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Tytuł:
3D block modelling of the Sin Quyen IOCG deposit, North Vietnam
Autorzy:
Hao, Duong Van
Nguyen, Dinh Chau
Klityński, Wojciech
Zygo, Władysław
Nowak, Jakub
Powiązania:
https://bibliotekanauki.pl/articles/27310153.pdf
Data publikacji:
2023
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
North Vietnam
iron oxide copper deposits
3D model
resources
deposit development
Opis:
The IOCG Sin Quyen deposit is located in the Red River shear zone of North Vietnam. The ore bodies are known as hydrothermal veins and are hosted in Proterozoic metapelite. A block modelling approach was used to build a 3D model of the ore bodies. An analysis was carried out on Surfer 11 computer software using the archival data recorded from several dozen boreholes distributed within the study area, as well as data obtained from the mineral and chemical analysis of 50 samples collected recently in the deposit. The ore bodies generally trend in a NW-SE direction with an average azimuth of 107° and dip of around 70°.The Cu content in the ore bodies is inhomogeneous. In the bed extension direction, the exponential correlation of Cu concentration in ore bodies is recognized within 2,500 m, while in the direction perpendicular to the bed strike, the exponential dependence is observed on 500 m of distance. The high-grade mineralisation of copper within the ore bodies is often at the altitude interval from ∼100 m to ∼150 m above sea level (asl). These bodies are also rich in uranium and gold bearing minerals. The total resources of Cu, U and Ag were estimated and amount to 361,000; 12.7 and 11.87 tonnes respectively. The model indicates the downward extension of some ore bodies to below 300 m beneath the ground surface.
Źródło:
Geology, Geophysics and Environment; 2023, 49, 2; 175--195
2299-8004
2353-0790
Pojawia się w:
Geology, Geophysics and Environment
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A successful operational initiative in copper oxide flotation: Sequential sulphidisation-flotation technique
Autorzy:
Asadi, Moharram
Soltani, Faraz
Mohammadi, Mohammad Reza Tavakoli
Khodadadi, Darban Ahmad
Abdollahy, Mahmoud
Powiązania:
https://bibliotekanauki.pl/articles/110770.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
copper oxide
sulphidisation
flotation
Opis:
One of the main challenges in the copper oxide processing industry is implementation of a flotation method to reduce operating costs. Sulphidising flotation is the most common used technique in which a sulphidisation agent is used to sulphidise the surface of the oxide minerals. In this research, the mentioned technique was used sequentially for the concentration of silicate-carbonate ore containing 3.1% Cu (malachite). The presence of 39% Cu in -38 μm size fraction (fine particles) of feed led to poor grades and recoveries in the initial tests. The addition of sodium sulfide and subsequent flotation at three sequential stages was identified as a successful operational initiative to solve this problem in the following tests. The dosages of 1500, 1567 and 100 g/Mg of sodium silicate, sodium sulfide and potassium amyl xanthate, respectively, the conditioning time of 5 min for sulphidisation and pH=9.72 were chosen as optimum operational conditions using central composite design (CCD) method of experiments design. The rougher concentrate with 9.28% grade and 81.15% recovery was obtained under these conditions. The grade of obtained concentrate was reached to 24% in the cleaner step. The total recovery of both steps was over 74%.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 2; 356-369
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
aaSolar cells based on copper oxide and titanium dioxide prepared by reactive direct-current magnetron sputtering
Autorzy:
Wisz, G.
Sawicka-Chudy, P.
Sibiński, M.
Starowicz, Z.
Płoch, D.
Góral, A.
Bester, M.
Cholewa, M.
Woźny, J.
Sosna-Głębska, A.
Powiązania:
https://bibliotekanauki.pl/articles/1818199.pdf
Data publikacji:
2021
Wydawca:
Polska Akademia Nauk. Stowarzyszenie Elektryków Polskich
Tematy:
solar cells
copper oxide
titanium dioxide
reactive magnetron sputtering
Opis:
In this study, solar cells based on copper oxide and titanium dioxide were successfully manufactured using the reactive direct-current magnetron sputtering (DC-MS) technique with similar process parameters. TiO₂/CuO, TiO₂/Cu₂O/CuO/Cu₂O, and TiO₂/Cu₂O solar cells were manufactured via this process. Values of short-circuit current efficiencies, short-circuit current density, open-circuit voltage, and maximum power of PV devices were investigated in the range of 0.02÷0.9%, 75÷350 µA, 75÷350 µA/cm², 16÷550 mV, and 0.6÷27 µW, respectively. The authors compare solar cells reaching the best and the worst conversion efficiency results. Thus, only the two selected solar cells were fully characterized using I-V characteristics, scanning electron microscopy, X-ray diffraction, ellipsometry, Hall effect measurements, and quantum efficiency. The best conversion efficiency of a solar cell presented in this work is about three times higher in comparison with the authors’ previous PV devices.
Źródło:
Opto-Electronics Review; 2021, 29, 3; 97--104
1230-3402
Pojawia się w:
Opto-Electronics Review
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analysis of chemical and phase composition of copper oxide prepared by direct current sputtering for photovoltaic applications
Autorzy:
Sawicka-Chudy, P.
Wielgosz, M.
Wal, A.
Cieniek, B.
Wisz, G.
Głowa, Ł.
Cholewa, M.
Sawicka, J.
Powiązania:
https://bibliotekanauki.pl/articles/101735.pdf
Data publikacji:
2018
Wydawca:
Instytut Polityki Energetycznej im. Ignacego Łukasiewicza
Tematy:
XRF
XRD
copper oxide
photovoltaics
Opis:
This paper presents the application of X-ray fluorescence and X-ray diffraction methods for the study of copper oxide structures as an absorber layer in thin-film solar cells. The layers of copper oxide were applied by direct current magnetron sputtering. Quantitative and qualitative analysis of oxide layers were performed using XRF (X-ray fluorescence). The studies showed a high copper content in both samples, amounting to 98% and 96%, as well as trace amounts of other elements (nickel, lead). The XRD (X-ray diffraction) study showed Cu20 and Cu8O phases, amorphism ranging from 24% to 44%, and crystallinity from 55% to 75%. Crystallites of 30 nm were also determined. The aim of the study was to determine the chemical and phase composition of the layers obtained and to determine the degree of their contamination depending on the parameters of the manufacturing technology in terms of their application in photovoltaics. One of the samples showed an advantage both in terms of material and structural composition.
Źródło:
Energy Policy Studies; 2018, 1 (2); 3-11
2545-0859
Pojawia się w:
Energy Policy Studies
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Anodic growth of copper oxide nanostructures in glow discharge
Autorzy:
Breus, A.
Abashin, S.
Lukashov, I.
Serdiuk, O.
Powiązania:
https://bibliotekanauki.pl/articles/2201134.pdf
Data publikacji:
2022
Wydawca:
Stowarzyszenie Komputerowej Nauki o Materiałach i Inżynierii Powierzchni w Gliwicach
Tematy:
nanotechnology
plasma synthesis
copper oxide nanostructure
glow discharge
nanotechnologia
synteza plazmowa
nanostruktura tlenku miedzi
wyładowanie jarzeniowe
Opis:
Purpose: Application of plasma glow discharge to copper oxide nanostructure growth is studied. The simplicity of the proposed technique may be beneficial for the development of new plasma reactors for large-scale production of diverse metal oxide nanostructures. Design/methodology/approach: Copper sample was placed on anode of a setup designed to ignite plasma glow discharge. The proposed approach allows eliminating the negative effects of ion bombardment, like sputtering and generation of defects on a surface of the growing nanostructures, but preserves the advantages of thermal growth. The growth process was explained in terms of thermal processes interaction occurring on a surface of the anode with the glow discharge plasma. Findings: Plasma treatment resulted in generation of reach and diverse nanostructures that was confirmed by SEM images. Nanowire-like, flower-like, anemone-like nanostructures and nanodisks composed into the nanoassemblies are observed; the nanostructures are associated with microbabbles on CuO layer. These findings allow concluding about the possible implementation of the proposed method in industry. Research limitations/implications: The main limitation is conditioned by the lack of heat supplied to the anode, and absence of independent control of the heat and ion fluxes; thus, the additional heater should be installed under the anode in order to expand the nomenclature of the nanospecies in the future studies. Practical implications: High-productivity plasma process in copper oxide nanostructures synthesis was confirmed in this research. It may be applied for field emitter and supercapacitor manufacturing. Originality/value: Oxide nanostructure synthesis is conducted by use of a simple and well-known glow discharge technique in order to expand the production yield and diversity of nanostructure obtained in the processes of thermal growth.
Źródło:
Archives of Materials Science and Engineering; 2022, 113, 3; 24--33
1897-2764
Pojawia się w:
Archives of Materials Science and Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Antiviral Activities of Cu2+ Ions in Viral Prevention, Replication, RNA Degradation, and for Antiviral Efficacies of Lytic Virus, ROS-Mediated Virus, Copper Chelation
Autorzy:
Ishida, Tsuneo
Powiązania:
https://bibliotekanauki.pl/articles/1177808.pdf
Data publikacji:
2018
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Capsid protein
Copper chelation
Copper homeostasis
Copper oxide nanoparticles
Cu2+ and Cu1+ ions
DNA/RNA virus
HSV
ROS
Viral replication
mRNA degradation or decay
Opis:
Copper has been known for decades that marked changes of micronutrient homeostasis in the host are accompanied by infection or inflammation. Copper levels in the serum are significantly elevated in response to inflammation that copper accumulates at sites of inflammation. Easily oxidized copper oxide nanoparticles (CuONPs) are widely used as catalysts that the ability of CuONPs to reduce bacterial population and virus application is enhanced. The mechanism of copper-mediated inactivation of herpes simplex virus (HSV) is by which cupric ions oxidatively damage biomolecules. Virus-mediated subjugation and modulation of host lipids during infection that the life cycle of most viruses proceeds through a series of basic steps: binding and internalization, fusion, uncoating, of the viral genome, its replication, assembly of new particles, and budding or release of the newly made viruses. The HIV-1 protein Vpu is an 81-amino-acid (16-kDa) type I which the presence of Vpu leads to the degradation of BST-2 via an endosome-lysosome degradation pathway. Oxidative degradation by a Cu-metalloenzyme, and ubiquitin-mediated degradation of cellular proteins were exploited. Copper can disrupt the lytic cycle of the Coccolithovirus. Lysins represent a novel class of anti-infectives derived from bacteriophage which lysins are bacterial cell wall hydrolytic enzymes that selectively and rapidly kill specific bacteria. Regarding copper induced cellular toxicity, several mechanisms have been proposed based on the formations of ROS by free Cu ions as cupric and cuprous ions can participate in redox reactions. ROS (O2ˉ,･OH, OHˉ), Cu+ and H2O2 play the important roles for viral inactivations. Thujaplicin-copper chelates inhibit influenza virus-induced apoptosis. Pyrrolidine dithiocarbamate as a metal ion binding agent inhibits the activity of the viral proteases of polyprotein processing and RNA replication of HRV. Chelation enables metals are capable of ligand scavenging via complexation, since reverse transcriptase enzyme inhibits the growth and replication of RNA tumor viruses. Thus, copper complex and copper chelation enhance antiviral efficacy.
Źródło:
World Scientific News; 2018, 99; 148-168
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Badanie zawartości miedzi w strumieniach technologicznych procesu wytwarzania poli(tlenku fenylenu)
Analysis of copper content in the poly(phenylene oxide) production process streams
Autorzy:
Kolasa, D.
Ratajczak, W.
Talma-Piwowar, M.
Krakowiak, J.
Majewska, E.
Polarczyk, K.
Powiązania:
https://bibliotekanauki.pl/articles/947148.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Chemii Przemysłowej
Tematy:
poli(tlenek fenylenu)
skład strumieni technologicznych
oznaczanie miedzi
mineralizacja próbek
poly(phenylene oxide)
process streams composition
determination of copper
sample digestion
Opis:
Przedstawiono wyniki oznaczania zawartości miedzi w strumieniach technologicznych pochodzących z procesu otrzymywania poli(tlenku fenylenu) (PPO) metodą polimeryzacji strąceniowej 2,6-dimetylofenolu z użyciem soli miedzi(II) jako kokatalizatora. Techniką FAAS (płomieniowa absorpcyjna spektrometria atomowa) badano mineralizaty próbek pochodzących z węzła odzysku rozpuszczalników (metanol lub etanol, toluen) i z węzła odzysku składników układu katalitycznego [jony miedzi(II), morfolina]. Zaproponowano procedurę analityczną obejmującą, na etapie przygotowania roztworów do badań, mineralizację próbek za pomocą nowoczesnego systemu do roztwarzania mikrofalowego Ultra WAVE (Milestone). Metoda ta (w połączeniu z techniką FAAS) pozwala na szybkie i sprawne oznaczanie zawartości miedzi w ciekłych próbkach z matrycą organiczną (metanol/etanol – toluen, morfolina) i wodno-organiczną.
Results of copper determination in process streams coming from the poly(phenylene oxide) (PPO) production by precipitation polymerization of 2,6-dimethylphenol using the copper(II) salt as a co-catalyst have been presented. A microwave-assisted sample preparation analytical procedure for the determination of copper in stream samples from the organic solvents (methanol or ethanol, toluene) and the catalyst components [copper(II) ions, morpholine] recovery nodes using a modern Milestone Ultra WAVE digestion system combined with the FAAS technique has been proposed. The method is useful for quick and efficient determination of copper in liquid samples with organic (methanol/ethanol – toluene, morpholine) mixtures and aqueous-organic matrix.
Źródło:
Polimery; 2018, 63, 4; 290-296
0032-2725
Pojawia się w:
Polimery
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Copper (II) Oxide particles as Adsorbent for Removal of Alkali Blue; Isotherm and Kinetic Studies
Autorzy:
Ibrahim, M. A.
Ibrahim, M. B.
Powiązania:
https://bibliotekanauki.pl/articles/1158766.pdf
Data publikacji:
2018
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Adsorption
Copper (II) Oxide particles
FTIR
Isotherm
Kinetics
Opis:
Adsorption behaviour of copper (II) oxide particles (CuO-Ps) for the removal of Alkali Blue (AB) was studied. Different adsorption variables such as contact time, initial concentration and pH for the adsorption process were investigated by batch adsorption studies. FTIR was carried out to determine the functional groups present at the surface of the particle with functional groups such as –OH, C=C, C-H, C≡C detected. The percentage removal and optimum contact time for the removal of AB was 84.8% at 10 min. The experimental isotherms data were analyzed using Langmuir, Temkin, Freundlich and Dubinin-Radushkevich (D-R) isotherms and it was observed that AB fits closely to Langmuir with R2 value of 0.884. Kinetics studies shows that the adsorption process fits better to pseudo-second order with the experimental values of qe 4.242 been closer to the calculated values of the qe 4.108. Effect of pH shows that it adsorb better at the initial pH of 5.30. Lower value of mean square energy of 0.707 kJ/mol indicates that the adsorption process is physical. The results indicated that copper (II) oxide particle can be used as a low-cost adsorbent for the removal of AB from aqueous solutions.
Źródło:
World Scientific News; 2018, 114; 208-217
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Evaluation of the quality of titanium oxide and copper oxide layers by means of optical microscopy
Autorzy:
Głuszek, A.
Sawicka-Chudy, P.
Wisz, G.
Sibiński, M.
Cholewa, M.
Powiązania:
https://bibliotekanauki.pl/articles/101772.pdf
Data publikacji:
2018
Wydawca:
Instytut Polityki Energetycznej im. Ignacego Łukasiewicza
Tematy:
titanium oxide
copper oxide
optical microscopy
histograms
Opis:
The aim of this paper is to analyse high-resolution optical images of the surface layers of titanium oxide and copper oxide. The materials were produced using the PREVAC Modular Platform for layer deposition located at the University of Rzeszów. Images with a magnification of 50x were obtained using an optical microscope. On the basis of the results obtained, the quality of the layers was evaluated based on the image analysis. The quantitative method of analysis was applied, as a result of which the conditions of the manufacturing process for which the obtained layers had the highest homogeneity were indicated. The minimum range of grey shade counting was from 65 to 150 and the maximum range from 135 to 220. The standard deviation was from 8 to 40%.
Źródło:
Energy Policy Studies; 2018, 1 (2); 39-51
2545-0859
Pojawia się w:
Energy Policy Studies
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Extraction of vanadium and potassium compounds from the spent vanadium catalyst from the metallurgical plant
Autorzy:
Mazurek, K.
Powiązania:
https://bibliotekanauki.pl/articles/779744.pdf
Data publikacji:
2012
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
kwas siarkowy
tlenek siarki
katalizatory wanadu
ługowanie
wanad
potas
miedź
cynk
arsen
ołów
XRF
sulfuric acid
sulfur oxide
spend vanadium catalysts
leaching
recovery
vanadium
potassium
copper
zinc
arsenic
lead
Opis:
A spent vanadium catalyst, from the plant of metallurgical type, was leached in a sulfuric acid solution to recover vanadium and potassium compounds. The effect of time, temperature, concentration of acid, catalyst particle size and phase ratio was studied. Additionally the concentration of iron, copper, zinc, arsenic and lead compounds was determined. The flow sheet for the proposed process of spent vanadium catalyst leaching is presented.
Źródło:
Polish Journal of Chemical Technology; 2012, 14, 2; 49-53
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Investigation of Metal Oxides as Catalysts for the Thermal Decomposition of Potassium Chlorate(VII)
Autorzy:
Wojewódka, A.
Zakusylo, R.
Kravets, V.
Romanchenko, A.
Jarosz, T.
Powiązania:
https://bibliotekanauki.pl/articles/358236.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
metal oxide catalysts
thermal decomposition
potassium perchlorate
manganese oxide
copper oxide
differential thermal analysis
Opis:
The results of studies on the thermal decomposition of potassium chlorate(VII) (PP) and the catalytic effects of copper, iron, nickel, titanium, magnesium, chromium and manganese oxides on the process are presented in this paper. The investigated oxides are ranked according to the magnitude of their catalytic effect; of these, CuO and МnО2 show the best catalytic performance. These oxides reduce the PP decomposition temperature from 919.3 K down to even 825.2 K. The share of the catalytic additive in the composition, required to achieve a desirable thermal decomposition profile, was found to be no more than 0.5 wt.%. The activation energy of the decomposition process was determined, using the modified Freeman and Carroll method for both neat PP and PP supplemented with MnO2; the addition of the catalyst produced a 48.8% decrease in the activation energy of thermal decomposition.
Źródło:
Central European Journal of Energetic Materials; 2018, 15, 2; 327-338
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mechanical Properties of Graphene Oxide–Copper Composites
Autorzy:
Duda, P.
Muzyka, R.
Robak, Z.
Kaptacz, S.
Powiązania:
https://bibliotekanauki.pl/articles/351676.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
composites of copper
graphene oxide
surface microgeomety
tribological properties
Opis:
Due to their characteristics, sintered Cu-C composites are materials used in electrical equipment. These characteristics include high electrical conductivity, thermal conductivity and excellent resistance to abrasion. Currently, graphite nanopowder is used successfully as a carbon material. Metal-graphite, which is created on its basis, exists in different proportions of graphite to metal. A larger graphite content has a positive effect on smaller wear of commutators and rings. In contrast, a material with a higher copper content is used at high current densities. An example of such machines is a DC motor starter characterized by low voltage and large current. Tribological properties of Cu-C composites depend on the form of carbon they include. Owing to the capability to manufacture graphene, it has become possible to produce composites with its content. The present study tested the effect of a graphene oxide content on tribological properties in contact with steel. Tests were conducted on a ball-on-disk apparatus in conditions of dry friction. Microscopic observation was performed on the Hitachi SU70 field emission electron microscope. EDS analyses were performed using the Thermo Scientific X-ray Microanalysis system. Disk wear and surface geometrical structure parameters (SGP) of the samples after tribological tests were determined on the basis of measurements made on the Talysurf 3D contact profilometer from Taylor Hobson.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 2A; 863-868
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mineralizacja polimetaliczna z kopalni Beiyi w okręgu rud żelaza Shilu na wyspie Hajnan w południowych Chinach
The polymetallic mineralization from the Beiyi mine, Shilu iron ores district, Hainan Island (Southern China)
Autorzy:
Mikulski, S.Z.
Bakun-Czubarow, N.
Xu, D.
Wang, Z.
Powiązania:
https://bibliotekanauki.pl/articles/2062063.pdf
Data publikacji:
2012
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
kruszce
rudy siarczkowe miedzi i kobaltu
rudy żelaza
amalgamat Ag-Hg
analizy w mikroobszarze
kopalnia Beiyi
złoże Shilu
Wyspa Hajnan
Chiny
ore mineralogy
ores
copper-cobalt sulfides
iron oxide
Ag-Hg amalgamate
microprobe analyses
Beiyi mine
Shilu deposit
Hainan Island
China
Opis:
W regionie górniczym Shilu posiadającym olbrzymie zasoby rud żelaza typu BIF (Banded Iron Formation), oprócz mineralizacji tlenkami Fe (głównie hematyt), występuje lokalnie w spągu 6 poziomu stratygraficznego grupy Shilu, bogata polimetaliczna mineralizacja siarczkowa Cu–Co. W regionie górniczym Shilu występują słabo zmetamorfizowane skały wulkanoklastyczne i węglanowe zaliczane do mezo- i neoproterozoiku, w które intrudowały różnego wieku granitoidy. Przedmiotem badań mikroskopowych w świetle odbitym i w mikroskopie elektronowym CAMECA SX 100, wyposażonym w przystawkę EDS i WDS, była polimetaliczna mineralizacja kruszcowa z kopalni Beiyi i jej okolic. Mineralizacja kruszcowa, głównie pirotynowo-chalkopirytowa oraz kobaltonośny piryt (do ok. 11% wag. Co), występuje w zmienionych skałach węglanowo-krzemianowych i silnie okwarcowanych skałach diopsydowo-tremolitowych w postaci impregnacji, żyłek i masywnych agregatów ziarnistych. Pirotyn i chalkopiryt zawierają liczne wrostki oraz tworzą przerosty z innymi minerałami (sfaleryt, galena, glaukodot, costibit, kobaltyn, arsenopiryt, ullmannit, siegenit, tytanit, Co-bravoit i kasyteryt). Niewielkie kryształy (10–20 μm średnicy) tworzą minerały Bi (matyldyt i cosalit) i argentyt. W paragenezie z barytem, kalcytem i chlorytem pojawiają się amalgamaty Ag–Hg oraz cynober. Wyniki prac pozwoliły rozpoznać nowe, dotychczas nieopisywane ze złoża minerały. Rezultaty badań wskazują na krystalizację minerałów kruszcowych podczas 4–5 oddzielnych etapów precypitacji kruszców z roztworów hydrotermalnych, w zakresie od temperatur średnich do niskich. Wstępne wyniki oznaczeń wieku izotopowego metodą Re–Os młodszej generacji pirytów (pozbawionych domieszek kobaltu) wskazują na ich precypitację w interwale 240–260 mln lat.
The famous Shilu iron-polymetallic ore mining district located in western Hainan Island, South China, occurs within Meso- and Neoproterozoic low-grade metamorphosed volcanoclastics and carbonates, that belong to the 6th sequence of the Shilu Group. Granitoid intrusions of different ages occur in the surroundings of the mining area. The Shilu deposit is considered to be a structurally reworked as well as hydrothermally altered and enriched ore deposit of a Banded Iron Formation type. The deposit is a very important iron producer from hematite (and minor magnetite) ores. Our work focused on the polymetallic sulfide mineralization that underlies the iron oxide ores. We selected several samples of sulfide ores from the Shilu deposit of the Beiyi mine and its close vicinity. We performed detailed ore microscopic studies as well as electron microprobe analyses using the CAMECA SX 100 equipped with EDS and WDS systems. Pyrrhotite, chalcopyrite and Co-bearing pyrite (up to 11 wt% Co) dominated among ore sulfides in the studied samples. These ore minerals occur in calc-silicate rocks and strongly silicified diopside, tremolite-bearing rocks, either as disseminated grains, sometimes in veinlets, or in aggregates that may form massive ores. Pyrrhotite and chalcopyrite may contain numerous solid inclusions, overgrowths and intergrowths of subordinate sulfides (sphalerite, galena), sulfosalts (glaucodot, costibite, cobaltite, arsenopyrite, ullmannite), sulfospinels (siegenite) and cassiterite that belong to the minerals crystallizing at medium to low temperatures. Among these minerals, siegenite and Co-bravoite dominate. Tiny crystals (10–20 μm in size) of Bi-minerals (matildite, cosalite) and argentite are also present. Moreover, in association with barite, calcite and chlorite, Ag-Hg amalgamate and cinnabar can occur. The results of our study point to the multistage medium- to low-temperature hydrothermal precipitation of ore sulfides during 4–5 separate stages. Preliminary results of Re-Os isotope datings indicate that pyrites of younger generation (lack of significant Co admixture) crystallized during 240–260 Ma.
Źródło:
Biuletyn Państwowego Instytutu Geologicznego; 2012, 452; 181--197
0867-6143
Pojawia się w:
Biuletyn Państwowego Instytutu Geologicznego
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Morphology and properties of the graphene layer on the copper substrate
Autorzy:
Pietrzak, K.
Olesińska, W.
Strąk, C.
Siedlec, R.
Gładki, A.
Powiązania:
https://bibliotekanauki.pl/articles/778091.pdf
Data publikacji:
2015
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
copper
graphene
graphene oxide
reduced graphene oxide
Opis:
The aim of the work presented in the article was to clarify controversial comments about anti-corrosion and mechanical properties of graphene coatings, deposited on copper substrates. It was designed special experimental cycle comprising: preparation of graphene forms and copper, the observation of layers Cu / GO (rGO) after the thermal reduction processes and oxidative test in air at 150°C temperature and 350 h in time. The resulting coatings and graphene layers were subjected to tribological test for hardness. The observed differences in the continuity of the coverage copper surface by graphene forms, allowed to understand the macroscopic effect of increased hardness and wear resistance layers rGO/Cu.
Źródło:
Polish Journal of Chemical Technology; 2015, 17, 4; 104-108
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ozone decomposition on ZnO catalysts obtained from different precursors
Autorzy:
Milenova, Katya I.
Nikolov, Penko M.
Kasabova, Nikoleta A.
Avramova, Ivalina A.
Powiązania:
https://bibliotekanauki.pl/articles/778353.pdf
Data publikacji:
2014
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
ozone decomposition
zinc oxide catalyst
manganese doping
copper doping
nanosize
Opis:
Kinetic investigations for ozone conversion on three different series of zinc oxide catalysts, containing pure ZnO and doped with Mn or Cu one with dopant content less than 1 wt.% were carried out. The different samples were obtained from carbonate, nitrate and acetate precursors. The as prepared catalysts were characterized by AAS, XRD, IR, EPR and BET methods. The mean size of the crystallites determined by XRD data is in the range 27÷68 nm. The presence of Mn2+ and Cu2+ ions into the ZnO matrix was established by EPR. The ozone decomposition was investigated for 30÷75°C temperature range. The zinc carbonate precursor samples show highest activity, while the nitrate precursor ones show lowest activity toward reaction decomposition of ozone in the whole temperature range. At 75°C two of the catalyst, obtained from carbonate precursor - ZnO and CuZnO show 100% conversion.
Źródło:
Polish Journal of Chemical Technology; 2014, 16, 4; 55-59
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
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