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Tytuł:
Stable isotope composition of carbon dioxide emitted from anthropogenic sources in the Kraków region, Southern Poland
Autorzy:
Zimnoch, M.
Powiązania:
https://bibliotekanauki.pl/articles/148175.pdf
Data publikacji:
2009
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
stable isotopes
carbon dioxide
anthropogenic sources
Kraków
Opis:
The summary of the measurements of CO2 stable isotopic composition emitted from different anthropogenic sources in the Krakow region is presented. The sources are divided into three main groups . high emission (electric and heat power plants), low emission (coal and methane burning in the households) and car traffic (gasoline, diesel and LPG supplied engines equipped and not equipped with catalyst). Presented results include two measurement campaigns made in the years 1995 and 2000. The measurements revealed three well-defined groups with respect to carbon isotope composition (delta13CVPDB): .30.60 plus-minus sign 0.37 per mille (thousand) sign (car traffic) .23.82 plus-minus sign 0.10 per mille (thousand) sign (coal burning) and .51.8 plus-minus sign 1.1per mille (thousand) sign (methane burning). The oxygen isotope composition (delta18OVPDB-CO2) of CO2 varied in a broad range, from ca. .11per mille (thousand) sign to ca. .22 per mille (thousand) sign, the most negative values being observed for coal and methane burning and the most positive for cars equipped with a catalyst. No significant isotopic shift has been observed between two measurement campaigns.
Źródło:
Nukleonika; 2009, 54, 4; 291-295
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Benthic foraminifera in Hornsund, Svalbard: Implications for paleoenvironmental reconstructions
Autorzy:
Zajączkowski, Marek
Szczuciński, Witold
Plessen, Birgit
Jernas, Patrycja
Powiązania:
https://bibliotekanauki.pl/articles/2051580.pdf
Data publikacji:
2010
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Arctic
Spitsbergen
benthic foraminifera
oxygen and carbon stable isotopes
paleotemperature
fjords
Źródło:
Polish Polar Research; 2010, 4; 349-375
0138-0338
2081-8262
Pojawia się w:
Polish Polar Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Reconstruction of postglacial paleoproductivity in Long Lake, King George Island, West Antarctica
Autorzy:
Yoon, Ho-Il
Khim, Boo-Keun
Lee, Kyung
Park, Yu-Hyeon
Yoo, Kyu-Cheul
Powiązania:
https://bibliotekanauki.pl/articles/2051902.pdf
Data publikacji:
2006
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Antarctica
lake sediment
paleoclimate
diatoms
organic carbon
carbon isotopes
Źródło:
Polish Polar Research; 2006, 27, 3; 189-206
0138-0338
2081-8262
Pojawia się w:
Polish Polar Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Habitat and hydrocarbon potential of the Kimmeridgian strata in the central part of the Polish Lowlands
Autorzy:
Więcław, D.
Powiązania:
https://bibliotekanauki.pl/articles/2060197.pdf
Data publikacji:
2016
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Polish Lowlands
Kimmeridgian
source rock
hydrocarbon potential
biomarkers
carbon stable isotopes
Opis:
The quantity, genetic type and maturity of organic matter dispersed in the Kimmeridgian strata of the central part of the Polish Lowlands were determined on the basis of results of Rock-Eval, stable carbon isotope composition of bitumen, their fractions and kerogen, biomarker distribution in saturate and aromatic hydrocarbon fraction, elemental composition of kerogen, vitrinite reflectance and maceral composition analyses of 225 rock samples collected from 32 boreholes. The study was conducted separately for Lower and Upper Kimmeridgian rocks in the Szczecin-Miechów and Kościerzyna-Puławy synclinoriums and Mid-Polish Anticlinorium. The best source rocks with TOC up to 6.8 wt.%, were found in the vicinity of Gostynin in the Mid-Polish Anticlinorium. Generally, the Upper Kimmeridgian strata are fair and good potential source-rocks whereas the Lower Kimmeridgian strata have much lower hydrocarbon potential. Gas-prone, terrigenous Type-III kerogen predominates in the Lower Kimmeridgian strata. The contribution of oil-prone, marine Type-II kerogen increases in the Upper Kimmeridgian rocks. In the whole profile, only low-sulphur kerogen was recorded, although the situation, when high-sulphur Type-IIS kerogen was mixed with re-worked, non-generative Type-IV kerogen supplied to the sedimentary basin with rocks from eroded land, cannot be excluded. Sedimentary conditions of organic material were variable, usually anoxic and suboxic with domination of siliclastic material in mineral matrix. The maturity of the dispersed organic matter refers mostly to the final phase of the microbial process, or to the initial phase of the low-temperature thermogenic process (oil window). The most mature rocks, corresponding up to 0.75% in the vitrinite reflectance scale, were recognised in the deepest buried parts of the basin (axial part of the Mogilno-Łódź Segment of the Szczecin-Miechów Synclinorium). The most prospecting source rocks were recognised in this area.
Źródło:
Geological Quarterly; 2016, 60, 1; 192--210
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Habitat and hydrocarbon potential of the Palaeozoic source rocks in the Kraków–Rzeszów area (SE Poland)
Autorzy:
Więcław, D.
Kotarba, M. J.
Kowalski, A.
Kosakowski, P.
Powiązania:
https://bibliotekanauki.pl/articles/191373.pdf
Data publikacji:
2011
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
source rock
hydrocarbon potential
Rock-Eval pyrolysis
biomarkers
stable carbon isotopes
Palaeozoic basement
Małopolska Block
Polish Carpathian Foredeep
Opis:
The quantity, genetic type and maturity of organic matter dispersed in Ordovician, Silurian, Devonian and Lower Carboniferous strata in the basement of the Carpathian Foredeep between Kraków and Rzeszów were determined based on the results of organic geochemical analyses of 600 rock samples collected from 44 wells. The best source rocks were found in the Silurian strata where the total organic carbon (TOC) content is up to 6.6 wt% and the median value equals ca. 1.5 wt%. The median values of the initial organic carbon contents in individual wells vary from 1.2 to 3.5 wt%. The Ordovician, Lower Devonian and clastic facies of the Lower Carboniferous strata can be considered as an additional source of hydrocarbons with the median TOC values of 0.27, 0.56 and 0.53 wt%, respectively. The Middle and Upper Devonian strata as well as the carbonate facies of the Lower Carboniferous strata have much lower quantities of organic carbon, although in these strata levels with elevated TOC contents were observed. In the Lower Palaeozoic and Lower Devonian strata, the oil-prone, low-sulphur Type II kerogen is present, whereas in the younger divisions presence of the gas-prone Type III kerogen is visible. In the Lower Carboniferous clastics gas-prone kerogen dominates. The Silurian and clastic facies of the Lower Carboniferous strata have been deposited in the normal marine conditions, whereas the Ordovician, Devonian and carbonate facies of the Lower Carboniferous strata usually experienced reducing conditions. The source rocks are mostly at the initial and middle phase of the low-temperature thermogenic processes. Locally, immature (in the Lower Carboniferous carbonates in the vicinity of Łąkta gas-condensate field) or late-mature (in the Middle and Upper Devonian strata in the area of Grobla–Pławowice oil field) source rocks were observed.
Źródło:
Annales Societatis Geologorum Poloniae; 2011, 81, No 3; 375-394
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Inkluzje fluidalne w halicie oraz bituminy w solach ewaporatów mioceńskich ukraińskiego Przedkarpacia jako wskaźnik występowania nagromadzeń węglowodorów w niżej leżących utworach
Fluid inclusions in halite and bitumens in rock salt from Miocene evaporites in the Ukrainian Fore-Carpathian region: as indicators of hydrocarbon accumulations in the underlying strata
Autorzy:
Więcław, D.
Lytvyniuk, S. F.
Kovalevych, V. M.
Peryt, T.M.
Powiązania:
https://bibliotekanauki.pl/articles/2074593.pdf
Data publikacji:
2008
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
inkluzje fluidalne
bituminy
trwałe izotopy węgla
miocen
zapadlisko przedkarpackie
ewaporaty
fluid inclusions
bitumens
stable carbon isotopes
biomarkers
Miocene
Carpathian Foredeep
evaporites
Opis:
Fluid inclusions in halite from Miocene rock salt of the Ukrainian Carpathian Foredeep Basin in locations where evaporites overlie oil and gas reservoir rocks are characterized by their high methane content and the presence of oil droplets in some of them. They are thus similar to fluid inclusions reported from geochemical aureoles around oil and gas accumulations in the Zechstein (Upper Permian) of western Poland (Kovalevych et al., 2008). Geochemical analyses of bitumen in bulk samples of rock salt (including content and distribution of n-alkanes and isoprenoids, carbon isotope ratios) suggest a varied origin: hydrocarbon extracted from halite from boreholes located in proximity (proved or assumed) of oil and gas deposits (Lopushna-7, Grynivka-525) are probably related to organic material dispersed within the rock salt itself, and those from the barren areas (Verkhniy Strutyn-29) are most probably cogenetic with oil accumulated in the deposits of the Boryslav-Pokuttya Nappe.
Źródło:
Przegląd Geologiczny; 2008, 56, 9; 837-841
0033-2151
Pojawia się w:
Przegląd Geologiczny
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Origin and maturity of oils in the Ukrainian Carpathians and their Mesozoic basement
Autorzy:
Więcław, D.
Kotarba, M. J.
Kowalski, A.
Koltun, Y. V.
Powiązania:
https://bibliotekanauki.pl/articles/2058970.pdf
Data publikacji:
2012
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Ukrainian Carpathians
Carpathian Foredeep
biomarkers
stable carbon isotopes
Opis:
Geochemical characteristics of 25 oils collected from Skiba Unit of the Outer Carpathians, Boryslav-Pokuttya Unit of the Carpathian Foredeep and their Mesozoic basement in the western Ukraine are presented in the paper. The first recognised oil family consists of almost all oils accumulated in the flysch sequence of the Outer Carpathians and the Carpathian Foredeep which have very similar geochemical characteristics. These oils were generated from Type II or II/III kerogen deposited in clastic sediments. They are low-sulphur and migrated short distances. Slight biodegradation processes are visible only in oils accumulated in shallow deposits in the Skiba Unit. Their source rocks are the Oligocene Menilite Shales from the Boryslav-Pokuttya Unit. Oils from the Kokhanivka and Orkhovychi deposits (the Mesozoic basement of the Carpathian Foredeep) constitute the second family. These oils are extremely heavy, high-sulphur and were generated from high-sulphur Type IIS kerogen deposited in the carbonate environment. The most probable source rocks for these oils are the Upper Jurassic strata. Oil collected from the Vola Blazhivska deposit (the Boryslav-Pokuttya Unit) shows intermediate parameters between the oil families described above. It is characterized by the presence of oleanane and high sulphur content. It was generated from the Menilite Shales containing high-sulphur kerogen. All oils were generated at an early stage or the peak of oil window.
Źródło:
Geological Quarterly; 2012, 56, 1; 158-168
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Origin of liquid hydrocarbons accumulated in the Miocene strata of the Polish Carpathian Foredeep and its Palaeozoic–Mesozoic basement
Autorzy:
Więcław, D.
Powiązania:
https://bibliotekanauki.pl/articles/191540.pdf
Data publikacji:
2011
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
oil origin
biomarkers
stable carbon isotopes
oil-oil correlation
Palaeozoic–Mesozoic basement
Polish Carpathian Foredeep
Opis:
Petroleum geochemical data of 34 oils and condensates accumulated in the Carpathian Foredeep and its Mesozoic and Palaeozoic basement were used to assess their origin and genetic type. The analysed liquid hydrocarbons are characterized by variable densities and sulphur contents. No relationship between these parameters and the reservoir rock age has been found. Secondary processes of evaporative fractionation and biodegradation are evidenced for some oils. These processes proceeded most intensively on the oil from Góra Ropczycka-1K well. The oils from Opaka-1, Lubaczów-157 and Góra Ropczycka-1K wells were generated from organic matter deposited in the Upper Jurassic carbonates. The oil from the inflow in Załazie-2 well originated from the Cambrian strata, but also contains biomarkers characteristic of Miocene strata. The next family, genetically connected with the Silurian and Ordovician source rocks, consists of oils accumulated in the Lower Carboniferous carbonates in Nosówka deposit and in the Upper Jurassic in the inflow into Łękawica-1 well. The condensates collected from the Miocene (Łękawica-1, Pilzno-37, Tarnów-39 and -45 wells) and Upper Jurassic strata (Łąkta-27 and Tarnów-5 wells) were generated by organic matter dispersed in the Middle Jurassic or Lower Carboniferous clastic facies. The remaining oils, from Grobla-Pławowice, Wierzchosławice, Jastrząbka Stara, Partynia-Podborze, Dąbrowa Tarnowska, Brzezówka and Zagorzyce deposits, and the inflows into Tarnów-47 and Pilzno-12 wells were generated from kerogen enriched in organic sulphur usually dispersed in carbonate rocks. Such a type of sediments occurs in the Devonian and Lower Carboniferous strata. Also, these strata as well as the underlying Silurian rocks have sufficient maturity for generation of the discussed oils. The oleanane in the discussed oils most probably originates from kerogen of the Upper Cretaceous or Miocene strata, through which these oils migrated and eluted this biomarker.
Źródło:
Annales Societatis Geologorum Poloniae; 2011, 81, No 3; 443-458
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
From carbonate platform to euxinic sea – the collapse of an Early/Middle Devonian reef, Cantabrian Mountains (Spain)
Autorzy:
van Loevezijn, G. B. S.
Raven, J. G. M.
Powiązania:
https://bibliotekanauki.pl/articles/94474.pdf
Data publikacji:
2017
Wydawca:
Uniwersytet im. Adama Mickiewicza w Poznaniu
Tematy:
Anoxia
Basal Choteč Event
Cantabria
carbon isotopes
Eifelian
Emsian
anoksja
Kantabria
izotopy węgla
eifel
ems
Opis:
The Santa Lucía Formation represents the major phase in Devonian reef development of the Cantabrian Zone (Cantabrian Mountains, northwest Spain). In the present study the transition from the carbonate platform deposits of the Santa Lucía Formation to the overlying euxinic basinal deposits of the Huergas Formation is described. These transitional strata are connected to the Basal Choteč Event and represent a condensed sedimentation of micritic dark-grey and black limestones with an upward increase of dark shale intercalations with iron mineralisation surfaces and storm-induced brachiopod coquinas. The transitional beds are grouped into a new unit, the Cabornera Bed, which consists of lime-stone, limestone-shale and shale facies associations, representing a sediment-starved euxinic offshore area just below the storm wave base. Four stages in reef decline can be recognised: a reef stage, an oxygen-depleted, nutrient-rich stage, a siliciclastic-influx stage and a pelagic-siliciclastic stage. Additional geochemical and geophysical investigations are needed to verify the results presented herein.
Źródło:
Geologos; 2017, 23, 3; 143--161
1426-8981
2080-6574
Pojawia się w:
Geologos
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ageing of organic matter in incubated freshwater sediments; in fer ences from C and H isotope ratios of methane
Autorzy:
Szynkiewicz, A.
Modelska, A.
Jedrysek, M-O.
Kurasiewicz, M.
Mastalerz, M.
Powiązania:
https://bibliotekanauki.pl/articles/2059090.pdf
Data publikacji:
2008
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
methanogenic pathways
carbon and hydrogen isotopes
incubation
freshwater sediments
Opis:
The freshwater sediments were incubated under anaerobic conditions for 570 and 879 days to in vestigate the potential variations in methanogenic pathways due to increasing sediment age and recalcitrance of organic matter. The methanogenic pathways did not shift from acetate fermentation toward CO2 reduction, as indicated by the observed variations of the isotopic composition of methane in natural conditions. It appeared, however, that the observed decrease of methane concentration (from 86 to 39%) and continuous in crease in d13C(CH4) (from –69.7 to –59.0‰) and dD(CH4) values (from –381 to –320‰) resulted mainly from exhaustion of at least one methanogenic substratein the incubated sediments. To better understand processes controlling the variations of delta exp.13C(CH4) and deltaD(CH4) values relative to ageing of organic matter, the method of principal component analysis (PCA) was used. This method offers good comparison of the relation ships between variables when a larger number of parameters control a given process in the same time period. In this study, the PCA indicated three distinctive factors that controlled decomposition of organic matter during the incubation. Factor 1 explained 33% of observed variations among the variables and had positive (0.93–0.92) loadings for electric conductivity and DIC concentration and negative loading for delta exp.13C(CH4) val ues (–0.72). Factor 2 accounted for 28% and had high posi ive loading for deltaD(CH4) value (0.86) and high negative loading for methane concentration (–0.81). Factor 3 accounted for 19% and exhibited high positive loadings for temperature (0.90) and delta exp.13C(DIC) value (0.69). Factors 1 and 2 were directly linked to the methanogenesis and indicated that bigger accumulation of bio-products in sediments is likely important for variations of delta exp.3C and deltaD of methane. This study shows that method of principal component analysis might be a useful tool while studying biogeochemical carboncy cleduring early digenesis of freshwater sediments.
Źródło:
Geological Quarterly; 2008, 52, 4; 383-383
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Metodyka analiz izotopowych rozpuszczonego węgla nieorganicznego (DIC) i ich zastosowania w badaniach hydrogeologicznych i środowiskowych
Methodology and application of stable isotope analysis of dissolved inorganic carbon (DIC) in hydrogeology and environmental studies
Autorzy:
Szynkiewicz, A.
Drzewicki, W.
Jędrysek, M. O.
Powiązania:
https://bibliotekanauki.pl/articles/2074490.pdf
Data publikacji:
2006
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
rozpuszczony węgiel nieorganiczny (DIC)
izotop węgla
dissolved inorganic carbon
carbon isotopes
Opis:
The analysis of carbon isotope composition of dissolved inorganic carbon (DIC) is widely applied in hydrogeology and environmental studies. The method of analysis is simple and based on conversion of all DIC species to gaseus CO2 under acidic conditions. However, the analytical procedure may involve significant carbon isotope fractionation. Our experimental analysis showed that increasing the time of CO2 extraction influences the increase of ä13C(DIC) value as a result of re-dissolution of CO2 in the water expanded on the vacuum line or/and carbon isotope exchange between the extracted CO2 and the atmospheric CO2. The long time of sample storage yields an increase of ä13C(DIC) value and decrease of DIC concentration. The analytical precision up to š 0,1‰ may be achieved in the case of waters being analyzed few days after sampling. DIC concentration was evaluated according to height of peak 44 in the mass spectrum. The analytical precision of this method was š 2 mgCO2 per dm3. This method is very useful because the measurements of the height of peak 44 and carbon isotope composition of DIC can be performed simultaneously. However, this method is reliable for waters containing more than 4 mg CO2 per dm3
Źródło:
Przegląd Geologiczny; 2006, 54, 9; 797-806
0033-2151
Pojawia się w:
Przegląd Geologiczny
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Respiration and assimilation processes reflected in the carbon isotopic composition of atmospheric carbon dioxide
Autorzy:
Szaran, J.
Niezgoda, H.
Trembaczowski, A.
Powiązania:
https://bibliotekanauki.pl/articles/146953.pdf
Data publikacji:
2002
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
atmosphere
carbon dioxide
carbon isotopes
delta-C-13
respiration
Opis:
This paper presents diurnal variations of concentration and carbon isotopic composition of atmospheric carbon dioxide caused by respiration and assimilation processes. Air samples were collected during early and late summer in 1998 in unpolluted area (village Guciow located near the Roztocze National Park, SE Poland) in three different environments: uncultivated field on a hill, a meadow in the Wieprz river valley and a forest. The effect is very strong during intensive vegetation growth on a sunny day and clear night. The largest diurnal variations in atmospheric CO2 concentration and its carbon isotopic composition in June above the meadow were about 480 ppm and 10‰, respectively.
Źródło:
Nukleonika; 2002, 47,suppl.1; 59-61
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Calibration of temperature carbon isotopic effect (Peat Bogs Hala Izerska, Izerskie Mts. and Szrenica, Karkonosze Mts.)
Autorzy:
Skrzypek, G.
Jędrysek, M. O.
Keller-Sikora, A.
Powiązania:
https://bibliotekanauki.pl/articles/1186009.pdf
Data publikacji:
2005
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
izotopy trwałe
węgiel
temperatura
profil torfowy
stable isotopes
carbon
temperature
peat core
Opis:
Dwa rdzenie torfowe pochodzące z Karkonoszy i Gór Izerskich zostały przeanalizowane pod kątem zależności składu izotopowego węgla i temperatury powietrza okresu wegetacji w miejscu poboru. Ciągłe rdzenie torfowe o długości całkowitej 160 i 195 cm, obejmujące ostanie 4500 lat, podzielono na próbki o miąższości 4-6 cm. Uzyskane wartości ?13C zawierają się w przedziale od -26,85 do -21,8‰. Próbki z poszczególnych części rdzeni zostały skorelowane wiekowo na podstawie datowań radiowęglowych (14C). Temperatura powietrza była monitorowana za pomocą automatycznych rejestratorów HOBO Oneset podczas sezonu wegetacyjnego 2004. Na podstawie analizy temperatur stwierdzono, że sezon wegetacyjny w Karkonoszach (punkt na wysokości 1240 m n.p.m.) trwa od 29 kwietnia do 7 października przy średniej temperaturze powietrza 9,2 stopni C, natomiast na Hali Izerskiej od 27 kwietnia do 7 października przy średniej temperaturze 10,4 stopni C (wysokość 857 m n.p.m., las) i 11,5stopni C (843 m n.p.m., otwarta przestrzeń, hala). Wzrost temperatury powietrza sezonu wegetacyjnego o 1stopień C powoduje zmianę wartości ?13C materii organicznej roślin torfotwórczych o -0,83‰
Źródło:
Polish Geological Institute Special Papers; 2005, 16; 123-126
1507-9791
Pojawia się w:
Polish Geological Institute Special Papers
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Surface geochemical survey at Starunia palaeontological site and vicinity (Carpathian region, Ukraine)
Autorzy:
Sechman, H.
Kotarba, M. J.
Dzieniewicz, M.
Powiązania:
https://bibliotekanauki.pl/articles/191493.pdf
Data publikacji:
2009
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
surface geochemical survey
stable carbon isotopes
methane origin
gaseous hydrocar bon C2-C5
carbon dioxide origin
woolly rhinoceros
Starunia
Carpathian region
Ukraine
Opis:
A surface geochemical survey was carried out in an abandoned ozokerite mine in Starunia, where remnants of a mammoth and three woolly rhinoceroses and one almost completely preserved rhinoceros carcass were found in 1907 and 1929. In total, 689 measurement sites were defined within the selected 300×350 m rectangle (ca. 10.5 ha). The analysed soil gases vary in their molecular and isotopic compositions. Several zones with anomalous methane concentrations over 10 vol% were identified in the study area. These anomalous concentrations correlate well with total C2-C5 alkane anomalies (over 1 vol%). The zones with carbon dioxide concentrations over 15 vol% are generally shifted SW of those, where the methane and the sum of C2-C5 alkanes anomalies were identified. High helium concentrations of crustal origin (over 0.001 vol%) are clustered near fault zones. In a majority of cases methane is of thermogenic origin, migrating to the near-surface zone from deep-seated accumulations. Microbial methane, or methane with a high microbial component, is genetically related to recent swamps. The high variability of concentrations of gaseous components together with the highly variable isotopic composition of individual gases in the soil, indicate their thermogenic and/or microbial origin, and point to the lithological diversity of Quaternary sediments in the study area. Several zones with thermogenic gaseous hydrocarbons and helium were delineated. It is likely that during the Pleistocene winters, under a thick ice and snow cover, the tundra lake and swamp zones around outflows of brines, oil, helium and thermogenic gases had a higher temperature, which resulted in melting and cracking of the ice cover. These sites would be more prospective for future search of well-preserved large vertebrates.
Źródło:
Annales Societatis Geologorum Poloniae; 2009, 79, No 3; 375-390
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Changes in paleo-circulation and the distribution of ammonite faunas at the Coniacian–Santonian transition in central Poland and western Ukraine
Autorzy:
Remin, Z.
Gruszczyński, M.
Marshall, J. D.
Powiązania:
https://bibliotekanauki.pl/articles/139412.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Coniacian–Santonian transition
paleogeography
paleo-circulation
ammonites
carbon stable isotopes
oxygen stable isotopes
paleogeografia
amonity
izotopy węgla
izotop tlenu
Opis:
Ammonite distribution patterns and carbon and oxygen stable isotopes from the Lipnik-Kije (Poland) and Dubovcy (Ukraine) sections allow us to propose a model of sea water paleo-circulation in central Europe for the Coniacian-Santonian interval. The tectonic evolution of the south-eastern part of Poland, and expansion of the Krukienic Island areas, appears to have been one of the most important factors affecting paleotemperatures and the distribution of ammonite faunas in the shallow, epicontinental sea in this part of Europe. In the Lipnik-Kije section, low-latitude Tethyan ammonites, especially of the genera Nowakites, Parapuzosia and Saghalinites, are mixed with the cold water loving ammonite genus Kitchinites in the Lower Santonian. In the Dubovcy section (western Ukraine), Tethyan ammonites disappear abruptly in the earliest Santonian, giving place to temperate ammonites of the Kitchinites group in the early Early Santonian and to Boreal belemnites of the genus Gonioteuthis in the Middle and Late Santonian. Despite evidence for the effects of diagenesis in both sections, bulk-rock δ18O records from the limestones support higher seawater paleotemperatures in the Polish sea and cooler conditions in the western Ukraine. The proposed paleo-circulation model and paleotemperature distribution across Europe is supported independently by changes in faunal and nannoflora evidence (ammonites, foraminifera and nannoplankton), and rather unexpectedly with the bulk δ18O data. These data allow the recognition of the end-Coniacian–Early Santonian cooling event, resulting from cold currents flowing from the north, which is traceable, with different magnitude, in several European sections. Facies changes in both sections are related to the input of terrigenous material, and linked to Subhercynian tectonic movements which affected the eastern (Ukrainian) and central (Holy Cross) segment of the Mid Polish Trough at different times. Uplift and sediment input moved westwards through time. Clastic input is detectable at the Coniacian–Santonian boundary in the Ukrainian segment. Similar facies changes reached the Holy Cross segment in Poland distinctly later, somewhen in the Middle Santonian. It is likely that tectonics together with paleo-circulation changes markedly restricted or even cut-off the western Ukraine area from Tethyan ocean influences in the Early Santonian.
Źródło:
Acta Geologica Polonica; 2016, 66, 1; 107-124
0001-5709
Pojawia się w:
Acta Geologica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 53

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