- Tytuł:
- The extraordinary gravity of three atom 4π-components and 1,3-dienes to C20-nXn fullerenes; a new gate to the future of Nano technology
- Autorzy:
-
Siadati, Seyyed Amir
Rezazadeh, Solmaz - Powiązania:
- https://bibliotekanauki.pl/articles/35114894.pdf
- Data publikacji:
- 2022
- Wydawca:
- Radomskie Towarzystwo Naukowe
- Tematy:
-
[3+2] cycloaddition
nanotechnology
C20 fullerene
actuators
reaction mechanism
functionalization
[3+2] cykloaddycja
nanotechnologia
fuleren C20
aktuatory
mechanizm reakcji
funkcjonalizacja - Opis:
- A quick glance to the adsorption, sensing, and energy storage abilities of C<sub>20</sub> fullerene and its derivatives indicate that this small carbon cluster may have extraordinary properties which would make it a key part of the future of Nano actuators and Nano machines. For example, in the case of the gravity of three atom 4π-components (TACs) to these carbon cages, it should be noted that; the rate constants (K)s of the reaction of C<sub>20</sub> fullerene with 1,3-butadiene (Diels-Alder (DA) process), and with 2-furan nitrile oxide ([3+2] cycloaddition (32CA process)) are 2.51(10<sup>11</sup>) M<sup>-1</sup> s<sup>-1</sup>, and 1.4(10<sup>7</sup>) M<sup>-1</sup>s<sup>-1</sup>, respectively. However, the rate constant of the 32CAreaction between norbornadiene and 3,4-dihydro isoquinoline-N-oxide is about 2.56(10<sup-5</sup>) M<sup>-1</sup> s<sup>-1</sup> (both by DFT and by experimental results). This simple comparison could show the extraordinary gravity of some TACs and dienes to C<sub>20</sub> fullerenes.
- Źródło:
-
Scientiae Radices; 2022, 1, 1; 46-68
2956-4808 - Pojawia się w:
- Scientiae Radices
- Dostawca treści:
- Biblioteka Nauki
Artykuł