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Tytuł:
Study of Interactions Between Individual Phenolics of Aronia with Barley Beta-Glucan
Autorzy:
Jakobek, Lidija
Matić, Petra
Ištuk, Jozo
Barron, Andrew R.
Powiązania:
https://bibliotekanauki.pl/articles/1363268.pdf
Data publikacji:
2021-05-11
Wydawca:
Instytut Rozrodu Zwierząt i Badań Żywności Polskiej Akademii Nauk w Olsztynie
Tematy:
adsorption isotherms
adsorption capacity
non-linear models
chokeberry
interactions
Opis:
Beneficial effects of aronia phenolics are determined by their interactions with dietary fibers, such as beta-glucan. The aim of this research was to study interactions between aronia phenolics and beta-glucan by investigating the adsorption process. Phenolic compounds were extracted from aronia, analyzed using high-performance liquid chromatography, and adsorbed onto beta-glucan at pH 1.5. The adsorption data were modeled by using Langmuir, Dubinin-Radushkevich, and Hill isotherms with a novel non-linear regression developed especially for adsorption isotherms. Aronia phenolics adsorbed onto beta-glucan in amounts 31-250 mg/g (individual anthocyanins), 44-123 mg/g (individual flavonols), and 51 mg/g (neochlorogenic acid). The correlation between adsorption capacities and phenolic content was high (r2=0.94), which suggested that the adsorption might be concentration dependent. Modeling with a novel non-linear regression allowed more precise determination of adsorption isotherm parameters. Furthermore, there was a correlation between maximum adsorption capacities predicted by models and measured adsorption capacities (r2 0.76, 0.81, and 0.34 for Langmuir, Dubinin-Radushevich, Hill isotherms, respectively). The suggested bonds involved in interactions are non-covalent bonds (H bonds, Van der Waals forces). Principal component analysis showed that anthocyanins, flavonols, and phenolic acids could differently behave in the adsorption process, which could be due to differences in the chemical structures (ionic nature of anthocyanins, nonionic nature of flavonols and phenolic acids at low pH). In conclusion, aronia phenolics interacted with beta-glucan by adsorbing onto its surface, and the novel modeling developed by our team was helpful in the interpretation of this process. Interactions should be further studied due to their importance for the beneficial effects of aronia.
Źródło:
Polish Journal of Food and Nutrition Sciences; 2021, 71, 2; 187-196
1230-0322
2083-6007
Pojawia się w:
Polish Journal of Food and Nutrition Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption of CO2 by surface modified coal-based activated carbons: kinetic and thermodynamic analysis
Autorzy:
Xinzhe, Liu
Mingyang, Zhang
Juan, Chen
Zhengyu, Hu
Shuaifei, Xian
Mingxuan, Tang
Chenchen, Zhang
Powiązania:
https://bibliotekanauki.pl/articles/2174813.pdf
Data publikacji:
2022
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
Surface modification
CO2 adsorption capacity
adsorption kinetics
thermodynamic parameters
Opis:
The effects of different surface modifiers on the CO2 adsorption capacity of coal-based activated carbons were studied, and the diffusion behavior, adsorption kinetics and thermodynamic parameters of CO2 in activated car-bons were analyzed. The results show that compared with ethylene glycol, 1,2-propylenediamine and zinc chloride, potassium hydroxide and sodium hydroxide can greatly improve CO2 adsorption capacity. The adsorption rate is faster, and the adsorption capacity is larger, with the maximum CO2 adsorption capacity being 33.54 mL/g. Fick’s law can well describe the diffusion behavior of CO2 in activated carbon. The addition of a surface modifier can increase the diffusion coefficient. The diffusion of CO2 in activated carbon falls into the category of crystal diffusion. The adsorption kinetics of CO2 before and after surface modification follow the Bangham equation. During the adsorption process, δ H < 0, δ G < 0, δ S < 0. Surface modification can reduce adsorption heat and promote adsorption, and the adsorption process is dominated by physisorption.
Źródło:
Polish Journal of Chemical Technology; 2022, 24, 3; 19--28
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption Capacity of Maize Biomass Parts in the Remediation of Cu2+ Ion Polluted Water
Autorzy:
Duru, Chidi Edbert
Duru, Ijeoma Akunna
Powiązania:
https://bibliotekanauki.pl/articles/1113924.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Adsorption capacity
Copper
Maize husk
Remediation
Removal efficiency
Opis:
We investigated the efficiency of maize biomass parts - seed chaff, stalk, cob and husk, in the remediation of Cu2+ ion polluted water in modeled solutions. The adsorption capacity of these parts followed the order of husk > stalk > cob > seed chaff, with values of 9.65 mg/g, 4.83 mg/g, 3.70 mg/g and 2.48 mg/g, respectively. Maximum adsorption capacity of each part was reached in 45 min. Herein, the husk giving the best removal efficiency of 80.80%. Characterization of the maize husk using PIXE showed that potassium is the main cation on this biomass, with concentration 5.602 g/kg. FTIR scans of the husk before and after adsorption of Cu2+ ions gave shifts in adsorption bands on -OH carrying molecules, indicating that complexation is a mechanism in the metal ion removal process. The multi porous structure of the husk, and uniform surface coverage by ions observed from SEM images before and after adsorption, shed more light on the high adsorption efficiency shown by this natural waste material.
Źródło:
World News of Natural Sciences; 2017, 12; 51-62
2543-5426
Pojawia się w:
World News of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characterization of Spent Bleaching Earth as an Adsorbent Material for Dye Removal
Autorzy:
Yulikasari, Andriyan
Nurhayati, Ervin
Utama, Widya
Warmadewanthi, Idaa
Powiązania:
https://bibliotekanauki.pl/articles/2086386.pdf
Data publikacji:
2022
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
adsorbent
adsorption capacity
surface area
SBE
spent bleaching earth
Opis:
Initial research has been carried out to determine the potential of SBE as an adsorbent material through chemical and surface area characterization. Several analyses were performed, including oil content, BET, SEM-EDS, XRD, FTIR, and adsorption capacity. The oil content of the SBE samples were 0.05–0.09%, well below the standard (3%) of hazardous material classification according to the Indonesian government regulation. The chemical composition of SBE, measured by EDS, was dominated by Si and Al elements. XRD analysis revealed two 2-theta diffraction peaks indicated the presence of crystalline SiO2 and Al2O3 phases. Additionally, the results of the FTIR test also showed the dominance of Si-O and Al-O-H functional groups. The SBE morphology, as observed in SEM image, exhibited irregular shape and porous surface covered by impurities. These results supported by the BET data which showed SBE surface area of 10.86 m2g-1 and a mesopore volume of 2.49 cm3 (STP)g-1. Batch adsorption study conducted using low and high range concentration of methylene blue produced a maximum adsorption capacity of 7.993 mg/g and 40.485 mg/g, respectively. The adsorption isotherm analysis showed that the adsorption mechanism was in accordance with the Langmuir isotherm model. Considering its chemical characteristic, SBE has met the criteria for adsorbent material. Nevertheless, the small surface area requires SBE to be activated prior to use.
Źródło:
Journal of Ecological Engineering; 2022, 23, 4; 96--104
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Removal Performance of Bio-Sorption on Sunflower Seed Husk for Copper and Lead Ions from Aqueous Solutions
Autorzy:
Abdulhusain, Noor Alaa
Mokif, Layla Abdulkareem
Powiązania:
https://bibliotekanauki.pl/articles/24201773.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
heavy metal
industrial wastewater
adsorption capacity
sunflower seed husk
Opis:
This study was concerned with the feasibility of using sunflower seed husk (waste material from the food industry) as a low-cost and available sorbent material to remove copper and lead ions. Sunflower seed husk was used for the biosorption of heavy metal ions (Pb(II) and Cu(II)) from aqueous solutions. The properties of natural adsorbent were characterized using Fourier transform infrared spectroscopy (FTIR). Pb(II) and Cu(II) adsorption were investigated in batch experiments through several influencing operating parameters, including contact time, sorbent dosage, initial pH, and initial concentration. The Pseudo-first-order and pseudo-second-order models were also applied to the experimental data to determine the adsorption kinetics. The results showed that adsorption of both ions fitted well by pseudo-Second-order, with determination coefficient R2 = 0.99, for both ions with SSE (1.628, 1.345) for Pb(II) and Cu(II), respectively.
Źródło:
Journal of Ecological Engineering; 2023, 24, 5; 110--117
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fixed-bed adsorptive removal of metanil yellow from simulated wastewater in a fixed-bed column by nitric acid-treated-H3PO4-activated carbon (NATPAAC) from oil palm fruit mesocarpfibre
Autorzy:
Isiuku, B. O.
Ojike, C. A.
Akakuru, O. U.
Ibe, F. C.
Powiązania:
https://bibliotekanauki.pl/articles/1112874.pdf
Data publikacji:
2018
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Adsorption capacity
activated carbon
fixed-bed column
kinetic models
metanil yellow
Opis:
We carried out fixed-bed column adsorption of metanil yellow from simulated wastewater on NATPAAC derived from oil palm fruit mesocarpfibre so as to determine the adsorption capacity, qe, of the carbon under the effects of inlet concentration, Co, carbon bed height, H and dye solution flow rate, Q. Our results indicate that the optimum qe was 15.982 mg/g by Co 25 mg/L, H 4.1cm and Q 8 mL/min. In the study, qe was observed to decrease with increase in Co and Q. The optimum bed height was 4.1cm. Our experimental data were modelled by applying Thomas and Yoon-Nelson kinetic models. Correlation coefficient, R2 values (generally above 0.85) show that the two kinetic approaches provide an effective model of the experimental data. We conclude that oil palm fruit mesocarpfibre has potential as a precursor for production of carbon for acid-dye removal from wastewater.
Źródło:
World News of Natural Sciences; 2018, 17; 157-172
2543-5426
Pojawia się w:
World News of Natural Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Coalification as a process determining the methane adsorption ability of coal seams
Autorzy:
Dutka, Barbara
Godyń, Katarzyna
Powiązania:
https://bibliotekanauki.pl/articles/1853877.pdf
Data publikacji:
2021
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
metan
petrografia
adsorpcja
coal bed methane
degree of coalification
petrography
adsorption capacity
Opis:
The paper presents the results of a study of methane adsorption on coal samples with various degrees of metamorphism, coming from the Polish and Czech parts of the Upper Silesian Coal Basin (USCB). The range of coalification of the samples was from bituminous with vitrinite reflectance Ro equal to about 0.5% to para-anthracite coals with Ro equal to over 2%. The methane adsorption capacity was determined at the temperature 303 K for each of the studied coal seams. Methane adsorption isotherms were approximated using the Langmuir model. The relationship between the Langmuir isotherm parameters (am and PL) and the degree of coalification was presented. It was shown that the degree of coalification of the coal substance affects the adsorption ability of coal with respect to methane and determines the value of the Langmuir isotherm parameters. The study was conducted in order to present the distribution of adsorption capacity of Upper Silesian coals in relation to improving work safety in active mines as well as designing technologies that use coal bed methane (CBM) from balance and off-balance resources.
Źródło:
Archives of Mining Sciences; 2021, 66, 2; 181-195
0860-7001
Pojawia się w:
Archives of Mining Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption of lead ions onto chemically activated carbon from waste tire char and optimization of the process using response surface methodology
Autorzy:
Rutto, Hilary
Seidigeng, Tumisang
Malise, Lucky
Powiązania:
https://bibliotekanauki.pl/articles/204781.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
waste tire pyrolysis char
chemical activation
central composite design
CCD
adsorption capacity
numerical optimization
Opis:
Tires play an important role in the automobile industry. However, their disposal when worn out has adverse effects on the environment. The main aim of this study was to prepare activated carbon from waste tire pyrolysis char by impregnating KOH onto pyrolytic char. Adsorption studies on lead onto chemically activated carbon were carried out using response surface methodology. The effect of process parameters such as temperature (°C), adsorbent dosage (g/100 ml), pH, contact time (minutes) and initial lead concentration (mg/l) on the adsorption capacity were investigated. It was found out that the adsorption capacity increased with an increase in adsorbent dosage, contact time, pH, and decreased with an increase in lead concentration and temperature. Optimization of the process variables was done using a numerical optimization method. Fourier Transform Infrared Spectra (FTIR) analysis, X-ray Diffraction (XRD), Thermogravimetric analysis (TGA) and scanning electron microscope were used to characterize the pyrolytic carbon char before and after activation. The numerical optimization analysis results showed that the maximum adsorption capacity of 93.176 mg/g was obtained at adsorbent dosage of 0.97 g/100 ml, pH 7, contact time of 115.27 min, initial metal concentration of 100 mg/and temperature of 25°C. FTIR and TGA analysis showed the presence of oxygen containing functional groups on the surface of the activated carbon produced and that the weight loss during the activation step was negligible.
Źródło:
Archives of Environmental Protection; 2019, 45, 4; 92-103
2083-4772
2083-4810
Pojawia się w:
Archives of Environmental Protection
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Techno-Functional and Bioactive Properties and Chemical Composition of Guava, Mamey Sapote, and Passion Fruit Peels
Autorzy:
López-Martínez, Leticia X.
Villegas-Ochoa, Mónica A.
Domínguez-Avila, J. Abraham
Yahia, Elhadi M.
Gonzalez-Aguilar, Gustavo A.
Powiązania:
https://bibliotekanauki.pl/articles/24024619.pdf
Data publikacji:
2023-11-02
Wydawca:
Instytut Rozrodu Zwierząt i Badań Żywności Polskiej Akademii Nauk w Olsztynie
Tematy:
tropical fruits
phenolic profile
antioxidant potential
enzyme inhibition
glucose adsorption capacity
fat/oil binding capacity
sodium cholate binding capacity
Opis:
Due to their nutritional and sensorial characteristics, tropical fruits like guava, mamey sapote, and passion fruit are regularly incorporated into daily diets. Their by-products, especially peels, are approximately 10 to 35% of their weight and possess an important content of bioactive compounds, such as dietary fiber and phenolics. The nutritional, technological, physio-functional properties and phenolic compound compositions of guava, mamey sapote, and passion fruit peels were studied. Peels had promising techno- and physio-functional characteristics, good dietary fiber contents (45.18-61.42 g/100 g), and phenolic profiles with ferulic acid, gallic acid, p-coumaric, and catechin as the main compounds. Peel powders also showed excellent DPPH radical scavenging activity (125.3–252.4 µmol TE/100 g) and Trolox equivalent antioxidant capacity, TEAC (369.2–656.8 µmol TE/100 g). The α-amylase and lipase inhibitory activity varied from 28.15 to 51.4% and 30.89 to 57.15%, respectively. Higher values of α-glucosidase inhibition capacity were found, ranging from 51.64 to 70.32%. The chemical composition and properties reported in the present work suggest that peel powders of these guava, mamey sapote, and passion fruit could be used as constituents in different foods, such as bakery and meat goods, with beneficial health effects like control of hyperglycemia, improved intestinal function, and control of overweight; however, more studies are necessary for animal models and humans to confirm these bioactivities conclusively.
Źródło:
Polish Journal of Food and Nutrition Sciences; 2023, 73, 4; 311-321
1230-0322
2083-6007
Pojawia się w:
Polish Journal of Food and Nutrition Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Impact of ground adsorption capacity on the change in chemical composition of groundwater
Wpływ pojemności adsorpcyjnej gruntu na zmianę składu chemicznego wód podziemnych
Autorzy:
Aniszewski, Andrzej
Powiązania:
https://bibliotekanauki.pl/articles/204679.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
advection
dispersion
non-linear adsorption
adsorption capacity parameters
mass transport model
doradztwo
dyspersja
nieliniowa adsorpcja
parametry zdolności adsorpcyjnej
model transportu masowego
Opis:
Demonstrating the impact of time-dependent ground adsorption capacity on the change in chemical composition of groundwater is an important issue in understanding the groundwater mass transport process. Commonly used parameters characterizing ground adsorption capacity (Ra, ux* = ux/Ra, Δ C*max) were analyzed in this work to demonstrate time-varying values of this capacity for a chosen type of ground. Analysis of values of the selected parameters showed a gradual time decline in ground adsorption capacity as well as a gradual increase of groundwater contamination. This gradual increase in groundwater contamination over time is also important in practice. It implies the necessity to use more and more advanced (expensive) methods of water treatment in groundwater intakes.
Wykazanie wpływu zależnej od czasu pojemności adsorpcyjnej gruntu na zmianę składu chemicznego wód podziemnych jest ważnym zagadnieniem w zrozumieniu procesu transportu masy wód podziemnych. W niniejszej pracy przeanalizowano powszechnie stosowane parametry charakteryzujące pojemność adsorpcyjną gruntu (Ra, ux* = ux/Ra, Δ C*max ), aby wykazać zmienne w czasie wartości tej pojemności. Dokładna analiza wartości liczbowych wybranych parametrów wykazała spadkową w czasie tendencję pojemności adsorpcyjnej gruntu, a także stopniowy wzrost zanieczyszczenia wód gruntowych. Ten stopniowy w czasie wzrost zanieczyszczenia wód gruntowych jest również ważny w praktyce. Wiąże się bowiem z koniecznością stosowania coraz bardziej zaawansowanych (kosztownych) metod uzdatniania wód podziemnych pobieranych z ujęć.
Źródło:
Archives of Environmental Protection; 2020, 46, 2; 35-41
2083-4772
2083-4810
Pojawia się w:
Archives of Environmental Protection
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Sorpcja fosforu przez mursze i utwory torfowe w rejonie doliny Biebrzy
Phosphorus srption by moorsh and peat formations in the Biebrza valley
Autorzy:
Sapek, B.
Powiązania:
https://bibliotekanauki.pl/articles/339360.pdf
Data publikacji:
2011
Wydawca:
Instytut Technologiczno-Przyrodniczy
Tematy:
energia adsorpcji
fosfor
gleby torfowo-murszowe
izoterma adsorpcji Langmuira
pojemność adsorpcyjna
utwory organiczne
adsorption capacity
energy of adsorption
Langmuir adsorption isotherm
organic deposits
peat-muck soils
phosphorus
Opis:
Badano pojemność adsorpcyjną i energię adsorpcji murszów oraz utworów torfowych względem fosforu w profilu gleby torfowo-murszowej na tle właściwości fizykochemicznych gleb odwodnionego torfowiska niskiego w dolinie Biebrzy. Oceniono wpływ rodzaju utworu zalegającego w profilu gleby oraz jego właściwości sorpcyjne w aspekcie możliwości przenikania związków fosforu do wody gruntowej. Gleby tego obszaru cechują się budową warstwową, z czego wynika zmienność właściwości sorpcyjnych zalegających w nich utworów torfowych różnego pochodzenia i stopnia humifikacji (rozkładu - R) oraz przeobrażenia masy organicznej wierzchnich warstw murszu (stopnia zmurszenia - Z). Wykazano zależność obliczonych z równania izotermy adsorpcji Langmuira wartości maksymalnej adsorpcji fosforu (b) i energii adsorpcji (k) od rodzaju i stopnia humifikacji torfu zalegającego w profilu gleby oraz stopnia przeobrażenia masy murszu. Zależność ta nie zawsze jest prostą funkcją liniową. Mursze o podobnej do torfów maksymalnej pojemności sorpcyjnej wiążą fosfor z mniejszą siłą niż torfy. Jak można przypuszczać, skutkiem odmiennej pojemności sorpcyjnej i siły wiązania fosforu oraz zależności od wymienionych cech utworów będzie zróżnicowanie migracji jego związków nieorganicznych i organicznych w profilu gleby i przenikanie do wody gruntowej.
Adsorption capacity and adsorption energy of phosphorus in moorsh and peat deposits were investigated in the profile of peat-moorsh soil and compared with of physical and chemical properties of soils of drained lowland bog in the Biebrza valley. The effect of deposit situated in the soil profile and its sorption properties were estimated in view of a possibility of phosphorus permeation into groundwater. The soils of this area are characterised by laminar structure resulting in the instability of sorption properties of peat deposits of different origin, humification (decomposition - R) and transformation of the organic mass of surface moorsh layers (moorshing - Z). Maximum phosphorus adsorption (b) and adsorption energy (k), calculated from the Langmuir adsorption isotherm, were related to the degree of peat humification and to the transformation of moorsh mass. This relationship was not always linear. Muck formations with the maximum adsorption capacity comparable to peat bound phosphorus less intensively. As may be supposed, different sorption capacity and binding force of phosphorus will result in different migration of inorganic and organic P compounds to ground waters.
Źródło:
Woda-Środowisko-Obszary Wiejskie; 2011, 11, 3; 219-235
1642-8145
Pojawia się w:
Woda-Środowisko-Obszary Wiejskie
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption of Lead Ions from Aqueous Solutions onto Rice Husks, Continuous System
Autorzy:
Hawal, Laith Hamdan
Al-Sulttani, Ali Omran
Kariem, Nagam Obaid
Powiązania:
https://bibliotekanauki.pl/articles/2027895.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
adsorption
lead
rice husk
removal capacity
pH
Opis:
The continuous system of lead adsorption on rice husks was investigated in this paper. A fixed bed study was performed in many tests to investigate the influence of pH, the adsorbent height, the initial concentration of lead, the flow rate and processing time on the lead adsorption process. The results demonstrated that the lead removal capacity decreased when the pH value of the solution and the flow rate increased. The lead removal capacity increased due to the decreased initial concentration of lead. The results showed that the removal capacity increases along with the processing time and the adsorbent height in column. The largest removal was (81%) at pH of 4, the adsorbent height (50 cm), the initial concentration of lead (10 mg/l), the processing time (90 min.) and the flow rate (10 ml/min.). As a result, rice husks can be used to remove the lead instead of expensive commercial adsorbents, due to its availability, inexpensive and perfect adsorption property.
Źródło:
Journal of Ecological Engineering; 2021, 22, 10; 269-274
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adenine adsorption in different pH acetate buffer
Autorzy:
Gugała-Fekner, Dorota
Powiązania:
https://bibliotekanauki.pl/articles/2146951.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
adenine
adsorption
differential capacity
electroreduction
acetate buffer
Opis:
The research results facilitate the description of adenine adsorption on the mercury electrode with reference to the pH of the supporting electrolyte which was the acetate buffer with pH of 3, 4, 5 and 6. The thermodynamic analysis indicates that the curves of the differential capacity of the studied systems with adenine do not overlap with the curves for the supporting electrolyte – the acetate buffer. This indicates the occurrence of adsorption of the studied compound on the mercury electrode within the whole range of applied concentrations in the case of every tested pH value of the acetate buffer. Adsorption energy and interaction constants were determined using the Frumkin isotherm and the viral isotherm. It was demonstrated that a adenine molecule is adsorbed on the mercury electrode in a buffer with pH 4, 5 and 6 through the negative pole, whereas in a buffer with pH 3 through the positive pole. Physical adsorption was observed in the studied systems. This is indicated by the occurrence of a typical maximum on the curve of the relation the relative surface excess amounts and the potential of the electrode; crossed curves of the following relation surface charge of the electrode from its potential (surface charge of the electrode from its potential σ = f(E)) at one point and, thus, the possibility of determining electrical parameters characterizing maximum adsorption as well as the absence of linearity of the function free energy of adsorption as a function of electrode potential ∆G0 = f(E).
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 2; art. no. 144446
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ammonium Adsorption Onto a Contaminated Soil-Water Environment Amended with Organic Matter
Autorzy:
Al-Saedi, Rasha
Hammood, Zaman Ageel
Chyad, Tasnim Fahim
Powiązania:
https://bibliotekanauki.pl/articles/1839546.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
ammonium
adsorption
calcareous soil
compost
cation exchange capacity
Opis:
In this research, the ability of calcareous soil to absorb ammonium was investigated and the effect of compost amendment as a natural organic source on ammonium adsorption was also studied. The pH, dissolved ammonium concentrations, ammonium adsorption capacity, and cation exchangeable capacity for the soil samples were analyzed in relation to an untreated control and treatment with compost under ambient temperature and different initial ammonium concentrations (10, 20, 30, 40, 50, 70, and 100 mg/L). The amounts of ammonium adsorbed increased along with initial concentrations of dissolved ammonium for control and treatment with compost. The models evaluated in this study included the Langmuir and Freundlich isotherms. Ammonium adsorption was found to conform to the Freundlich equation isotherm more than that with Langmuir. The highest adsorption capacity was exhibited by 100 mg/L added initial ammonium concentration. Adding compost as a source of organic matter enhanced the adsorption capacity of calcareous soil with an increase in the adsorption of 36%, which indicated that the organic matter is a key limiting parameter in the mechanism of ammonium adsorption. Ammonium adsorption by calcareous soils is an important process in identifying the ammonium nitrogen route in soil-water systems.
Źródło:
Journal of Ecological Engineering; 2021, 22, 1; 188-194
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Magnitude of hydrocarbon sorption capacity of sandy soils analysis
Autorzy:
Fąfara, Z.
Powiązania:
https://bibliotekanauki.pl/articles/298961.pdf
Data publikacji:
2013
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
loose soils
hydrocarbon migration
adsorption of hydrocarbons
sorption capacity of soil
Opis:
This paper summarizes the author's previous studies on the sorption of hydrocarbons in sandy soils. Completed several independent series of measurements for various models of soil. There were used unleaded petrol and diesel fuel as petroleum products. A large amount of collected information allows you to draw some interesting conclusions, which may be the basis for generalizations. The detected regularity can afford to develop a several models that can be successfully used to describe the intensity of hydrocarbon sorption processes in soils. These processes have a significant impact on the hydrocarbon migration in the soil by reducing the pollution zone and extending the time of migration. Inaccurate description of the magnitude sorption capacity will lead to large differences between the actual scenario of hydrocarbon migration in soil and its numerical simulation.
Źródło:
AGH Drilling, Oil, Gas; 2013, 30, 1; 65-75
2299-4157
2300-7052
Pojawia się w:
AGH Drilling, Oil, Gas
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 20

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