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Tytuł:
Application of multifunctional fluids to improve hydrocarbon production
Autorzy:
Knapik, E.
Stopa, J.
Powiązania:
https://bibliotekanauki.pl/articles/299010.pdf
Data publikacji:
2013
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
foam
gas wells dewatering
corrosion inhibitor
synergism
Opis:
In the course of the mature gas fields exploitation there are many technical problems including the corrosion damage, formation of hydrates and water cut. In many cases, an effective solution of these problems is the dosage of appropriately selected chemicals. Commercially available corrosion inhibitors, hydrate inhibitors, demulsifiers and foaming agents are injected in a form of single, multifunctional mixture through one liner which reduces injection costs. The paper presents the results of laboratory tests, which aim was to investigate synergism and antagonism in multifunctional mixture containing different commercially available surfactants, corrosion and hydrate inhibitors. Correlations between final product composition and performances such as liquid unloading efficiency, corrosion protection and pour point were studied. The described approach allows to adapt the tertiary mixture composition (foaming agent + corrosion inhibitor + hydrates inhibitor) to the current production conditions. The polarization behavior of electrodes in brines with and without mixture of additives has been studied by a cyclic voltammetric method. The addition of increasing concentrations of each chemicals causes the reduction in the corrosion current density. The measurements using a modified method of the US Bureau of Mines show synergistic effect of surfactants and corrosion inhibitor on foamabilities. Multifunctional mixtures are stable under storage conditions and not cause any compatibility problems with reservoir fluids.
Źródło:
AGH Drilling, Oil, Gas; 2013, 30, 1; 117-125
2299-4157
2300-7052
Pojawia się w:
AGH Drilling, Oil, Gas
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Impact assessment of effectiveness of thiourea and THAM for corrosion process on carbon steel in calcium chloride environment
Autorzy:
Malinowski, S.
Jaroszyńska-Wolińska, J.
Powiązania:
https://bibliotekanauki.pl/articles/390655.pdf
Data publikacji:
2016
Wydawca:
Politechnika Lubelska. Wydawnictwo Politechniki Lubelskiej
Tematy:
corrosion inhibitor
thiourea
THAM
carbon steel
anticorrosive properties
Opis:
The main objective of this paper is to present a comparison of the corrosion inhibiting effect of thiourea and THAM (tri(hydroxymethyl)aminomethane) on carbon steel samples immersed in calcium chloride solutions. The testing has shown that to inhibit the corrosive action of the calcium chloride solution, the thiourea solution can be successfully replaced by the THAM solution. The study was performed with the use of st3s, structural and reinforcing steel. In the case of st3s steel samples, the application of the 0.01% THAM solution causes a decrease of its weight loss by about 60%. The application of a 10-times stronger THAM solution causes an increase of the corrosion inhibition on the tested samples by about 20%. A combined protective action of the thiourea and THAM solutions brings about an increase of the corrosion process inhibition by about 70% both for the st3s and the structural samples. The 0.01% and 0.1% THAM solutions applied to inhibit the corrosion process on structural samples cause an increase of the corrosion protection by about 50% and 15% respectively.
Źródło:
Budownictwo i Architektura; 2016, 15, 2; 65-72
1899-0665
Pojawia się w:
Budownictwo i Architektura
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption and corrosion inhibition behavior of stainless steel 316 by aliphatic amine compounds in acidic solution
Adsorpcja i hamowanie korozji stali nierdzewnej 316 przez alifatyczne związki aminowe w kwaśnym roztworze
Autorzy:
Goudarzi, N.
Peikari, M.
Reza Zahri, M.
Reza Mousavi, H.
Powiązania:
https://bibliotekanauki.pl/articles/356447.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
korozja
stal nierdzewna
Armohib 28
corrosion inhibitor
stainless steel 316
Opis:
Gravimetric and electrochemical measurements were performed to investigate the effectiveness of an aliphatic amine compound with trade name of Armohib 28. It was found that the percentage inhibition efficiency increased with the increase of the compound concentration. Polarization curves indicate that the inhibitor under investigation acts as cathodic type which retards the rate of corrosion reactions by adsorbing on to the steel surface according to Langmuir adsorption isotherm. The activation energy and thermodynamic parameters were calculated and analyzed. The data obtained from electrochemical impedance spectroscopy (EIS) were analyzed to model the corrosion inhibition process through equivalent circuit.
W celu zbadania skuteczności alifatycznego związku aminowego o nazwie handlowej Armohib 28 przeprowadzono pomiary grawimetryczne i elektrochemiczne. Stwierdzono, że procentowa skuteczność hamowania wzrosła wraz ze wzrostem stężenia związku. Krzywe polaryzacji wskazują, że badany inhibitor działa jak inhibitor typu katodowego, który opóźnia szybkość reakcji korozji adsorbując na powierzchni stali według izotermy adsorpcji Langmuira. Energia aktywacji i parametry termodynamiczne zostały obliczone i analizowane. Dane uzyskane z elektrochemicznej spektroskopii impedancyjnej (EIS) wykorzystano do modelowania procesu hamowania korozji przy użyciu obwodu zastępczego.
Źródło:
Archives of Metallurgy and Materials; 2012, 57, 3; 845-851
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Organiczne związki fosfinowe, jako inhibitory korozji stali zbrojeniowej w betonie skażonym jonami chlorkowymi
Phosphinium compounds as corrosion inhibitors for reinforcement in chloride-rich environments
Autorzy:
Klakočar-Ciepacz, M.
Kotlarz, M.
Falewicz, P.
Powiązania:
https://bibliotekanauki.pl/articles/161871.pdf
Data publikacji:
2014
Wydawca:
Polski Związek Inżynierów i Techników Budownictwa
Tematy:
beton
korozja zbrojenia
chlorki
inhibitor korozji
związek fosfinowy
concrete
reinforcement corrosion
chlorides
corrosion inhibitor
phosphinium compound
Opis:
W artykule przedstawiono wyniki badań metodą potencjodynamiczną i spektroskopii impedancyjnej (EIS) skuteczności ochrony przed korozją stali zbrojeniowej w roztworze symulującym ciecz porową betonu skażonego jonami chlorkowymi za pomocą opracowanego preparatu inhibitorowego. Preparat inhibitorowy jest mieszaniną kwasu dietyloaminometylo( heksa-metylenoiminometylo)fosfinowego, kwasu cytrynowego i siarczanu cynku. Stwierdzono, że opracowany preparat inhibitorowy chroni przed korozją stal zbrojeniową ze skutecznością 66,6% (obniża szybkość korozji do wartości 0,014 mm/rok), a charakter jego działania jest mieszany katodowo-anodowy.
The effectiveness of corrosion protection of the dietyloaminometylo(heksametylenoimino-metylo)phosphine acid and its mixture with citric acid and zinc sulfate in a pore simulating solution with Cl- ions for reinforcing bar was calculated by use both methods: the pototentiodynamic test and impedance spectroscopy (EIS). The effectiveness of corrosion protection for reinforcing bar by developed inhibitive mixture is 66.6% (corrosion rate 0,014 mm/yr.). The inhibitive mixture behaves as mixed inhibitor: cathodic-anodic.
Źródło:
Przegląd Budowlany; 2014, R. 85, nr 5, 5; 40-42
0033-2038
Pojawia się w:
Przegląd Budowlany
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Olej ochronny o niskiej lepkości do czasowej ochrony elementów metalowych przed korozją
Low viscosity protective oil for temporary protection of metal components against corrosion
Autorzy:
Ziółkowska, Monika
Frydrych, Jarosław
Powiązania:
https://bibliotekanauki.pl/articles/1833974.pdf
Data publikacji:
2020
Wydawca:
Instytut Nafty i Gazu - Państwowy Instytut Badawczy
Tematy:
korozja
olej ochronny
czasowa ochrona
lepkość
elementy metalowe
inhibitor korozji
corrosion
protective oil
temporary protection
viscosity
metal components
corrosion inhibitor
Opis:
Corrosion of metals is the gradual destruction of metal under the impact of environmental factors. Chemical or electrochemical processes on the surface of the metal cause irreversible changes in the structure of the metal. To prevent this, during storage or transport, the surfaces of metal elements must be protected against environmental factors, which include: high air humidity, acid rain and variable temperature. These factors accelerate the corrosion process, which cannot be eliminated, but can be reduced by protecting metal elements with e.g. protective oils. Some metals have the ability to passivate, which is a natural protective agent that prevents corrosion. It consists in the formation of an oxide of this metal on the metal surface. Where there is no natural protection against corrosion, protective measures must be used. This paper presents the technology for the production of protective oil for temporary protection against corrosion. The innovation of this project is that the oil will form a thin, well adhering protective layer on the metal surface, which can be easily removed. It is characterised by very low viscosity and low dripping time. It is possible to achieve by using proper base oil with carefully selected anti-corrosion additives. Based on the standard PN-75/C-04154 Petroleum products. Rust protection by metal preservatives the humidity cabinet test method, corrosion tests were carried out. The paper presents the results of a humidity cabinet test for an oil mixture based on deeply refined base oil and properly selected refining additives. The test results confirmed very good anti-corrosive properties of the developed oil due to the use of a corrosion inhibitor and an oxidation inhibitor. The thickness of the protective layer formed on the metal surface was calculated based on a mathematical formula. The resulting layer forms a thin oil film, easy to remove and protecting the metal surface from corrosion.
Źródło:
Nafta-Gaz; 2020, 76, 11; 864--869
0867-8871
Pojawia się w:
Nafta-Gaz
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Investigation of Corrosion Inhibitors by Nuclear Quadrupole Resonance Relaxometry Method
Autorzy:
Sinyavsky, N. Y.
Mershiev, I. G.
Korneva, I. P.
Powiązania:
https://bibliotekanauki.pl/articles/117155.pdf
Data publikacji:
2015
Wydawca:
Uniwersytet Morski w Gdyni. Wydział Nawigacyjny
Tematy:
corrosion inhibitor
Nuclear Quadrupole Resonance (NQR)
nuclear magnetic resonance (NMR)
Regularized Inverse Laplace Transform (RILT)
Inhibition
corrosion
Relaxation Time Distribution
Nuclear Magnetization Diffusion
Opis:
The changes taking place with the corrosion-resistant coating, but not the state of the surface subjected to corrosion are investigated in this paper in contrast to traditional approaches. We used the method of nitrogen relaxometry NQR and multi-exponential inversion of decay of longitudinal and transverse components of the nuclear magnetization is applied for the first time for this purpose. The results of experimental studies of changes in the distributions of spin-spin and spin-lattice relaxation of crystallite powder of sodium nitrite and urotropin, the mixture of which is used as a corrosion inhibitor of ferrous metals are considered.
Źródło:
TransNav : International Journal on Marine Navigation and Safety of Sea Transportation; 2015, 9, 4; 587-590
2083-6473
2083-6481
Pojawia się w:
TransNav : International Journal on Marine Navigation and Safety of Sea Transportation
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Investigation of the inhibitory-bactericidal effect of amidoamine-based inorganic complexes against microbiological and atmospheric corrosion
Autorzy:
Aghazada, Y.J.
Abbasov, V.M.
Mursalov, N.I.
Abdullayev, S.E.
Yolchuyeva, U.J.
Powiązania:
https://bibliotekanauki.pl/articles/778541.pdf
Data publikacji:
2020
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
corrosion
inhibitor
bactericide
adsorption
amidoamine
Opis:
In the process, inorganic complexes of amidoamines obtained from the interaction of natural petroleum acid and oleic acids with diethylenetriamine have been developed and their effectiveness as inhibitor-bactericides has been investigated. The effect of the synthesized reagents on the kinetics of the corrosion process of steel and the activity of sulphate-reducing bacteria in 3% NaCl solution saturated with CO2 and in the biphasic water–isopropyl alcohol medium with H2S dissolved has been analyzed. The thermodynamic and kinetic parameters of the corrosion process were calculated. The adsorption of the complexes was investigated using the Langmuir isotherm and the correlation constant was determined. State of the metal surface was investigated by SEM method in CO2 and H2S media, with and without inhibitors, and the metal surface contact of complexes was studied by computer molecular simulation.
Źródło:
Polish Journal of Chemical Technology; 2020, 22, 3; 29-37
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Photochemical screening and corrosion inhibition of Poupartia birrea back extracts as a potential green inhibitor for mild steel in 0.5 M H2SO4 medium
Autorzy:
Louis, H.
Japari, J.
Sadia, A.
Philip, M.
Bamanga, A.
Powiązania:
https://bibliotekanauki.pl/articles/1118151.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Poupartia birrea
corrosion
inhibitor
mild steel
Opis:
Corrosion of metals is a serious environmental problem and has been given much attention in the oil and gas industries. In several industrial processes (acid cleaning and etching, removal of rust and scale), metal surfaces are often made to come in contact with acids. In the present study, an attempt was made to examine Poupartia birrea (P. birres) back extract as a potential green corrosion inhibitor for mild steel in a 0.5 M H2SO4 medium, using the weight loss determination method. The results of our work indicate that highest inhibition efficiency exhibited by Poupartia birrea is 70%. The inhibiting effect of the studied extract could be attributed to the presence of phytochemical constituents present in the extract that are adsorbed on the surface of the mild steel. The plant extract can, hence, be considered as being eco-friendly and an effective green corrosion inhibitor for mild steel exposed to an acid medium.
Źródło:
World News of Natural Sciences; 2017, 10; 95-100
2543-5426
Pojawia się w:
World News of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Optimization of corrosion inhibition of Picralima nitida leaves extract as green corrosion inhibitor for zinc in 1.0 M HCl
Autorzy:
Ezeugo, J. N. O.
Onukwuli, O. D.
Omotioma, M.
Powiązania:
https://bibliotekanauki.pl/articles/1113582.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Picralima nitida
Zinc
corrosion
inhibitor
optimization
Opis:
Herein, the optimization of inhibitive action of the ethanol extract of oil from Picralima nitida leaves, towards acid corrosion of zinc, was tested using weight loss and thermometry methods. We found that the extract acts as a good corrosion inhibitor for zinc corrosion in 0.1 M HCl solutions. The inhibition action of the extract was discussed in view of Langmuir adsorption isotherm. This revealed that spontaneous processes govern the adsorption of the extract on zinc surface. Herein, the inhibition efficiency (IE) increases in line with corresponding increase in extract concentration. The temperature effect of the corrosion inhibition on the IE was also studied. This indicated that the presence of the extract increases the needed activation energy of the corrosion reaction. Furthermore, in our work, an optimal inhibition efficiency IE (%) of 86.78 was obtained at optimum inhibitor concentration of 1.2 gl-1, optimum temperature and time of 313 k and 8 hrs, respectively. From the calculated thermodynamic parameters, it can be said, then, that Picralima nitida extract provides good protection to zinc against pitting corrosion in chloride ion containing solutions.
Źródło:
World News of Natural Sciences; 2017, 15; 139-161
2543-5426
Pojawia się w:
World News of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Investigation on Corrosion Inhibition of Hura Crepitans for 2101 Duplex Stainless Steel in an Acidic Environment
Autorzy:
Temitayo, Ogunmodede O.
Vawe, Humwapwa
Johnson, Jonathan
Adewole, Ezekie
Ilesanmi, Osasona
Powiązania:
https://bibliotekanauki.pl/articles/2201784.pdf
Data publikacji:
2022
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
corrosion
steel
Hura crepitans
inhibitor
sulphuric acid
Opis:
Corrosion is a global menace which has imparted the world economy greatly. One of the solutions proffered to these challenges is the use of inhibitors. Several natural inhibitors have been used to protect engineering materials from corroding. This research is focused on investigating the inhibitive properties of Hura crepitans seed (HCS) on Duplex Stainless Steel 2101 (DSS2101) in H2SO4. The selected plant part was subjected to characterization to determine the presence of organic anti-corrosion agents present. From the result, phytochemicals such as saponin, tannins, steroid and flavonoids were observed. The presence of the organic group accounted for the inhibitive efficiency recorded in the environment. The polarization studies revealed that generally the inhibitor produced from seed extract of Hura crepitans, improved the corrosion resistance of DSS2101 in 0.5M H2SO4. The optimum corrosion inhibitor efficiency was observed at 0.2% inhibitors in 0.5M H2SO4 for 2101DSS.
Źródło:
Advances in Science and Technology. Research Journal; 2022, 16, 4; 56--63
2299-8624
Pojawia się w:
Advances in Science and Technology. Research Journal
Dostawca treści:
Biblioteka Nauki
Artykuł
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