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Tytuł:
Bismuth minerals of the Beregovo ore field: mineral assemblages and spatial zonation (Transcarpathian, Ukraine)
Autorzy:
Biruk, S.V.
Skakun, L.Z.
Powiązania:
https://bibliotekanauki.pl/articles/2059386.pdf
Data publikacji:
2000
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Transcarpathian
epithermal deposit
bismuth mineralization
Opis:
New compositional data on Bi-mineralization from ores of epithermal gold -(+copper)-silver-base metal deposits of the Beregovo ore field in the Ukraine are presented. The Bi-minerals are developed at deep levels of these deposits and occupy narrow zones at the limits of the ore bodies, Bi-sulphosalts from a temporal range (from early to late) of: Ag-Pb-Bi and Ag-Cu-Pb-Bi (+Pb-Cu-Bi) and Bi(2)S(3) Bi-minerals escaped from destruction during successive processes owing to their occurrence in a dense quartz matrix. Spatially Bi-mineralization is developed as a frontal zone of massive chalcopyrite aggregates.
Źródło:
Geological Quarterly; 2000, 44, 1; 39-46
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of Milling Duration on the Thermoelectric Properties of n-Type Bi2Te2.7Se0.3
Autorzy:
Park, Min-Soo
Koo, Hye-Young
Park, Yonh-Ho
Ha, Gook-Hyun
Powiązania:
https://bibliotekanauki.pl/articles/354698.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
thermoelectric
bismuth telluride
powder
milling
Opis:
In this study, an oxide reduction process and a reduction-sintering process were employed to synthesize a thermoelectric alloy from three thermoelectric composite oxide powders, and the thermoelectric properties were investigated as a function of the milling duration. Fine grain sizes were analyzed by via X-ray diffraction and scanning electron microscopy, to investigate the influence of the milling duration on the synthesized samples. It was found that microstructural changes, the Seebeck coefficient, and the electrical resistivity of the compounds were highly dependent on the sample milling duration. Additionally, the carrier concentration considerably increased in the samples milled for 6 h; this was attributed to the formation of antisite defects introduced by the accumulated thermal energy. Moreover, the highest value of ZT (=1.05) was achieved at 373K by the 6-h milled samples. The temperature at which the ZT value maximized varied according to the milling duration, which implies that the milling duration of the three thermoelectric composite oxide powders should be carefully optimized for their effective application.
Źródło:
Archives of Metallurgy and Materials; 2019, 64, 2; 591-595
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
SEM studies of ore minerals in skarns from Garby Izerskie, Karkonosze-Izera block, south-western Poland
Autorzy:
Rybicki, M.
Karwowski, Ł.
Banasik, K.
Powiązania:
https://bibliotekanauki.pl/articles/100745.pdf
Data publikacji:
2013
Wydawca:
Uniwersytet Śląski. Wydział Nauk o Ziemi
Tematy:
Karkonosze
SEM
bizmut
Garby Izerskie
bismuth telluride
acanthite
native bismuth
native gold
native silver
skarns
Opis:
In “Stanisław” quarry, that is located on Garby Izerskie, ore minerals-bearing calcsilicate skarns were found in 2009. The samples were studied using microscopical method of reflected light and scanning electron microscopy (SEM). Based on SEM study, the predominant ore minerals in investigated samples are chalcopyrite, pyrrhotite, bismuth telluride and native bismuth. Moreover, acanthite, native gold and native silver were also identified. Our studies are the first report of above mentioned minerals from the Garby Izerskie area.
Źródło:
Contemporary Trends in Geoscience; 2013, 2, 1; 61-66
2299-8179
Pojawia się w:
Contemporary Trends in Geoscience
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Extraction and separation of zinc, lead, silver, and bismuth from bismuth slag
Autorzy:
Xing, Peng
Ma, Baozhong
Wang, Chengyan
Chen, Yongqiang
Powiązania:
https://bibliotekanauki.pl/articles/109744.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
bismuth
zinc
lead
silver
extraction
separation
Opis:
The present paper deals with the extraction and separation of zinc, lead, silver, and bismuth from a refractory bismuth refining slag via a hydrometallurgical route. The process consists of a preliminary leaching of zinc with water, followed by the selective leaching of lead and silver with a calcium chloride solution, leading to the crystallization of lead chloride and the cementation of silver. The diagrams of the total concentrations of [Pb]/[Ag] versus [Cl-] and temperature in the Pb/Ag-Cl-H2O system were drawn, respectively, to determine the optimum concentration of leaching agent and leaching temperature. The potential-pH diagram of the Pb/Ag/Bi-H2O system indicates that the preferential leaching of lead and silver could be achieved. Finally, 98.8% of lead and 90.4% of silver were selectively removed by further leaching the water leaching residue with 400 g/dm3 of CaCl2 solution at pH 4.5 and 80 °C, while only 3.7% of bismuth was leached in this stage. Fifty-nine percent of lead in the leach liquor was separated out as PbCl2 by natural cooling. Ninety-five percent of silver in mother liquor was recovered by cementation with a lead sheet. The depleted CaCl2 solution can be sent to the leaching step again to close the loop.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 1; 173-183
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Separation and Immobilization of Vanadium from Industrial Fly Ash as an Insoluble Inorganic Pigmen
Autorzy:
Kwolek, P.
Czubajewski, K.
Wojnicki, M.
Powiązania:
https://bibliotekanauki.pl/articles/351844.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
recovery
inorganic pigments
solubility
vanadium
bismuth
immobilisation
Opis:
It has been shown that the precipitation of bismuth orthovanadate from a fly ash leachate is a promising method of vanadium recovery. BiVO4 obtained after appropriate heat treatment can be sold as a pigment. The yield of recovery of solubilised vanadium is equal to 68% and the precipitate is free from nickel impurity. The precipitate is insoluble in the solutions with pH ≥ 3. In more acidic media the solubility of precipitate increases with the decreasing pH. The solubility of the precipitate increases also with the increasing concentration of chloride ions.
Źródło:
Archives of Metallurgy and Materials; 2020, 65, 2; 901-909
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Performance of Mn/Bi2O3 Pyrotechnic Time Delay Compositions
Autorzy:
Tichapondwa, Shepherd M.
Guo, Shasha
Roux, Willem E.
Powiązania:
https://bibliotekanauki.pl/articles/27787886.pdf
Data publikacji:
2021
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
manganese
bismuth trioxide
time delay
pyrotechnics
binder
Opis:
Chemical time delay detonators are used widely in mine blasting applications. In order to achieve effective blasting, detonations must follow a precisely controlled timing sequence in a specified firing pattern. Silicon fuel-based pyrotechnic compositions are widely used in mining detonators and are well studied. However, some of these formulations are deemed to be problematic, as they contain heavy metals which are bio-accumulative and toxic to the environment. Therefore, there is need to explore alternative formulations which are suitable for these applications. Manganese-fueled systems are attractive due to their metallic properties and several oxidation states of the manganese fuel. This study focused on characterizing the burn properties of Mn/Bi2O3 compositions for slow to intermediate time delay applications. The compositions supported combustion in the 25 to 55 wt.% Mn range in an inert helium atmosphere. Burn rates between 2.5 and 11.2 mm·s–1 were recorded in open burn tests, whilst closed burn tests in glass tubes resulted in burn rates of 6.3 to 11.2 mm·s–1. Both X-ray diffraction analysis of the reaction products and thermodynamic simulations confirmed that MnO and Bi are the main reaction products, with unreacted Mn and Bi2O3 also being detected. This suggests that the dominant reaction for this composition is a simple thermite-type reaction.
Źródło:
Central European Journal of Energetic Materials; 2021, 18, 1; 46--62
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structural and optical properties of nanostructured bismuth oxide
Autorzy:
Ali, R. S.
Powiązania:
https://bibliotekanauki.pl/articles/412556.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
thin films’ bismuth oxide
optical properties
structural properties
Opis:
Thin films of bismuth oxide have been prepared utilizing vacuum evaporation. XRD anyalysis reveal that all the films were tetragonal polycrystalline structure with a preferred orientation along (002) plane. SEM images indicate that the grain size fall in the category of nanosize. AFM results assure that the nanonstructure behavior of thin films. Optical studies show that these films have a direct transition with optical energy gap equal to 2.5 eV.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 15; 64-72
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Morphology and Structure of the Erbium Stabilized Bismuth Oxide Thin Films Deposited by PLD Technique
Autorzy:
Kąc, S.
Szwachta, G.
Cieniek, Ł.
Moskalewicz, T.
Powiązania:
https://bibliotekanauki.pl/articles/356362.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Pulsed Laser Deposition
thin films
bismuth oxide
surface topography
Opis:
The aim of the work was to obtain thin bismuth oxide films containing, at room temperature, the Bi1,5Er0,5O3 phase. This phase corresponds to the structure of the high-temperature δ-Bi2O3 phase, in pure bismuth oxide, characterized by the highest ionic conductivity of all known solid state ionic conductors. The high-temperature δ-Bi2O3 phase with the face centered cubic structure, in pure bismuth oxide, occurs only at temperature above 730°C. Stabilization of the δ-Bi2O3 phase at room temperature was achieved by an addition of the erbium together with the employ-ment of the Pulsed Laser Deposition (PLD) technique. The influence of an amount of Er alloying and the film thickness on surface morphology, microstructure, phase composition of thin films were investigated. The velocity of deposition of thin layers of bismuth stabilized with erbium in the PLD process using the Nd: YAG laser was about 0.5 nm/s.The investigation results of erbium doped bismuth oxide thin films deposited onto (0001) oriented Al2O3 monocrystalline substrate are presented. Thin films of uniform thickness, without cracks, and porosity were obtained. All deposited thin films (regardless of the film thickness or erbia (Er2O3) content) exhibited a columnar structure. In films stabilized with erbium, up to approx. 250 nm thickness, the columns have a diameter at the base from 25 to 75 nm. The columns densely and tightly fill the entire volume of the films. With increasing of the film thickness increases, porosity also significantly increases. In thin layers containing from 20 to 30 mole % Er2O3 the main identified phase at room temperature is Bi1,5Er0,5O3. It is similar to the defective fluorite-type structure, and belongs to the Fm-3m space group. This phase corresponds to the structure of the high-temperature δ-Bi2O3 phase in pure bismuth oxide.
Źródło:
Archives of Metallurgy and Materials; 2019, 64, 3; 969-974
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Pd-P Layer on the Bonding Strength of Bi-Te Thermoelectric Elements
Autorzy:
Bae, Sung Hwa
Han, Se Hun
Son, Injoon
Kim, Kyung Tae
Powiązania:
https://bibliotekanauki.pl/articles/353621.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
bismuth telluride
thermoelectric module
electroless Pd-P plating
bonding strength
Opis:
In this study, the effect of electroless Pd-P plating on the bonding strength of the Bi-Te thermoelectric elements was investigated. The bonding strength was approximately doubled by electroless Pd-P plating. Brittle Sn-Te intermetallic compounds were formed on the bonding interface of the thermoelectric elements without electroless Pd-P plating, and the fracture of the bond originated from these intermetallic compounds. A Pd-Sn solder reaction layer with a thickness of approximately 20 μm was formed under the Pd-P plating layer in the case of the electroless Pd-P plating, and prevented the diffusion of Bi and Te. In addition, the fracture did not occur on the bonding interface but in the thermoelectric elements for the electroless Pd-P plating because the bonding strength of the Pd-Sn reaction layer was higher than the shear strength of the thermoelectric elements.
Źródło:
Archives of Metallurgy and Materials; 2019, 64, 3; 963-968
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
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