.pdf
Data publikacji:
2022
Wydawca:
Politechnika Białostocka. Oficyna Wydawnicza Politechniki Białostockiej
Tematy:
biocomposites
PLA
titanium dioxide
pigments
organosilicon modifiers
functional nanocomposites
Opis:
This chapter describes the methodology of obtaining polylactide (PLA) biocomposites with the TiO2 modified by organosilicon compounds: disiloxane and functionalized octaspherosilicate designed for use in additive technologies. The paper presents general information about polylactide, titanium dioxide and the used organosilicon modifiers (silsesqioxanes and polysiloxanes). In the paper the authors compare the effect of two types of TiO2 from different manufacturers on the properties of polymer biocomposites, which can be used in biomedical applications. The properties of the obtained composites with the use of additive FDM technology were characterized mechanically (tensile strength, flexural strength, impact strength), and the particle size of the TiO2 pigment nanofillers used was measured. All the composites were pretreated using a plastic processing technique with two different mass ratios of TiO2 filler content (1.5%; 0.5%). The properties of PLA/TiO2 composites depend on the filler concentration. The applied fillers had a positive effect on the improvement of the mechanical properties of the produced polymer composites. This effect was additionally intensified by the introduction of organosilicon modifiers.
Źródło:
Advances in biomedical engineering; 165–179
9788367185400
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Radiolytic synthesis of gold nanoparticles in HEMA-based hydrogels : potentialities for imaging nanocomposites
Autorzy:
Dziarabina, Katsiaryna
Pinaeva, Uliana
Kadłubowski, Sławomir
Ulański, Piotr
Coqueret, Xavier
Powiązania:
https://bibliotekanauki.pl/articles/2055680.pdf
Data publikacji:
2021
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
functional hydrogels
gold nanoparticles
nanocomposites
network properties
radiation--induced reactions
stimuli-responsiveness
Opis:
This article reports on the radiolytic synthesis of nanocomposites containing gold nanoparticles (AuNPs) within two types of hydrogels based on 2-hydroxyethyl methacrylate (HEMA): (i) plain networks with various contents in ethylene glycol dimethacrylate (EGDMA), as a cross-linker and (ii) stimuli-responsive (SR) networks prepared from these monomers copolymerized with [2-(methacryloyloxy)ethyl]trimethylammonium chloride (MADQUAT) to confer pH-switchable swelling. Hydrogels were prepared by photopolymerization with well-defi ned composition and a high degree of monomer conversion using two experimental procedures, as xerogels or in aqueous solution. Besides MADQUAT, acrylic acid (AA) or N-isopropylacrylamide have been tested as copolymers, yielding pH- or temperature-sensitive hydrogels, respectively. Isothermal swelling in water was affected by monomer composition. Electron beam (EB) irradiation at doses up to 100 kGy of poly(HEMA) xerogels and water-swollen networks prepared with 0.5 wt% of EGDMA had a moderate impact on swelling characteristics and thermomechanical properties of the plain materials, whereas small amounts of extractables were formed. Poly(HEMA)-based nanocomposites containing AuNPs were successfully obtained by EB irradiation of samples swollen by aqueous solutions of Au(III). The effects of dose and cross-linking density on the formation of AuNPs were monitored by UV-visible spectroscopy. Irradiation at well-defined temperatures of the Au(III)-loaded SR hydrogels induced the formation of nanoparticles with size-dependent features, whereas the efficiency of Au(III) reduction at 10 kGy was not significantly affected by the network structure. EB-induced reduction of Au(III) in poly(HEMA) hydrogels using a lead mask to generate well-defined patterns yielded coloured and long-lasting images in the zones where the nanocomposite was formed.
Źródło:
Nukleonika; 2021, 66, 4; 165--177
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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