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Tytuł:
Mid-oceanic seamount carbonates in Eastern Paleotethyan suture zones
Autorzy:
Ueno, Katsumi
Powiązania:
https://bibliotekanauki.pl/articles/24202095.pdf
Data publikacji:
2023
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
Tethys
carbonates
Opis:
Mid-oceanic seamount-capping (atoll-type) carbonates make a popular stratigraphic entity in the geology of Japan since they are often seen as various-sized (but usually large and typically huge) exotic blocks within ancient (mostly Permian to early Cretaceous) accretionary complexes distributed in the Japanese Islands. These carbonates consist of very thick and pure (in the sense that it lacked input of continental detritus), usually massive and fossiliferous, shallow-marine limestone, and rest on oceanic-island basalts (OIB) of hot-spot origin, formed in the Panthalassa Ocean. Stratigraphically, they comprise a unique sedimentary succession that records long-term (sometimes over 80 myr.), continuous, shallow-marine environmental and biotic changes during late Paleozoic and early Mesozoic times of the oceanic sector with a stable tectonic setting, and can only be found within the accretionary orogen in the context of Ocean Plate Stratigraphy (OPS). Thus, the mid-oceanic seamount carbonate succession is a “surefire” geological item for the investigation of the ancient subduction zone and suture zone. On the basis of my research expertise working on these mid-oceanic carbonates in Japan over many years, especially in the Carboniferous–Permian Akiyoshi Limestone known as the most typical seamount-capping atoll-type carbonate body in the Panthalassa Ocean, I exported this, essentially “made-in-Japan” and “cultivated-in-Japan”, geological concept of “mid-oceanic seamount carbonates within the accretionary orogen” to Southeast Asian geology, for better understanding the general geotectonic subdivision and evolution of the relevant region, especially for clarifying the position of Paleotethyan suture zones and the geohistory of the Eastern Paleotethys Ocean. In today’s Southeast Asia, Paleotethyan mid-oceanic seamount carbonates are distributed in Northern Thailand and western Yunnan, SW China where Gondwana and Tethys meet together. Of these two regions, Northern Thailand is subdivided into three basic geotectonic domains; from east to west the Cathaysian Indochina Block, Sukhothai Zone (a Permian–Triassic island arc developed along the Indochina margin), and peri-Gondwanan Sibumasu Block. In the eastern part of Sibumasu, a geotectonically peculiar area called the Inthanon Zone can be identified on which Paleotethyan oceanic rocks including the Carboniferous–Permian Doi Chiang Dao Limestone of mid-oceanic seamount origin are widely distributed. This limestone succession, sometimes making kilometer-sized huge limestone blocks, is estimated to be 1000 m thick or more, and consists mostly of shallow-marine fossiliferous massive limestone without siliciclastic intercalation throughout. Basalts having intra-plate (oceanic volcanic island) geochemistry are observed at the base of the succession. Foraminifers, especially fusulines, are the fundamental fossil group for establishing its detailed chronostratigraphy, and they clarified that the limestone continuously accumulated from the Visean (middle Early Carboniferous) to the Changhsingian (latest Permian) over the time of 90 myr. In western Yunnan, the Changning–Menglian Belt is defined between the Lincang Massif (a Permian–Triassic island arc system formed along the easterly Simao Block with Cathaysian affinity) to the east and the peri-Gondwanan Baoshan Block to the west. The Changning–Menglian Belt, subdivided into the East, Central, and West zones, entirely has been regarded as a closed remnant (suture zone) of the Paleotethys Ocean, but actually it is only in the Central Zone where oceanic rocks are distributed. Paleotethyan mid-oceanic carbonates in this belt are called the Banka Limestone, which is over 1200 m in total thickness and generally massive and pure, being free from continental siliciclastic input for the entire succession spanning nearly 90 myr. Foraminiferal (mostly fusuline) biostratigraphy suggested continuous deposition ranging from the Visean to the Changhsingian without significant hiatus in the succession. Thus, the Banka Limestone in western Yunnan is exactly correlated in view of lithostratigraphy, chronostratigraphy, and tectonostratigraphy to the Doi Chiang Dao Limestone in Northern Thailand. In a broad geotectonic perspective, the Paleotethyan oceanic rocks including the Doi Chiang Dao Limestone, distributed in the Inthanon Zone are considered to form various-sized tectonic outliers upon autochthonous basement rocks of Sibumasu now, which consists of early Paleozoic– Triassic sedimentary, meta-sedimentary, and igneous intrusive rocks. Similarly, those distributed in the Central Zone of the Changning–Menglian Belt are structurally resting by almost flat-lying faults (thrusts) upon siliciclastic rocks of the West and/or East zones, which presumably represent passive-margin (continental slope) sediments of the westerly, Gondwanan Baoshan Block. These mid-oceanic rocks are interpreted to have been once incorporated within an accretionary prism formed by the subduction of the Paleotethyan oceanic lithosphere beneath the Permian–Triassic island arc system represented by the Lincang Massif–Sukhothai Zone. The resultant collision of the Cimmerian (peri-Gondwanan) Sibumasu–Baoshan Block to the Cathaysian Indochina–Simao Block, thus the closure of the Paleotethys Ocean in present-day Southeast Asia, at around Triassic–Jurassic boundary time emplaced rocks of the accretionary complexes (containing Paleotethyan oceanic rocks as exotic blocks) onto the marginal part of the Sibumasu–Baoshan Block as large thrust sheets (nappe).
Źródło:
Geotourism / Geoturystyka; 2023, 1-2 (72-73); 75--76
1731-0830
Pojawia się w:
Geotourism / Geoturystyka
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Corrosion of carbonate speleothems by an allogenic river inferred from petrography and a weight loss experiment : a case study from the Demänová Cave System, Slovakia
Autorzy:
Sala, Przemysław
Bella, Paweł
Powiązania:
https://bibliotekanauki.pl/articles/27311293.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
Karst
carbonates
hiatus
dissolution
palaeoenvironment
Opis:
The crystallization of speleothems can be interrupted by the invasion of allogenic water into cave passages. These interruptions were studied, both in speleothems currently submerged in an underground river and in speleothem sections, which were found at the lowermost fluvially active passage level of the Demänová Cave System. The interaction between speleothems and allogenic water, undersaturated with respect to calcite, is manifested in the presence of siliciclastic material and the corrosion of calcite crystals. The progressive development of corrosion features depends on the duration of the interaction of calcite crystals with allogenic water. Moreover, the movement of the water and siliciclastic deposition over the speleothems can influence the corrosion process. The estimated rate of corrosion, caused by the underground Demänovka River and measured by the weight loss of experimental tablets, is up to 0.029 mm/y. U-series dating indicated that the interaction of speleothems with allogenic water occurred during the Vistulian (Weichselian). The identification of corrosion episodes, caused by allogenic water, is a step towards understanding the origin of hiatuses and establishing criteria for recognition of them.
Źródło:
Annales Societatis Geologorum Poloniae; 2023, 93, 4; 467--481
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Formation of calcite by chemolithoautotrophic bacteria – a new hypothesis, based on microcrystalline cave pisoids
Autorzy:
Gradziński, M.
Chmiel, M.J.
Motyka, J.
Powiązania:
https://bibliotekanauki.pl/articles/191736.pdf
Data publikacji:
2012
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
microbial carbonates
biomineralization
biofilm
speleothems
Carpathians
Opis:
A new mechanism, stimulating the precipitation of calcite, is postulated. The supersaturation with respect to carbonate minerals is changed, as a result of CO2consumption by chemolithoautotrophic, hydrogen-oxidizing bacteria. This mechanism controls the growth of atypical, microcrystalline cave pisoids in Perlová Cave, in Slovakia. The pisoids grow under calm conditions in rimstone pools, where they are bathed continuously in stagnant water. The water is supersaturated, with respect to calcite and aragonite. The bacteria inhabit the outer parts of the pisoids, covered by biofilms. The biofilm influences the supply of the Ca2+ ion, slows down the precipitation rate, and favors calcite precipitation over that of aragonite. The calcite initially precipitates as bacterial replicas, which further act as seeds for the growing calcite crystals. This process leads to the obliteration of the primary, bacterial fabrics. Since hydrogen-oxidizing bacteria occur in a wide spectrum of natural habitats, the mechanism of calcification, postulated above, also may operate in other environments.
Źródło:
Annales Societatis Geologorum Poloniae; 2012, 82, 4; 361--369
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The impact of fossils on diagenetically controlled reservoir quality : the Zechstein Brońsko Reef
Autorzy:
Fheed, Adam
Powiązania:
https://bibliotekanauki.pl/articles/191256.pdf
Data publikacji:
2019
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
carbonates
dissolution channels
diagenesis
fossils
porosity
Opis:
Although the sedimentation and diagenesis of the Polish Zechstein Limestone strata (Ca1, Permian) already have been investigated, relatively little has been done to resolve their petrophysical potential. Therefore, the gap between sedimentological and petrophysical studies was bridged through an integrated analysis of geological and geophysical data. The results of core description, polarized-light microscopy, well log interpretations and laboratory measurements on core samples were combined with previously published nuclear magnetic resonance (NMR) and X-ray microtomography (μCT) data, especially helpful in the recognition of pore geometry. The Ca1 strata of the Brońsko-1 and Brońsko-2 wells, located on the Zechstein Brońsko Reef (West Poland), were studied to determine the influence of fossils on porosity and permeability. It was concluded that greater diversification of the original biota led to an increase in porosity and variation in pore geometry. While encrusting organisms such as foraminifers promoted the development of channel and fracture porosity, the dissolution of the primarily aragonitic bivalve and gastropod shells and the shells of terebratulid brachiopods often gave rise to the formation of cavernous and mouldic porosity. The channels appear to be most common in the bryozoan-foraminifer biofacies, representing a shallowing of the depositional environment. Caverns, in turn, corresponded to the organisms of the brachiopod-bryozoan and the lightly karstified bivalve-gastropod biofacies, both of which probably experienced the influence of sabkha conditions, leading to a general decrease in porosity. The bryozoan zoecia tended to enhance both primary intraparticle voids, and after their dissolution, secondary intraparticle pores, which showed limited connectivity in the high-energy Acanthocladia biofacies, where considerable fragmentation of fossils took place, hence decreasing the permeability. Anhydrite cementation was found to be the most pronounced factor controlling porosity destruction, while dolomitization enhanced it significantly, especially for the stromatolitic biofacies, where small, unconnected vugs were formed owing to this process. The permeability is typically below 100 mD, and this is caused by the rich diagenetic history of the reef, that recorded marine, sabkha-related and burial cementation, now represented by the different fabrics of anhydrite, calcite, and dolomite.
Źródło:
Annales Societatis Geologorum Poloniae; 2019, 89, 1; 47-81
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Cenomanian heterozoan carbonates in the north-central Alborz, north-east Kelardasht, north Iran
Autorzy:
Kavoosi, Mohammad Ali
Ezoji, Neda
Powiązania:
https://bibliotekanauki.pl/articles/2060116.pdf
Data publikacji:
2021
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
heterozoan carbonates
condensed
Cenomanian
north-east Kelardasht
Opis:
Detailed field surveys, petrographic investigation and SEM and EDS analyses have been used to evaluate Cenomanian glauconitic heterozoan carbonates in north-east Kelardasht, north-central Alborz, north Iran. Lithofacies and microfacies analyses led to recognition of six microfacies types related to the inner-, mid- and outer-ramp facies belts of a carbonate ramp. The heterozoan nature of these carbonates is inferred from a predominance of echinoderms associated with calcispheres, planktonic foraminifers, a lack of ooid grains, and a low carbonate production rate, together with a high content of glauconite grains and prevailing high-Mg calcite mineralogy. Petrographic and SEM studies reveal that glauconite filling skeletal grains retains the shape and morphology of host grains, signifying an authigenic origin at low sedimentation rates and slightly reducing conditions. SEM images show cauliflower and rosette structures associated with well-developed lamellae indicating an authigenic origin of evolved glauconite grains. Our findings are compatible with a nutrient-rich waters and palaeoecological stress related to relative sea-level rise and eutrophic conditions, which contributed to the generation of these heterozoan carbonates despite the hot greenhouse conditions during the Cenomanian in the north-central Alborz Mountains.
Źródło:
Geological Quarterly; 2021, 65, 3; 65: 37
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Probable root structures and associated trace fossils from the Lower Pleistocene calcarenites of Favignana Island, southern Italy : dilemmas of interpretation
Autorzy:
Uchman, A.
Ślączka, A.
Renda, P.
Powiązania:
https://bibliotekanauki.pl/articles/2060614.pdf
Data publikacji:
2012
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
ichnology
root structures
burrows
carbonates
Quaternary
Mediterranean Sea
Opis:
Two types of large, branched structures from the Lower Pleistocene (Calabrian) high-energy calcarenites of Favignana Island are described: Faviradixus robustus gen. et sp. nov. and Egadiradixus rectibrachiatus gen. et sp. nov. They may be interpreted as root structures of large plants, trees and trees or shrubs, respectively. The former taxon co-occurs with the marine animal trace fossils Ophiomorpha nodosa, Ophiomorpha isp., Thalassinoides isp. and Beaconites isp. The interpretation as root structures although tentative is probable and can be related to short emergence episodes for the formation of E. rectibrachiatus or to longer emergence, responsible for the discontinuity at the base of the overlying Tyrrhenian deposits, for F. robustus. Calcified root mats of smaller plants associated with the Tyrrhenian or younger emergence surfaces are common.
Źródło:
Geological Quarterly; 2012, 56, 4; 745--756
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Stable isotope composition of carbonates in loess at the Carpathian margin (SE Poland)
Autorzy:
Łącka, Bożena
Łanczont, Maria
Komar, Maryna
Madeyska, Teresa
Powiązania:
https://bibliotekanauki.pl/articles/2026059.pdf
Data publikacji:
2008
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
loess
authigenic carbonates
carbon and oxygen stable isotopes
Vistulian
Opis:
Sam ples for the study were col lected from, known from the lit era ture, out crop pro files in Zar zecze, Ra dymno, Dybawka, Tarnawce and Pikulice- Nehrybka, situ ated at the Car pa thian bor der, in the vi cin ity of the Prze myoel town, close to the San River val ley (SE Po land). They rep re sent the Vis tulian loess- palaeosol se quences. Car bon ates oc cur mainly in the lo esses rep re sent ing OIS 2 and 3. Pol len analy sis, car ried out for two pro files (Tarnawce, Ra dymno), throws light on pa laeoe co logi cal con di tions of loess cover for ma tion and trans for ma tion. Iso topic analy sis of authigenic car bon ates was car ried out on car bon ate ce mented bod ies dis persed through out the loess in forms of nod ule, rhi zolith and rhi zo cre tion and on bio clasts, mainly snail shells, os tra cod valves, and sparse glob ules (proba bly the in ter nal shells of the na ked snails). In the suc ces sions stud ied, the up per Vistulian loess de pos ited in en vi ron ment with poor veg e ta tion, con tains rhizoliths and rhizocretions mainly, while in the mid dle and lower Vistulian loess with well de vel oped soils, gley ho ri zons, and in ter ca la tions of sub aque ous sed i ments, re mains of snail shells and ostracod valves pre vail. The two main forms of car bon ates dif fer mark edly in iso to pic com po si tion from one an other. These dif fer ences seem to be more im por tant than those be tween sam ples of one form of car bon ates along par tic u lar sec tions. That is the re sult of nu mer ous fac tors af fect ing the frac tion ation of car bon and, in par tic u lar, ox y gen sta ble iso topes in the en vi ron ment of pre cip i ta tion of authigenic cal cite. The iso to pic com po si tion of car bon ates ce ment ing sed i ments is con trolled mainly by biomineralization of or ganic mat ter and lo cal cli ma tic pa ram e ters which were rather slightly dif fer en ti ated dur ing the for ma tion of the stud ied sed i ments. The d13C val ues for bioclasts vary in a broader range than for calcitic ce ments. Usu ally the snail shell car bon ate is more en riched with heavier car bon iso tope than that from ostracod valves, re sult ing from the iso to pic equi lib rium with pre cip i ta tion and with sur face wa ters, re spec tively. Bas ing on our study we can con clude that fluc tu a tions of iso tope com po si tion of authigenic car bon ates make it hard to ap ply as a paleoclimatic in di ca tor. How - ever, the gen eral trend of d18O vari a tion in ana lysed car bon ate frac tions from leoss-palaeosol se quences dis plays some con nec tions with cli ma tic fluc tu a tions.
Źródło:
Studia Quaternaria; 2008, 25; 3-21
1641-5558
2300-0384
Pojawia się w:
Studia Quaternaria
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Stable isotopic and mineralogical investigations of an arid Quaternary lacustrine palaeoenvironment, Western Qaidam, China
Autorzy:
Bojar, A. V.
Rieser, A.
Neubauer, F.
Bojar, H. P.
Genser, J.
Liu, Y.
Ge, X. H.
Powiązania:
https://bibliotekanauki.pl/articles/2058952.pdf
Data publikacji:
2005
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Qaidam
Quaternary
stable isotopes
celestine
carbonates
hypersaline lacustrine environment
Opis:
Stable isotope analyses on carbonates from lake evaporites collected from the non-marine western Qaidam basin yield a positive excursion from Pliocene to Quaternary times. At Dafeng Shan, the Quaternary sequences are composed of alternating layers of celestine/dolomite and aragonite/calcite/barite with distinct isotopic compositions. The sequence described at Dafeng Shan formed in a low energy, hypersaline lacustrine environment as indicated by the microstructures and evaporitic minerals as well as by the absence of lithoclasts. The peloids, ooids and oncoids described are related to microbialactivities in saline lake. The oxygen isotopic composition of the carbonates vary between +34.4 and +39.8‰ (SMOW), representing the heaviest values measured until now. The δ18 O and the δ34 S isotopic composition of the celestine range between 20.1 to 22.3‰ (SMOW) and +19 to +22‰ (CDT) respectively, suggesting sulfur recycling via sulfide oxidation. The carbon isotopic compositions of the carbonates show a large negative excursion of up to -30‰. The microstructures, mineralogy and isotopic compositions as well as the geological context suggest oxidation of methane from a deep source.
Źródło:
Geological Quarterly; 2005, 49, 2; 173-184
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Sedimentological and micropalaeontological evidence to elucidate post-evaporitic carbonate palaeoenvironments of the Saudi Arabian latest Jurassic
Autorzy:
Hughes, G.
Naji, N.
Powiązania:
https://bibliotekanauki.pl/articles/2061333.pdf
Data publikacji:
2008
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Saudi Arabia
Tithonian
Hith Firmation
Manifa Reservoir
micropalaeontology
evaporates
carbonates
Opis:
The Hith Formation forms the youngest lithostratigraphic unit of the Jurassic Shaqra Group. It represents the culmination of a succession of hypersaline and euryhaline cycles that characterise the Late Jurassic of Saudi Arabia. The Formation is poorly exposed in central Saudi Arabia, but it has been studied in detail in subsurface eastern Saudi Arabia where the upper carbonate member hosts an important hydrocarbon reservoir called the Manifa Reservoir. Chronostratigraphic control is absent from the formation itself, and the Tithonian age is suggested for the Hith Formation based on its stratigraphic position between the underlying Arab Formation of Late Kimmeridgian age, and the overlying Sulaiy Formation, of Late Tithonian to Berriasian age. The Hith Formation needs redefining in the light of new lithological evidence, and a tripartite member scheme is suggested. This includes the lower anhydrite-dominated member here termed the “anhydrite” member, and considered to represent hypersaline subaqueous deposition within a restricted deep lagoon during the lowstand systems tract of the Manifa sequence. A “transitional“ member consists of interbedded anhydrites and carbonates and approximates with the transgressive zone. The overlying “carbonate” member represents the results of a prograding shallow, normal salinity marine succession related to the highstand systems tract. Interbedded carbonates within the evaporites are interpreted to represent superimposition of a higher frequency, possibly 4th order eustatic cyclicity. The “carbonate“ member hosts the Manifa Reservoir, and here proposed as the Manifa Member, consist of five parasequences, each of which represents a shoaling-upwards cycle with a succession of up to five repeated lithofacies and biofacies that commences with a stromatolitic, microfaunally-barren unit followed by fine-grained grainstones with a monospecific but abundant ostracod biofacies. A succession of coarse pelloidal grainstones with rare foraminifera, including Redmondoides lugeoni, Trocholina alpina with a variety of unidifferentiated valvulinids and miliolids then follows, that passes vertically into coarse ooid grainstones, with rare Redmondoides lugeoni, forming the uppermost part of each parasequence.
Źródło:
Volumina Jurassica; 2008, 6, 1; 61-73
1896-7876
1731-3708
Pojawia się w:
Volumina Jurassica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Polyurethane foams with pyrimidine rings
Autorzy:
Kania, E.
Lubczak, J.
Powiązania:
https://bibliotekanauki.pl/articles/778772.pdf
Data publikacji:
2014
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
barbituric acid
glycidol
alkylene carbonates
oligoetherols
polyurethane foams
thermal stability
Opis:
Oligoetherols based on pyrimidine ring were obtained upon reaction of barbituric acid with glycidol and alkylene carbonates. These oligoetherols were then used to obtain polyurethane foams in the reaction of oligoetherols with isocyanates and water. The protocol of foam synthesis was optimized by the choice of proper kind of oligoetherol and synthetic composition. The thermal resistance was studied by dynamic and static methods with concomitant monitoring of compressive strength. The polyurethane foams have similar physical properties as the classic ones except their enhanced thermal resistance. They stand long-time heating even at 200°C. Moreover thermal exposition of foams results generally in increase of their compressive strength.
Źródło:
Polish Journal of Chemical Technology; 2014, 16, 3; 1-6
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Hydrothermal veins linked with the Variscan structure of the Prague Synform (Barrandien, Czech Republic): resolving fluid-wall rock interaction
Autorzy:
Halavínová, M.
Melichar, R.
Slobodník, M.
Powiązania:
https://bibliotekanauki.pl/articles/2059098.pdf
Data publikacji:
2008
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Bohemian Massif
Palaeozoic
Variscan veins
carbonates
isotope geochemistry
fluid systems
Opis:
Variscan syntectonic hy dro ther mal veins of the Prague Synform are important traces of small-scale fluid migration in Lower Palaeozoic sedimentary rocks — a process induced by late Variscan tectogenesis. Two main structural types of Variscan syntectonic calcite veins were recognised during fieldwork. Veins of Type I have an irregular or sigmoidal shape and are often arranged in en echelon arrays. A shearing regime during the formation of this type is deduced. Veins of a second structural type (Type II) have a more regular and straight shape relative to those of Type I and in some places form a dense network. The structural position of the Type II veins is related to structural elements of Variscan folds. Veins were formed due to interlayer-slip combined with fold- related fracturing that gave rise to the infilling of dilational structures. A tensional regime also permits growth of the fibrous veins. Two princpal directions were distinguished within the Type II veins. The first one is NNW–SSE and the second one shows a perpendicular ENE–WSW orientation. These directions seem to be parallel and/or perpendicular to the nappearchitec ture of the Prague Synform. Variscan syntectonic veins crystallised in a relatively closed, rock-buf fered system. Extraction of chemical components from surrounding rocks is indicated by a combined microprobe/cathodoluminescent study and by isotope geochemistry. The carbon isotope values of hydrothermal calcites reflect the carbon isotope composition of the host rocks. The delta exp.13C values of vein calcites and their host Silurian rocks are between –0.29 and –1.98‰ PDB. The same relationships were found between the veins and the host Devonian limestones (from 1.72 to 2.52‰ PDB). Samples close to the Silurian/Devonian boundary show transition values between 0.25 and + 1.16‰ PDB. The Sr-isotopic signature supports a genetic link between the calcite veins and the host rocks. The 87Sr/86Sr ra tio in calcites ranges between 0.708619 and 0.708738 and in wall rocks be tween 0.708755 and 0.709355. Aqueous and hydrocarbon-rich fluid systems have been found in fluid inclusions. Liquid hydrocarbons show mostly a light blue fluorescence suggesting the presence of higher hydrocarbons. They are more abundant in dark Silurian rocks, which are rich in organic matter. Lower salinities (0.5–8.9 eq. wt.% NaCl) and homogenization temperatures with a maximum around 140gradeC are typ i cal for the aqueous (H2O–NaCl) system. The oxygen isotopic composition of fluids ranges between –2.80 and +3.33‰ SMOW. This indicates that transformed formation waters in teracted with the host rocks and/or deeply circulating isotopically depleted meteoric waters. Intersections with the isochore specify border trapping temperatures between 127 and 160grade C and pressures from 300 to 1070 bars.
Źródło:
Geological Quarterly; 2008, 52, 4; 309-309
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Cryogenic carbonates and cryogenic speleothem damage in the Za Hájovnou Cave (Javoříčko Karst, Czech Republic)
Autorzy:
Žak, K.
Lipták, V.
Filippi, M.
Orvošová, M.
Hercman, H.
Matouškova, Š.
Powiązania:
https://bibliotekanauki.pl/articles/2060084.pdf
Data publikacji:
2018
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
cryogenic cave carbonates
speleothem damage
Javoříčko Karst
U-series dating
Opis:
A new locality of coarse-grained cryogenic cave carbonates has been found in the Za Hájovnou Cave in Javoříčko Karst in Central Moravia, Czech Republic. Crystals and crystal aggregates, usually up to 15 mm in size, form typical loose accumulations on the surface of large fallen limestone blocks and clays covering the bottoms of several cave chambers distant from the cave entrance. The cryogenic origin of the carbonates is supported by their mode of occurrence, specific crystal and aggregate morphology, and C and O stable isotope data. U-series dating of one sample of cryogenic carbonate (age 29.5 ±0.1 ka) indicated that a period of karst water freezing occurred in marine isotope stage (MIS) 3, within the Weichselian. The cave also hosts numerous examples of speleothem damage. As shown in this paper, some of these are clearly connected with freezing conditions and cave ice action.
Źródło:
Geological Quarterly; 2018, 62, 4; 829--839
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Geneza krzemieni górnego oksfordu w Krzemionkach Opatowskich
Genesis of the Upper Oxfordian flints in Krzemionki Opatowskie, Poland
Autorzy:
Gutowski, P.
Pieńkowski, G.
Powiązania:
https://bibliotekanauki.pl/articles/2077299.pdf
Data publikacji:
2004
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
krzemionka opatowska
krzemień
shallow water carbonates
decapod burrows
sedimentary discontinuities
Opis:
Early diagenetic concretionary flint nodules from the Upper Oxfordian oolitic and micritic limestones represent silicified crustacean burrows. Their occurence is confined to very shallow carbonate facies of barrier, lagoonal, and tidal flat origin. Fills of crustacean burrows commonly provided a nucleation centre for flint formation and thereby the template on which flint nodule beds were constructed. The reason for the special relationship between flint and crustacean burrows probably lie in the original texture (high permeability) of the burrow networks and also in the organic content (including the microbial assemblages) lowering the pH. Nodule horizons are developed more or less parallel to bedding, to form several widespread horizons of the regional correlative significance.
Źródło:
Volumina Jurassica; 2004, 2, 1; 29-36
1896-7876
1731-3708
Pojawia się w:
Volumina Jurassica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
An advanced ensemble modeling approach for predicting carbonate reservoir porosity from seismic attributes
Autorzy:
Topór, Tomasz
Sowiżdżał, Krzysztof
Powiązania:
https://bibliotekanauki.pl/articles/27310145.pdf
Data publikacji:
2023
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
machine learning
model stacking
ensemble method
carbonates
seismic attributes
porosity prediction
Opis:
This study uses a machine learning (ML) ensemble modeling approach to predict porosity from multiple seismic attributes in one of the most promising Main Dolomite hydrocarbon reservoirs in NW Poland. The presented workflow tests five different model types of varying complexity: K-nearest neighbors (KNN), random forests (RF), extreme gradient boosting (XGB), support vector machine (SVM), single layer neural network with multilayer perceptron (MLP). The selected models are additionally run with different configurations originating from the pre-processing stage, including Yeo–Johnson transformation (YJ) and principal component analysis (PCA). The race ANOVA method across resample data is used to tune the best hyperparameters for each model. The model candidates and the role of different pre-processors are evaluated based on standard ML metrics – coefficient of determination (R2), root mean squared error (RMSE), and mean absolute error (MAE). The model stacking is performed on five model candidates: two KNN, two XGB, and one SVM PCA with a marginal role. The results of the ensemble model showed superior accuracy over single learners, with all metrics (R2 0.890, RMSE 0.0252, MAE 0.168). It also turned out to be almost three times better than the neural net (NN) results obtained from commercial software on the same testing set (R2 0.318, RMSE 0.0628, MAE 0.0487). The spatial distribution of porosity from the ensemble model indicated areas of good reservoir properties that overlap with hydrocarbon production fields. This observation completes the evaluation of the ensemble technique results from model metrics. Overall, the proposed solution is a promising tool for better porosity prediction and understanding of heterogeneous carbonate reservoirs from multiple seismic attributes.
Źródło:
Geology, Geophysics and Environment; 2023, 49, 3; 245--260
2299-8004
2353-0790
Pojawia się w:
Geology, Geophysics and Environment
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Carbonate minerals with magnesium in triassic terebratula limestone in the term of limestone with magnesium application as a sorbent in desulfurization of flue gases
Minerały węglanowe zawierające magnez w wapieniach triasowych warstw terebratulowych w aspekcie zastosowania wapieni z magnezem jako sorbentu w procesie odsiarczania spalin
Autorzy:
Stanienda-Pilecki, K.
Powiązania:
https://bibliotekanauki.pl/articles/219948.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
limestone
carbonates with magnesium
sorbent
desulfurization
wapień
fazy węglanowe z magnezem
odsiarczanie
Opis:
This article presents the results of studies of Triassic (Muschelkalk) carbonate rock samples of the Terebratula Beds taken from the area of the Polish part of the Germanic Basin. It is the area of Opole Silesia. The rocks were studied in the term of possibility of limestone with magnesium application in desulfurization of flue gases executed in power plants. Characteristic features of especially carbonate phases including magnesium-low-Mg calcite, high-Mg calcite, dolomite and huntite were presented in the article. They were studied to show that the presence of carbonate phases with magnesium, especially high-Mg calcite makes the desulfurization process more effective. Selected rock samples were examined using a microscope with polarized, transmitted light, X-ray diffraction, microprobe measurements and FTIR spectroscopy. The results of studies show a domination of low magnesium calcite in the limestones of the Terebratula Beds. In some samples dolomite and lower amounts of high-Mg calcite occurred. Moreover, huntite was identified. The studies were very important, because carbonate phases like high-Mg calcite and huntite which occurred in rocks of the Triassic Terebratula Beds were not investigated in details by other scientists but they presence in limestone sorbent could influence the effectiveness of desulfurization process.
W artykule zaprezentowano wyniki badań wapieni triasowych (wapienia muszlowego) warstw terebratulowych. Próbki pobrano w obszarze Śląska Opolskiego (polska część zbiornika germańskiego). Próbki poddano badaniom w celu określenia możliwości zastosowania wapieni z magnezem w procesie odsiarczania gazów spalinowych, stosowanym w zakładach energetycznych. Charakterystyczne własności faz węglanowych, w szczególności tych zawierających magnez, takich jak kalcyt niskomagnezowy, kalcyt wysokomagnezowy, dolomit i huntyt, przedstawiono w niniejszym artykule. Badania wykonano w celu wykazania, że obecność faz węglanowych zawierających magnez, w szczególności wysokomagnezowy kalcyt, wpływają na zwiększenie efektywności procesu odsiarczania spalin. Próbki wapieni poddano badaniom, obejmującym m.in. analizę mikroskopową w świetle przechodzącym, dyfraktometrię rentgenowską, badania w mikroobszarach oraz spektroskopię w podczerwieni FTIR. Wyniki badań wskazują na dominację niskomagnezowego kalcytu w wapieniach warstw terebratulowych. W niektórych próbkach zidentyfikowano dolomit i mniejsze ilości kalcytu wysokomagnezowego. Ponadto oznaczono również huntyt. Przeprowadzenie badań było bardzo istotne, ponieważ fazy węglanowe takie jak kalcyt wysokomagnezowy i huntyt, które zidentyfikowano w wapieniach triasowych warstw terebratulowych nie były wcześniej, przez innych naukowców szczegółowo badane, a ich obecność w sorbencie węglanowym może wpływać na polepszenie efektywności procesu odsiarczania spalin.
Źródło:
Archives of Mining Sciences; 2017, 62, 3; 459-482
0860-7001
Pojawia się w:
Archives of Mining Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł

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