- Tytuł:
- Luminescence Properties of CaAl₂O₄:Eu³⁺, Gd³⁺ Phosphors Synthesized by Combustion Synthesis Method
- Autorzy:
-
Verma, N.
Singh, K.
Marí, B.
Mollar, M.
Jindal, J. - Powiązania:
- https://bibliotekanauki.pl/articles/1030093.pdf
- Data publikacji:
- 2017-10
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
phosphors
luminescence
combustion method
calcium aluminate - Opis:
- CaAl₂O₄:Eu³⁺ (1 mol.%) co-doped with varying concentration of Gd³⁺ (1, 2, 5, and 10 mol.%) were prepared by combustion synthesis method at 600°C and further annealed at 1000°C. All the compositions were investigated for their structural and photoluminescence properties. It was observed that both states of europium i.e. Eu³⁺ and Eu²⁺ were present and ratio of these states changes on heating at 1000°C. The materials synthesized at 600°C showed high intense peak around 440 nm due to presence of Eu²⁺ and less intense peaks in the red region which were due to presence of Eu³⁺. On annealing the compounds at 1000°C, intensity of peak around 440 nm decreases and intensity of peaks in the red region increases significantly. The ⁵D₀ → ⁷F₃ transition due to Eu³⁺ at 657 nm appears as the highest intensity peak. All co-doped samples annealed at 1000°C showed the higher intensity than the mono doped sample which is due to energy transfer from the Gd³⁺ to Eu³⁺. The second rare-earth ion (Gd³⁺) acts as sensitizer and enhances the photoluminescence intensity. The X-ray diffraction spectra reveal the monoclinic phase of CaAl₂O₄ in all the samples which showed that Eu³⁺ and Gd³⁺ do not change the crystalline structure of calcium aluminate.
- Źródło:
-
Acta Physica Polonica A; 2017, 132, 4; 1261-1264
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł