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Tytuł:
Sorption of Cd(II), Ni(II) and Zn(II) on natural, sodium-, and acid-modified clinoptilolite-rich tuff
Autorzy:
Abatal, M.
Olguin, M. T.
Abdellaoui, Y.
El Bouari, A.
Powiązania:
https://bibliotekanauki.pl/articles/208078.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
heavy metals
clinoptilolite
cadmium removal
metale ciężkie
klinoptylolit
usuwanie kadmu
Opis:
Sorption of Cd2+, Ni2+and Zn2+ions on natural (ZPCli), sodium modified (ZPCliNa) and acid modified (ZPCliH) zeolites have been investigated in function of the contact time, pH, and metal concentration by the batch technique. The characterization of ZPCIi, ZPCliNa, and ZPCliH materials was performed using X-ray powder diffraction, scanning electron microscopy and energy dispersive X-ray spectroscopy techniques. The surface area (BET) and the pHpzcwere also determined. The pH in the point of the zero charge of ZPCli, ZPCliNa, and ZPCliH zeolites was 8.25, 8.00, and 2.05, respectively. The kinetic sorption data for ZPCli, ZPCliNa and ZPCliH were well fitted to the pseudo-second order model (R2> 0.99). The linear model described the Cd, Ni and Zn sorption isotherms for ZPCliH, while for ZPCliNa and ZPCliH it was the Freundlich model. The unmodified and modified zeolitic materials showed the highest sorption capacity for Cd2+, lower for Zn2+ and Ni2+.
Źródło:
Environment Protection Engineering; 2018, 44, 1; 41-59
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Investigation on the structural, optical and topographical behavior of Cadmium oxide polycrystalline thin films using electrochemical depositing method at different times
Autorzy:
Abd, Ahmed N.
Dawood, Mohammed O.
Hassoni, Majid H.
Hussein, Ali A.
Powiązania:
https://bibliotekanauki.pl/articles/1192094.pdf
Data publikacji:
2016
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Cadmium oxide
thin film
optical characteristics of film
electrochemical depositing method
Opis:
The optical and structure properties of Cadmium oxide (CdO) thin film prepared by electrochemical deposition method at different times (15, 30 and 60) min were investigated in this paper. Results of optical Transmission, absorption, reflection spectra, optical conductance, refractive index, extension coefficient, real and imaginary dielectric constants studies are reported. The optical transmittance of the CdO thin film which formed at room temperature was 20% at wavelength ≈350 nm then increases to 60% at wavelength ≈1100 nm for thin film of CdO. The band-gap was also calculated from the equation relating absorption coefficient with the wavelength. The energy band gap changes from 2.3eV (Bulk CdO) to 2.45eV (CdO thin film). The plotted graphs show the optical characteristics of the film which varied with the wavelength and the photon energy. The optical conductance and band-gap indicated that the film is transmitting within the visible range. The dielectric constant and optical conductance of the film initially decreases slowly with increase in photon energy. The extinction coefficient and refractive index of the films also evaluated, which affected with the change in transmittance. The structure of synthesised CdO thin film was analyzed by X-ray diffraction XRD which revealed that the CdO thin film are polycrystalline and have several peaks of cubic face structure. The crystallite size, dislocation density, microstrain and number of dislocations of the thin film were calculated and listed.
Źródło:
World Scientific News; 2016, 37; 249-264
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Migration of Cadmium and Antimony from Zinc Oxide Emitted from a Sintering Machine in Zn and Pb Pyrometallurgical Process into Environment
Możliwość migracji kadmu i antymonu z tlenku cynku pochodzącego z maszyny spiekalniczej pyrometalurgicznego otrzymywania Zn i Pb do środowiska
Autorzy:
Adamczyk, Zdzisław
Nowińska, Katarzyna
Powiązania:
https://bibliotekanauki.pl/articles/1812067.pdf
Data publikacji:
2019
Wydawca:
Politechnika Koszalińska. Wydawnictwo Uczelniane
Tematy:
pyrometallurgy
zinc
lead
zinc oxide
cadmium
antimony
Eh-pH diagrams
ground-water environment
pirometalurgia
cynk
ołów
tlenek cynku
kadm
antymon
diagramy Eh-pH
środowisko gruntowo-wodne
Opis:
The pyrometallurgical process of production of zinc and lead realized in The Zinc Smelting Plant "Miasteczko Śląskie" S.A. poses a potential threat to the natural environment. Technologies applied in the process produce toxic pollutants, among which one of the most important is dust which contains Pb, Zn, Cd, As, Sb, Tl, etc. The detailed determination of chemical and mineral compositions of the dust allows to understand its behaviour in the environment and observe migration pathways. The paper presents results of investigations of the migration possibility to the soil and water environment of trace elements cadmium and antimony present in one of the main phases, zinc oxide, emitted with dusts from various operations of pyrometallurgical extraction of Zn and Pb at the Miasteczko Slaskie Zinc Smelting Plant, Poland. The quantity of elements was estimated on the basis of: (i) dust fall, (ii) zinc oxide content in dust, (iii) element content in zinc oxide, and (iv) mobility of zinc oxide under the hypergenic conditions of the soil and water environment of the Smelting Plant area. Among the elements considered, cadmium and antimony emitted with zinc oxide contained in dusts from the Sintering Machine will pose a potential hazard for the soil and water environment of the Miasteczko Slaskie Zinc Smelting Plant area.
Proces pirometalurgicznego otrzymywania cynku i ołowiu metodą Imperial Smelting Process (ISP) stwarza potencjalne zagrożenie dla środowiska naturalnego. Proces technologiczny ISP jest źródłem toksycznych zanieczyszczeń, spośród których jednymi z najważniejszych są pyły zawierające w swym składzie między innymi takie pierwiastki jak Pb, Zn, Cd, As, Sb, Tl. Dokładne poznanie składu chemicznego i mineralnego zanieczyszczeń pyłowych pozwala na określenie ich zachowania się w środowisku, prześledzienie drogi migracji. W pracy przedstawiono wyniki badań możliwości migracji do środowiska gruntowo-wodnego pierwiastków śladowych występujących w jednej z głównych faz – siarczku cynku – emitowanej z pyłami pochodzącymi z różnych odcinków technologicznych pyrometalurgicznego otrzymywania Zn i Pb w Hucie Cynku Miasteczko Śląskie S.A., Polska. Ilość pierwiastków została oszacowana na podstawie: (i) opadu pyłu, (ii) udziału siarczku cynku w pyle, (iii) zawartości pierwiastka w siarczku cynku oraz (iii) mobilności siarczku cynku w warunkach hipergenicznych środowiska gruntowo-wodnego rejonu huty. Potencjalne zagrożenie dla środowiska gruntowo-wodnego rejonu Huty Cynku „Miasteczko Śląskie” S.A., spośród rozpatrywanych pierwiastków, będą stanowić kadm oraz antymon emitowane wraz z siarczkiem cynku zawartym w pyłach Maszyny Spiekalniczej
Źródło:
Rocznik Ochrona Środowiska; 2019, Tom 21, cz. 2; 1307-1317
1506-218X
Pojawia się w:
Rocznik Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Removal of chromium(VI) from wastewater through ion exchange. Kinetic and scale up studies
Autorzy:
Ahmad, Syed Waqas
Zafar, Muhammad Shahzad
Ahmad, Sajjad
Zia-Ul-Haq, M.
Ashraf, Muhammad
Rabbani, Javed
Ullah, Sami
Powiązania:
https://bibliotekanauki.pl/articles/208034.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
ion exchange
industrial wastewater
anion resin
heavy metals
cadmium
wymiana jonowa
ścieki przemysłowe
żywica anionowa
metale ciężkie
kadm
Opis:
Chromium(VI) ions were removed from industrial wastewater. In this regard, a rig was fabricated carrying alkaline anion resin. Various experiments were carried out by varying pH, temperature and volumetric flow rate of solution by employing a rig to study the kinetics of the ion exchange process. The rate constant (k) and maximum solid phase concentration of exchanged solute (q0) were calculated using the Thomson equation to scale up the purification process of industrial runoff of chromium(VI) from the tanning, photography and ceramic industry. Experimental optimization revealed that developed setup will remove chromium(VI) to a level of 5 mg/dm3 from 300 mg/dm3 in 40 000 dm3 of wastewater. To achieve the best results for the flow rate of 10 000 3 3/day, 12.03 kg of anionic resin were recommended by fixing the pH of the setup at 7.4 while maintaining the treatment temperature at 20 °C.
Źródło:
Environment Protection Engineering; 2019, 45, 1; 17-29
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Biochar as a Cadmium Scavenger in the Aquatic Environment Remediation: Date Seeds as Raw Material
Autorzy:
Al-Tarawneh, Amjad
Powiązania:
https://bibliotekanauki.pl/articles/2068474.pdf
Data publikacji:
2022
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
biochar
date seed
pyrolysis
cadmium
adsorption
isotherm
spectroscopy
Opis:
It was found that date seeds are suitable for biochar production due to their low moisture content 8.92%, low ash yield 1.05%, and high organic matter content 78.3%. The biochar was produced by pyrolysis at 350, 450 and 550°C. The effect of pyrolysis temperature on the physicochemical characteristics of biochar was investigated. It was found that the porosity, water holding capacity, ash content, pH, organic matter, fixed carbon, and the elemental content of Na, K, Ca, Mg, Fe, Mn, P, Zn, Ba, Cr, Cu, Ni, Pb, Ti, and V were increased along with pyrolysis temperature. Meanwhile, the biochar yield, bulk density, and the total content of N and S were decreased. The biochar was tested as a sustainable adsorbent to investigate the adsorption of Cd from contaminated water. The adsorption isotherms of Cd on biochar were determined based on Langmuir equation. The maximum adsorption of Cd at 25°C and pH 7 were 667, 714, and 833 mg/kg for the biochars produced at 350, 450, and 550°C, respectively. On the basis of the physicochemical characteristics of the biochar and the findings from Langmuir equation that showed the biochar produced at 550°C has the highest adsorption capacity for Cd, the desorption/adsorption experiment was carried out using the biochar produced at 550°C. The adsorption of Cd by biochar was directly proportional to the Cd concentrations. It was increased from 0.009 mmol/0.5g at 0.01 mmol Cd to 0.12 mmol/0.5g at 0.2 mmol Cd concentration. The desorption of Cd from biochar was increased proportionally to cadmium concentrations from 0.01 to 0.05 mmol and became constant above 0.05 mmol, regardless of the increment of cadmium concentrations. High retention potential for the cadmium that adsorbed within the biochar was proven in this study with desorption/adsorption percentage of 16%. These findings provide a successful example of date seeds converting into the sustainable adsorbent for Cd removal from aquatic environment to achieve the conception of eco-friendly production, which should be studied further.
Źródło:
Journal of Ecological Engineering; 2022, 23, 3; 270--280
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Substrate Temperature on Structural and Optical Properties of CdO Thin Films
Autorzy:
Ali, H. R. A.
Powiązania:
https://bibliotekanauki.pl/articles/411893.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
cadmium oxide
spray pyrolysis technique
XRD
AFM
thin films
sol-gel
Opis:
Thin films of CdO have been prepared by spray pyrolysis technique. XRD analysis reveals that all the prepared samples were polycrystalline and have preferred orientation along [111] orientation. The surface topography was determined by AFM which indicate that surface roughness and rms roughness were increased by the increasing of substrate temperature. The optical energy gap were determined and its value lies between (2.4-2.5) eV.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 8; 47-55
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structural and optical properties of nanocrystalline CdS films prepared by spray pyrolysis
Autorzy:
Aljarrah, Radhyah M. S.
Aljobory, Adnan H.
Powiązania:
https://bibliotekanauki.pl/articles/1179009.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Cadmium Sulphide
CdS films
spray pyrolysis
Opis:
Cadmium Sulphide (CdS) thin films are produced using spray pyrolysis deposition technique. Films are annealed in air at 400, 500, and 600 K of 1 h. It characterized by X-Ray Diffraction (XRD), Atomic Force Microscope (AFM) and optical properties of CdS. XRD shows that these films are polycrystalline in nature with cubic and hexagonal crystalline structure. The crystallite size, microstrain, and dislocation density were measured. AFM shows that the total substrate surface is finely covered with uniformly distributed spherical shaped grains. Optical transmittance was shown that direct transition with band gap energy was decreased between 2.44 to 2.27 eV with annealing.
Źródło:
World Scientific News; 2017, 87; 175-190
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Cadmium concentrations in the Bahia Blanca Estuary (Argentina). Potential effects of dissolved cadmium on the diatom Thalassiosira curviseriata
Autorzy:
Andrade, S.J.
Pucci, A.E.
Marcovecchio, J.E.
Powiązania:
https://bibliotekanauki.pl/articles/48820.pdf
Data publikacji:
2000
Wydawca:
Polska Akademia Nauk. Instytut Oceanologii PAN
Tematy:
Argentina
cadmium concentration
Bahia Blanca Estuary
potential effect
toxicity
Thalassiosira curviseriata
estuary
diatom
Opis:
Concentrations of dissolved and particulate cadmium were measured in the water of the Bah´ıa Blanca Estuary, one of the most highly industrialised regions in Argentina. Simultaneously, Cd contents were also determined in samples of phytoplankton. Thus, the estuary was characterised from the viewpoint of Cd occurrence. Additionally, a microscale environment was selected within the estuary in order to carry out an ecotoxicological study. Thus, environmental parameters (i.e. temperature, salinity, nutrients, chlorophyll a) were measured weekly at Puerto Cuatreros (in the inner estuary) during winter, when the phytoplankton bloom occurs; during the other seasons sampling was done twice a week. In addition, cells of the diatom Thalassiosira curviseriata – the dominant species in the phytoplankton bloom – were isolated and cultivated in the laboratory. The monoclonal cultures obtained were exposed to increasing concentrations of Cd under controlled environmental conditions and the growth rate inhibition was measured. As a preliminary conclusion it was found that Cd levels in the Bah´ıa Blanca Estuary are significantly lower than the EC50 value for T. curviseriata.
Źródło:
Oceanologia; 2000, 42, 4
0078-3234
Pojawia się w:
Oceanologia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Manganese, zinc, cadmium and lead in plants of Dolgie Great Lake
Mangan, cynk, kadm i ołów w roślinach jeziora Dołgie Wielkie
Autorzy:
Antonowicz, J.
Trojanowski, J.
Powiązania:
https://bibliotekanauki.pl/articles/85177.pdf
Data publikacji:
2003
Wydawca:
Akademia Pomorska w Słupsku
Tematy:
manganese
zinc
cadmium
lead
plant
Myriophyllum spicatum
Potamogeton lucens
Acorus calamus
Nuphar luteum
Lake Dolgie Wielkie
metal concentration
Źródło:
Baltic Coastal Zone. Journal of Ecology and Protection of the Coastline; 2002-2003, 07
1643-0115
Pojawia się w:
Baltic Coastal Zone. Journal of Ecology and Protection of the Coastline
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of pH and organic substances on the zinc and cadmium binding by the polynuclear Al13
Autorzy:
Badora, A.
Powiązania:
https://bibliotekanauki.pl/articles/795311.pdf
Data publikacji:
1998
Wydawca:
Szkoła Główna Gospodarstwa Wiejskiego w Warszawie. Wydawnictwo Szkoły Głównej Gospodarstwa Wiejskiego w Warszawie
Tematy:
pH
organic substance
zinc
cadmium
polynuclear aluminium complex
aluminium
heavy metal binding
Opis:
The aim of the present study was to determine the influence of the reaction and organic substance on the effectiveness of zinc and cadmium binding by Al₁₃ The presence of organic substance in the combinations with Al₁₃ and toxic elements did not block the binding Al₁₃ activity. However, its type and amount influenced the effects of cadmium and zinc immobilisation and mobilisation. Cadmium in the solution was antagonistically related to zinc and other microelements in the plant which was confirmed in the mineral composition and presentation of the studied plants.
Źródło:
Zeszyty Problemowe Postępów Nauk Rolniczych; 1998, 456
0084-5477
Pojawia się w:
Zeszyty Problemowe Postępów Nauk Rolniczych
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Biosorption of Heavy Metals from Synthetic Wastewater by Using Macro Algae Collected from Iraqi Marshlands
Autorzy:
Bahaa, Shaymaa
Al-Baldawi, Israa Abdulwahab
Yaseen, Safaa Rasheed
Abdullah, Siti Rozaimah Sheikh
Powiązania:
https://bibliotekanauki.pl/articles/123810.pdf
Data publikacji:
2019
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
adsorption
Cladophora
copper
cadmium
chromium
aqueous solutions
Opis:
Biosorption is fast, effective and low cost process. It takes place in a wide range of temperature and it can be used for almost all types of heavy metals. The aim of this study was to investigate the ability of locally collected green macro algae to remove copper, chromium and cadmium from synthetic wastewater. The fresh algae were converted into dry powder as biosorbent. In the investigations, 1 g of macro algae powder was exposed to synthetic waste water contaminated with 10 mg/L concentration of copper, chromium and cadmium in separate exposure for 2 hours. The best removal efficiency for copper, chromium and cadmium were 70%, 80% and 85%, respectively, from the initial concentration of 10 mg/L. While macro algae are abundantly available in marshlands of south Iraq, it can be preferably utilized as biosorbent to remove heavy metals from the industrial wastewater.
Źródło:
Journal of Ecological Engineering; 2019, 20, 11; 18-22
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of organic waste for adsorption of Zn(II) and Cd(II) ions
Autorzy:
Bakalár, Tomáš
Pavolová, Henrieta
Powiązania:
https://bibliotekanauki.pl/articles/208191.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
cadmium
zinc
hazelnut
orange peel
heavy metals
Freundlich isotherm
kadm
cynk
orzech laskowy
skórka pomarańczowa
metale ciężkie
Izoterma Freundlicha
Opis:
Biosorption of Zn(II) and Cd(II) ions from aqueous solutions onto organic waste – orange peel, hazelnut shell, and walnut shell was studied using batch adsorption experiments. In the biosorption studies, equilibrium metal ion concentration was determined. Experimental data obtained were analysed in terms of Freundlich, Langmuir, Temkin, Dubinin–Radushkevich, Redlich–Peterson, Sips, Toth, and Khan isotherms. The results of the study showed that orange peel, hazelnut shell, and walnut shell can be adequately used as low-cost alternatives for the removal of Zn(II) and Cd(II) ions from aqueous solutions with maximum sorption capacities of 15.51 and 19.8 mg/g, 11.55 and 16.65 mg/g, and 26.60 and 21.10 mg/g, respectively. The highest removal efficiency of Zn(II) and Cd(II) ions was obtained for hazelnut shells. The process was fast and about 90% of metal ions were removed by all the studied biosorbents. The sorption process was possibly chemisorption occurring on a heterogeneous surface.
Źródło:
Environment Protection Engineering; 2019, 45, 2; 35-54
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Cadmium acts as a silent killer of liver by inducing oxidative stress and hepatocellular injury and a possible amelioration by vitamin B12 and folic acid in rat model
Autorzy:
Banerjee, A.
Nandi, P.
Bhattacharya, C.
Kabir, Z.
Mukherjee, S.
Maji, B.K.
Powiązania:
https://bibliotekanauki.pl/articles/1918855.pdf
Data publikacji:
2019-08-26
Wydawca:
Uniwersytet Medyczny w Białymstoku
Tematy:
Cadmium
liver
hepatocellular injury
oxidative stress
Opis:
Purpose: To investigate the involvement of oxidative stress in Cadmium (Cd) induced alteration in the functional status of the liver. And to assess the efficacy of folic acid and vitamin B12 in preventing Cd-induced damage in the same. Materials and methods: The experiment was carried out for four weeks. For the experiment, 25 healthy male adult Wistar albino rats were randomly selected and were divided into five equal groups and treated as control, treated with Cd, supplemented with vitamin B12 and folic acid and in the combination of these two. After 28 days the liver function enzymes and oxidative stress parameters were measured. Results: Cd is the silent killer of the hepatic system through the induction of oxidative stress in male rats. From this investigation, it is evident that the folic acid+vitamin B12 possess significant hepatoprotective and antioxidant activity against Cd-induced hepatotoxicity in the rat model. In addition, results revealed that the folic acid alone and or in combination with vitamin B12 blunted the hepatotoxic effect significantly. Conclusions: Based on results obtained, it can be concluded that folic acid and vitamin B12 offer a protective effect in Cd-induced oxidative stress associated with hepatocellular injury. Folic acid and vitamin B12 can be considered as a potent natural antioxidant which has the capacity to provide protection against Cd-induced oxidative stress in the liver in rats. However, to elucidate the exact mechanism of this modulatory effect and to examine its potential therapeutic effects further studies are essential.
Źródło:
Progress in Health Sciences; 2019, 1; 105-117
2083-1617
Pojawia się w:
Progress in Health Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Cd2+-promoted mitochondrial permeability transition: a comparison with other heavy metals.
Autorzy:
Belyaeva, Elena
Glazunov, Vadim
Korotkov, Sergey
Powiązania:
https://bibliotekanauki.pl/articles/1043302.pdf
Data publikacji:
2004
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
copper
mercury
mitochondrial permeability transition
respiratory chain
cadmium
Opis:
We compared action of Cd2+, Hg2+, and Cu2+ on isolated rat liver mitochondria in the absence of added Ca2+ and Pi. The heavy-metal ions produced dose-dependently: (1) enhanced membrane permeabilizaton manifested in mitochondrial swelling and activation of basal respiration, (2) inhibition of uncoupler-stimulated respiration, and (3) membrane potential dissipation. Among the metals, Cu2+ exhibited maximal stimulatory effect on basal respiration and minimal inhibitory action on DNP-uncoupled respiration whilst Cd2+ promoted the strongest depression of uncoupled respiration and the largest swelling in NH4NO3 medium. Dithiothreitol induced a basal respiration release if added after high [Cd2+] and [Hg2+], and the stimulation was CsA-insensitive.
Źródło:
Acta Biochimica Polonica; 2004, 51, 2; 545-551
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mitochondrial respiratory chain inhibitors modulate the metal-induced inner mitochondrial membrane permeabilization
Autorzy:
Belyaeva, Elena
Powiązania:
https://bibliotekanauki.pl/articles/1040305.pdf
Data publikacji:
2010
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
copper
mercury
stigmatellin
selenite
permeability transition pore
cadmium
mitochondria
zinc
Opis:
To elucidate the molecular mechanisms of the protective action of stigmatellin (an inhibitor of complex III of mitochondrial electron transport chain, mtETC) against the heavy metal-induced cytotoxicity, we tested its effectiveness against mitochondrial membrane permeabilization produced by heavy metal ions Cd2+, Hg2+, Cu2+ and Zn2+, as well as by Ca2+ (in the presence of Pi) or Se (in form of Na2SeO3) using isolated rat liver mitochondria. It was shown that stigmatellin modulated mitochondrial swelling produced by these metals/metalloids in the isotonic sucrose medium in the presence of ascorbate plus tetramethyl-p-phenylenediamine (complex IV substrates added for energization of the mitochondria). It was found that stigmatellin and other mtETC inhibitors enhanced the mitochondrial swelling induced by selenite. However, in the same medium, all the mtETC inhibitors tested as well as cyclosporin A and bongkrekic acid did not significantly affect Cu2+-induced swelling. In contrast, the high-amplitude swelling produced by Cd2+, Hg2+, Zn2+, or Ca2+ plus Pi was significantly depressed by these inhibitors. Significant differences in the action of these metals/metalloids on the redox status of pyridine nucleotides, transmembrane potential and mitochondrial respiration were also observed. In the light of these results as well as the data from the recent literature, our hypothesis on a possible involvement of the respiratory supercomplex, formed by complex I (P-site) and complex III (S-site) in the mitochondrial permeabilization mediated by the mitochondrial transition pore, is updated.
Źródło:
Acta Biochimica Polonica; 2010, 57, 4; 435-441
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
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