Informacja

Drogi użytkowniku, aplikacja do prawidłowego działania wymaga obsługi JavaScript. Proszę włącz obsługę JavaScript w Twojej przeglądarce.

English (EN)·Polski (PL)·Yкраїнський (UK)
Przejdź do strony domowej biblioteki Centralna Biblioteka Wojskowa Link otwiera się w nowym oknie Logo biblioteki Prolib Integro - strona głównaCentralna Biblioteka Wojskowa

Wyszukujesz frazę "esr" wg kryterium: Temat

  Lista filtrów
Wyrównaj
Wyświetlanie 1-15 z 23
Tytuł:
Uranium - Doping Effects on Structural and Spectral Features of Vanadate Ceramics
Autorzy:
Elsabawy, Khaled M.
Powiązania:
https://bibliotekanauki.pl/articles/1192708.pdf
Data publikacji:
2016
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
212 Vanadate
Ceramic
ESR
IR
Uranium Doping
X- ray
Opis:
212-Vanadate ceramics with formula Bi2SrV2-xUxO9, where (0 ≤ x ≤ 0.6 mole ) were carefully synthesized by solution routes with sintering temperature at 880oC for 24 hrs. Structural analysis with XRD proved that uranium (IV)-dopant can substitute successfully until x = 0.55 mole on the Bi-layered perovskite crystal structure without damaging the original structure . It was observed that U – doping have slight to moderate effects on both ESR-signals and conduction mechanism of U-doped Bi-Sr-V-O regime. Electrical measurements indicated that the energy gap Eg and number of electrons in conduction band Ncb increase as the ratio of U doping increases from x = 0.05 till x = 0.6 mole respectively due to the increasing of paramagnetic character of uranium than vanadium.
Źródło:
World Scientific News; 2016, 30; 103-116
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Model of binary biological mixture fractionation in gravity field and in centrifugal-force field
Model procesu frakcjonowania binarnych mieszanin biologicznych w polu grawitacji i w polu sił odśrodkowych
Autorzy:
Górka, Andrzej
Powiązania:
https://bibliotekanauki.pl/articles/1857125.pdf
Data publikacji:
2020
Wydawca:
Wojskowa Akademia Techniczna im. Jarosława Dąbrowskiego
Tematy:
biological mixture fractionation
blood component sedimentation
mixture fractionation process model
peripheral blood ESR testing
fractionation in gravity field
fractionation in centrifugal-force field
frakcjonowanie mieszanin biologicznych
sedymentacja składników krwi
model procesu frakcjonowania mieszanin
badanie OB krwi obwodowej
frakcjonowanie w polu grawitacji
frakcjonowanie w polu sił odśrodkowych
Opis:
The publication describes a simplified model of the process of fractionation of binary biological mixtures in a closed reference system. The description of the model uses a balance of masses and forces forcing microparticle movement in a base fluid matrix. The movement, consistent with the direction of the excitation forces, was limited to independent migration channels with diameters comparable to the diameters of the migrating microparticles. In this model, the parameters of the densification process of the separated fraction in a single migration channel were applied to the entire volume of the fractioned mixture. The developed model applies to theoretical bases of the erythrocyte sedimentation rate (ESR).
W publikacji opisano uproszczony model procesu frakcjonowania binarnych mieszanin biologicznych w zamkniętym układzie odniesienia. W opisie modelu wykorzystano bilans mas i sił wymuszających ruch mikrocząstek w osnowie płynu bazowego. Ruch ten, zgodny z kierunkiem działania sił wymuszających ograniczono do niezależnych kanałów migracji o średnicy porównywalnej do średnicy migrujących mikrocząstek. W modelu tym, parametry procesu zagęszczania wyodrębnianej frakcji w pojedynczym kanale migracji odniesiono do całej objętości frakcjonowanej mieszaniny. Opracowany model dotyczy teoretycznych podstaw pomiaru opadu Biernackiego (OB).
Źródło:
Biuletyn Wojskowej Akademii Technicznej; 2020, 69, 2; 15-34
1234-5865
Pojawia się w:
Biuletyn Wojskowej Akademii Technicznej
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Badanie procesu transferu ładunku wzbudzanego światłem w organicznych ogniwach słonecznych za pomocą czasowo rozdzielczej fotoluminescencji i pobudzanego światłem elektronowego rezonansu spinowego
Detection of Photo-Induced Charge Transfer in Organic Solar Cells by Time-Resolved Photoluminescence and Light-Induced Electron Spin Reseonance
Autorzy:
Grankowska-Ciechanowicz, S.
Iwan, A.
Wołoś, A.
Korona, K. P.
Kamińska, M.
Powiązania:
https://bibliotekanauki.pl/articles/160166.pdf
Data publikacji:
2014
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Elektrotechniki
Tematy:
transfer ładunku
organiczne ogniwa słoneczne
czasowo rozdzielcza fotoluminescencja
pobudzany światłem elektronowy rezonans spinowy
charge transfer
organic solar cells
TRPL
(L)ESR
Opis:
Organiczne ogniwa słoneczne są jednym z obiecujących sposobów przetwarzania energii słonecznej w elektryczną. Procesem mającym decydujący wpływ na ich działanie, jest transfer ładunku wzbudzany światłem. Techniki pomiarowe, które znalazły zastosowanie do bezpośredniej detekcji tego procesu, to czasowo rozdzielcza fotoluminescencja (TRPL – ang. time-resolved photoluminescence) i pobudzany światłem elektronowy rezonans spinowy (LESR – ang. light-induced electron spin resonance). Efektywny transfer ładunku, przy pomocy TRPL, rejestrowany jest jako wygaszanie luminescencji w wyniku przestrzennego rozseparowania ładunków przeciwnego znaku, a za pomocą LESR jako dwie linie pochodzące od dodatniego polaronu po stronie donora i ujemnego polarnu po stronie akceptora. W niniejszej pracy omówione zostaną wymienione techniki pomiarowe oraz ich zastosowanie do detekcji efektywnego transferu ładunku w organicznych ogniwach słonecznych.
The organic solar cells are considered as promising way to convert solar energy into electricity. A crucial step in their operations is a photo-induced charge transfer (CT). Techniques, which directly detect this phenomenon, are Time-Resolved Photoluminescence (TRPL) and Light-induced Electron Spin Resonance (LESR). Effective photo-induced CT results in electrons and holes separation and creation of positive and negative polarons. First process is registered by TRPL as luminescence quenching, second by LESR as two lines, one from positive, and another from negative polarons. In this article, both techniques will be described as well their application in effective CT detection.
Źródło:
Prace Instytutu Elektrotechniki; 2014, 264; 65-71
0032-6216
Pojawia się w:
Prace Instytutu Elektrotechniki
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Setna rocznica śmierci Edmunda Biernackiego (1866-1911) — filozofa medycyny i wynalazcy metody pomiaru szybkości sedymentacji erytrocytów
The Hundredth Anniversary of Edmund Biernacki s Death (1866-1911) — a Philosopher of Medicine and an Inventor of the Erythrocyte Sedimentation Rate
Autorzy:
Grzybowski, Andrzej
Sak, Jarosław
Powiązania:
https://bibliotekanauki.pl/articles/530537.pdf
Data publikacji:
2011
Wydawca:
Polskie Towarzystwo Historii Filozofii i Medycyny
Tematy:
Edmund Biernacki
odczyn Biernackiego
historia medycyny
filozofia medycyny
Biernacki Reaction (ESR)
history of medicine
philosophy of medicine
Opis:
Edmund Faustyn Biernacki (1866-1911) był lekarzem i jednym z przedstawicieli polskiej szkoły filozofii medycyny, a także pierwszym naukowcem, który w 1897 roku wykorzystał w diagnostyce klinicznej odkryte przez siebie zjawisko sedymentacji erytrocytów. Niestety historyczne fakty dotyczące dokonania tego odkrycia przez Biernackiego przez długi czas były nieznane w piśmiennictwie anglojęzycznym. W setną rocznicę śmierci Biernackiego warto przypomnieć jego osiągnięcia zarówno jako internisty, naukowca-eksperymentatora, filozofa medycyny, jak i wynalazcy metody oznaczania sedymentacji krwinek czerwonych.
Edmund Faustyn Biernacki (1866-1911) was a physician and one of the representatives of the Polish school of philosophy of medicine as well as the first scientist who used the erythrocyte sedimentation rate in medical diagnostics in 1897. Unfortunately, this historical fact about discovery of ESR by Biernacki was unknown in the English language literature. On the hundredth anniversary of Biernacki s death, it is worth to remind his achievements as an internist, scientist-experimenter, philosopher of medicine and inventor of the erythrocyte sedimentation rate.
Źródło:
Archiwum Historii i Filozofii Medycyny; 2011, 74; 29-36
0860-1844
Pojawia się w:
Archiwum Historii i Filozofii Medycyny
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Association between estrogen receptor alpha gene polymorphisms and bone mineral density in Polish female patients with Graves disease
Autorzy:
Ignaszak-Szczepaniak, Magdalena
Horst-Sikorska, Wanda
Dytfeld, Joanna
Gowin, Ewelina
Słomski, Ryszard
Stajgis, Marek
Powiązania:
https://bibliotekanauki.pl/articles/1039960.pdf
Data publikacji:
2011
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
Graves' disease
bone mineral density
ESR1 gene polymorphisms
premenopausal women
Opis:
Graves' (GD) hyperthyroidism leads to reduced bone mineral density (BMD) accompanied by accelerated bone turnover. Ample studies have identified association between estrogen receptor (ESR1) gene polymorphism and decreased BMD and osteoporosis. In contrast, number of publications that link ESR1, BMD and Graves' disease is limited. The purpose of this study was to identify the association between ESR1 polymorphisms and BMD in premenopausal women with GD and to determine whether ESR1 polymorphic variants can predispose to GD. The study included 75 women aged 23-46 years with GD and 163 healthy controls. BMD was measured at lumbar spine and femoral neck. We investigated two SNPs in the ESR1 gene and analyzed genetic variants in the form of haplotypes reconstructed by statistical method. Three out of four possible haplotypes of the PvuII and XbaI restriction fragment length polymorphisms were found in GD patients: px (55.3 %), PX (33.3 %) and Px (11.4 %). Women homozygous for xx of XbaI and for pp of PvuII had the lowest BMD at lumbar spine. Moreover, the px haplotype predisposed to reduced lumbar BMD. No associations were observed for femoral neck BMD. No statistically significant relationship were found between ESR1 polymorphisms or their haplotypes and GD. These results indicate that the PvuII and the XbaI polymorphisms of ESR1 gene are associated with bone mineral density in premenopausal women with GD and may help to estimate the risk of bone loss particularly at lumbar spine. However, none of the ESR1 gene alleles predict the risk of GD in Polish female patients.
Źródło:
Acta Biochimica Polonica; 2011, 58, 1; 101-109
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Training effects of Dahn Taekwondos Spondylitis Improvement Program on ankylosing spondylitis: a case study
Autorzy:
Jung, Sungwook
Park, Jusik
Johnson, John Arthur
Powiązania:
https://bibliotekanauki.pl/articles/1922195.pdf
Data publikacji:
2019-11-20
Wydawca:
PPHU Projack Jacek Wąsik
Tematy:
complementary and alternative medicine (CAM)
ankylosing spondylitis
C-reactive protein (CRP)
erythrocyte sedimentation rate (ESR)
Bath Ankylosing Spondylitis Metrology Index (BASMI)
Ki
Opis:
This case study applied the Dahn Taekwondo Spondylitis Improvement Program (DTSIP) to a 30-year-old male with ankylosing spondylitis five times a week for 28 weeks. Materials and Methods: A 32-year-old male with ankylosing spondylitis underwent the Dahn Taekwondo Spondylitis Improvement Program (DTSIP), an amalgamated program of standard Western medicine practices and complementary and alternative medicine (CAM) exercises based in the oriental medicine practices of yoga and taekwondo. The subject performed the DTSIP 5 times a week for 90 minutes for 28 weeks. Results: First, blood C-reactive protein (CRP), erythrocyte sedimentation rate (ESR), and platelet levels decreased by approximately 29-71%. Second, blood leukocyte counts decreased by about 11%. Third, as a result of Bath Ankylosing Spondylitis Metrology Index (BASMI) measurement, tragus to wall (TWD), lumbar side flexion (LSF), LF (lumbar flexion), and intermalleolar distance (IMD) were improved substantially. The students' cervical vertebrae and thoracic and lumbar vertebrae ranges of motion were additionally improved. The range of motion of the shoulder and hip joint improved. Conclusions: Therefore, the DTSIP seems to have a positive effect on the inflammation, immune functions, and spine and joint range of motion in the subject of this case study. Future studies are required with a wider sample population to validate these results.
Źródło:
Physical Activity Review; 2019, 7; 219-233
2300-5076
Pojawia się w:
Physical Activity Review
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study of Capacitor & Diode Aging effects on Output Ripple in Voltage Regulators and Prognostic Detection of Failure
Autorzy:
K, Preethi Sharma
Vijayakumar, T
Powiązania:
https://bibliotekanauki.pl/articles/2055277.pdf
Data publikacji:
2022
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Buck
MOSFET
ESR
SMPS
voltage ripple
Opis:
Objectives: To design and simulate a buck converter and detector circuit which can prognostically indicate the power supply failure. Failure of Aluminium Electrolytic Capacitor (AEC) is considered as the parameter causing the power supply failure. To analyse variation of output ripple voltage due to possible changes in the Equivalent Series Resistance (ESR) and effective capacitance of the capacitor and design a detector to detect the failure of power supply prognostically. Methods: A DC-DC buck converter in SMPS topology is designed by assuming an input voltage of 12V with 3 volts possible fluctuations and an output voltage of 3.3 volts is desired. Simulation is carried out to measure the variation in output ripple voltage caused due to aging of electrolytic capacitor using TINA by Texas Instruments. A detector is also designed to compare the ripple voltage and a predefined threshold voltage so as to indicate the possible failure of Switched Mode Power Supply (SMPS) well in advance by monitoring the output ripple increase. Novelty: Having a fault tolerant power supply is very important in safety critical applications. Here by monitoring the output ripple variation, the degradation of AEC is predicted by calculating the ESR and capacitance variation. This simple yet effective prognostic detection will support in the design of fault tolerant power supplies. Highlight: It is found that, the ripple at the output increases with aging of the electrolytic capacitor, as with time the equivalent capacitance decreases and Equivalent Series Resistance (ESR) of the capacitor increases. The designed detector output is found to prognostically indicate the failure of SMPS.
Źródło:
International Journal of Electronics and Telecommunications; 2022, 68, 2; 281--286
2300-1933
Pojawia się w:
International Journal of Electronics and Telecommunications
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Taurine-EVA copolymer-paraffin rods dosimeters for EPR high-dose radiation dosimetr
Autorzy:
Maghraby, A. M.
Mansour, A.
Abdel-Fattah, A. A.
Powiązania:
https://bibliotekanauki.pl/articles/147366.pdf
Data publikacji:
2014
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
EPR
ESR
radiation dosimetry
taurine
alanine
Opis:
Taurine/EPR rods (3 × 10 mm) have been prepared by a simple technique in the laboratory where taurine powder was mixed with a molten mixture of paraffin wax and an ethylene vinyl acetate (EVA) copolymer. The binding mixture EVA/Paraffin does not present interference or noise in the EPR signal before or after irradiation. The rods show good mechanical properties for safe and multi-use handling. An EPR investigation of radiation induced radicals in taurine rods revealed that there are two types of radicals produced after exposure to gamma radiation (60Co). EPR spectra were recorded and analyzed – also the microwave power saturation and modulation amplitude were studied and optimized. Response of taurine to different radiation doses (1.5–100 kGy) was studied and found to follow a linear relationship up to 100 kGy. Radiation induced radicals in taurine persists and showed a noticeable stability over 94 days following irradiation. Uncertainities associated with the evaluation of radiation doses using taurine dosimeters were discussed and tabulated. It was found that taurine possesses good dosimetric properties using EPR spectroscopy in high doses in addition to its simple spectrum.
Źródło:
Nukleonika; 2014, 59, 1; 9-13
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spin trapping studies of essential oils in lipid systems
Autorzy:
Makarova, K.
Drązikowska, K.
Suska, B.
Zawada, K.
Wawer, I.
Powiązania:
https://bibliotekanauki.pl/articles/147786.pdf
Data publikacji:
2015
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
spin trapping ESR
essential oils
DFT calculations
lipids
Opis:
In the present work, we report the results of a spin trapping ESR study of four essential oils widely used for skin care products such as creams and bath salts. The studied essential oils are Rosmarini aetheroleum (rosemary), Menthae piperitae aetheroleum (mint), Lavandulae aetheroleum (lavender), and Thymi aetheroleum (thyme). Fenton reaction in the presence of ethanol was used to generate free radicals. The N-tert- -butyl-α-phenylnitrone (PBN) was used as a spin trap. In the Fenton reaction, the rosemary oil had the lowest effect on radical adduct formation as compared to the reference Fenton system. Since essential oils are known to be lipid soluble, we also conducted studies of essential oils in Fenton reaction in the presence of lipids. Two model lipids were used, namely 1,2-dioleoyl-sn-glycero-3-phosphocholine (DOPC) and 1,2-dipalmitoyl-sn- -glycero-3-phosphocholine (DPPC). The obtained results suggested that in the presence of DOPC lipids, the •OH and PBN/•CHCH3(OH) radicals are formed in both phases, that is, water and lipids, and all the studied essential oils affected the Fenton reaction in a similar way. Whereas, in the DPPC system, the additional type of PBN/X (aN = 16.1 G, aH = 2.9 G) radical adduct was generated. DFT calculations of hyperfi ne splittings were performed at B3LYP/6-311+G(d,p)/EPR-II level of theory for the set of c-centered PBN adducts in order to identify PBN/X radical.
Źródło:
Nukleonika; 2015, 60, No. 3, part 1; 461-468
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The impact of humic substances on the liposome structures : ESR method
Autorzy:
Man, D.
Pisarek, I.
Braczkowski, M.
Powiązania:
https://bibliotekanauki.pl/articles/147392.pdf
Data publikacji:
2013
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
EYL liposome
ESR method
humic substances
Opis:
In this paper the changes of membrane fluidity of liposome with additions of humic substances (humic and fulvic acids) were examined. Liposome were done by the sonication of lecithin EYL. Concentrations of humic substances in attitude to EYL varied between 0–10% of weight. The technique of electron spin resonance (ESR) were used for the examination followed by three spin probes with a variety placement of the membrane located. TEMPO probe melted in the hydrophobic membrane and in the aquatic solution which allowed to determine the spectroscopic partition parameter (F), indicating the changes that occur in water-lipid interphase. Probe 5-DOXYL placed directly under the heads of polar lipids and the order parameter measuring by the TII showed the changing of membrane fluidity at surface area. 16-DOXYL probe penetrated the middle of the lipid bilayer membrane and allowed to determine the rotational correlation time τ parameter, which gives us information about changing of the liquidity lipid bilayer. Studies showed that the tested humic substances significantly changed the membrane fluidity of liposome. The dynamics of this process depends on both: the fraction of humic substances and its quality and quantity as well as the placement area of the membrane.
Źródło:
Nukleonika; 2013, 58, 3; 439-442
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The influence of selected amino acids on the dynamic properties of the liposome membranes : ESR study
Autorzy:
Man, D.
Broda, M.
Buczek, A.
Kawecka, A.
Siodłak, D.
Powiązania:
https://bibliotekanauki.pl/articles/146690.pdf
Data publikacji:
2013
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
EYL liposomes
electron spin resonance (ESR) method
N-methylation
amino acids
peptides
Opis:
In this work the changes in the fluidity of liposome membranes caused by alanine and butyrine derivatives (Ac-Ala-NMe2 and Ac-Abu-NMe2) were investigated. Liposomes were obtained in the process of egg yolk lecithin (EYL) sonication. The concentration of the admixture in the proportion to EYL varied from 0 to 25% mole. The electron spin resonance (ESR) spectroscopy was used with two different spins probes. Each spin probe penetrates different regions of liposome membrane. The TEMPO probe occurs both in the hydrophobic part of the membrane and in the water environment what allows to determine the spectroscopic parameter F of division of this probe into the membrane and its water surrounding. DOXYL is localized in the central part of the lipid bilayer and is used to obtain the spectroscopic parameter τ – rotation correlation time – whose value gives information about fluidity changes in the middle of the lipid bilayer. The study indicated that the tested as admixtures N-methylated model peptides significantly changed the fluidity of liposome membranes. The dynamic of this process depends both on amino acids derivative and on the membrane region. Both studied compounds increased the fluidity of the surface layer of liposome membrane. At the same time, butyrine derivative caused the stiffening of the middle part of liposome bilayer, but alanine derivative slightly increased the fluidity of this region.
Źródło:
Nukleonika; 2013, 58, 3; 443-446
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The last Middle Pleistocene interglacial in Lithuania: insights from ESR-dating of deposits at Valakampiai, and from stratigraphic and palaeoenvironmental data
Autorzy:
Molodkov, A.
Bolikhovskaya, N.
Gaigalas, A.
Powiązania:
https://bibliotekanauki.pl/articles/2059885.pdf
Data publikacji:
2002
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Lithuania
Middle Pleistocene
Snaigupele Interglacial
OIS 7
ESR dating
mollusc shells
palynostratigraphy
correlation
Opis:
The penultimate (Snaigupele, oxygen isotope stage (OIS) 7) interglacial has proved controversial in Lithuania because of palynological similarities between Holsteinian, SnaigupĹlĹ and Eemian interglacial deposits in the Lithuanian terrestrial record. Furthermore, no warm interglacial period has been recognised between the Holsteinian (OIS 11) and Eemian (OIS 5) in the neighbouring Baltic countries, Estonia and Latvia. In this study, we provide electron spin resonance (ESR) dates of two freshwater mollusc shell samples collected from lacustrine sediments at the Valakampiai site which are thought to be Snaigupele in age. Shells analysed gave mutually consistent dates of 116.0 š 10.8 and 110.0 š 12.1 ka with an average age of about 113.3 ka. These dates are thus significantly younger than OIS 7, and more closely correspond to OIS 5 (Eemian). The possible occurrence of this late Middle Pleistocene OIS 7 interglacial episode in Lithuania and other Baltic countries is evaluated with reference to the nearest and most complete long terrestrial sequences from the central and southeastern parts of the East-European Plain.
Źródło:
Geological Quarterly; 2002, 46, 4; 363-375
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Impact of humic acids on EYL liposome membranes : ESR method
Autorzy:
Pytel, B.
Filipiak, A.
Pisarek, I.
Olchawa, R.
Man, D.
Powiązania:
https://bibliotekanauki.pl/articles/146924.pdf
Data publikacji:
2015
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
EYL liposomes
ESR method
humic substances
Opis:
In this paper, the effects of model (commercial) and natural (extracted from peat) humic substances on the membrane of liposomes formed with egg yolk lecithin (EYL) are presented. In our research, mass concentrations of fulvic and humic acids were used, which in relation to lecithin varied from 0% to 13%. To study membrane fluidity, electron spin resonance (EPR) was used with two spin probes, penetrating various regions of the lipid bilayer. The effects of model and natural humic substances (humic acids – HAs and fulvic acids – FAs) on the lipid membrane in different regions were researched: the lipid-water interphase, and in the middle of the lipid bilayer. It was shown that FA and HA impact the fluidity of liposome membranes in different ways. Increased mass concentrations of HAs decreased membrane fluidity in both acids: extracted from peat and the model. However, increased mass concentration of FAs extracted from peat, decreased membrane fluidity in the surface region, at the same time stiffening the central part of the bilayer. Increasing the concentration of FAs extracted from peat had the opposite effect when compared to model FA. This effect may be related to the complexation of xenobiotics present in the soil environment and their impact on biological membranes.
Źródło:
Nukleonika; 2015, 60, No. 3, part 1; 455-459
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
In situ methanolic solvent synthesis, spectroscopic and thermogravimetric characterizations of three new transition metal complexes of trimethoprim drug
Autorzy:
Refat, Moamen S.
Al-Humaidi, Jehan Y.
El-Sayed, Mohamed Y.
Hassan, Reham F.
Powiązania:
https://bibliotekanauki.pl/articles/1849325.pdf
Data publikacji:
2021
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
complexation
trimethoprim
transition metals
TGA
thermogravimetric analysis
FTIR
Fourier transform infrared spectroscopy
ESR
kinetic thermodynamic parameters
Opis:
Trimethoprim drug (TMP) complexes of copper (II), cobalt (II), and nickel (II) were prepared and discussed by using elemental analysis (C, H, N analysis), magnetic, molar conductance, FTIR, Raman spectroscopy, electron spin resonance (ESR) and UV-vis spectroscopy analyses. TMP drug coordinated as a tridentate ligand towards the respected three metal ions through two nitrogen atoms of amino groups and nitrogen atom of pyrimidine ring which flanked between –NH2 groups, these assignments confirmed by spectroscopic, magnetic, ESR and thermogravimetric analyses with formulas [Cu(TMP)(H2O)3]Cl2, [Co(TMP)(H2O)3]Cl2 and [Ni(TMP) (H2O)]Cl2. Copper (II) and cobalt (II) complexes have an octahedral geometrical structure included one TMP molecule, three coordinated water molecules and two uncoordinated chlorine atoms while, nickel(II)–TMP complex has a tetrahedral geometric configuration that involved one TMP molecule, one coordinated water molecule and two uncoordinated chlorine atoms. The activation energies and other kinetic thermodynamic parameters were estimated based on the employed of the Coats-Redfern and Horowitz-Metzger equations. The nano–structured form of the synthesized TMP complexes was confirmed dependent on the transmission electron microscopy (TEM).
Źródło:
Polish Journal of Chemical Technology; 2021, 23, 1; 60-67
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and spectroscopic interpretations of Co(II), Ni(II) and Cu(II) decxycholate complexes with molecular docking of COVId-19 protease
Autorzy:
Refat, Moamen S.
Bakare, Safyah B.
Altalhi, Tariq A.
Alam, Kehkashan
Al-Hazmi, Ghaferah H.
Powiązania:
https://bibliotekanauki.pl/articles/1849269.pdf
Data publikacji:
2021
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
deoxycholic acid
complexes
ESR
TGA/DSC
molecular docking
Opis:
Co(II), Ni(II) and Cu(II) decxycholate complexes are interesting due to their biologically active and deliberate interest in the research due to their coordination properties. The microanalytical ‘elemental analysis’, molar conductivity, (infrared and Raman) spectroscopy, thermal analyses (TGA/DSC), UV-vis spectra, and ESR for copper(II) decxycholate complex investigations were performed in the structural assignments of Co(II), Ni(II) and Cu(II) decxycholate complexes. Reaction of the sodium deoxycholate ligand (C24H39O4Na) with three transition metal ions form the complexes of formulae, [M(C24H39O4)2(H2O)2] . xH2O where M = Co(II), Ni(II) and Cu(II) where x = 2 for Cu(II) and x = 4 in case of M = Co(II) or Ni(II) metal ions. The FTIR spectra of the complexes show that decxycholate molecule is present as bidentate ligand. Molecular docking utilizing to additionally examine the interaction of COVID-19 (6LU7) with different complexes of deoxycholic acid with Co(II), Ni(II) and Cu(II). Furthermore, in the case of Co(II) deoxycholate complex, the probe is surrounded by amino residues Met235, Pro241, Glu240, Pro108, Gln110, Phe294, and Ile152. The probe molecule of Ni(II) deoxycholate complex is sited close to amino acids Tyr126, Tyr239, Leu287, Leu272, and Lys137. For, Cu(II) deoxycholate complex, the residues of amino acids comprise of Pro132, Pro108, Gln110, Gly109, Ile200, Asn203, Val202, His246, Pro293 and Tyr154. The binding energy was determined from the docking reads for Co(II)–6LU7, Ni(II)–6LU7 and Cu(II)–6LU7 deoxycholate compounds were found to be −446.99, −500.52, −398.13 kcal mol−1 individually.
Źródło:
Polish Journal of Chemical Technology; 2021, 23, 2; 54-59
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 23

Ta witryna wykorzystuje pliki cookies do przechowywania informacji na Twoim komputerze. Pliki cookies stosujemy w celu świadczenia usług na najwyższym poziomie, w tym w sposób dostosowany do indywidualnych potrzeb. Korzystanie z witryny bez zmiany ustawień dotyczących cookies oznacza, że będą one zamieszczane w Twoim komputerze. W każdym momencie możesz dokonać zmiany ustawień dotyczących cookies