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    Tytuł:
    Application of diethylenetriaminepenta pentasodium salt as an eco-friendly depressant to effectively improve the flotation separation of scheelite and calcite
    Autorzy:
    Zhou, Hepeng
    Wu, Handan
    Guo, Jiangfeng
    Tang, Xuekun
    Huang, Wen
    Luo, Xianping
    Powiązania:
    https://bibliotekanauki.pl/articles/27323649.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    flotation
    scheelite
    calcite
    diethylenetriaminepenta pentasodium salt
    depressant
    adsorption
    Opis:
    Diethylenetriaminepenta (methylene-phosphonic acid) pentasodium salt (DTPMPA), an eco-friendly reagent, was tried for the first time as a depressant for flotation separation of scheelite from calcite. Micro-flotation tests show that DTPMPA can selectively depress the floatability of calcite. In contrast, DTPMPA barely affects the flotation behavior of scheelite. Based on the selective depress effect, floatation separation of scheelite and calcite can be effectively achieved by using DTPMPA as depressant in artificially mixed minerals flotation tests. Based on a series of measurements, it found the surface of calcite was positively charged due to the existence of Ca ion site, which can be chelated with –PO3H- functional group on the surface of DTPMPA. In the flotation process, DTPMPA can be chemically absorbed on the surface of calcite to inhibit further collector adsorption. On contrast, little DTPMPA was adsorbed on the surface of scheelite due to the spatial site resistance and electrostatic repulsion induced by surface WO42+. All in all, these results exhibit DTPMPA has excellent selective depression ability on calcite, which can be potentially applied in the actual scheelite flotation process.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 6; art. no. 174718
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    The selective depression effect of sodium hexametaphosphate on the separation of chlorite and specularite
    Autorzy:
    Zhao, Fugang
    Yu, Xiankun
    Gao, Xiangpeng
    Li, Mingyang
    Chen, Xiangxiang
    Powiązania:
    https://bibliotekanauki.pl/articles/24085963.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    flotation
    depressant
    chlorite
    specularite
    adsorption
    Opis:
    Flotation is the most known beneficiation method for the separation of complex and refractory iron ores. As a typical iron-containing silicates, it is difficult to separate chlorite from specularite, because of the similar surface physicochemical properties. In this study, the selective depression effect of sodium hexametaphosphate (SHMP) was conducted via the cationic micro-flotation. The surface adsorption mechanism between SHMP and the two mineral surface was explored through surface adsorption amount tests, Zeta-potential measurements, Fourier transform infrared (FT-IR) and X-ray photoelectron spectroscopy (XPS) analyses. The micro-flotation results indicated that SHMP could selectively depress around 90% of chlorite, while its effect on the floatability of specularite was negligible (<20% depressing). The surface adsorption amount tests, Zeta-potential measurements analysis demonstrated that SHMP selectively adsorb on chlorite surface while on the surface of specularite is feeble. The further surface adsorption analysis via FT-IR and XPS proved that SHMP selective adsorption occurred on the chlorite surface mainly by chemisorption mainly through the chelation reaction between O in the phosphate groups of SHMP molecular and metal ions on surface of chlorite.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 2; art. no. 166495
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of depressants in the selective flotation of smithsonite and calcite using potassium lauryl phosphate as collector
    Autorzy:
    Sun, Qing
    Feng, Qiming
    Shi, Qing
    Powiązania:
    https://bibliotekanauki.pl/articles/110635.pdf
    Data publikacji:
    2019
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    smithsonite
    calcite
    flotation
    depressant
    separation
    Opis:
    In order to selectively separate smithsonite and calcite using potassium lauryl phosphate as collector and reveal the depression mechanism, the approaches of micro-flotation and zeta potential measurements were adopted. The effects of sodium hexametaphosphate (SHMP), water glass (WG), carboxymethyl cellulose (CMC) and lignosulfonate calcium (LSC) as depressants on smithsonite and calcite have been studied through micro-flotation. The single mineral flotation tests show that LSC can depress calcite, but it has little effect on smithsonite flotation. Flotation separation of a mixture of smithsonite and calcite can be completed to obtain a zinc concentrate grade up to 33.85% Zn with a recovery of 70.06%. The zeta potential results illustrate that LSC has higher tendency to be adsorbed on the surface of calcite. However, there is little adsorption of LSC on smithsonite.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2019, 55, 1; 89-96
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect and mechanism of depressant CK102 on flotation separation of fluorite and dolomite
    Autorzy:
    Li, Zhengyao
    Wang, Xuewen
    Xu, Chengyan
    Sun, Tichang
    Liu, Weiran
    Wei, Jinzhi
    Powiązania:
    https://bibliotekanauki.pl/articles/2146904.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    fluorite
    dolomite
    flotation
    depressant CK102
    adsorption
    Opis:
    For a low grade dolomite type fluorite ore in the Hebei province, it was observed that the depressant CK102, a mixture of sulfuric acid, sodium silicate and aluminum sulfate, can effectively inhibit the gangue mineral dolomite in the flotation of fluorite. However, the inhibition mechanism of the depressant is still unclear. In this paper, the flotation separation performance and underlying mechanism of CK102 inhibiting dolomite were investigated through mineral flotation tests, adsorption measurements, infrared spectroscopy, and X-ray photoelectron spectroscopy (XPS). The flotation results showed that the inhibition effect of CK102 on dolomite flotation was much more remarkable than that of fluorite flotation under optimum conditions. Adsorption measurements revealed that there was competitive adsorption between the depressant and collector and that the adsorption of the depressant CK102 prevented the collector modified sodium oleate from adsorbing onto the surface of minerals. The FT-IR and XPS results showed that the co-oxygen cross-linked component of the depressant CK102 chemisorbed on the surface of dolomite; the CaSiO3 precipitation was generated from the reaction of CK102 with Ca2+ groups on the surface of the dolomite; Al2MgO8Si2 precipitation was also generated from Mg2+ reacting with the sodium silicate and aluminum sulfate of CK102. The above adsorptions and reactions enhanced the hydrophilicity of the dolomite surface and the dolomite was effectively depressed.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 3; art. no. 145796
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Comparison of the depression effect of two thiol depressants on the separation of specularite and aegirite
    Autorzy:
    Li, Mingyang
    Zhang, Chen
    Gao, Xiangpeng
    Xie, Xian
    Tong, Xiong
    Powiązania:
    https://bibliotekanauki.pl/articles/2175426.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    aegirite
    specularite
    flotation
    depressant
    iron-bearing silicate
    Opis:
    In this work, two thiol-type reagents, thioglycolic acid (TGA) and mercaptopropionic acid (MPA), were firstly exploited and compared as aegirite depressants with sodium oleate (NaOl) as the collector to separate specularite from aegirite by flotation. The adsorption performances and mechanisms of TGA and MPA on aegirite surface were investigated via flotation experiments, Zeta potential tests, adsorption measurements, contact angle dimensions, and surface characterizations. The results of flotation indicated that TGA and MPA exhibited a considerable depression impact on the flotation of aegirite but little effect on specularite. TGA depicted more excellent depression performance than MPA, which was confirmed by HLB calculation. The results demonstrated that TGA and MPA favorably adsorbed on aegirite surface instead of specularite, hindering the subsequent adsorption of NaOl on specularite and resulting in the surface being hydrophilic. XPS results revealed that TGA and MPA were significantly adsorbed on the surface of aegirite through an interaction between the carboxyl and thiol groups of the depressants and the Si and Fe on the surface of aegirite.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 6; art. no. 152164
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effective separation of specularite and aegirite using chitosan as a novel depressant
    Autorzy:
    Li, Mingyang
    Zhang, Pengpeng
    Gao, Xiangpeng
    Tong, Xiong
    Xie, Xian
    Powiązania:
    https://bibliotekanauki.pl/articles/2175424.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    flotation
    iron-bearing silicates
    aegirite
    specularite
    chitosan
    depressant
    Opis:
    As a typical iron-bearing silicate gangue, aegirite often associates with specularite. Due to the iron element contained in aegirite, it has similar surface properties to specularite. Flotation is by far one of the most efficient methods of processing this kind of iron ore. But the traditional depressants unable to take action in the separation of specularite and aegirite. Chitosan was used as a novel depressant to attempt to separate specularite from aegirite through microflotation tests, adsorption tests, contact angle measurements, Zeta potential measurements, and XPS analysis. The flotation results indicate that chitosan show more strong depression effect on specularite than aegirite. Zeta potential measurements, contact angle measurements and adsorption tests demonstrate that chitosan is more inclined to adsorb on the specularite surface than aegirite, which hinders the subsequent adsorption of collector sodium oleate and increases difference in hydrophobicity between the two minerals. The XPS results of specularite validate the adsorption of chitosan on specularite, and illustrate that electrons of chitosan were partially transferred to oxygen and iron atoms in specularite during the adsorption process.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 6; art. no. 151692
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Insights into the depression effect and adsorption mechanism of HACC on chalcopyrite surface in Cu-Mo flotation separation
    Autorzy:
    Li, Mingyang
    Zhang, Pengpeng
    Xiangpeng, Gao
    Huang, Lingyun
    Powiązania:
    https://bibliotekanauki.pl/articles/27323662.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    chalcopyrite
    molybdenite
    flotation
    adsorption
    depressant
    Opis:
    In this study, hydroxypropyltrimethyl ammonium chloride chitosan (HACC) was first introduced as a depressant during separating chalcopyrite from molybdenite (Cu-Mo). The selective effects of HACC on the separation of Cu-Mo were conducted by single-mineral flotation experiments. The findings from this study revealed that HACC helped separate Cu and Mo efficiently at pH 6 with 8 mg/dm3 of HACC, resulting in 76.22% and 5.38% of Mo and Cu flotation recovery, respectively. The adsorption mechanism of HACC was investigated via zeta potential, adsorption density, and contact angle measurement along with FT-IR and XPS analyses. The contact angle and adsorption density measurements offer indisputable proof that HACC can adsorb on the surface of chalcopyrite. Furthermore, FT-IR and XPS analyses confirm that N atoms in quaternary ammonium groups of HACC interact with Cu sites on the surface of chalcopyrite. The findings also suggest that HACC adsorbs on the surface without significantly impacting molybdenite. All these results confirm that HACC can be an effective chalcopyrite depressant.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 6; art. no. 172481
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    The effect of a novel depressant on the separation of talc and copper –nickel sulfide ore
    Autorzy:
    Gu, Guohua
    Chen, Zhixiang
    Zhao, Kaile
    Song, Siyu
    Li, Shuangke
    Wang, Chongqing
    Powiązania:
    https://bibliotekanauki.pl/articles/110492.pdf
    Data publikacji:
    2019
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    Sodium alginate
    talc
    copper–nickel sulfide
    polysaccharide depressant
    flotation
    Opis:
    This paper researched the influence of the polysaccharide polymer sodium alginate (SAG) on the depression of talc at a fixed room temperature about 25 °C through micro flotation and batch flotation experiments, zeta potential and contact angle measurements as well as infrared spectroscopy analysis. The flotation results displayed that the SAG had a significant influence on the flotation of talc but less influence on sulphide flotation. Compared with the depressant carboxymethyl cellulose (CMC) and guar gum, using of the SAG gave the highest copper recovery. It could not only eliminate a talc removal step, but also significantly decrease in the depressant consumption by half at least. Sodium alginate apparently adsorbs on the talc surface and promotes hydrophilization, as revealed by contact angle tests (contact angle decreased from 75 to 33° after treating with SAG). It is demonstrated that the SAG obviously absorbed at the surface of talc but rarely for chalcopyrite through the results of zeta potential measurements and infrared spectroscopy analysis.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2019, 55, 1; 116-127
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of food-grade guar gum on flotation separation of chalcopyrite and monoclinic pyrrhotite in low-alkali systems
    Autorzy:
    Chen, Xiong
    Gu, Guohua
    Li, Lijuan
    Chen, Zhixiang
    Powiązania:
    https://bibliotekanauki.pl/articles/110629.pdf
    Data publikacji:
    2019
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    food-grade guar gum
    chalcopyrite
    monoclinic pyrrhotite
    flotation depressant
    Opis:
    The flotation separation of chalcopyrite from monoclinic pyrrhotite using food-grade guar gum (FGG) as a depressant was studied through micro flotation and flotation kinetics experiments, zeta potential, adsorption measurements and scanning electron microscope (SEM) analysis as well as infrared spectroscopy analysis. The flotation tests showed that the reagent scheme of depressant FGG 40 mg/dm3, collector PAX (potassium amyl xanthate) 10 mg/dm3 and frother MIBC (Methyl isobutyl carbinol) 10 mg/dm3 at pH 8.0 could achieve selective flotation separation of chalcopyrite from monoclinic pyrrhotite (a concentrate with Cu grade of 22.35% and recovery of 82.52% was achieved from the mixed minerals flotation), which indicated that FGG exhibited a selective depression effect on monoclinic pyrrhotite The kinetics, zeta potential, adsorption, SEM and infrared studies revealed that the depressant FGG could absorb more strongly on the surface of monoclinic pyrrhotite than chalcopyrite. Additionally, the results revealed that the interaction of FGG with the monoclinic pyrrhotite surface was governed primarily by strong chemisorption, whereas FGG mainly bonded to chalcopyrite through hydrogen bonding bonding. This property was the reason why FGG had excellent depression selectivity toward monoclinic pyrrhotite and weak depression effect on chalcopyrite flotation.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2019, 55, 2; 437-447
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Selective separation of chalcopyrite from jamesonite with guar gum
    Autorzy:
    Chen, Xiong
    Gu, Guohua
    Zhu, Renfeng
    Wang, Chongqing
    Powiązania:
    https://bibliotekanauki.pl/articles/110473.pdf
    Data publikacji:
    2019
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    guar gum
    chalcopyrite
    jamesonite
    flotation depressant
    Opis:
    A novel reagent, guar gum (GG), is investigated as the depressant on the depression of chalcopyrite and jamesonite, when mixed aerofloat (CSU11) is used as the collector in flotation tests. Kinetics, dynamic potential, adsorption and infrared spectra analysis are performed to study the interaction mechanism between GG and minerals. The flotation results display that selective flotation separation of chalcopyrite from jamesonite is achieved under conditions of depressant GG 2.5 mg/dm3, collector CSU11 10 mg/dm3 and frother MIBC (Methyl isobutyl carbinol) 10 mg/dm3 at pH 5.3. As to mixed minerals flotation, the Cu grade and recovery in the concentrate is 21.35 % and 85.12 %, respectively, indicating that GG has a selective depression effect on jamesonite. Flotation kinetics shows that the addition of GG can dramatically reduce the floatability of jamesonite but hardly influences that of chalcopyrite. The zeta potential and adsorption reveal that the depressant GG adsorbs strongly on the surface of jamesonite. Infrared spectra reveal a dominant chemisorption between GG and jamesonite, while GG occurs weak chemisorption on chalcopyrite surface. This is the reason why GG has excellent selectivity for jamesonite and less effect on chalcopyrite.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2019, 55, 1; 237-247
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-10 z 10

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