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    Wyświetlanie 1-19 z 19
    Tytuł:
    Mechanistic study on the flotation of barite with C18H33NaO2 under microwave radiation based on UV-visible spectrophotometric analysis
    Autorzy:
    Guo, Jing
    Wen, Ming
    Wu, Jingxuan
    Powiązania:
    https://bibliotekanauki.pl/articles/2175439.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    UV-visible spectrophotometer
    microwave
    barite
    flotation mechanism
    Opis:
    Based on the pure mineral flotation tests of barite, this study investigated the effect law of microwave on barite flotation by using a UV-visible spectrophotometer (L5), solution chemistry calculation, and zeta potential, scanning electron microscope (SEM), and other testing methods. Additionally, red flotation kinetic analysis was carried out to deeply explore the mechanism of C18H33NaO2 flotation of barite under microwave radiation. Mineral flotation tests showed that after microwave treatment, the flotation recovery of barite and deionized water increased by 2.67% and 3.35%, respectively, while that of the microwave action pulp and chemically added pulp decreased by 2.90% and 8.51%, respectively. Microwave action on barite can improve its flotation recovery (up to 95.27%). The action of microwave heating can improve the positive electrical properties of the surface of barite, and accordingly, its specific surface area would be enlarged. In this case, the adsorption rate of sodium oleate on the surface of barite increased, thereby improving the flotation recovery. The flotation kinetics analysis revealed that the k-value of the primary kinetic model was the most informative among the four models of flotation kinetics, and its fitting results can truly reflect the flotation results of barite before and after the microwave action. Through the analysis of barite flotation adsorption experiment under microwave action and with sodium oleate as a collector, this study revealed the mechanism of C1818H33NaO2 on barite flotation under a microwave roaster. This study provides an important reference for the research on efficient barite flotation.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 6; art. no. 156349
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Molecular dynamic simulations study of 2-((2- (decyloxy)ethyl)amino)lauric acid adsorption on the α-quartz (1 0 1) surface
    Autorzy:
    Luo, Binbin
    Zhu, Yimin
    Sun, Chuanyao
    Li, Yanjun
    Han, Yuexin
    Powiązania:
    https://bibliotekanauki.pl/articles/109736.pdf
    Data publikacji:
    2019
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    α-quartz
    molecular dynamic
    2-((2-(decyloxy)ethyl)amino)lauric acid
    flotation mechanism
    Opis:
    Adsorption mechanism of a novel amphoteric collector 2-((2-(decyloxy)ethyl)amino)lauric acid (CH<3>dolny(CH2)9CH(NH(CH2)3-O-(CH2)9CH3)COOH, LDEA) on the α-quartz (1 0 1) surface has been investigated through molecular dynamic (MD) simulation calculations at a molecular level. The adsorption process showed that the LDEA collector could be adsorbed onto α-quartz’s (1 0 1) surface as the H atom in the polar carboxyl and amino functional group of the collector moved closer to the O atom of quartz (1 0 1) surface. The interaction energies of the collector LDEA molecule and its ionic derivative species on α-quartz surfaces in vacuum and aqueous solutions are in the order of pH 4 < pH 12 < in vacuum < pH 10 < pH 6, which demonstrating that the α-quartz (1 0 1) surface could absorb the collector LDEA in the forms of electrostatic and hydrogen bonding interactions. It also reveals that the optimal pulp pH range for LDEA adsorption on α-quartz’s surface is between neutral and weak alkali environment (pH 6 - 10). The trend obtained from molecular modeling has been validated by microflotation studies on quartz at different pHs.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2019, 55, 5; 1209-1216
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    New insights into the promotion mechanism of $(NH_4)_2SO_4$ in sulfidization flotation: a combined experimental and computational study
    Autorzy:
    Chen, Daixiong
    Liu, Mengfei
    Hu, Bo
    Dong, Yanhong
    Xue, Wei
    He, Peng
    Chen, Fang
    Zhu, Jianyu
    Zhang, Chenyang
    Powiązania:
    https://bibliotekanauki.pl/articles/1446762.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    malachite
    promotion
    sulfidization
    flotation
    mechanism
    Opis:
    Ammonium sulfate ((NH4)2SO4) exhibits promoting effects in malachite sulfidization flotation. However, the promotion mechanism remains poorly understood. In this study, micro-flotation tests, zeta-potential measurements, scanning electron microscopy coupled with energy-dispersive spectroscopy (SEM-EDS), atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and materials studio simulation (DFT) were used to investigated the promotion mechanism of $(NH_4)_2SO_4$. Micro-flotation test demonstrates that the recovery of malachite from 73% increased to 83%, when the (NH4)2SO4 was added. Contact angle and zeta potential test results indicate that addition of $Na_2S•9H_2O$ changes the surface properties of malachite and provide the conditions for adsorption of butyl xanthate (BX). After promoting the sulfidization by $(NH_4)_2SO_4$, BX is more effective in improving the hydrophobicity. SEM-EDS and AFM results show that $(NH_4)_2SO_4$ can improve performance and stability of sulfidization. X-ray photoelectron spectroscopy indicates that after sulfidization, polysulfides and cuprous were appeared in malachite surface, infers that a redox reaction occurs between sulfur and copper on the surface of malachite. After addition of $(NH_4)_2SO_4$, the percentage of polysulfides and cuprous were increased, it implies $(NH_4)_2SO_4$ can accelerate the redox reaction. Computational results show that after adding $(NH_4)_2SO_4$, the adsorption energy of HS- on the malachite surface is reduced, implies that $(NH_4)_2SO_4$ can improve the stability of HS-adsorption on the surface of malachite.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 5; 57-70
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Study of flotation behavior and mechanism of cervantite activation by copper ions
    Autorzy:
    Wang, J.
    Wang, Y.
    Fu, K.
    Xu, L.
    Wang, Z.
    Sun, H.
    Xiao, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/110228.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    flotation
    cervantite
    copper ions
    activation mechanism
    Opis:
    Copper-ion activation plays a highly important role in cervantite (Sb2O4) flotation. Without metal-ion activation, cervantite cannot be floated by sodium oleate. In this study, flotation tests were conducted to study the effect of Cu2+ on the flotation behaviours of cervantite and quartz (SiO2) as the main gangue mineral. Metal-ion adsorption capacities, zeta potentials, solution chemistry and X-ray photoelectron spectra were analyzed to study the adsorption behavior and mechanism of copper ions and sodium oleate interaction with the minerals surfaces. The results demonstrate that under weakly acidic conditions, cervantite can be flotated and separated from quartz by the addition of copper ions. The reason is that copper ions can be selectively adsorbed on the cervantite surface under weakly acidic conditions, thereby promoting the adsorption of sodium oleate onto the cervantite surface by chemical adsorption. Conversely, copper ions are weakly adsorbed on quartz surfaces below pH 6.1, and sodium oleate cannot be adsorbed on quartz surfaces by chemical adsorption. The hydroxy copper species are integral to the selective activation of cervantite over quartz.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 3; 814-825
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Flotation separation of rutile from almandine using octadecyl amine polyoxyethylene ether as collector
    Autorzy:
    Li, Hongqiang
    Zheng, Huifang
    Chen, Qian
    Kasomo, Richard M.
    Leng, Jiahao
    Weng, Xiaoqing
    Song, Shaoxian
    Xiao, Linbo
    Tian, Chengtao
    Powiązania:
    https://bibliotekanauki.pl/articles/1449410.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    rutile
    almandine
    flotation separation
    adsorption mechanism
    Opis:
    In this study, the flotation separation of rutile from almandine using cationic surfactant Octadecyl amine polyoxyethylene ether (AC1815) as a new collector was investigated. The adsorption mechanism of AC1815 on rutile was illustrated through zeta potential measurement, infrared spectrum and XPS analyses. The flotation experiments demonstrated that AC1815 exhibited an excellent collecting ability and selectivity for rutile. The results of zeta potential measurements and XPS analysis indicated that more AC1815 was adsorbed on rutile surface instead of almandine. The adsorption mechanism of AC1815on rutile was mainly attributed to the electrostatic interaction between the positively charged molecules of AC1815 and the negatively charged rutile surface, and the hydrogen bonding between the protonated $≡NH^+$, $≡N$ group of AC1815 and $Ti-OH$ on rutile surface.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2020, 56, 4; 653-664
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effective flotation separation of scheelite and calcite by applying methylene phosphonic acid sodium as a novel and green depressant
    Autorzy:
    Zhou, Hepeng
    Wu, Handan
    Guo, Jiangfeng
    Tang, Xuekun
    Huang, Wen
    Luo, Xianping
    Powiązania:
    https://bibliotekanauki.pl/articles/24086193.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    scheelite
    calcite
    inhibition mechanism
    flotation separation
    Opis:
    It is known that the flotation separation of scheelite and calcite is quite difficult due to their similar surface properites. To slove the problem, ethylenediaminetetra (methylene phosphonic acid) sodium (EDTMPS), an environmentally friendly reagent, was employed as an efficient depressant for flotation separation of calcite for the first time. In flotation experiments, it demonstrates that EDTMPS could strongly inhibit the flotation of calcite but barely affect the flotaiton behavior of scheelite, showing excellent dpress ability and selectivity. Based on a series of measurements including contact angle analysis, zeta potential, and XPS analysis, it was found that large amout of EDTMPS could be absorbed on the surface of calcite through strong chemical chelation reaction and thus inhibiting the further adsorption of NaOL. On the contrary, little EDTMPS was absorbed on that of scheelite owing to the negatively charged tungstate ions on the surface in relative terms. All in all, these results exhibit EDTMPS has excellent selective inhibition ability on calcite, which can be potentially applied in actual scheelite and calcite flotation separation process.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 3; art. no. 168517
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Flotation behavior and adsorption mechanism of sodium lauroamphoacetate to cassiterite
    Autorzy:
    Chen, Y.
    Lv, H.
    Tong, X.
    Xie, X.
    Powiązania:
    https://bibliotekanauki.pl/articles/109885.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    sodium lauroamphoacetate
    flotation behavior
    adsorption mechanism
    cassiterite
    Opis:
    The flotation behavior and adsorption mechanism of cassiterite using sodium lauroamphoacetate (SLA) as a collector were investigated by adsorption tests, micro-flotation tests, zeta potential measurements, Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) analysis. Adsorption test results indicated that the adsorption of SLA on the cassiterite surface increased continually with the increase of SLA concentration. Micro-flotation test results demonstrated that SLA had a stronger collecting ability to cassiterite than salicylhydroxamic acid (SHA) and sodium oleate (NaOL) in the pH range of 2-12, and showed a higher selectivity in the separation of cassiterite-quartz than in cassiterite-clinochlore. The zeta potential measurement results indicated that the isoelectric point (IEP) of cassiterite minerals changed from pH 3.9 to 3.4, suggesting the adsorption of SLA on cassiterite surface. The FTIR spectra and XPS analysis further confirmed that SLA chemically adsorbed on cassiterite surface.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 2; 386-394
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Dispersive effect of low molecular weight sodium polyacrylate on pyrite-serpentine flotation system
    Autorzy:
    Zhao, K.
    Yan, W.
    Wang, X.
    Gu, G.
    Deng, J.
    Zhou, X.
    Hui, B.
    Powiązania:
    https://bibliotekanauki.pl/articles/110158.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    dispersant
    serpentine
    flotation
    surface potential
    dispersion mechanism
    Opis:
    In this work, the dispersive effect of low molecular weight sodium polyacrylate (PAAS) on serpentine, and its dispersion mechanism were systematically investigated through zeta potential measurements, micro and batch flotation as well as adsorption tests. At pH 5, where flotation of iron sulphide was routinely performed, pyrite and serpentine minerals were oppositely charged, and therefore they were attracted to each other. Slime coatings of serpentine adhered to the surface of pyrite, decreasing the adsorption density of a collector on the pyrite surface, but also reducing the flotation recovery. PAAS increased the flotation recovery of pyrite by promoting dispersion between pyrite and serpentine. The effective flotation separation of pyrite from the refractory iron sulphide ore was possible by using PAAS as a dispersant. Anionic PAAS adjusted the surface potential of serpentine through adsorption on the serpentine surface and changed the interaction between pyrite and serpentine particles from attractive to repulsive, and then dispersed pyrite and serpentine.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 2; 1200-1213
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Influencing mechanisms of sodium hexametaphosphate on molybdenite flotation using sea water
    Autorzy:
    Wang, Lizhangzheng
    Li, Yubiao
    Fan, Ruihua
    Fan, Rong
    Powiązania:
    https://bibliotekanauki.pl/articles/109351.pdf
    Data publikacji:
    2019
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    sodium hexametaphosphate
    flotation
    molybdenite
    sea water
    mechanism
    Opis:
    Flotation using sea water has been considered as a promising alternative to concentrate molybdenite (MoS2) under alkaline conditions due to scarcity of fresh water and increasingly strict regulations on the quality of discharged water. However, the MoS2 recovery with sea water during flotation has not been satisfactory, owing to the depressing effects from the hydrophilic metallic species onto MoS2 surface. This study combines experimental and theoretical studies of MoS2 flotation to investigate how the physicochemical properties of MoS2 vary with the addition of a dispersant, sodium hexametaphosphate (SHMP), and in sea and fresh water. Our experimental results show that the addition of SHMP during flotation has increased the recovery of MoS2, via reducing the adsorption of the hydrophilic metallic precipitation onto MoS2 surface. The DLVO calculation confirms that the addition of SHMP increases the floatability of MoS2 by dispersing the formed hydrophilic metallic precipitation (Mg(OH)2 colloids) from the MoS2 surface, via reversing attraction force to repulsion force, thereby improving MoS2 flotation recovery.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2019, 55, 5; 1091-1098
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Strengthening the rough selection effect of n-ethyl o-isopropyl thionocarbamate (Dow: Z-200) on chalcopyrite by ultrasonic pretreatment
    Autorzy:
    Wang, Yan
    Wang, Yubin
    Yu, Bo
    Wang, Xin
    Ma, Xiaoxiao
    Powiązania:
    https://bibliotekanauki.pl/articles/1448798.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    ultrasonic pretreatment
    Z-200
    action mechanism
    chalcopyrite flotation
    Opis:
    In this study, the properties of $(CH_3)_2CHOC(S)NHC_2H_5$(Dow: Z-200) after the ultrasonic pretreatment was characterized by employing surface tension, viscosity, and Fourier transform infrared (FTIR) spectroscopy, and its influence on chalcopyrite rough selecting was investigated. The results indicate that the pretreated Z-200 can improve the index of chalcopyrite roughing. And, under the same reagent system, the recovery of copper reached 82.84% which was an increase of 24.44% compared with the untreated when Z-200 after ultrasonic pretreatment was applied to the rough separation of chalcopyrite. The reason why ultrasonic can strengthen the flotation effect of Z-200 on chalcopyrite is that ultrasonic pretreatment can decrease the surface tension and viscosity of Z-200 and enhance its foaming performance. Meanwhile, the ultrasonic cavitation destroys the molecular structure of Z-200, so that the relative proportion of methyl absorption peak and amine absorption peak in Z-200 increases. This also further improves the collection performance and foaming performance of Z-200 and strengthens its separation effect on chalcopyrite. The research provides a new idea for Z-200 to act on chalcopyrite and improve its flotation efficiency, reduce the amount of flotation reagent, and its pollution to the environment. It also provides a theoretical basis for expanding the application of ultrasonic technology in the field of flotation.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 1; 64-74
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of compound phosphate collector on flotation separation of jamesonite from marmatite and insights into adsorption mechanism
    Autorzy:
    Huang, Weiqin
    Gu, Guohua
    Chen, Xiong
    Wang, Yanhong
    Powiązania:
    https://bibliotekanauki.pl/articles/1448921.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    compound phosphate
    jamesonite
    marmatite
    flotation separation
    adsorption mechanism
    Opis:
    Separating jamesonite and marmatite is difficult due to their similar response to traditional collectors. To improve the selectivity of the collector and simplify the reagent system, compound phosphate (MP) as a collector for the separation of jamesonite from marmatite was studied in this study. The flotation tests revealed that, compared with the most used butyl xanthate (BX), MP had the advantages of lower dosage and stronger selectivity under weak acid pulp. Under the optimum flotation conditions, a concentrate with the grade of 31.54% Pb, 6.93% Zn and the recovery of 89.87% Pb, 12.31% Zn could be obtained from mixed binary minerals flotation (mass ratio of 1:1). Adsorption, zeta potential, FT-IR and XPS analysis demonstrated that MP performed strong chemisorption on jamesonite surface while underwent weak physisorption on marmatite, this difference was responsible for the excellent selectivity of MP toward jamesonite flotation and weak collecting capacity to marmatite.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 1; 294-304
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Activation of quartz flotation by Cu2+, Ni2+ in the sodium ethylxanthogenate (EX) system
    Autorzy:
    Liu, Yang
    Tong, Xiong
    Xie, Rui-Qi
    Xie, Xian
    Song, Qiang
    Fan, Pei-Qiang
    Powiązania:
    https://bibliotekanauki.pl/articles/24085981.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    quartz
    flotation
    ions activation
    sodium ethylxanthogenate
    adsorption mechanism
    Opis:
    During the flotation of metal sulfide minerals, due to the interference of unavoidable ions, the quartz also partially floats in some cases. The studies on the mechanism of quartz being activated and floating up are still insufficient. In this study, the influence of the Cu2+ and Ni2+ unavoidable ions on the floatation of quartz was studied by micro-flotation experiments, adsorption detection, zeta potential measurement, solution composition calculation, infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS) analyses, and atomic force microscopy (AFM) observation. This provides a theoretical reference for further understanding the mechanism of sodium ethylxanthogenate and quartz surface, as well as the development of a new quartz depressant. The results of flotation showed that after activation by Cu2+ (1×10-4 mol/dm3) and Ni2+ (5×10-5 mol/dm3), the quartz was captured by sodium ethylxanthogenate (EX: 1.4×10-4 mol/dm3) under alkaline conditions (pH=10), while the best recoveries were obtained as 80% and 43%, respectively. The results of adsorption and zeta potential measurements showed that the precipitation rate of Cu2+ was greater than that of Ni2+ under alkaline conditions. Additionally, both Cu2+ and Ni2+ electrostatically adsorbed on the quartz surface and changed the zeta potential of quartz. The solution composition calculation further showed that Cu(OH)+, Cu(OH)2(s), and Ni(OH)+, Ni(OH)2(s) were the main components in the solution under alkaline conditions. The FT-IR and XPS analyses and AFM observations demonstrated that Cu and Ni species adsorbed on O atoms on the quartz surface, providing active sites for EX adsorption, and EX combines with Cu and Ni species on the quartz surface to generate -O-Cu-EX and -O-Ni-EX complexes. Finally, the quartz floated up due to the formation of hydrophobic products and firm adsorption.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 2; art. no. 166368
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    A review of the application of nanoparticles as collectors in ion flotation
    Autorzy:
    Sobouti, Arash
    Rezai, Bahram
    Hoseinian, Fatemeh Sadat
    Powiązania:
    https://bibliotekanauki.pl/articles/27323642.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    ion flotation
    nanoparticle surfactant
    synthetic chemical surfactant
    biosurfactant
    mechanism
    Opis:
    Ion flotation is one of the most promising and unique methods for reducing or removing toxic heavy metal ions, organic pollutants, or inorganic anions and cations from mining and metallurgical wastewater. It is a cost-effective and convenient method. In ion flotation, surface-active ions are removed from aqueous solutions by adding surfactants. Therefore, the main purpose of this review article was to summarize the application of various surfactants (nanoparticle surfactants, chemical synthetic surfactants, and biosurfactants) used in ion flotation. Then, the advantages, disadvantages, and prospects of surfactants were comprehensively discussed. Recent progress regarding nanoparticle surfactants in ion flotation and the mechanism of colligends binding with nanoparticles were evaluated.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 6; art. no. 176040
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of N-carboxybutyl chitosan on the flotation separation of apatite from dolomite
    Autorzy:
    Rao, Yubei
    Liu, Shanhui
    Gao, Jiewang
    Zhao, Yu
    Saffari, Pooya
    Kang, Shuo
    Liu, Zuwen
    Powiązania:
    https://bibliotekanauki.pl/articles/1446183.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    apatite
    dolomite
    flotation
    N-carboxybutyl chitosan (CBC)
    mechanism analysis
    Opis:
    With high-grade apatite resources exhausted and economic development, enhancing the apatite quality from calcium gangue such as dolomite has a great significance for production. However, it is difficult to separate apatite from dolomite effectively due to the similar surface properties. In this study, the N-carboxybutyl chitosan ($CBC$) was tested as a potential selective depressant to separate apatite from dolomite in the sodium oleate ($NaOL$). Flotation results of single mineral and artificially mixed mineral confirmed the selective depression effect of CBC. The depression mechanism of $CBC$ was investigated using wettability analysis, Fourier Transform Infrared ($FTIR$), and X-ray Photoelectron Spectroscopy ($XPS$) analyses. The results indicated that the $CBC$ adsorption quantity and intensity on the dolomite surface more than that on the apatite surface, which was due to $CBC$ absorbed on apatite surface by hydrogen bonding, while absorbed on dolomite surface mainly through chemical chelating between $Ca$ on the mineral surface and -COO- on the depressant. These adsorption differences led to the flotation separation of the two minerals.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 4; 27-35
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Acidified water glass in the selective flotation of scheelite from calcite, part II: species in solution and related mechanism of the depressant
    Autorzy:
    Kupka, Nathalie
    Kaden, Peter
    Jantschke, Anne
    Schach, Edgar
    Rudolph, Martin
    Powiązania:
    https://bibliotekanauki.pl/articles/1845224.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    acidified water glass
    scheelite calcite separation
    froth flotation
    mechanism
    Opis:
    Sodium silicate is one of the main depressants against calcite and fluorite in the scheelite flotation industry. In the first part of this article, the authors acidified sodium silicate (AWG) with three acids (sulfuric, oxalic and hydrochloric) to improve its performance. Results showed that acidified water glass outperforms alkaline water glass in terms of selectivity: it increases mainly the grade by further depressing silicates and calcium-bearing minerals. In most cases, AWG requires lower dosages to do so. The effect of acidified water glass is evaluated through Mineral Liberation Analysis (MLA), froth analysis, Raman and Nuclear Magnetic Resonance (NMR) spectroscopy in order to hypothesize its mechanism. MLA shows that AWG affects silicates and sulfides more intensely than semi-soluble salttype minerals. Froth observations indicate other species in solution associated to the acid having an impact on the flotation results. Raman spectroscopy and NMR measurements indicate that the solution undergoes deep depolymerization when water glass is acidified. Lower molecular weight silica species, specifically Si-O monomers such as SiO(OH)3- will be responsible for the depression of the gangue minerals and are the drivers of the selectivity of AWG, more than orthosilicic acid. Depolymerization is more or less effective depending on the mass ratio of the acid to water glass and depending on the acid.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2020, 56, 5; 797-817
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    The effect of Al(III) and Fe(III) ions on the flotation behavior of Kfeldspar with sodium oleate as the collector
    Autorzy:
    Chen, Yi
    Zhou, Jikui
    He, Guichun
    Hu, Hongxi
    Liu, Chao
    Yang, Jiping
    Lyu, Xianjin
    Powiązania:
    https://bibliotekanauki.pl/articles/27323648.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    K-feldspar flotation
    aluminum ion
    iron ion
    sodium oleate
    action mechanism
    Opis:
    The present study investigates the effects and mechanisms of aluminum (Al(III)) and iron (Fe(III)) ions on the flotation efficiency of potassium feldspar (K-feldspar) within oleate collector systems. The study employs micro-flotation experiments, solution chemistry calculations, zeta potential measurements, and FT-IR and XPS analyses to demonstrate that Al(III) and Fe(III) ions can significantly improve the flotation recovery of K-feldspar by altering its surface charge, bonding properties, and adsorption modes. The study also develops adsorption models for the flotation of K-feldspar activated by Al(III) and Fe(III), revealing the synergistic impacts of metal ion hydrolysis products and sodium oleate in the formation of hydrophobic complexes.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 6; art. no. 174724
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Enhancing low-rank coal flotation using a mixture of dodecane and n-valeraldehyde as a collector
    Autorzy:
    Liu, Zechen
    Liao, Yinfei
    An, Maoyan
    Lai, Qingteng
    Ma, Longfei
    Qiu, Yuliang
    Powiązania:
    https://bibliotekanauki.pl/articles/109432.pdf
    Data publikacji:
    2019
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    mixed collector
    oxygen-containing functional groups
    adsorption mechanism
    low rank coal
    flotation
    Opis:
    Low-rank coals are difficult to float using common hydrocarbon oily collectors, such as dodecane and diesel. In this investigation, a mixture of dodecane and n-valeraldehyde was used as a collector to enhance low-rank coal flotation. The changes of the contact angle and surface functional groups of low-rank coal were measured before and after different collectors’ adsorption to indicate its absorption mechanism. Surface tension of different collectors was also measured to identify its spreading performance. The results showed that the flotation performance using the mixture as a collector was much better than that using dodecane or n-valeraldehyde solely. When used the mixture of dodecane and n-valeraldehyde as collector, dodecane primarily covers the hydrophobic sites while n-valeraldehyde primarily covered the hydrophilic sites by hydrogen bond promoting adsorption of dodecane at these sites. There existed synergistic effect between dodecane and n-valeraldehyde. Additionally, n-valeraldehyde can reduce the surface tensions to improve the spreading performance of mixed collector on low-rank coal surface. The improvement both in adsorption and spreading was responsible for the enhancement of low-rank coal flotation by using the mixture.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2019, 55, 1; 49-57
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    The effect of ethylene oxide groups in dodecylamine polyoxyethylene ether on rutile flotation
    Autorzy:
    Huang, Junwei
    Chen, Qian
    Mao, Yuxuan
    Li, Hongqiang
    Powiązania:
    https://bibliotekanauki.pl/articles/1448539.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    rutile flotation
    dodecylamine polyoxyethylene ether
    ethylene oxide groups
    steric hinder effect
    adsorption mechanism
    Opis:
    To study the number of ethylene oxide (EO) groups effect on the flotation of rutile, three collectors with different EO number were evaluated: AC1203 (with three EO number), AC1210 (with ten EO number), AC1215 (with fifteen EO number). In addition to the flotation experiments, zeta potential measurements, collector adsorption experiments and XPS analysis were conducted to elucidate the adsorption mechanism. The results of flotation demonstrated that dodecylamine polyoxyethylene ether exhibited a profound collecting ability towards rutile mineral, it was worth mentioned that the recovery of rutile decreased with the increase of EO number. On the basis of zeta potential tests and XPS analysis, both protonated and neutral tertiary amine groups could act with rutile surface through electrostatic effect and hydrogen bond interaction. Furthermore, the results of collector adsorption experiments showed that with the increase of EO number, a lower adsorption density of collectors on rutile surface could be caused due to the steric hinder effects.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 1; 127-135
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Aglomeracja olejowa skały magnezytowej z udziałem mieszaniny jonowych surfaktantów
    The oil agglomeration of magnesite rock with participation of ionic surfactants mixtures
    Autorzy:
    Bastrzyk, A.
    Polowczyk, I.
    Sadowski, Z.
    Powiązania:
    https://bibliotekanauki.pl/articles/1819093.pdf
    Data publikacji:
    2013
    Wydawca:
    Politechnika Koszalińska. Wydawnictwo Uczelniane
    Tematy:
    aglomeracja olejowa
    mieszaniny jonowe
    fines cleaning wastes
    coal recovery
    adsorption
    dolomite
    calcite
    oleate
    suspensions
    flotation
    mechanism
    tension
    Opis:
    In this study, the adsorption of surfactant onto the magensite rock and the oil agglomeration of this mineral in aqueous suspension were investigated. The various concentration ratios of cationic and anionic surfactant were used. The results were evaluated by the recovery of carbonates in agglomerates. It was found that the process selectivity was highly dependent on the surfactants concentration ratio, pH, and the amount of salt added. The best separation of quartz from magnesite rock was observed at pH 9. The addition of larger quantity of sodium oleate (15.2 mg/gsolid) led to the increase of carbonates content in agglomerates up to 32.4%. However, the largest carbonates recovery was in the presence of 6.0 mg/gsolid of NaOl.
    Źródło:
    Rocznik Ochrona Środowiska; 2013, Tom 15, cz. 2; 1441-1459
    1506-218X
    Pojawia się w:
    Rocznik Ochrona Środowiska
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
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