- Tytuł:
- Kinetic analysis of thermogravimetric data collected from bigger samples
- Autorzy:
-
Nowicki, L.
Markowski, M. - Powiązania:
- https://bibliotekanauki.pl/articles/185111.pdf
- Data publikacji:
- 2012
- Wydawca:
- Polska Akademia Nauk. Czytelnia Czasopism PAN
- Tematy:
-
termograwimetria
kinetyka
redukcja tlenków metali
thermogravimetry
kinetics
thermal lag
cellulose pyrolysis
metal oxide reduction - Opis:
- Results for microcrystalline cellulose pyrolysis are presented, which includes thermogravimetric measurements and kinetic analysis of experimental data. The effect of sample mass size and heating rate on estimated values of activation energy and pre-exponential factor is demonstrated and a simple modification of procedure is proposed that allows for the correct values of kinetic parameters regardless of the experimental conditions. The efficiency of the proposed method is confirmed for two endothermic chemical reactions. A method of nonlinear regression is used for calculation of kinetic parameters for a single or TG curve or several curves simultaneously.
- Źródło:
-
Chemical and Process Engineering; 2012, 33, 1; 85-94
0208-6425
2300-1925 - Pojawia się w:
- Chemical and Process Engineering
- Dostawca treści:
- Biblioteka Nauki
Artykuł