Temat: butyl alcohol - Katalog OPAC zbiorów

Skocz do pozycji: 1.

Tytuł:: Kinetic investigations on esterification of maleic anhydride with butanols
Autorzy:: Bartoszewicz, Maria
Kulawska, Maria
Organek, Wiesław
Powiązania:: https://bibliotekanauki.pl/articles/2034054.pdf
Data publikacji:: 2020
Wydawca:: Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:: acidic catalysts
butyl alcohol
dibutyl maleate
esterification reaction
plasticizer
katalizator kwasowy
alkohol butylowy
reakcja estryfikacji
plastyfikator
Opis:: Kinetic studies of esterification reaction of maleic anhydride with butan-1-ol, 2-methylpropan-1-ol and butan-2-ol were carried out in a semibatch reactor, in the presence of four acidic catalysts: sulfuric acid, phosphotungstic acid, ion exchange resin Dowex 50WX8 and tetrabutyl zirconate. Phosphotungstic acid proved to be the most active catalyst. The temperature range was 383–413 K, the initial molar ratio of alcohol to acid ranged 2.2-5:1. The kinetic parameters were given. The kinetics appeared to be that of the second order with respect both to the acid and to the alcohol. The reaction carried out in the presence of tetrabutyl zirconate was very slow and depended only on acid concentration. The effect of temperature on the reaction rate follows the Arrhenius equation well.
Źródło:: Chemical and Process Engineering; 2020, 41, 4; 293-306
0208-6425
2300-1925
Pojawia się w:: Chemical and Process Engineering
Dostawca treści:: Biblioteka Nauki

Artykuł

Skocz do pozycji: 2.

Tytuł:: Theoretical evaluation of internal pressure in ternary and sub-binary liquid mixtures at various temperatures
Autorzy:: Madhumitha, J.
Santhi, N.
Alamelumangai, G.
Emayavaramban, M.
Powiązania:: https://bibliotekanauki.pl/articles/411846.pdf
Data publikacji:: 2012
Wydawca:: Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:: mieszanki ciekłe trójskładnikowe
benzen
heksan
alkohol sec-butylowy
ternary liquid mixtures
sub-binary liquid mixtures
benzene
hexane
sec-butyl alcohol
Opis:: The Internal pressures of Ternary and their sub-Binary liquid mixtures of benzene(1) + hexane(2) + sec-butyl alcohol(3) were calculated using density, velocity and molar refraction from the temperature range of 303.15K-318.15K. For the Binary liquid mixtures, the Experimental Internal pressure values were correlated through an equation proposed by Andiappan et.al. For the Ternary liquid mixture, the Experimental Internal pressure values were correlated through an equation proposed by us. The Experimental values and the Theoretical values are in close agrement with each other.
Źródło:: International Letters of Chemistry, Physics and Astronomy; 2012, 4; 82-95
2299-3843
Pojawia się w:: International Letters of Chemistry, Physics and Astronomy
Dostawca treści:: Biblioteka Nauki

Artykuł

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