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Wyszukujesz frazę "alkaline leaching" wg kryterium: Temat


Wyświetlanie 1-13 z 13
Tytuł:
Basic theory and optimization of gold containing antimony concentrate leaching by alkaline sulfide
Autorzy:
Wu, Hao
Feng, Yali
Li, Haoran
Liao, Shengde
Wang, Hongjun
Powiązania:
https://bibliotekanauki.pl/articles/109524.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
antimony concentrate
leaching process
alkaline leaching
kinetics
Opis:
As sodium sulfide is easily oxidized to polysulfide and thiosulfate which have a gold leaching effect, gold would dissolve in leaching solution when extracting stibium from gold containing antimony concentrate by alkaline sulfide. Through leaching test and kinetics analysis, the decomposition regularity of sodium sulfide and leaching rate were studied under different leaching conditions. The results indicated that the gold content in antimony concentrate was 28.41g/Mg, and the content of antimony and sulfur was 36.01% and 14.04%, respectively. The main metallic minerals were native gold, arsenopyrite, stibnite, and the gangue minerals were mainly quartz. Anodic polarization curve shows reduced iron powder can increase the peak potential of the oxidation of the leaching solution and it can effectively prevent the decomposition of sodium sulfide and the dissolution of gold. Optimized stibium-extraction efficiency was achieved under the following conditions: a concentration of sodium sulfide and sodium hydroxide at 110g/dm³ and 20g/dm³, respectively; a ratio of iron powder to concentrate of 1:30; a ratio of liquid to solid of 5:1; agitation speed of 600rad/min; reaction temperature of 353.15K; and a reaction time of 3 h. Under the optimized conditions, high antimony recovery (97.35%) and low gold dissolution (1.32%) were achieved.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 1; 248-257
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Alkaline Leaching of Low Zinc Content Iron-Bearing Sludges
Autorzy:
Gargul, K.
Jarosz, P.
Małecki, S.
Powiązania:
https://bibliotekanauki.pl/articles/355782.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
sludge
dust
alkaline leaching
Zn recovery
recycling
Opis:
Various types of waste materials containing zinc (e.g. dusts and sludges from gas dedusting process) are obtained in steel industry. The contents of Zn in these materials may vary considerably. Even a low concentration of zinc in recirculated products precludes their recycling in ferrous metallurgy aggregates. Long storage of this type of material can lead to contamination of soil and water by zinc compounds which can be leached out by acid rain, for example. This paper focuses on research involving alkaline leaching tests of low zinc content iron-bearing materials. These tests were preceded by the analysis of the elemental, phase and grain size composition, and analysis of the thermodynamic conditions of the leaching process. The main aim of research was to decrease the content of the zinc in the sludge to the level where it is suitable as an iron-bearing material for iron production (~1% Zn). Leaching at elevated temperatures (368 K, 60 min) has led to a decrease in the zinc content in the sludge of about 66%. The research revealed that long hour leaching (298 K, 100 hours) carried out at ambient temperatures caused a reduction in zinc content by 60% to the value of 1.15-1.2% Zn.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 1; 43-50
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Production of zinc powder from Co-Zn plant residue using selective alkaline leaching followed by electrowinning
Autorzy:
Kamran Haghighi, H.
Moradkhani, D.
Sardari, M. H.
Sedaghat, B.
Powiązania:
https://bibliotekanauki.pl/articles/951816.pdf
Data publikacji:
2015
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
zinc powder
HFC
alkaline leaching
sodium hydroxide
alkaline electrowinning
Opis:
Annually, gigagrams of cobalt residues, called hot filter cake (HFC), are produced from the Co neutralization step at Iranian zinc plants. With respect to the composition of HFC )i.e., 15-25% Zn, 0.5–1.5% Co, 3–8% Mn(, it can be used as a secondary source of zinc, cobalt and manganese. In the present study, for the first time, treatment of HFC for separation and recovery of zinc has been studied. The residue was treated by employing selective alkaline leaching, in order to recover the maximum amount of zinc, followed by zinc electrowinning process. As a results, a solution was obtained from alkaline leaching under the optimum condition of 75 °C, sodium hydroxide of 8 M, solid-to-liquid ratio dm3 of 1:10, and stirring speed of 600 rpm, having zinc recovery of 88.5 %. In the following step, the electrowinning process, under the optimum working conditions being current density 350 A/m2 and time 10 hours, was carried out to produce a zinc powder with high purity of 99 percent. Finally, a simple and effective conceptual flow diagram was proposed for the process.
Źródło:
Physicochemical Problems of Mineral Processing; 2015, 51, 2; 411-425
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Parametric optimization of coal desulfurization through Alkaline leaching
Autorzy:
Rehman, F.
Ahmad, S. W.
Zafar, M. S.
Ahmad, S.
Zia-Ul-Haq, M.
Powiązania:
https://bibliotekanauki.pl/articles/779964.pdf
Data publikacji:
2018
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
Desulfurization
Alkaline leaching
Response surface methodology
ANOVA
Central Composite design
Opis:
Desulfurization of Pakistani coal has been carried out through alkaline leaching. During present experimental investigation, the effect of operating parameters like alkali concentration, time, temperature and particle size has also been analyzed, graphically represented and critically discussed. Parametric optimization of leaching process has been carried out by using response surface methodology (RSM) based on central composite design (CCD). The analysis of variance (ANOVA) was performed in order to assess the highest level interactions of variables and three way interactions were observed significant. Further, the optimum value of total sulfur removal was observed as 53% when the operatic conditions fixed at 10% W/V, 60 min, 80°C and 140 mesh for alkaline concentration, leaching time, temperature and particle size, respectively.
Źródło:
Polish Journal of Chemical Technology; 2018, 20, 3; 103-109
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Leaching behaviour of zinc from a smithsonite ore in sodium hydroxide solutions
Autorzy:
Ehsani, Ilhan
Ucyildiz, Ayse
Obut, Abdullah
Powiązania:
https://bibliotekanauki.pl/articles/110552.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
alkaline leaching
calcium zincate
nonsulfide zinc ore
smithsonite
zinc carbonate
Opis:
In this study, the leaching behaviour of zinc from a smithsonite ore sample (23.43% Zn) having goethite and calcite as main gangue minerals was investigated in sodium hydroxide solutions using Xray diffraction and chemical analyses. Within the studied NaOH concentration range (1-4 mole/dm3), higher leaching ratio values for Zn were obtained by leaching at 298 K because of the decreased stability of soluble zincate species in solution at higher temperatures. When the concentration of NaOH solution was increased from 1 to 3 mole/dm3 at 298 K, leaching ratio value of Zn increased from 3.8 to 70.1%. At 4 mole/dm3 NaOH concentration, Zn leaching ratio value (70.9%) levelled off due to the formation of solid hydrated calcium zincate phase in leaching solution. On the other hand, very low leaching ratio values of Zn were obtained by leaching in 1 mole/dm3 NaOH solution at 298 K (3.8%) and 363 K (1.4%) due to the formation of solid zinc hydroxide and solid zinc oxide phases, respectively. It was observed that increasing leaching time from 1800 to 14400 s at 3 mole/dm3 NaOH concentration, favoured the formation of hydrated calcium zincate phase and so decreased the leaching ratio of Zn to a lower value (60.6%). The effect of solid/liquid ratio was also investigated and it was found that when solid/liquid ratio was decreased, Zn leaching ratio values decreased at constant OH/Zn mole ratio and increased at constant NaOH concentration conditions. Besides, for some of the experiments, leaching ratio values of lead were also given.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 2; 407-416
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Leaching of High Arsenic Content Dust and a New Process for the Preparation of Copper Arsenate
Autorzy:
Sheng, W.
Shen, Y.-Y.
Sheng-Quan, Z.
Powiązania:
https://bibliotekanauki.pl/articles/355005.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
high-arsenic dust
acidic leaching
alkaline leaching
copper arsenate
comprehensive utilisation of esources
Opis:
In this research, the high arsenic content dust of copper smelting, as a raw material, the extraction of copper and arsenic from the high arsenic content dust in the leaching system containing acidic and alkaline compounds was investigated. Meanwhile, the effects of acid/alkaline initial concentration, liquid to solid ratio, leaching temperature, leaching time on the leaching rate of copper and arsenic were studied. The optimum conditions for the leaching of high arsenic content dust and preparation of copper arsenate were determined. The results showed that acidic/alkaline leaching of high arsenic content dust was particularly effective. 93.2% of the copper, and 91.6% of the arsenic were leached in an acidic leaching process and 95% of the arsenic, while less than 3% of the copper, less than 5% of the antimony, less than 2% of the bismuth was also leached in an alkaline leaching process. A new method (the parallel flow drop precipitate method) was developed in the synthesis of copper arsenate process. The parallel flow drop method was employed to adjust the molar ratio (copper to arsenic) of the mixed solution of the acid-leaching solution and the alkali-leaching solution by taking the drop acceleration of an acidic leaching solution and an alkaline leaching solution at 10 mL/min and 12 mL/min, at a temperature of 60°C and a reaction time of 1h. Copper arsenate was prepared by mixing an acidic leaching solution and an alkaline leaching solution. The main phases of copper arsenate were CuHAsO4·1.5H2O and Cu5As4O15·9H2O. Copper arsenate contained 30.13% copper and 31.10% arsenic.
Źródło:
Archives of Metallurgy and Materials; 2018, 63, 3; 1167-1172
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A novel method to extract vanadium from high-grade vanadium slag: non-salt roasting and alkaline leaching
Autorzy:
Liu, B.
Meng, L.
Zheng, S.
Li, M.
Wang, S.
Powiązania:
https://bibliotekanauki.pl/articles/110480.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
high-grade vanadium slag
cleaner production
non-salt roasting
alkaline leaching
mechanisms
Opis:
A new method using non-salt roasting-alkaline leaching to treat vanadium slag was proposed in this study. The V(III) in vanadium slag is oxidized to V(V) by roasting and the latter can be effectively leached out as vanadate by alkaline leaching. This method possesses distinct advantage of being able to treat high-grade vanadium slag. For the South Africa high-grade vanadium slag, the maximum vanadium recovery of 98% was achieved when the reaction conditions were roasting temperature of 850 °C, roasting time of 2 h, alkali concentration of 30 wt.%, leaching temperature of 210 °C, and leaching time of 2 h. The roasting and leaching mechanisms have been well elucidated based on the XRD and SEM analysis results. The phases transitions of vanadium slag were clearly presented. This work has laid the foundation for the industrial application of non-salt roasting-alkaline leaching and provided new insights into effective extraction of high-grade vanadium slag.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 3; 657-667
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Recovery of vanadium and tungsten from spent selective catalytic reduction catalyst by alkaline pressure leaching
Autorzy:
Liu, Nana
Xu, Xinyang
Liu, Yuan
Powiązania:
https://bibliotekanauki.pl/articles/110694.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
spent SCR catalyst
alkaline pressure leaching
response surface method
Box-Behnken design
Opis:
Improving the efficiency of precious metal recovery from spent Selective Catalytic Reduction (SCR) catalyst provides economic benefits and promises sustainable use of resources. Here we demonstrate highly efficient alkaline pressure leaching method for the extraction of vanadium (V) and tungsten (W) from spent SCR catalyst. We analyzed the effects of experimental parameters such as the stirring speed, leaching agent concentration, leaching temperature, liquid-to-solid ratio, and leaching time. The Box-Behnken design of experiments and the response surface methodology have been employed to understand the impact of the leaching parameters and the impact of their interactions on the leaching rate of V and W. The results showed that the leaching agent concentration significantly promoted the recovery of V and W; the influence of the reaction temperature and leaching time moderately increased the leaching rate of the metals. Moreover, the efficiency of the alkaline pressure leaching technique was determined by the interactions between leaching time and reaction temperature, and the relationships between reaction temperature and leaching agent concentration. By using the response surface methodology, the optimal leaching conditions were found that the leaching agent concentration was 4.75 molL-1, the leaching temperature was 190 °C, and the reaction time was 44.5 min, and the predicted values of V and W leaching rates were 95.76% and 98.36%, respectively. Based on the excellent fitting between modeling and experimental results demonstrated in this work, we conclude that our study can shed light on the development of highly efficient and sustainable metal recovery strategies for practical applications.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 3; 407-420
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Dissolution of alkaline batteries in reductive acidic media
Autorzy:
Zeytuncu, B.
Powiązania:
https://bibliotekanauki.pl/articles/110179.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
alkaline battery
manganese
zinc
reductive leaching
sulfur
Opis:
In this paper, recovery of manganese and zinc from alkaline battery paste by leaching under atmospheric condition using elemental sulfur as a reductive agent and sulfuric acid was investigated. Different dissolution parameters, acid concentrations, liquid-to-solid ratios, reaction temperatures, leaching times and amounts of elemental sulfur were studied in detail. According to results, the Mn dissolution in reductive acidic media was an intermediate-controlled process with activation energy of 10.21±2.60 kJ/mol. After the leaching step, Mn and Zn were selectively precipitated from the leaching solution using sodium hydroxide. After solid/liquid separation, manganese(II,III) oxide (Mn3O4) was obtained by drying at 105 °C in air. Next, Mn3O4 was converted to manganese(IV) oxide (MnO2) by heating at 800 °C in air. After that the solution containing Zn(OH)42- was treated with sulfuric acid to form zinc hydroxide, separated and next converted to zinc oxide by heating at 600 °C in air. The final products were characterized by XRD. The results showed that the proposed process can be effectively used for recovery of Mn and Zn from alkaline batteries.
Źródło:
Physicochemical Problems of Mineral Processing; 2016, 52, 1; 437-450
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Direct conversion of alkaline earth metal hydroxides and sulfates to carbonates in ammonia solutions
Autorzy:
Ehsani, Ilhan
Ehsani, Arman
Ucyildiz, Ayse
Obut, Abdullah
Powiązania:
https://bibliotekanauki.pl/articles/2146856.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
alkaline earth metal
ammonia leaching
direct conversion
dissolved carbonate
smithsonite
Opis:
In this study, the direct conversion behaviors of different alkaline earth metal solids (the hydroxides and the sulfates of alkaline earth metals Ca, Sr, Ba and Mg) to their corresponding carbonates in dissolved carbonate-containing pregnant solutions obtained by direct leaching of a smithsonite (ZnCO3) ore sample in aqueous ammonia solutions having different concentrations (4 M, 8 M and 13.3 M NH3) were investigated by using X-ray diffraction analyses at alkaline earth metal to dissolved carbonate mole ratios of 1:1 and 1:2, for revealing the conversion possibilities of dissolved carbonate in the pregnant solutions to solid carbonate by-products. The results of direct conversion experiments showed that Ca(OH)2, CaSO4•2H2O, Sr(OH)2•8H2O and Ba(OH)2•8H2O converted to their corresponding carbonates, SrSO4 partially converted to SrCO3 as observed by the presence of unreacted SrSO4 peaks in X-ray diffraction patterns of the converted solids, and BaSO4 did not convert to BaCO3 because of its lower solubility with respect to BaCO3. On the other hand, it was observed that Mg(OH)2 did not convert to MgCO3, but MgSO4•7H2O converted dominantly to an uncommon phase, which was tentatively identified as Mg5Zn3(CO3)2(OH)12•H2O. In the study, a complete discussion on the conversion behaviors of alkaline earth metal solids to their corresponding carbonates was given considering the differences between their solubility product constants and the changes in the free energies of the theoretical conversion reactions. In addition, infrared spectra and scanning electron microscope images of some of the converted solids were also presented for characterization purposes.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 1; 169--180
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Novel Extraction Process Of Rare Earth Elements From NdFeB Powders Via Alkaline Treatment
Nowy sposób ekstrakcji pierwiastków ziem rzadkich z proszków NdFeB w roztworach alkalicznych
Autorzy:
Chung, K. W.
Kim, C.-J.
Yoon, H.-S.
Powiązania:
https://bibliotekanauki.pl/articles/355324.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
recycling
NdFeB magnet
alkaline treatment
leaching
selective leaching efficiency
recykling
magnes neodymowy
obróbka alkaliczna
ługowanie
wydajność
Opis:
The alkaline treatment of NdFeB powders in NaOH solution at various equivalent amounts of NaOH at 100°C was performed. The resultant powders were then leached in 0.5M H2SO4 solution at 25°C for 2 minutes. At 5 equivalents of NaOH, neodymium in NdFeB powders was partially transformed to neodymium hydroxide. The transformation of neodymium to neodymium hydroxide actually occurred at 10 equivalents of NaOH and was facilitated by increasing the equivalent of NaOH from 10 to 30. In addition, iron was partially transformed to magnetite during the alkaline treatment, which was also promoted at a higher equivalent of NaOH. The leaching yield of neodymium from alkaline-treated powders was increased with an increasing equivalent of NaOH up to 10; however, it slightly decreased with the equivalent NaOH of over 10. The leaching yield of iron was inversely proportional to that of rare earth elements. NdFeB powders treated at 10 equivalents of NaOH showed a maximum leaching yield of neodymium and dysprosium of 91.6% and 94.6%, respectively, and the lowest leaching yield of iron of 24.2%, resulting in the highest selective leaching efficiency of 69.4%.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 2B; 1301-1305
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of demineralization on the physiochemical structure and thermal degradation of acid treated indigenous rice husk
Autorzy:
Aslam, U.
Ramzan, N.
Iqbal, T.
Kazmi, M.
Ikhlaq, A.
Powiązania:
https://bibliotekanauki.pl/articles/779611.pdf
Data publikacji:
2016
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
demineralization
leaching agent
physiochemical structure
alkali and alkaline earth metals
thermal degradation
Opis:
Energy generation from biomass presents some serious problems like slagging, fouling and corrosion of boilers. To address these problems, demineralization of biomass is performed using different leaching agents. This study is focused on determining the influence of leaching agents and leaching time on the physiochemical structure of rice husk during demineralization. Dilute (5% wt) solutions of HCl and H2SO4 were used for the demineralization of rice husk separately with leaching time of 15, 60 and 120 minutes. It is shown that H2SO4 exhibited higher removal of alkali and alkaline earth metals (AAEM) comparatively as depicted by the 34.2% decrease in ash content along with an increase of 7.10% in the heating value. The acid has been seen to induce more notable changes in physiochemical structure as depicted by the FTIR spectra and SEM micrographs. The thermal degradation behavior of the demineralized rice husk has also been reported.
Źródło:
Polish Journal of Chemical Technology; 2016, 18, 3; 117-121
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Non-reductive acidic leaching as a method for recovery of zinc and manganese from Zn-C and Zn-MnO2 battery waste
Autorzy:
Sobianowska-Turek, Agnieszka
Banaszkiewicz, Kamil
Pasiecznik, Iwona
Marcinkowski, Tadeusz
Urbańska, Weronika
Powiązania:
https://bibliotekanauki.pl/articles/2032912.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
alkaline battery
Mn
Zn
acid leaching
spent battery
bateria alkaliczna
kwaśne ługowanie
bateria zużyta
Opis:
The dynamic growth of mobile technologies is a driving need for portable power sources. The most popular division of electrochemical cells relies on the type of chemical reaction within the cell. Current data coming from the Polish market show that despite the growth in the sale of secondary power sources, zinc-carbon and alkaline batteries are still the most popular. The results of non-reductive acidic leaching of zinc and manganese from the waste batteries stream have been presented. Manganese was leached with almost 100% yield in an experiment with a solid to liquid ratio equal to 4/1, pH of 1.04, and H2SO4 concentration of 72.5 wt. %. High yields were also obtained for zinc recovery from the waste stream (100% for two series with solid to liquid ratio 4/5, pH of 0.80; H2SO4concentration of 37.2 wt. %, and solid to liquid ratio 1/2; pH of 1.01; H2SO4 concentration of 27.3 wt. %). Besides, the quantitative and qualitative analysis of Zn-C and Zn-Mn batteries introduced to the Polish market and waste generated in the years 2010-2018 has been presented.
Źródło:
Environment Protection Engineering; 2021, 47, 2; 17-29
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-13 z 13

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